CN102281724B - Method for machining double-sided windowed plug hole - Google Patents

Method for machining double-sided windowed plug hole Download PDF

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Publication number
CN102281724B
CN102281724B CN 201110248035 CN201110248035A CN102281724B CN 102281724 B CN102281724 B CN 102281724B CN 201110248035 CN201110248035 CN 201110248035 CN 201110248035 A CN201110248035 A CN 201110248035A CN 102281724 B CN102281724 B CN 102281724B
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China
Prior art keywords
hole
welding resistance
egative film
printing ink
face
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Expired - Fee Related
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CN 201110248035
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Chinese (zh)
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CN102281724A (en
Inventor
左青松
王连山
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GCI Science and Technology Co Ltd
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GCI Science and Technology Co Ltd
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Priority to CN 201110248035 priority Critical patent/CN102281724B/en
Publication of CN102281724A publication Critical patent/CN102281724A/en
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Publication of CN102281724B publication Critical patent/CN102281724B/en
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Abstract

The invention discloses a method for machining a double-sided windowed plug hole. The method comprises the following steps of: when solder mask ink is printed on a component side (CS) of a printed circuit board (PCB) substrate, plugging the solder mask ink in a hole by a plugging and printing combined manner, wherein the plugged depth of the hole is smaller than the depth of the hole; covering the CS with a CS solder mask film, covering a solder side (SS) with an exposure hole film and exposing the CS and the SS, wherein a shading sheet is arranged at position, corresponding to the hole, on the CS solder mask film, and a light penetration point is arranged at the position, corresponding to the hole, on the exposure hole film; printing the solder mask ink on the SS and pre-drying the SS for solder mask; after the SS solder mask film is covered on the SS, exposing the SS, wherein a shading sheet is arranged at position, corresponding to the hole, on the SS solder mask film; and performing developing and solder mask on the PCB substrate, and drying. The embodiment of the invention can solve the problems of penetration of the white light from the hole, oil spilling in developing process and oil spilling after drying.

Description

The processing method of double-sided windowed plug hole
Technical field
The present invention relates to printed circuit board (PCB) (PCB) manufacturing process technology field, relate in particular to a kind of processing method of double-sided windowed plug hole.
Background technology
When making printed circuit board (PCB), in order to reach the purpose that stops welding stream tin, often be designed with onboard consent; And consider for heat radiation, usually be designed with copper face, thereby form double-sided windowed plug hole.
At present, the method of making double-sided windowed plug hole is as follows: hole on the PCB substrate, after filling with welding resistance printing ink in the hole and forming consent, aim at respectively the position of consent on the component side of substrate and solder side, add the diaphanous spot less than consent aperture, the part welding resistance in consent is exposed, solidify, through follow-up development, the welding resistance printing ink in the hole is developed a part, thereby forms double-sided windowed plug hole.
There is following shortcoming in existing double-sided windowed plug hole processing method: because the diaphanous spot that adds is less than consent aperture, in the hole, some welding resistance is unexposed, and through developing, in the hole, welding resistance is rushed out, and forms the development oil spilling.And after follow-up welding resistance in the baking process, in the hole, residual development liquid medicine and welding resistance solvent due to expanded by heating, can eject the welding resistance in the hole baking oil spilling after forming; And when pcb board is thinner, in development, the problem of the saturating white light of consent appears easily afterwards.
Summary of the invention
The embodiment of the present invention proposes a kind of processing method of double-sided windowed plug hole, can solve the problem of the saturating white light of consent, development oil spilling and rear baking oil spilling.
The processing method of the double-sided windowed plug hole that the embodiment of the present invention provides comprises:
S1, provide a PCB substrate, this substrate is provided with the hole for the treatment of consent; Component side and the solder side of substrate run through in described hole;
The mode of S2, the company's of employing plug band seal in seal welding resistance printing ink, is filled in welding resistance printing ink toward the top end opening in hole on component side, and preliminary drying component side welding resistance; Described welding resistance printing ink enter hole depth less than the degree of depth in hole;
S3, be covered with CS face welding resistance egative film at component side, be covered with at solder side the hole egative film that exposes to the sun, component side and solder side are exposed; On described CS face welding resistance egative film, the position in corresponding aperture has anti-dazzling screen, and on the described hole egative film that exposes to the sun, the position in corresponding aperture has diaphanous spot; Anti-dazzling screen on described CS face welding resistance egative film is circular anti-dazzling screen, and its diameter is greater than the aperture of consent; Diaphanous spot on the described hole egative film that exposes to the sun is circular diaphanous spot, and its diameter is greater than the aperture of consent;
S4, on solder side seal welding resistance printing ink, and preliminary drying solder side welding resistance;
S5, after solder side is covered with SS face welding resistance egative film, solder side is exposed; On described SS face welding resistance egative film, the position in corresponding aperture has anti-dazzling screen; Anti-dazzling screen on described SS face welding resistance egative film is circular anti-dazzling screen, and its diameter is greater than the aperture of consent;
S6, develop and welding resistance after baking process, stay welding resistance in described hole; Described welding resistance is solidificated in the middle part in described hole, is close to hole wall.
Wherein, described welding resistance printing ink is added with diluent.
In a preferred implementation, the squeegee pressure that connects plug band seal in described step S2 is 6Kg, and print speed printing speed is 6m/s.
The degree of depth in described hole is H; In described step S2, the hole depth that enters of described welding resistance printing ink is x; Wherein, 0.3H≤x≤0.7H.
The processing method of the double-sided windowed plug hole that the embodiment of the present invention provides, the mode that adopt to connect plug band seal is filled in welding resistance printing ink toward an end opening in hole, this welding resistance printing ink enter hole depth less than the degree of depth in hole; Add diaphanous spot at the other end opening in hole, the welding resistance printing ink of the phototropic face in the hole is exposed, solidify; Through follow-up development, only stay the welding resistance that a circle solidifies in the hole, thereby form double-sided windowed plug hole.The embodiment of the present invention the oil spilling problem can not occur when developing, and because a circle welding resistance that stays in the development metapore is close to hole wall, the phenomenon of the saturating white light of consent can not occur; In addition, because the welding resistance printing ink that stays in the hole is less, the also oil spilling problem with regard to not occurring drying by the fire after welding resistance, thus can shorten the drying-plate time of drying by the fire after welding resistance.
Description of drawings
Fig. 1 is the schematic flow sheet of an embodiment of the processing method of double-sided windowed plug hole provided by the invention;
Fig. 2 is the schematic diagram of step 1 of the processing method of double-sided windowed plug hole provided by the invention;
Fig. 3 is the schematic diagram of step 2 of the processing method of double-sided windowed plug hole provided by the invention;
Fig. 4 is the schematic diagram of step 4 of the processing method of double-sided windowed plug hole provided by the invention;
Fig. 5 is the schematic diagram of step 5 of the processing method of double-sided windowed plug hole provided by the invention;
Fig. 6 is the schematic diagram of step 7 of the processing method of double-sided windowed plug hole provided by the invention;
Fig. 7 is the schematic diagram of step 8 of the processing method of double-sided windowed plug hole provided by the invention.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is only the present invention's part embodiment, rather than whole embodiment.Based on the embodiment in the present invention, those of ordinary skills belong to the scope of protection of the invention not making the every other embodiment that obtains under the creative work prerequisite.
Referring to Fig. 1, be the schematic flow sheet of an embodiment of the processing method of double-sided windowed plug hole provided by the invention, the method comprises the following steps:
S1, provide a PCB substrate, this substrate is provided with the hole for the treatment of consent; Component side (being called for short the CS face) and the solder side (being called for short the SS face) of substrate run through in described hole;
The mode of S2, the company's of employing plug band seal in seal welding resistance printing ink, is filled in welding resistance printing ink toward the top end opening in hole on component side, and preliminary drying component side welding resistance; Described welding resistance printing ink enter hole depth less than the degree of depth in hole;
S3, be covered with CS face welding resistance egative film at component side, be covered with at solder side the hole egative film that exposes to the sun, component side and solder side are exposed; On described CS face welding resistance egative film, the position in corresponding aperture has anti-dazzling screen, and on the described hole egative film that exposes to the sun, the position in corresponding aperture has diaphanous spot;
S4, on solder side seal welding resistance printing ink, and preliminary drying solder side welding resistance;
S5, after solder side is covered with SS face welding resistance egative film, solder side is exposed; On described SS face welding resistance egative film, the position in corresponding aperture has anti-dazzling screen;
S6, develop and welding resistance after baking process.
Wherein, described welding resistance printing ink is added with diluent.Diluent is a kind of for dilution welding resistance printing ink, reduces the organic solvent of its viscosity.Different welding resistance printing ink is because its formula components, content are different, and its viscosity also is not quite similar, and the dilution dosage of required interpolation is also different, and for example: sun PSR-2000 KX700G printing ink, the addition of its diluent is in the 40ml/Kg left and right.
In preferred an enforcement, the squeegee pressure that connects plug band seal in step S2 is 6Kg, and print speed printing speed is 6m/s.The degree of depth of supposing hole on substrate is H, and the hole depth that enters of welding resistance printing ink is x in step S2, has: 0.3H≤x≤0.7H.
And the anti-dazzling screen on CS face welding resistance egative film is circular anti-dazzling screen, and its diameter is greater than the aperture of consent; The diaphanous spot that exposes to the sun on the egative film of hole is circular diaphanous spot, and its diameter is greater than the aperture of consent; Anti-dazzling screen on SS face welding resistance egative film is circular anti-dazzling screen, and its diameter is greater than the aperture of consent.
Need to prove, when specifically implementing, can also the company of employing the mode of plug band seal, fill in the welding resistance printing ink of desired depth in from an end of solder side toward the hole; Then add diaphanous spot in when exposure, then from an end of component side, the welding resistance of the phototropic face in the hole is exposed.
Below in conjunction with Fig. 2~Fig. 7, the processing method of double-sided windowed plug hole provided by the invention is described in detail.
Step 1: nog plate
After charging, the PCB substrate is carried out nog plate process, substrate is cut into suitable size.
As shown in Figure 2, the end face of substrate 1 is component side 10, and the bottom surface is solder side 20.Wherein, component side 10 is provided with CS upper thread road, establishes SS upper thread road on solder side 20, and the inside of substrate 1 is provided with internal layer circuit 2.
Substrate 1 is provided with the hole 3 for the treatment of consent, and component side 10 and solder side 20 are run through in hole 3.
Step 2: seal CS face welding resistance
The mode of the company's of employing plug band seal in seal welding resistance printing ink, is filled in welding resistance printing ink toward the top end opening in hole 3 on component side 10.
As shown in Figure 3, CS face welding resistance 11 is imprinted on component side 10, and the hole depth x that enters of welding resistance printing ink is 1/2 of hole depth H, and namely welding resistance printing ink is full of the space of hole 3 the first half, and the space non-filler of hole 3 the latter halfs.
The present embodiment adopts the mode of adding diluent, and dilution welding resistance printing ink makes its reduced viscosity.During the plug band India side formula seal CS of the company of employing face welding resistance, (for example, making squeegee pressure is 6Kg by controlling printing parameter, making print speed printing speed is 6m/s), make welding resistance printing ink hand-hole, the surface tension that has due to welding resistance printing ink itself again simultaneously can not make again welding resistance printing ink flow to the SS face along hole wall.
The present embodiment only with x=H/2 as preferred embodiment describing, when specifically implementing, x can also get the numerical value such as H/3,2H/3,2H/5,3H/5,4H/5.
Step 3: preliminary drying CS face welding resistance
Welding resistance to the CS face is toasted processing.
Step 4 a: contraposition, exposure
As shown in Figure 4, be covered with CS face welding resistance egative film 12 on component side 10, be covered with at solder side 20 the hole egative film 22 that exposes to the sun, then component side and solder side are exposed.
Wherein, on CS face welding resistance egative film 12, the position in corresponding aperture has circular anti-dazzling screen, and the diameter of this anti-dazzling screen is greater than the consent diameter.Be that a-quadrant shown in Figure 4 is shaded effect, the welding resistance at CS face mouth place is not exposed, and in follow-up developing process, this part welding resistance can be shown.
Exposing to the sun, the position in corresponding aperture has circular diaphanous spot on hole egative film 22, and the diameter of this diaphanous spot is greater than the consent diameter.Be that B shown in Figure 4 zone is diaphanous spot, during exposure, ultraviolet light shine inside inlet hole by diaphanous spot, and the part welding resistance of the phototropic face in the hole is exposed.The welding resistance that is C shown in Figure 4 zone is exposed, and solidifies, and in follow-up developing process, can not be developed.
Optionally, according to the needs of client's practical application, can also on CS face welding resistance egative film 12, diaphanous spot be set, thereby stay the welding resistance point on the CS of pcb board face.For example, as shown in Figure 4, be provided with diaphanous spot 101 and diaphanous spot 102 on CS face welding resistance egative film 12, the welding resistance on this diaphanous spot can stay after development.
Step 5: seal SS face welding resistance
Seal welding resistance printing ink on solder side 20, as shown in Figure 5, SS face welding resistance 21 overlays on component side 10.
Step 6: preliminary drying CS face, SS face welding resistance
Welding resistance to CS face, SS face is toasted processing.
Step 7: secondary contraposition, exposure
As shown in Figure 6, be covered with SS face welding resistance egative film 23 at solder side 20, then solder side exposes.
Wherein, on SS face welding resistance egative film 23, the position in corresponding aperture has circular anti-dazzling screen, and the diameter of this anti-dazzling screen is greater than the consent diameter.Be that D shown in Figure 6 zone is shaded effect, the welding resistance at SS face mouth place is not exposed, and in follow-up developing process, this part welding resistance can be shown.
Optionally, according to the needs of client's practical application, can also on SS face welding resistance egative film 23, diaphanous spot be set, thereby stay the welding resistance point on the SS of pcb board face.For example, as shown in Figure 6, be provided with diaphanous spot 201 and diaphanous spot 202 on SS face welding resistance egative film 23, the welding resistance on this diaphanous spot can stay after development.
Owing to component side being exposed in step 4, so this step 7 is only exposed to solder side.
Step 8: develop
As shown in Figure 7, after carrying out development treatment, only stay the welding resistance 113 that is cured when exposing to the sun the hole in step 4 in the hole.Welding resistance 113 is solidificated in the middle part in hole, is close to hole wall, therefore the phenomenon of the saturating white light of consent can not occur; And, because the welding resistance printing ink that stays in the hole is less, the oil spilling problem can be do not occurred in the baking process after follow-up welding resistance yet, thereby the drying-plate time of drying by the fire after welding resistance can be shortened.
In addition, as shown in Figure 7, corresponding to diaphanous spot 101 and the diaphanous spot 102 of Fig. 4, component side stays welding resistance 111 and welding resistance 112 after developing.Corresponding to diaphanous spot 201 and the diaphanous spot 202 of Fig. 6, solder side stays welding resistance 211 and welding resistance 212 after developing.
Step 9: dry by the fire after welding resistance
Pcb board is carried out after baking is processed after welding resistance, and the double-sided windowed plug hole work flow is completed in discharging.
The processing method of the double-sided windowed plug hole that the embodiment of the present invention provides, the mode that adopt to connect plug band seal is filled in welding resistance printing ink toward an end opening in hole, this welding resistance printing ink enter hole depth less than the degree of depth in hole; Add diaphanous spot at the other end opening in hole, the welding resistance printing ink of the phototropic face in the hole is exposed, solidify; Through follow-up development, only stay the welding resistance that a circle solidifies in the hole, thereby form double-sided windowed plug hole.The embodiment of the present invention the oil spilling problem can not occur when developing, and because a circle welding resistance that stays in the development metapore is close to hole wall, the phenomenon of the saturating white light of consent can not occur; In addition, because the welding resistance printing ink that stays in the hole is less, the also oil spilling problem with regard to not occurring drying by the fire after welding resistance, thus can shorten the drying-plate time of drying by the fire after welding resistance.
The above is the preferred embodiment of the present invention; should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention; can also make some improvements and modifications, these improvements and modifications also are considered as protection scope of the present invention.

Claims (3)

1. the processing method of a double-sided windowed plug hole, is characterized in that, comprising:
S1, provide a PCB substrate, this substrate is provided with the hole for the treatment of consent; Component side and the solder side of substrate run through in described hole;
The mode of S2, the company's of employing plug band seal in seal welding resistance printing ink, is filled in welding resistance printing ink toward the top end opening in hole on component side, and preliminary drying component side welding resistance; Described welding resistance printing ink enter hole depth less than the degree of depth in hole; The degree of depth in described hole is H; The hole depth that enters of described welding resistance printing ink is x; 0.3H≤x≤0.7H;
S3, be covered with CS face welding resistance egative film at component side, be covered with at solder side the hole egative film that exposes to the sun, component side and solder side are exposed; On described CS face welding resistance egative film, the position in corresponding aperture has anti-dazzling screen, and on the described hole egative film that exposes to the sun, the position in corresponding aperture has diaphanous spot; Anti-dazzling screen on described CS face welding resistance egative film is circular anti-dazzling screen, and its diameter is greater than the aperture of consent; Diaphanous spot on the described hole egative film that exposes to the sun is circular diaphanous spot, and its diameter is greater than the aperture of consent;
S4, on solder side seal welding resistance printing ink, and preliminary drying solder side welding resistance;
S5, after solder side is covered with SS face welding resistance egative film, solder side is exposed; On described SS face welding resistance egative film, the position in corresponding aperture has anti-dazzling screen; Anti-dazzling screen on described SS face welding resistance egative film is circular anti-dazzling screen, and its diameter is greater than the aperture of consent;
S6, develop and welding resistance after baking process, stay welding resistance in described hole; Described welding resistance is solidificated in the middle part in described hole, is close to hole wall.
2. the processing method of double-sided windowed plug hole as claimed in claim 1, is characterized in that, described welding resistance printing ink is added with diluent.
3. the processing method of double-sided windowed plug hole as claimed in claim 2, is characterized in that, in described step S2, the squeegee pressure that connects plug band seal is 6Kg, and print speed printing speed is 6m/s.
CN 201110248035 2011-08-26 2011-08-26 Method for machining double-sided windowed plug hole Expired - Fee Related CN102281724B (en)

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Family Cites Families (4)

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