CN102276305B - Biological organic fertilizer special for pollution-free medlar and preparation method thereof - Google Patents

Biological organic fertilizer special for pollution-free medlar and preparation method thereof Download PDF

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CN102276305B
CN102276305B CN2011102008409A CN201110200840A CN102276305B CN 102276305 B CN102276305 B CN 102276305B CN 2011102008409 A CN2011102008409 A CN 2011102008409A CN 201110200840 A CN201110200840 A CN 201110200840A CN 102276305 B CN102276305 B CN 102276305B
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fat
dregs
parts
organic fertilizer
oil dregs
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CN102276305A (en
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姜兴民
李涛
张�诚
孙应胜
李大刚
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SHANDONG GUANGDA FERTILIZER TECHNOLOGY Co Ltd
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SHANDONG GUANGDA FERTILIZER TECHNOLOGY Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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Abstract

The invention relates to a biological organic fertilizer special for pollution-free medlar and a preparation method thereof. The biological organic fertilizer comprises the following raw materials in parts by mass: 20-30 parts of pepper seed oil slag, 15-25 parts of soya-bean oil slag, 5-20 parts of xylitol slag, 25-35 parts of peanut straw, 5-15 parts of decomposed coal and 1-3 parts of microorganism bactericide. The biological organic fertilizer is prepared by using a batch-feeding fermentation and ageing method. The fertilizing applying method is as follows: 5-8 fertilizer applying pits are dug on the circumference which is 15-25 centimeters far away from a tree trunk before the medlar sprouts in spring, and the biological organic fertilizer is mixed with soil and then the mixture is applied to the pits; and earthing and watering are carried out. According to the invention, the biological organic fertilizer special for the medlar has high nutrition content, and the supply of the nutrition meets a medlar absorption law, thus the quality of the medlar can be improved by using the biological organic fertilizer.

Description

A kind of biological organic fertilizer special for pollution-free medlar and preparation method thereof
Technical field
The present invention relates to a kind of biological organic fertilizer, particularly a kind of bio-organic fertilizer for the production of nuisanceless matrimony vine special use and preparation method thereof belongs to the organic fertilizer production technical field.
Background technology
Matrimony vine occupies very consequence as famous and precious traditional Chinese medicine material at tcm field.At present, the tame matrimony vine area of China is nearly 100,000 hectares.Along with the improvement of scientific-technical progress and cultivation technique, China's matrimony vine production development is just with annual 11% speed fast development.
In the medlar cultivation management, the rational application of fertilizer is the important measures that improve output, improve quality.In recent years, in order to devote exclusive attention to output, blindness is applied fertilizer, excessive fertilization is serious.Although yield level improves constantly, quality is unstable, has affected stabilizing and increasing of economic benefit, to especially serious strike of the outlet of matrimony vine.Although standardized cultivation technology, technique for preparing dry and deep process technology are widelyd popularize in some place, but still be difficult to reach export requirement and international standard.No doubt the unreasonable use of agricultural chemicals is the factor that affects the matrimony vine quality, but fertilizer particularly fertilizer to contain hazardous substance also be one of reason that affects the matrimony vine quality.
At present, China's organic fertilizer production raw material is complicated, of a great variety, there is various problems in this to the matrimony vine fine quality production: at first, contain harmful ingredients in some fertilizer, as containing excessive heavy metal take sewage work's biochemical sludge, domestic waste as the fertilizer of main material production, the fertilizer take animal excrement as main material production contains some harmful fodder additives.Secondly, nutrient content is not suitable with matrimony vine high yield, high-quality needs, and the one, nutrient content is low, and the 2nd, proportioning is unreasonable between the nutrient.Moreover, because the degree difference of becoming thoroughly decomposed may cause matrimony vine growth nutrient deficiency in early stage or later stage to take off fertilizer, affect output.
The fertilizer practice that CN1962566A (CN200610149036.1) discloses four kinds of matrimony vine composite fertilizer specials and four kinds of liquid fertilizers and matched with it.Take urea, double superhosphate, vitriolate of tartar as raw material, provide four kinds of N, P, K proportioning diverse concentrated type matrimony vine composite fertilizer special and fertilizer practices thereof of using in the different steps of matrimony vine growth fertility; Use this invention, it is large that the individuality of matrimony vine becomes, and soluble solid, total reducing sugar, protein, amino acid, lycium barbarum polysaccharide content all rise to some extent.This fertilizer belongs to mineral manure.At present, application of organic fertilizers is comparatively general in matrimony vine produces, and particularly for the production of organic matrimony vine product, fertilizer special for organic is indispensable fertilizer variety especially.Have no at present relevant report.
Summary of the invention
For the deficiencies in the prior art, the invention provides nuisanceless production bio-organic fertilizer special of a kind of matrimony vine and preparation method thereof.The application method of this fertilizer also is provided.
Summary of the invention
The present invention is according to Features of Nutrient Absorption in the matrimony vine year breeding cycle, utilize the characteristics of different organism and contained various nutrients thereof to carry out reasonable disposition, and the fermentation maturity method by fed batch, make the fertilizer of inventing substantially meet matrimony vine absorption requirement aspect nutrient proportioning and the period nutrient supply two, nutrient content is high, can effectively increase yield of medlar, improve Lycium barbarum. L Quality, and can reach the standard of producing organic matrimony vine product.
Detailed Description Of The Invention
A kind of biological organic fertilizer special for pollution-free medlar, raw materials quality part is as follows:
20~30 parts of the Fructus Zanthoxyli oil dregs of fat,
15~25 parts of the soya-bean oil dregs of fat,
5~20 parts of Klinit dregs,
25~35 parts of peanut stalks,
5~15 parts of weathered coals,
1~3 part of microbiobacterial agent EM composite fungus agent;
Adopt the fermentation maturity method of fed batch to make: first with peanut stalk, the Fructus Zanthoxyli oil dregs of fat 1/3rd, the soya-bean oil dregs of fat 1/3rd, Klinit dregs 1/2nd with microbiobacterial agent EM composite fungus agent, mixed-stacking fermentation 7-11 days, add again the Fructus Zanthoxyli oil dregs of fat 1/3rd, 1/3rd and Klinit dregs of the soya-bean oil dregs of fat 1/2nd, mixed-stacking fermentation 6-9 days, add at last weathered coal, the Fructus Zanthoxyli oil dregs of fat 1/3rd and the soya-bean oil dregs of fat 1/3rd, mixed-stacking fermentation 5-7 days.
The described Fructus Zanthoxyli oil dregs of fat are Semen Pericarpium Zanthoxyli to be carried out squeeze and filter go out remaining residue behind the grease; The described soya-bean oil dregs of fat are soybean to be carried out the squeeze and filter grease go out rear remaining residue.
The waste residue that described Klinit dregs produces in take corn cob as raw material production wood sugar process; Moisture content≤45wt%, organic content 60-65wt%.
Described weathered coal is that to stand for a long time the comprehensive actions such as atmosphere, sunlight, sleet, underground water and mineral substance erosion be the product of weathering to brown coal, bituminous coal and the hard coal of earth's surface or shallow-layer, the nutritive element that contains abundant humic acids and various crop needs, granularity≤80 mesh sieves, the commercially available prod.
Described microbial fermentation microbial inoculum is EM composite fungus agent (EM is the abbreviation of EffectiveMicroorganesms), and it is that 5 sections 10 such as photosynthetic bacteria group, yeast flora, lactobacillus, actinomycete group, mycorhiza flora are belonged to 80 multiple-microorganisms compound a kind of typing microbial inoculum of cultivating in same state.Be brown translucent liquid, the pH value is between 3.5~4.5.Market is on sale.
Described peanut stalk is crushed to length below 1 centimetre.
According to the present invention, preferred technical scheme is as follows:
A kind of biological organic fertilizer special for pollution-free medlar, raw materials quality part is as follows:
24~26 parts of the Fructus Zanthoxyli oil dregs of fat,
16~18 parts of the soya-bean oil dregs of fat,
8.5~9.5 parts of Klinit dregs,
33~35 parts of peanut stalks,
12~14 parts of weathered coals,
1.5~2.5 parts of microbiobacterial agent EM composite fungus agents.
The preparation method of biological organic fertilizer special for pollution-free medlar of the present invention, step is as follows:
(1) by proportioning get pulverizing the peanut stalk whole, the Fructus Zanthoxyli oil dregs of fat 1/3rd, the soya-bean oil dregs of fat 1/3rd, Klinit dregs 1/2nd, microbiobacterial agent EM composite fungus agent, mix; The moisture of adjusting compound is 60~65wt%, timing when temperature rises to 50 ℃, heap fermentation 4~6 days; Timing when turning, temperature rise to 50 ℃ again, heap fermentation 3~5 days.
(2) get the Fructus Zanthoxyli oil dregs of fat 1/3rd, the soya-bean oil dregs of fat 1/3rd, 1/2nd the adding in the mixture that above-mentioned steps (1) fermented of Klinit dregs, adjustment moisture is 60~65wt%, timing when temperature rises to 50 ℃, heap fermentation 3~4 days; Timing when turning, temperature rise to 50 ℃ again, heap fermentation 3~5 days.
(3) with the Fructus Zanthoxyli oil dregs of fat and the soya-bean oil dregs of fat of residual content, add in the mixture that step (2) fermented with weathered coal, the moisture of adjusting compound is 60~65wt%, material temperature clocks when rising to 50 ℃, continues heap fermentation 5~7 days.
(4) step (3) gained fermentation material is dried or dry to moisture content less than 20wt%, get powdery product; Perhaps,
The gained fermentation material by the prior art granulation, is got granular product.
The nitrogen of biological organic fertilizer special for pollution-free medlar of the present invention, phosphorus, three kinds of nutrient total amounts of potassium reach 5%~8%.
The application of biological organic fertilizer special for pollution-free medlar of the present invention, fertilizing method be, digs 5~8 fertilising holes from 15~25 centimetres of circumferential lines of trunk before matrimony vine rudiment in spring, cheats dark 25~35 centimetres, with this fertilizer with apply in the hole after the soil of 2~4 times of weights mixes.Earthing, water.Other management is carried out according to a conventional method.400~600 kilograms of every mu of consumptions of this fertilizer.Applied once no longer imposes.
Excellent results of the present invention is as follows:
1. nutrient content is high, increases yield of medlar
According to China's standard, nitrogen, phosphorus, three kinds of nutrient total amounts of potassium are qualified organic commercial fertilizer more than or equal to 4% in the fertilizer, and therefore, the nitrogen of China's fertilizer, phosphorus, three kinds of nutrient total amounts of potassium scope are between 4%~6% at present.The present invention selects much higher kind of raw material of nutrient content to carry out composite becoming thoroughly decomposed, the fertilizer nitrogen of producing, phosphorus, three kinds of nutrient total amounts of potassium reach 5%~8%, obviously improved the nutrient content of fertilizer, be conducive to improve yield of medlar, particularly for the production of the organic matrimony vine that can not use chemical fertilizer, it increases output, and the effect of increasing economic efficiency is more obvious.
2. nutrient reasonable ratio
Biological organic fertilizer special for pollution-free medlar of the present invention be according in the matrimony vine year breeding cycle to demand and the various organic nutrient content of nutrient, selected different organic raw material cooperates fermentation to form, the nutrient reasonable ratio is with strong points.
3. nutrient supply meets the matrimony vine absorption
In the organic fertilizer production, organic fermentation maturity has two basic purposes, and the one, kill harmful organism, the 2nd, the macromolecular substance that contains the nutrients such as nitrogen, phosphorus in the organism is decomposed, discharge the small molecules form that crop can absorb.The time span of digest process is determining the degree of decomposition of organic molecule.Simultaneously, can continue after fertilizer is manured into soil to decompose, progressively discharge nutrient.Biological organic fertilizer special for pollution-free medlar of the present invention according in the matrimony vine year breeding cycle to the demand of nutrient, employing is carried out the fed batch mode to the fertilizer raw material, make in the finished product nutrient-lapsed time substantially meet matrimony vine and absorb requirement, avoid certain one-phase to produce and take off fertile phenomenon.
4. the fertilizer cleaning is pollution-free
The raw material of biological organic fertilizer special for pollution-free medlar of the present invention is all selected free of contamination organism, meets the nuisanceless production requirement of matrimony vine.Fertilizer of the present invention is particularly suitable for the production of organic matrimony vine.
Embodiment
The present invention will be further described below in conjunction with embodiment, but be not limited to this.Raw material consumption umber among the embodiment is mass parts, and all per-cents are mass percent.
The Fructus Zanthoxyli oil dregs of fat, Shandong Province's Laiwu City Yuntai Shan Mountain vegetable oil mill; The soya-bean oil dregs of fat are that Shandong wide life limited-liability company produces; Xylose residue, the waste residue that Shandong Longli Biology Science and Technology Co., Ltd produces in take corn cob as raw material production wood sugar process, moisture content is 40wt% approximately, organic content 60-65wt%; Weathered coal, granularity 60-80 order, Wuhai of Inner Mongolia covers commerce and trade company limited of Tang and sells; The microbial fermentation microbial inoculum is the EM composite fungus agent, and Jiangxi Tianyi Biologic Technology Development Co., Ltd. produces.
Embodiment 1: a kind of biological organic fertilizer special for pollution-free medlar, and raw material is composed as follows:
Fructus Zanthoxyli oil dregs of fat 25kg,
Soya-bean oil dregs of fat 17kg,
Klinit dregs 9kg,
Peanut stalk 34kg,
Weathered coal 13kg,
Microbiobacterial agent EM composite fungus agent 2kg.
The preparation method:
At first the peanut stalk is crushed to length below 1 centimetre.Get by prescription the peanut stalk whole, the Fructus Zanthoxyli oil dregs of fat 1/3rd, the soya-bean oil dregs of fat 1/3rd, Klinit dregs 1/2nd, microbiobacterial agent EM composite fungus agent is whole, mix.The moisture of adjusting compound is 60wt%, timing when temperature rises to 50 ℃, heap fermentation 4 days; Turning, temperature begin to clock when again rising to 50 ℃ heap fermentation 5 days.Get again the Fructus Zanthoxyli oil dregs of fat 1/3rd, the soya-bean oil dregs of fat 1/3rd, 1/2nd the adding in the mixture of above-mentioned fermentation of Klinit dregs, adjustment moisture is 60wt%, temperature begin to clock when rising to 50 ℃ heap fermentation 3 days, heap fermentation 5 days clocks when turning, temperature rise to 50 ℃ again.At last the remaining Fructus Zanthoxyli oil dregs of fat and the soya-bean oil dregs of fat are added in the gained fermenting mixture material with the whole of weathered coal, material temperature clocks when rising to 50 ℃, continues fermentation 5 days.The gained fermentation material is dried to moisture content 20wt%, get powdery product.
Embodiment 2: a kind of biological organic fertilizer special for pollution-free medlar, and feed composition is as follows:
Fructus Zanthoxyli oil dregs of fat 20kg,
Soya-bean oil dregs of fat 22kg,
Klinit dregs 13kg,
Peanut stalk 29kg,
Weathered coal 14.5kg,
Microbiobacterial agent 1.5kg.
The preparation method is with embodiment 1.
Embodiment 3: a kind of biological organic fertilizer special for pollution-free medlar, and feed composition is as follows:
Fructus Zanthoxyli oil dregs of fat 30kg,
Soya-bean oil dregs of fat 15kg,
Klinit dregs 18kg,
Peanut stalk 26kg,
Weathered coal 10kg,
Microbiobacterial agent 1kg.
The preparation method:
By prescription get pulverize the peanut stalk of length below 1 centimetre all, the Fructus Zanthoxyli oil dregs of fat 1/3rd, the soya-bean oil dregs of fat 1/3rd, Klinit dregs 1/2nd, microbiobacterial agent EM composite fungus agent is whole, mix.The moisture of adjusting compound is 65wt%, timing when temperature rises to 50 ℃, heap fermentation 6 days.Heap fermentation 3 days clocks when turning, temperature rise to 50 ℃ again.Get again the Fructus Zanthoxyli oil dregs of fat 1/3rd, the soya-bean oil dregs of fat 1/3rd, 1/2nd the adding in the mixture of above-mentioned fermentation of Klinit dregs, adjustment moisture is 65wt%, timing when temperature rises to 50 ℃, heap fermentation 3 days.When rising to 50 ℃ again, turning, temperature clock heap fermentation 3 days.At last the remaining Fructus Zanthoxyli oil dregs of fat and the soya-bean oil dregs of fat are added with weathered coal, material temperature clocks when rising to 50 ℃, continues fermentation 7 days.Get fermentation material.The gained fermentation material by the prior art granulation, is got granular product.
Embodiment 4: a kind of biological organic fertilizer special for pollution-free medlar, and feed composition is as follows:
Fructus Zanthoxyli oil dregs of fat 27kg,
Soya-bean oil dregs of fat 18kg,
Klinit dregs 15kg,
Peanut stalk 31kg,
Weathered coal 8kg,
Microbiobacterial agent 1kg.
The preparation method is with embodiment 3.
Comparative Examples: common fertilizer, Shandong Guangda Fertilizer Technology Co., Ltd. produces, organic content 38.6%, nitrogen, phosphorus, potassium total nutrient 4.72%.Be mass percent.
The effect of above embodiment 1~4 and Comparative Examples is as follows:
Test site: Xinjiang autonomous region Wusu City, Ningxia autonomous region Zhongning County.
Test period: year September in April, 2010 to 2010.
For examination matrimony vine kind: two places are No. 1, peaceful Qi all.
Embodiment 1-4 is identical with the Comparative Examples fertilizer amount, 500 kilograms every mu.Fertilizing method, embodiment 1-4 fertilizer and Comparative Examples fertilizer all are to dig 6 fertilising holes from 20 centimetres of left and right sides circumferential lines of trunk before matrimony vine rudiment in spring, dark approximately 30 centimetres of hole, with fertilizer with apply in the hole after about 3 times soil mixes.Earthing, water.Other management is carried out according to a conventional method.Effect sees Table 1.
Table 1. is compared the application effect of embodiment 1-4 with Comparative Examples
Figure BDA0000076630850000051

Claims (6)

1. biological organic fertilizer special for pollution-free medlar is characterized in that raw materials quality part is as follows:
20~30 parts of the Fructus Zanthoxyli oil dregs of fat,
15~25 parts of the soya-bean oil dregs of fat,
5~20 parts of Klinit dregs,
25~35 parts of peanut stalks,
5~15 parts of weathered coals,
1~3 part of microbiobacterial agent EM composite fungus agent;
Adopt the fermentation maturity method of fed batch to make: first with peanut stalk, the Fructus Zanthoxyli oil dregs of fat 1/3rd, the soya-bean oil dregs of fat 1/3rd, Klinit dregs 1/2nd with microbiobacterial agent EM composite fungus agent, mixed-stacking fermentation 7-11 days, add again the Fructus Zanthoxyli oil dregs of fat 1/3rd, 1/3rd and Klinit dregs of the soya-bean oil dregs of fat 1/2nd, mixed-stacking fermentation 6-9 days, add at last weathered coal, the Fructus Zanthoxyli oil dregs of fat 1/3rd and the soya-bean oil dregs of fat 1/3rd, mixed-stacking fermentation 5-7 days.
2. biological organic fertilizer special for pollution-free medlar as claimed in claim 1 is characterized in that raw materials quality part is as follows:
24~26 parts of the Fructus Zanthoxyli oil dregs of fat,
16~18 parts of the soya-bean oil dregs of fat,
8.5~9.5 parts of Klinit dregs,
33~35 parts of peanut stalks,
12~14 parts of weathered coals,
1.5~2.5 parts of microbiobacterial agent EM composite fungus agents.
3. biological organic fertilizer special for pollution-free medlar as claimed in claim 1 or 2 is characterized in that the described Fructus Zanthoxyli oil dregs of fat are Semen Pericarpium Zanthoxyli to be carried out squeeze and filter go out remaining residue behind the grease; The described soya-bean oil dregs of fat are soybean to be carried out the squeeze and filter grease go out rear remaining residue; The waste residue that described Klinit dregs produces in take corn cob as raw material production wood sugar process, moisture content≤45wt%, organic content 60-65wt%.
4. the preparation method of each described biological organic fertilizer special for pollution-free medlar of claim 1-3, step is as follows:
(1) by proportioning get pulverizing the peanut stalk whole, the Fructus Zanthoxyli oil dregs of fat 1/3rd, the soya-bean oil dregs of fat 1/3rd, Klinit dregs 1/2nd, microbiobacterial agent EM composite fungus agent, mix; The moisture of adjusting compound is 60 ~ 65wt%, timing when temperature rises to 50 ℃, heap fermentation 4 ~ 6 days; Timing when turning, temperature rise to 50 ℃ again, heap fermentation 3 ~ 5 days;
(2) get the Fructus Zanthoxyli oil dregs of fat 1/3rd, the soya-bean oil dregs of fat 1/3rd, 1/2nd the adding in the mixture that above-mentioned steps (1) fermented of Klinit dregs, adjustment moisture is 60 ~ 65wt%, timing when temperature rises to 50 ℃, heap fermentation 3 ~ 4 days; Timing when turning, temperature rise to 50 ℃ again, heap fermentation 3 ~ 5 days;
(3) with the Fructus Zanthoxyli oil dregs of fat and the soya-bean oil dregs of fat of residual content, add in the mixture that step (2) fermented with weathered coal, the moisture of adjusting compound is 60 ~ 65wt%, material temperature clocks when rising to 50 ℃, continues fermentation 5 ~ 7 days;
(4) step (3) gained fermentation material is dried or dry to moisture content less than 20wt%, get powdery product; Perhaps,
The gained fermentation material by the prior art granulation, is got granular product.
5. the application of each described biological organic fertilizer special for pollution-free medlar of claim 1-3, it is characterized in that fertilizing method is, before matrimony vine rudiment in spring, dig 5~8 fertilising holes from 15~25 centimetres of circumferential lines of trunk, cheat dark 25~35 centimetres, with this fertilizer with apply in the hole after the soil of 2~4 times of weights mixes; Earthing, water.
6. the application of biological organic fertilizer special for pollution-free medlar as claimed in claim 5 is characterized in that 400~600 kilograms of every mu of consumptions of this fertilizer.
CN2011102008409A 2011-07-18 2011-07-18 Biological organic fertilizer special for pollution-free medlar and preparation method thereof Expired - Fee Related CN102276305B (en)

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Cited By (1)

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CN106518453A (en) * 2016-12-04 2017-03-22 钦州市星火计划办公室 Water-soluble fertilizer for flowering of orchids and preparation method of fertilizer

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CN103265354B (en) * 2013-04-24 2015-03-04 陆玉 Bio-organic fertilizer prepared from modeling clay slag as main material and preparation method thereof
CN104447007B (en) * 2014-12-06 2017-11-21 北京航天恒丰科技股份有限公司 A kind of bioorganic compound fertilizer and its production and use
CN106588319A (en) * 2016-12-04 2017-04-26 钦州市星火计划办公室 Special-purpose fertilizer used for wolfberry and preparation method thereof
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CN1785921A (en) * 2004-12-06 2006-06-14 邵建华 Production of organic fertilizer by drying and dewatering colloid industrial waste slag
CN101503315A (en) * 2009-03-18 2009-08-12 华富腐植酸集团有限公司天水银宝化工厂 Humic acid biological organic composite bacterial manure and production process
CN101734959A (en) * 2009-12-18 2010-06-16 山东光大肥业科技有限公司 Special organic fertilizer for solanaceous fruit organic vegetables and preparing method thereof

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Publication number Priority date Publication date Assignee Title
CN1088563A (en) * 1992-12-25 1994-06-29 郭城 The production method of efficient biological organic complex fertilizer
CN1785921A (en) * 2004-12-06 2006-06-14 邵建华 Production of organic fertilizer by drying and dewatering colloid industrial waste slag
CN101503315A (en) * 2009-03-18 2009-08-12 华富腐植酸集团有限公司天水银宝化工厂 Humic acid biological organic composite bacterial manure and production process
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106518453A (en) * 2016-12-04 2017-03-22 钦州市星火计划办公室 Water-soluble fertilizer for flowering of orchids and preparation method of fertilizer

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