CN102276038A - 聚合硫酸铁-羧甲基马铃薯淀粉复合絮凝剂及其制备和应用 - Google Patents
聚合硫酸铁-羧甲基马铃薯淀粉复合絮凝剂及其制备和应用 Download PDFInfo
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- CN102276038A CN102276038A CN2011101562572A CN201110156257A CN102276038A CN 102276038 A CN102276038 A CN 102276038A CN 2011101562572 A CN2011101562572 A CN 2011101562572A CN 201110156257 A CN201110156257 A CN 201110156257A CN 102276038 A CN102276038 A CN 102276038A
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- Prior art keywords
- potato starch
- ferric sulfate
- carboxymethyl potato
- bodied ferric
- flocculation agent
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920001592 potato starch Polymers 0.000 title claims abstract description 72
- 239000002131 composite material Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 238000005189 flocculation Methods 0.000 claims abstract description 56
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims abstract description 44
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims abstract description 40
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims abstract description 40
- 238000004065 wastewater treatment Methods 0.000 claims abstract description 8
- 230000016615 flocculation Effects 0.000 claims description 53
- 239000003795 chemical substances by application Substances 0.000 claims description 50
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 229920002472 Starch Polymers 0.000 claims description 13
- 239000008107 starch Substances 0.000 claims description 13
- 235000019698 starch Nutrition 0.000 claims description 13
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000011790 ferrous sulphate Substances 0.000 claims description 7
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 7
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 7
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 7
- 206010013786 Dry skin Diseases 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 claims description 6
- 239000012153 distilled water Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 241000370738 Chlorion Species 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 230000001476 alcoholic effect Effects 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 238000006386 neutralization reaction Methods 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- -1 1-carboxymethyl Chemical group 0.000 claims 1
- 239000002351 wastewater Substances 0.000 abstract description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 abstract description 4
- 230000005591 charge neutralization Effects 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 238000010408 sweeping Methods 0.000 abstract 1
- 229920000592 inorganic polymer Polymers 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000008394 flocculating agent Substances 0.000 description 3
- 229920000620 organic polymer Polymers 0.000 description 3
- 229920005613 synthetic organic polymer Polymers 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 208000024827 Alzheimer disease Diseases 0.000 description 1
- 206010003591 Ataxia Diseases 0.000 description 1
- 206010039966 Senile dementia Diseases 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 159000000013 aluminium salts Chemical class 0.000 description 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 231100000567 intoxicating Toxicity 0.000 description 1
- 230000002673 intoxicating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000001537 neural effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Abstract
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CN 201110156257 CN102276038B (zh) | 2011-06-09 | 2011-06-09 | 聚合硫酸铁-羧甲基马铃薯淀粉复合絮凝剂及其制备和应用 |
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CN 201110156257 CN102276038B (zh) | 2011-06-09 | 2011-06-09 | 聚合硫酸铁-羧甲基马铃薯淀粉复合絮凝剂及其制备和应用 |
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CN102276038A true CN102276038A (zh) | 2011-12-14 |
CN102276038B CN102276038B (zh) | 2013-05-29 |
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CN 201110156257 Expired - Fee Related CN102276038B (zh) | 2011-06-09 | 2011-06-09 | 聚合硫酸铁-羧甲基马铃薯淀粉复合絮凝剂及其制备和应用 |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103030201A (zh) * | 2013-01-15 | 2013-04-10 | 玉林师范学院 | 复合絮凝剂及其制备方法 |
CN104355383A (zh) * | 2014-11-25 | 2015-02-18 | 天津水运工程勘察设计院 | 用于处理港口含油废水的复合絮凝剂溶液及其制备方法 |
CN105776354A (zh) * | 2014-12-22 | 2016-07-20 | 祐鼎(福建)光电材料有限公司 | 聚合硫酸铁的制备方法 |
CN108863590A (zh) * | 2018-08-17 | 2018-11-23 | 佛山市森昂生物科技有限公司 | 一种利用废水制备复合肥的方法 |
CN109354145A (zh) * | 2018-11-23 | 2019-02-19 | 昆明理工大学 | 一种用硅藻土制备有机废水改性絮凝剂的方法 |
CN111573800A (zh) * | 2020-04-30 | 2020-08-25 | 广西夏阳环保科技有限公司 | 一种天然复合聚合硫酸铁水处理药剂及其制备方法 |
CN112694136A (zh) * | 2021-02-07 | 2021-04-23 | 杭州金丰环保科技有限公司 | 一种聚合硫酸铁的合成方法及聚合硫酸铁 |
CN113233646A (zh) * | 2021-05-17 | 2021-08-10 | 紫金铜业有限公司 | 一种高浓度含砷污酸的处理工艺 |
Citations (10)
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JPH11128955A (ja) * | 1997-10-31 | 1999-05-18 | Ebara Corp | 水の凝集処理方法 |
JP2001219005A (ja) * | 2000-02-09 | 2001-08-14 | Ebara Corp | 凝集剤及び水処理における凝集処理方法 |
CN1323752A (zh) * | 2000-05-11 | 2001-11-28 | 大连理工大学 | 一种高分子水处理药剂与磁场共用使用的水处理方法 |
CN1490256A (zh) * | 2003-08-27 | 2004-04-21 | 中国科学院沈阳应用生态研究所 | 一种经济型无机-有机复合絮凝剂 |
CN1524801A (zh) * | 2003-09-15 | 2004-09-01 | 武汉理工大学 | 一种水处理净化工艺中的混凝方法 |
JP2007061718A (ja) * | 2005-08-30 | 2007-03-15 | Ku System:Kk | 複合凝集剤 |
CN101531413A (zh) * | 2008-03-16 | 2009-09-16 | 吴全环 | 新型环保复合絮凝剂组成及混凝方法 |
CN101723503A (zh) * | 2009-12-16 | 2010-06-09 | 暨南大学 | 一种有机无机复合高效脱色絮凝剂及其制备方法与应用 |
CN102060363A (zh) * | 2010-12-31 | 2011-05-18 | 中国矿业大学 | 一种煤层气采出水的混凝处理方法 |
CN102060362A (zh) * | 2010-10-28 | 2011-05-18 | 广东工业大学 | 一种淀粉基复合絮凝剂的制备方法及其应用 |
-
2011
- 2011-06-09 CN CN 201110156257 patent/CN102276038B/zh not_active Expired - Fee Related
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11128955A (ja) * | 1997-10-31 | 1999-05-18 | Ebara Corp | 水の凝集処理方法 |
JP2001219005A (ja) * | 2000-02-09 | 2001-08-14 | Ebara Corp | 凝集剤及び水処理における凝集処理方法 |
CN1323752A (zh) * | 2000-05-11 | 2001-11-28 | 大连理工大学 | 一种高分子水处理药剂与磁场共用使用的水处理方法 |
CN1490256A (zh) * | 2003-08-27 | 2004-04-21 | 中国科学院沈阳应用生态研究所 | 一种经济型无机-有机复合絮凝剂 |
CN1524801A (zh) * | 2003-09-15 | 2004-09-01 | 武汉理工大学 | 一种水处理净化工艺中的混凝方法 |
JP2007061718A (ja) * | 2005-08-30 | 2007-03-15 | Ku System:Kk | 複合凝集剤 |
CN101531413A (zh) * | 2008-03-16 | 2009-09-16 | 吴全环 | 新型环保复合絮凝剂组成及混凝方法 |
CN101723503A (zh) * | 2009-12-16 | 2010-06-09 | 暨南大学 | 一种有机无机复合高效脱色絮凝剂及其制备方法与应用 |
CN102060362A (zh) * | 2010-10-28 | 2011-05-18 | 广东工业大学 | 一种淀粉基复合絮凝剂的制备方法及其应用 |
CN102060363A (zh) * | 2010-12-31 | 2011-05-18 | 中国矿业大学 | 一种煤层气采出水的混凝处理方法 |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103030201A (zh) * | 2013-01-15 | 2013-04-10 | 玉林师范学院 | 复合絮凝剂及其制备方法 |
CN103030201B (zh) * | 2013-01-15 | 2014-08-06 | 玉林师范学院 | 复合絮凝剂及其制备方法 |
CN104355383A (zh) * | 2014-11-25 | 2015-02-18 | 天津水运工程勘察设计院 | 用于处理港口含油废水的复合絮凝剂溶液及其制备方法 |
CN104355383B (zh) * | 2014-11-25 | 2016-06-22 | 天津水运工程勘察设计院 | 用于处理港口含油废水的复合絮凝剂溶液及其制备方法 |
CN105776354A (zh) * | 2014-12-22 | 2016-07-20 | 祐鼎(福建)光电材料有限公司 | 聚合硫酸铁的制备方法 |
CN108863590A (zh) * | 2018-08-17 | 2018-11-23 | 佛山市森昂生物科技有限公司 | 一种利用废水制备复合肥的方法 |
CN109354145A (zh) * | 2018-11-23 | 2019-02-19 | 昆明理工大学 | 一种用硅藻土制备有机废水改性絮凝剂的方法 |
CN111573800A (zh) * | 2020-04-30 | 2020-08-25 | 广西夏阳环保科技有限公司 | 一种天然复合聚合硫酸铁水处理药剂及其制备方法 |
CN112694136A (zh) * | 2021-02-07 | 2021-04-23 | 杭州金丰环保科技有限公司 | 一种聚合硫酸铁的合成方法及聚合硫酸铁 |
CN113233646A (zh) * | 2021-05-17 | 2021-08-10 | 紫金铜业有限公司 | 一种高浓度含砷污酸的处理工艺 |
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CN102276038B (zh) | 2013-05-29 |
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