CN102245552A - 从甘油制备丙烯醛的方法 - Google Patents

从甘油制备丙烯醛的方法 Download PDF

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Publication number
CN102245552A
CN102245552A CN2009801498045A CN200980149804A CN102245552A CN 102245552 A CN102245552 A CN 102245552A CN 2009801498045 A CN2009801498045 A CN 2009801498045A CN 200980149804 A CN200980149804 A CN 200980149804A CN 102245552 A CN102245552 A CN 102245552A
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CN
China
Prior art keywords
glycerol
catalyst
zirconium
acrolein
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2009801498045A
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English (en)
Chinese (zh)
Inventor
维吉妮·贝利埃尔-巴卡
斯特凡·洛里当
让-马克·米莱
帕斯卡兰·洛里奥尔-加尔贝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique
Adisseo France SAS
Original Assignee
Centre National de la Recherche Scientifique
Adisseo France SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique, Adisseo France SAS filed Critical Centre National de la Recherche Scientifique
Priority to CN201610190995.1A priority Critical patent/CN105837420B/zh
Publication of CN102245552A publication Critical patent/CN102245552A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/18—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C07C45/66—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups by dehydration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2009801498045A 2008-12-16 2009-12-16 从甘油制备丙烯醛的方法 Pending CN102245552A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610190995.1A CN105837420B (zh) 2008-12-16 2009-12-16 从甘油制备丙烯醛的方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0858624A FR2939791B1 (fr) 2008-12-16 2008-12-16 Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
FR08/58624 2008-12-16
PCT/FR2009/052577 WO2010076510A2 (fr) 2008-12-16 2009-12-16 Procede de preparation d'acroleine a partir de glycerol ou de glycerine

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201610190995.1A Division CN105837420B (zh) 2008-12-16 2009-12-16 从甘油制备丙烯醛的方法

Publications (1)

Publication Number Publication Date
CN102245552A true CN102245552A (zh) 2011-11-16

Family

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Family Applications (2)

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CN2009801498045A Pending CN102245552A (zh) 2008-12-16 2009-12-16 从甘油制备丙烯醛的方法
CN201610190995.1A Expired - Fee Related CN105837420B (zh) 2008-12-16 2009-12-16 从甘油制备丙烯醛的方法

Family Applications After (1)

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Country Status (10)

Country Link
US (2) US20110288323A1 (enExample)
EP (1) EP2365954B1 (enExample)
JP (1) JP6116799B2 (enExample)
KR (1) KR101778103B1 (enExample)
CN (2) CN102245552A (enExample)
ES (1) ES2709479T3 (enExample)
FR (1) FR2939791B1 (enExample)
RU (1) RU2531277C2 (enExample)
SG (1) SG171721A1 (enExample)
WO (1) WO2010076510A2 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104892382A (zh) * 2015-05-28 2015-09-09 珠海凯美科技有限公司 甘油液相氧化制备丙烯醛的方法
CN104918908A (zh) * 2012-10-30 2015-09-16 安迪苏法国联合股份有限公司 从甘油制备丙烯醛的方法
CN105164089B (zh) * 2013-02-04 2018-04-27 安迪苏法国联合股份有限公司 通过催化转化至少一种醇来制备烯烃的方法

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2939791B1 (fr) 2008-12-16 2011-01-14 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
FR2961507B1 (fr) * 2010-06-17 2016-03-04 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine
FR2966456B1 (fr) * 2010-10-26 2013-03-15 Adisseo France Sas Procede d'obtention d'acroleine par deshydratation catalytique de glycerol ou de glycerine
KR101616528B1 (ko) 2013-07-16 2016-04-28 주식회사 엘지화학 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법
US9796648B2 (en) 2014-05-02 2017-10-24 University Of Tennessee Research Foundation Glycerol dehydration methods and products thereof
KR102052708B1 (ko) * 2015-12-22 2019-12-09 주식회사 엘지화학 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법
KR102044428B1 (ko) * 2015-12-23 2019-12-02 주식회사 엘지화학 글리세린으로부터 아크릴산의 제조방법
KR102210508B1 (ko) * 2015-12-23 2021-02-01 주식회사 엘지화학 글리세린 탈수 반응용 촉매의 제조 방법 및 아크롤레인의 제조 방법
CN109305899B (zh) * 2017-07-28 2021-09-03 中国石油化工股份有限公司 甘油脱水生产丙烯醛的方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU52208A1 (ru) * 1936-04-22 1936-11-30 Ю.Н. Вольнов Способ получени акролеина из глицерина
US4524077A (en) * 1983-11-14 1985-06-18 Monsanto Company Liquid 2-hydroxy-4-methylthiobutyric acid and process for the preparation thereof
DE102005003990A1 (de) * 2005-01-28 2006-08-03 Degussa Ag Herstellung von 3-(Alkylthio)propanal
FR2882053B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
FR2882052B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acroleine
FR2884818B1 (fr) * 2005-04-25 2007-07-13 Arkema Sa Procede de preparation d'acide acrylique a partir de glycerol
WO2007058221A1 (ja) * 2005-11-15 2007-05-24 Nippon Shokubai Co., Ltd. 多価アルコールの脱水方法
JP4041512B2 (ja) 2006-03-30 2008-01-30 株式会社日本触媒 グリセリン脱水用触媒、グリセリン脱水用触媒の製造方法、アクロレインの製造方法、およびアクロレイン誘導体の製造方法
WO2007132926A1 (en) 2006-05-12 2007-11-22 Nippon Shokubai Co., Ltd. Production method of acrolein
TW200811086A (en) 2006-07-11 2008-03-01 Adisseo Ireland Ltd Process for preparing 2-hydroxy-4-(methylthio)butyronitrile and methionine
FR2907445B1 (fr) 2006-10-20 2010-09-03 Rhodia Recherches & Tech Composition a acidite elevee a base d'oxyde de zirconium, d'oxyde de titane et d'oxyde de tungstene,procede de preparation et utilisation dans le traitement des gaz d'echappement
FR2907444B1 (fr) 2006-10-20 2008-12-19 Rhodia Recherches & Tech Composition a acidite elevee a base d'oxydes de zirconium,de silicium et d'au moins un autre element choisi parmi le titane,l'aluminium,le tungstene,le molybdene,le cerium,le fer et le manganese
WO2008066079A1 (en) * 2006-12-01 2008-06-05 Nippon Shokubai Co., Ltd. Method for producing acrylic acid
DE102007004351A1 (de) 2007-01-29 2008-07-31 Evonik Degussa Gmbh Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin
DE102007004350A1 (de) * 2007-01-29 2008-07-31 Evonik Degussa Gmbh Verfahren zur Regenerierung eines Katalysators
JP2008266165A (ja) 2007-04-17 2008-11-06 Nippon Shokubai Co Ltd アクロレインの製造方法
FR2920767B1 (fr) 2007-09-06 2009-12-18 Arkema France Procede de vaporisation reactive de glycerol
WO2009136537A1 (ja) 2008-04-16 2009-11-12 日本化薬株式会社 グリセリンの脱水反応によるアクロレイン及びアクリル酸の製造用触媒と、その製造方法
WO2009127889A1 (en) 2008-04-16 2009-10-22 Arkema France Process for manufacturing acrolein from glycerol
FR2938535B1 (fr) 2008-11-20 2012-08-17 Arkema France Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres renouvelables
FR2939791B1 (fr) 2008-12-16 2011-01-14 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
FR2954312B1 (fr) 2009-12-21 2012-02-10 Adisseo France Sas Procede de preparation d'acroleine par deshydratation catalytique de glycerol ou glycerine
FR2961507B1 (fr) 2010-06-17 2016-03-04 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104918908A (zh) * 2012-10-30 2015-09-16 安迪苏法国联合股份有限公司 从甘油制备丙烯醛的方法
CN105164089B (zh) * 2013-02-04 2018-04-27 安迪苏法国联合股份有限公司 通过催化转化至少一种醇来制备烯烃的方法
CN104892382A (zh) * 2015-05-28 2015-09-09 珠海凯美科技有限公司 甘油液相氧化制备丙烯醛的方法

Also Published As

Publication number Publication date
WO2010076510A2 (fr) 2010-07-08
WO2010076510A3 (fr) 2010-10-14
US20140171676A1 (en) 2014-06-19
ES2709479T3 (es) 2019-04-16
RU2011123484A (ru) 2013-01-27
RU2531277C2 (ru) 2014-10-20
FR2939791B1 (fr) 2011-01-14
EP2365954A2 (fr) 2011-09-21
US20110288323A1 (en) 2011-11-24
US9447009B2 (en) 2016-09-20
KR20110094198A (ko) 2011-08-22
CN105837420A (zh) 2016-08-10
FR2939791A1 (fr) 2010-06-18
KR101778103B1 (ko) 2017-09-13
CN105837420B (zh) 2019-09-13
JP6116799B2 (ja) 2017-04-19
EP2365954B1 (fr) 2018-11-07
JP2012512236A (ja) 2012-05-31
SG171721A1 (en) 2011-07-28

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Application publication date: 20111116