CN102230278B - Concentrated fabric softener and preparation method thereof - Google Patents
Concentrated fabric softener and preparation method thereof Download PDFInfo
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- CN102230278B CN102230278B CN 201110150530 CN201110150530A CN102230278B CN 102230278 B CN102230278 B CN 102230278B CN 201110150530 CN201110150530 CN 201110150530 CN 201110150530 A CN201110150530 A CN 201110150530A CN 102230278 B CN102230278 B CN 102230278B
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- 239000002979 fabric softener Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 37
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 20
- 239000003094 microcapsule Substances 0.000 claims abstract description 20
- 238000003756 stirring Methods 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 8
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 8
- 239000003960 organic solvent Substances 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims abstract description 3
- 230000001105 regulatory effect Effects 0.000 claims abstract 2
- 229920001296 polysiloxane Polymers 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 14
- 239000000194 fatty acid Substances 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- 150000003863 ammonium salts Chemical class 0.000 claims description 12
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 7
- 235000019270 ammonium chloride Nutrition 0.000 claims description 7
- 239000001110 calcium chloride Substances 0.000 claims description 7
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 7
- 230000002087 whitening effect Effects 0.000 claims description 7
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 6
- 239000000989 food dye Substances 0.000 claims description 6
- 239000003643 water by type Substances 0.000 claims description 6
- 238000012856 packing Methods 0.000 claims description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000003205 fragrance Substances 0.000 abstract description 12
- 238000001914 filtration Methods 0.000 abstract description 5
- -1 diester quaternary ammonium salt Chemical class 0.000 abstract 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- 239000010703 silicon Substances 0.000 abstract 2
- 239000004599 antimicrobial Substances 0.000 abstract 1
- 238000005282 brightening Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 description 8
- PMPJQLCPEQFEJW-HPKCLRQXSA-L disodium;2-[(e)-2-[4-[4-[(e)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C\C1=CC=C(C=2C=CC(\C=C\C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-HPKCLRQXSA-L 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 5
- 241000282326 Felis catus Species 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000007865 diluting Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- WTFCBWXBJBYVOS-UHFFFAOYSA-L lithium;sodium;dichloride Chemical compound [Li+].[Na+].[Cl-].[Cl-] WTFCBWXBJBYVOS-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000001507 sample dispersion Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a concentrated fabric softener, containing the following components in parts by weight: 10-35 parts of diester quaternary ammonium salt, 0.1-1 part of viscosity breaking agent, 0.01-0.2 part of acidity regulator, 0.05-0.5 part of organic silicon defoaming agent and 62-90 parts of deionized water. The preparation method comprises the following steps of: 1) heating the deionized water to the temperature of 70-75 DEG C, adding the diester quaternary ammonium salt, and stirring until the diester quaternary ammonium salt is dissolved; 2) adding the viscosity breaking agent,and stirring; 3) cooling, adding the organic silicon defoaming agent, adding one or two of water soluble organic solvent and brightening agent, and stirring; 4) adding the acidity regulator, adding one or mixture of more than two of microcapsule essence, antiseptic agent and food colourant, and regulating the PH value to be 3-5; and 5) filtering with a filter screen in 200-300 meshes, and packaging. The product disclosed by the invention has the advantages that the concentrated fabric softener is high power concentrated, has long-acting fragrance and can be biodegradable compared with the traditional fabric softener.
Description
Technical field
The present invention relates to a kind of concentrated fabric softener and preparation method thereof.
Background technology
Growth in the living standard along with people, larger change is occuring in people's consumption idea, single clothes cleaning has not satisfied people and has consumed needs of life, and then the laundry care agent is just arisen at the historic moment, especially fabric softener has been come into huge numbers of families, winter-spring season, dry air, fabric softener just solves the puzzlement that static brings to people easily, and traditional fabric softener adopts distearyl dimethyl ammonium chloride (D1821), this raw material biological degradability is poor, is easily caused environmental pollution by sludge absorption in sewage disposal; Traditional fabric softener working substance content only has 3%～4%, and about 95% is water, brings unnecessary cost waste for like this transportation, packing, is unfavorable for saving energy and reduce the cost, water-saving and emission-reducing; The fragrance remaining time of traditional fabric softener on clothing only has 2～3 mostly.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides a kind of concentrated fabric softener, contain the composition of following parts by weight:
Biester quarternary ammoniumsalt 10-35 part,
Viscosity-depression agent 0.1-1 part,
Acidity regulator 0.01-0.2 part,
Silicone antifoam agent 0.05-0.5 part,
Deionized water 62-90 part.
Preferably, above-mentioned concentrated fabric softener also contains microcapsule essence 0.2-0.4 part.
Preferably, above-mentioned concentrated fabric softener also contains whitening agent 0.05-0.2 part.
Preferably, above-mentioned concentrated fabric softener also contains sanitas 0.05-0.1 part.
Preferably, above-mentioned concentrated fabric softener also contains 4～7 parts of water-miscible organic solvents.Above-mentioned water-miscible organic solvent is ethanol or Virahol.
Preferably, above-mentioned concentrated fabric softener also contains food dye.
Preferably, described Biester quarternary ammoniumsalt is bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyl, described viscosity-depression agent is one or more mixtures arbitrarily in calcium chloride, sodium-chlor, the lithium chloride, and described acidity regulator is one or more any mixture in citric acid, ammonium chloride, the acetic acid.
Preferably, above-mentioned concentrated fabric softener is grouped into by the one-tenth of following massfraction:
15 parts of Biester quarternary ammoniumsalts,
0.2 part of viscosity-depression agent,
0.01 part of acidity regulator,
0.3 part of microcapsule essence,
0.1 part of silicone antifoam agent,
0.05 part in whitening agent,
0.05 part of sanitas,
84.29 parts of deionized waters.
The present invention also provides the method for the above-mentioned concentrated fabric softener of preparation, and step is as follows:
1) remove ionized water, heat temperature raising 70-75 ℃, add Biester quarternary ammoniumsalt, be stirred to dissolving;
2) add viscosity-depression agent, stir, to reduced viscosity;
3) cooling when temperature is fallen 40～50 ℃, adds silicone antifoam agent, also adds in water-miscible organic solvent and the whitening agent one or both, stirs, and makes it dissolving;
4) add acidity regulator, also add one or more mixtures in microcapsule essence, sanitas and the food dye, the adjusting pH value is 3-5;
5) filter rear the packing with 200～300 mesh filter screens.
Fabric softener of the present invention adopts Biester quarternary ammoniumsalt, it is bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyl, since in its pair backbone with the ester group key, therefore this series products at biological degradability than the dialkyl quaternary ammonium salt superior performance, more friendly to environment, be cats product of new generation, have the advantages such as good flexibility, static inhibitor, outstanding biological degradability, corresponding compatibleness, dispersiveness rewetting; Product of the present invention adopts highly effective viscosity-reducing agent calcium chloride, sodium-chlor, lithium chloride, only needs just can make on a small quantity the concentrated 5-10 of product doubly, and raw material is easy to get, and cost is lower; Product utilization of the present invention is international state-of-the-art microcapsule essence technology at present, successfully breaks through the short problem of product fragrance remaining time, and microcapsules rupture in the motion slowly discharges fragrance, can reach more than 15 days in the fragrance remaining time on the clothing; Product of the present invention adopts silicone antifoam agent, when realizing the easy rinsing of product, auxiliary submissive effect is arranged.Therefore, the more traditional fabric softener of product of the present invention have that high power is concentrated, Longaacting fragrance-aretaining, biological degradation, advantages of environment protection.The present invention is a kind of novel concentrated fabric softener.
Embodiment
The invention will be further described below in conjunction with specific embodiment, can be implemented so that those skilled in the art can better understand the present invention also, but illustrated embodiment is not as a limitation of the invention.
Embodiment 1:
The concentrated fabric softener of the present embodiment, its component and mass fraction thereof are:
15 parts of bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyls,
0.2 part of lithium chloride,
0.01 part of citric acid,
0.3 part of microcapsule essence,
1,410 0.1 parts of silicone antifoam agents
0.05 part of fluorescent brightener CBS-X,
0.05 part of sanitas (KF88)
84.29 parts of deionized waters
Bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyl is the Biester quarternary ammoniumsalt cats product, and available from Boxing Huarun Grease Chemical Co., Ltd, silicone antifoam agent 1410 is available from Dow Corning Corporation, and microcapsule essence is available from the U.S. beneficial company of sweet smell.
The preparation method of above-mentioned concentrated fabric softener:
1. add first the deionized water that measures, then be heated to 70-75 ℃, add bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyl, stir and make its dissolving.
2. add lithium chloride, whitening agent CBS-X, continue to stir, system viscosity is reduced.
3. when treating that system temperature falls 40 ℃, add silicone antifoam agent 1410, microcapsule essence, sanitas (KF88), stir and make it dissolving.
4. adding citric acid, the regulation system pH value is 3-5.
5. pack after filtering with 300 mesh filter screens.
The physico-chemical property of the concentrated fabric softener of the present embodiment preparation: viscosity (25 ℃, mpas): 1500; PH value (25 ℃, 1% aqueous solution): 4.3; Solid content (%): 13.76.
The use of the concentrated fabric softener of the present embodiment preparation: the fabric softener that the present embodiment makes is got in an amount of adding clear water after diluting 5 times with water, and the clothing that cleans up was steeped into 1～5 minute, and taking-up is dried.
Submissive effect experiment: experimental procedure and the results are shown in Table 1.The submissive successful of the softener of the present embodiment is better than the commercially available prod as a result.
Fragrance remaining time: after measured, the sustainable lasting of the softener of the present embodiment 1 month, and commercially available prod lasting 2～3 only.
Embodiment 2.
A kind of concentrated fabric softener, its component and mass fraction thereof are:
30 parts of bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyls,
0.8 part in calcium chloride,
0.02 part of ammonium chloride,
0.4 part of microcapsule essence,
1,410 0.3 parts of silicone antifoam agents,
0.1 part of fluorescent brightener CBS-X,
0.1 part of sanitas (KF88),
5.5 parts of ethanol,
62.78 parts of deionized waters.
The preparation method of above-mentioned concentrated fabric softener:
1. add first the deionized water that measures, then be heated to 70-75 ℃, add bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyl, stir and make its dissolving.
2. add calcium chloride, ethanol, fluorescent brightener CBS-X, continue to stir, system viscosity is reduced.
3. when treating that system temperature falls 40 ℃, add silicone antifoam agent 1410, microcapsule essence, sanitas (KF88), stir and make it dissolving.
4. adding ammonium chloride, the regulation system pH value is 3-5.
5. pack after filtering with 300 mesh filter screens.
The physico-chemical property of the concentrated fabric softener of the present embodiment preparation: viscosity (25 ℃, mpas): 5500; PH value (25 ℃, 1% aqueous solution): 3.5; Solid content (%): 28.1.
The use of the concentrated fabric softener of the present embodiment preparation: the fabric softener that the present embodiment makes is got in an amount of adding clear water after diluting 10 times with water, and the clothing that cleans up was steeped into 1～5 minute, and taking-up is dried.
Submissive effect: experimental procedure and the results are shown in Table 1.The submissive successful of the softener of the present embodiment is better than the commercially available prod as a result.
Fragrance remaining time: after measured, sustainable lasting 1 wheat harvesting period of the softener of the present embodiment, and commercially available prod lasting 2～3 only.
Embodiment 3:
The concentrated fabric softener of the present embodiment, its component and mass fraction thereof are:
10 parts of bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyls,
0.1 part of lithium chloride,
0.05 part in sodium-chlor
0.1 part of acetic acid,
0.1 part of ammonium chloride,
0.1 part of microcapsule essence,
1,410 0.4 parts of silicone antifoam agents,
0.05 part of fluorescent brightener CBS-X,
0.05 part of sanitas (KF88),
4 parts of Virahols,
86.05 parts of deionized waters.
Bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyl is the Biester quarternary ammoniumsalt cats product, and available from Boxing Huarun Grease Chemical Co., Ltd, silicone antifoam agent 1410 is available from Dow Corning Corporation, and microcapsule essence is available from the U.S. beneficial company of sweet smell.
The preparation method of above-mentioned concentrated fabric softener:
1. add first the deionized water that measures, then be heated to 70-75 ℃, add bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyl, stir and make its dissolving.
2. add lithium chloride, sodium-chlor, fluorescent brightener CBS-X, continue to stir, system viscosity is reduced.
3. when treating that system temperature is down to 40 ℃, add silicone antifoam agent 1410, microcapsule essence, sanitas (KF88), stir and make it dissolving.
4. add acetic acid and ammonium chloride, the regulation system pH value is 3-5.
5. pack after filtering with 300 mesh filter screens.
The physico-chemical property of the concentrated fabric softener of the present embodiment preparation:
Viscosity (25 ℃, mpas): 700; PH value (25 ℃, 1% aqueous solution): 4.0; Solid content (%): 9.16.
The use of the concentrated fabric softener of the present embodiment preparation: the fabric softener that the present embodiment makes is got in an amount of adding clear water after diluting 3.3 times with water, and the clothing that cleans up was steeped into 1～5 minute, and taking-up is dried.
Submissive effect: experimental procedure and the results are shown in Table 1.The submissive successful of the softener of the present embodiment is better than the commercially available prod as a result.
Fragrance remaining time: after measured, the sustainable lasting of the softener of the present embodiment is more than 1 month, and commercially available prod lasting 2～3 days only.
Embodiment 4:
The concentrated fabric softener of the present embodiment, its component and mass fraction thereof are:
35 parts of bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyls,
0.7 part in calcium chloride,
0.3 part in sodium-chlor
Ammonium chloride 0.15
0.4 part of microcapsule essence,
1,410 0.4 parts of silicone antifoam agents,
0.1 part of fluorescent brightener CBS-X,
0.05 part of sanitas (KF88),
62.85 parts of deionized waters,
0.05 part of food dye.
Bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyl is the Biester quarternary ammoniumsalt cats product, and available from Boxing Huarun Grease Chemical Co., Ltd, silicone antifoam agent 1410 is available from Dow Corning Corporation, and microcapsule essence is available from the U.S. beneficial company of sweet smell.
The preparation method of above-mentioned concentrated fabric softener:
1. add first the deionized water that measures, then heat temperature raising 70-75 ℃, add bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyl, stir and make its dissolving.
2. add calcium chloride, sodium-chlor, fluorescent brightener CBS-X, continue to stir, system viscosity is reduced.
3. when treating that system temperature is down to 40 ℃, add silicone antifoam agent 1410, microcapsule essence, sanitas (KF88), food dye stirs and makes it dissolving.
4. adding citric acid, the regulation system pH value is 3-5.
5. pack after filtering with 300 mesh filter screens.
The physico-chemical property of the concentrated fabric softener of the present embodiment preparation:
Viscosity (25 ℃, mpas): 6500; PH value (25 ℃, 1% aqueous solution): 3.2; Solid content (%): 32.92.
The use of the concentrated fabric softener of the present embodiment preparation: the fabric softener that the present embodiment makes is got in an amount of adding clear water after diluting 11.6 times with water, and the clothing that cleans up was steeped into 1～5 minute, and taking-up is dried.
Submissive effect: experimental procedure and the results are shown in Table 1.The submissive successful of the softener of the present embodiment is better than the commercially available prod as a result.
Fragrance remaining time: after measured, the sustainable lasting of the softener of the present embodiment is more than 1 month, and commercially available prod lasting 2～3 days only.
Submissive effect experiment
1. material
20 * 20cm
2Some of identical towels, graduated scale, 2000mL beaker, 5000mL beaker.
2. experimental procedure
Towel is divided into some groups, and 10 every group, first group, second group, the 3rd group, the 4th group is used for respectively embodiment 1, the embodiment 2 of this product, the test of embodiment 3, embodiment 4, and other groups are used for commercially available softener product, and the difference label; Get respectively embodiment and commercially available softener product by the listed addition of table 1, add respectively the 2000g tap water, dispersed with stirring is even; Respectively embodiment sample dispersion liquid is injected No. 1, No. 2, No. 3, No. 4 beakers of 5000mL, commercially available softener product dispersion liquid injects other corresponding label beakers of 5000mL; Simultaneously with first group, second group ... other group towels immerse respectively No. 1, No. 2, No. 3 ... in the beaker of 5000mL, then complete wetting 5 minutes is taken out respectively nature and dried; With twice doubling of every towel, stack by original group, measure every group of height with graduated scale, record also compares its height, and highly large submissive effect is better.The results are shown in Table 1.
Table 1
The towel stack height that conclusion, the softener of the embodiment of the invention 1～4 preparation were processed is greater than commercially available softener, and the present invention is submissive respond well.
The above embodiment is the preferred embodiment that proves absolutely that the present invention lifts, and protection scope of the present invention is not limited to this.Being equal to that those skilled in the art do on basis of the present invention substitutes or conversion, all within protection scope of the present invention.Protection scope of the present invention is as the criterion with claims.
Claims (9)
1. a concentrated fabric softener is characterized in that, contains the composition of following parts by weight:
Biester quarternary ammoniumsalt 10-35 part,
Viscosity-depression agent 0.1-1 part,
Acidity regulator 0.01-0.2 part,
Silicone antifoam agent 0.05-0.5 part,
Deionized water 62-90 part;
Wherein, described Biester quarternary ammoniumsalt is bis-fatty acid ethoxycarbonyl hydroxyethyl methylsulfuric acid ammonium methyl, described viscosity-depression agent is one or more mixtures arbitrarily in calcium chloride, sodium-chlor, the lithium chloride, and described acidity regulator is one or more any mixture in citric acid, ammonium chloride, the acetic acid.
2. concentrated fabric softener according to claim 1 is characterized in that, also contains microcapsule essence 0.2-0.4 part.
3. concentrated fabric softener according to claim 1 is characterized in that, also contains whitening agent 0.05-0.2 part.
4. concentrated fabric softener according to claim 1 is characterized in that, also contains sanitas 0.05-0.1 part.
5. concentrated fabric softener according to claim 1 is characterized in that, also contains 4 ~ 7 parts of water-miscible organic solvents.
6. concentrated fabric softener according to claim 5 is characterized in that, described water-miscible organic solvent is ethanol or Virahol.
7. concentrated fabric softener according to claim 1 is characterized in that, also contains food dye.
8. concentrated fabric softener according to claim 1 is characterized in that, is grouped into by the one-tenth of following massfraction:
15 parts of Biester quarternary ammoniumsalts,
0.2 part of viscosity-depression agent,
0.01 part of acidity regulator,
0.3 part of microcapsule essence,
0.1 part of silicone antifoam agent,
0.05 part in whitening agent,
0.05 part of sanitas,
84.29 parts of deionized waters.
9. prepare the method for each described concentrated fabric softener of claim 1 ~ 7, it is characterized in that, step is as follows:
1) removes ionized water, be heated to 70-75 ℃, add Biester quarternary ammoniumsalt, be stirred to dissolving;
2) add viscosity-depression agent, stir, to reduced viscosity;
3) cooling when temperature is down to 40 ~ 50 ℃, adds silicone antifoam agent, also adds in water-miscible organic solvent and the whitening agent one or both, stirs, and makes it dissolving;
4) add acidity regulator, also add one or more mixtures in microcapsule essence, sanitas and the food dye, regulating the pH value is 3-5;
5) filter rear the packing with 200 ~ 300 mesh filter screens.
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| CN 201110150530 CN102230278B (en) | 2011-06-07 | 2011-06-07 | Concentrated fabric softener and preparation method thereof |
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| CN 201110150530 CN102230278B (en) | 2011-06-07 | 2011-06-07 | Concentrated fabric softener and preparation method thereof |
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| CN113249974A (en) * | 2021-06-16 | 2021-08-13 | 广东水卫仕生物科技有限公司 | Clothing fragrance-retaining effervescent tablet with softening effect and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1142847A (en) * | 1993-12-13 | 1997-02-12 | 普罗格特-甘布尔公司 | Viscosity stable concentrated liquid fabric softener compositions |
| CN1168689A (en) * | 1994-10-07 | 1997-12-24 | 普罗格特-甘布尔公司 | Fabric softening composition containing chlorine scavengers |
| CN1219955A (en) * | 1996-03-22 | 1999-06-16 | 普罗格特-甘布尔公司 | Concentrated fabric softening composition with good freeze/thaw recovery and highly unsaturated fabric softener compound therefor |
| CN101208417A (en) * | 2005-05-06 | 2008-06-25 | 高露洁-棕榄公司 | Fabric care composition comprising polymer encapsulated fabric or skin beneficiating ingredient |
| CN101581037A (en) * | 2009-06-09 | 2009-11-18 | 深圳市成为工贸有限公司 | Particles capable of softening clothes and preparation method thereof |
| CN101600785A (en) * | 2006-12-28 | 2009-12-09 | 花王公司 | Non-rinse fabric softener |
| CN101736580A (en) * | 2009-12-21 | 2010-06-16 | 北京绿泽宇和科技有限公司 | Fabric maintenance softener |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6620777B2 (en) * | 2001-06-27 | 2003-09-16 | Colgate-Palmolive Co. | Fabric care composition comprising fabric or skin beneficiating ingredient |
-
2011
- 2011-06-07 CN CN 201110150530 patent/CN102230278B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1142847A (en) * | 1993-12-13 | 1997-02-12 | 普罗格特-甘布尔公司 | Viscosity stable concentrated liquid fabric softener compositions |
| CN1168689A (en) * | 1994-10-07 | 1997-12-24 | 普罗格特-甘布尔公司 | Fabric softening composition containing chlorine scavengers |
| CN1219955A (en) * | 1996-03-22 | 1999-06-16 | 普罗格特-甘布尔公司 | Concentrated fabric softening composition with good freeze/thaw recovery and highly unsaturated fabric softener compound therefor |
| CN101208417A (en) * | 2005-05-06 | 2008-06-25 | 高露洁-棕榄公司 | Fabric care composition comprising polymer encapsulated fabric or skin beneficiating ingredient |
| CN101600785A (en) * | 2006-12-28 | 2009-12-09 | 花王公司 | Non-rinse fabric softener |
| CN101581037A (en) * | 2009-06-09 | 2009-11-18 | 深圳市成为工贸有限公司 | Particles capable of softening clothes and preparation method thereof |
| CN101736580A (en) * | 2009-12-21 | 2010-06-16 | 北京绿泽宇和科技有限公司 | Fabric maintenance softener |
Non-Patent Citations (1)
| Title |
|---|
| 邹文苑.织物柔软剂的发展趋势.《日用化学品科学》.1999,(第5期),第11-16页. * |
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