CN102216356B - 具有宽分布的a嵌段的ab二嵌段共聚物的制备方法 - Google Patents

具有宽分布的a嵌段的ab二嵌段共聚物的制备方法 Download PDF

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Publication number
CN102216356B
CN102216356B CN200980144985.2A CN200980144985A CN102216356B CN 102216356 B CN102216356 B CN 102216356B CN 200980144985 A CN200980144985 A CN 200980144985A CN 102216356 B CN102216356 B CN 102216356B
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China
Prior art keywords
block
segmented copolymer
molecular weight
polymerization
initiator
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Expired - Fee Related
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CN200980144985.2A
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English (en)
Chinese (zh)
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CN102216356A (zh
Inventor
H·考茨
S·巴尔克
S·芬勒
D·施塔施克
C·米斯
L·灿德尔
J·吕克特
J·克莱因
T·默勒
V·埃尔布
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Graft Or Block Polymers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
CN200980144985.2A 2008-11-12 2009-10-06 具有宽分布的a嵌段的ab二嵌段共聚物的制备方法 Expired - Fee Related CN102216356B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102008043658.5 2008-11-12
DE102008043658A DE102008043658A1 (de) 2008-11-12 2008-11-12 Verfahren zur Herstellung von AB-Diblockcopolymeren mit einem breit verteilten A-Block
PCT/EP2009/062932 WO2010054897A1 (de) 2008-11-12 2009-10-06 Verfahren zur herstellung von ab-diblockcopolymeren mit einem breit verteilten a-block

Publications (2)

Publication Number Publication Date
CN102216356A CN102216356A (zh) 2011-10-12
CN102216356B true CN102216356B (zh) 2014-10-29

Family

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CN200980144985.2A Expired - Fee Related CN102216356B (zh) 2008-11-12 2009-10-06 具有宽分布的a嵌段的ab二嵌段共聚物的制备方法

Country Status (8)

Country Link
US (1) US8816011B2 (OSRAM)
EP (1) EP2346915B1 (OSRAM)
JP (1) JP5546550B2 (OSRAM)
CN (1) CN102216356B (OSRAM)
AU (1) AU2009315876A1 (OSRAM)
BR (1) BRPI0921206A2 (OSRAM)
DE (1) DE102008043658A1 (OSRAM)
WO (1) WO2010054897A1 (OSRAM)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5888648B2 (ja) * 2012-02-29 2016-03-22 ニッタ株式会社 感温性粘着剤の製造方法
EP2824155A1 (de) * 2013-07-09 2015-01-14 HILTI Aktiengesellschaft Reaktionsharz-Zusammensetzung und deren Verwendung
JP2016029129A (ja) * 2014-07-25 2016-03-03 日立化成株式会社 接着剤組成物及び接着フィルム
US9587062B2 (en) 2014-12-15 2017-03-07 Henkel IP & Holding GmbH and Henkel AG & Co. KGaA Photocrosslinkable block copolymers for hot-melt adhesives
EP3034520A1 (de) * 2014-12-19 2016-06-22 HILTI Aktiengesellschaft Reaktionsharz-Zusammensetzung und deren Verwendung
EP3184499A1 (de) * 2015-12-21 2017-06-28 HILTI Aktiengesellschaft Reaktionsharz-zusammensetzung, mehrkomponenten-system und deren verwendung
JP6928473B2 (ja) * 2017-04-11 2021-09-01 大日精化工業株式会社 コーティング剤、被膜、及び被膜の製造方法
US12258495B2 (en) 2018-12-28 2025-03-25 Saint-Gobain Performance Plastics Corporation Adhesive composition and methods of forming the same
CN110982025A (zh) * 2019-12-12 2020-04-10 湖北工业大学 一种纳米粉体用羟基烷基嵌段乳液聚合物及其atrp制备方法
CN110982024A (zh) * 2019-12-12 2020-04-10 湖北工业大学 一种纳米粉体用羟基苯环嵌段乳液聚合物及其atrp制备方法
CN114574131A (zh) * 2022-02-18 2022-06-03 中国乐凯集团有限公司 胶粘剂及其制备方法和应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999020659A1 (en) * 1997-10-23 1999-04-29 The B.F. Goodrich Company End-functionalized polymers by controlled free-radical polymerization process and polymers made therefrom
US7825199B1 (en) * 1999-03-23 2010-11-02 Carnegie Mellon University Catalytic processes for the controlled polymerization of free radically (co)polymerizable monomers and functional polymeric systems prepared thereby

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5807937A (en) 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
US6310149B1 (en) 1996-06-12 2001-10-30 University Of Warwick Polymerization catalyst and process
TW593347B (en) 1997-03-11 2004-06-21 Univ Carnegie Mellon Improvements in atom or group transfer radical polymerization
US6482900B1 (en) 1997-09-22 2002-11-19 Kaneka Corporation Polymer, process for producing the polymer, and curable composition containing the polymer
US6649701B1 (en) 1998-03-27 2003-11-18 Kaneka Corporation Polymer and process for producing polymer
EP1153942B1 (en) 1998-09-02 2006-11-08 Kaneka Corporation Polymer, processes for producing polymer, and composition
EP1637550B1 (en) 1999-03-23 2017-09-20 Carnegie Mellon University Catalytic processes for the controlled polymerization of free radically (co) polymerizable monomers and functional polymeric systems prepared thereby
JP4447753B2 (ja) * 2000-08-11 2010-04-07 株式会社カネカ ブロック共重合体を含有する硬化性組成物
US20050085592A1 (en) 2002-02-13 2005-04-21 Akio Taniguchi Block copolymer
JP4454495B2 (ja) 2002-05-31 2010-04-21 株式会社Ａｄｅｋａ アクリルゾル組成物
EP1433799A3 (en) * 2002-12-23 2004-07-14 Ucb, S.A. Star shaped acrylic block copolymer
JP2004203917A (ja) * 2002-12-24 2004-07-22 Mitsubishi Chemicals Corp ミクロ相分離構造を形成するブロックポリマーおよびそれを用いた化粧料
DE10350786A1 (de) 2003-10-29 2005-06-02 Röhm GmbH & Co. KG Mischungen zur Herstellung von Reaktivschmelzklebstoffen sowie daraus erhältliche Reaktivschmelzklebstoffe
DE102005045458A1 (de) 2005-09-22 2007-03-29 Röhm Gmbh Verfahren zur Herstellung von ABA-Triblockcopolymeren auf (Meth)acrylatbasis
DE102006015846A1 (de) 2006-04-03 2007-10-04 Röhm Gmbh Kupferentfernung aus ATRP-Produkten mittels Zugabe von Schwefelverbindungen
DE102006035726A1 (de) 2006-07-28 2008-01-31 Evonik Röhm Gmbh Verfahren zur Herstellung von ABA-Triblockcopolymeren auf (Meth)acrylatbasis
DE102006037350A1 (de) * 2006-08-09 2008-02-14 Evonik Röhm Gmbh Verfahren zur Herstellung von halogenfreien ATRP-Produkten
DE102006037352A1 (de) 2006-08-09 2008-02-14 Evonik Röhm Gmbh Verfahren zur Herstellung von säureterminierten ATRP-Produkten
DE102006037351A1 (de) 2006-08-09 2008-02-14 Evonik Röhm Gmbh Verfahren zur Herstellung von hydroxytelecheler ATRP-Produkten
DE102006048154A1 (de) 2006-10-10 2008-04-17 Evonik Röhm Gmbh Verfahren zur Herstellung von silyltelechelen Polymeren
DE102008002016A1 (de) 2008-05-28 2009-12-03 Evonik Röhm Gmbh Verfahren zur Herstellung von silyl-funktionalisierten ABA-Triblockcopolymeren auf (Meth)acrylatbasis
DE102008043666A1 (de) * 2008-11-12 2010-05-20 Evonik Röhm Gmbh Verfahren zur Herstellung von AB-Diblockcopolymeren mit einem bimodalen verteilten A-Block

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999020659A1 (en) * 1997-10-23 1999-04-29 The B.F. Goodrich Company End-functionalized polymers by controlled free-radical polymerization process and polymers made therefrom
US7825199B1 (en) * 1999-03-23 2010-11-02 Carnegie Mellon University Catalytic processes for the controlled polymerization of free radically (co)polymerizable monomers and functional polymeric systems prepared thereby

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Anne-Vale´rie Ruzette et al..Molecular Disorder and Mesoscopic Order in Polydisperse Acrylic Block Copolymers Prepared by Controlled Radical Polymerization.《Macromolecules》.2006,第39卷5804-5814. *

Also Published As

Publication number Publication date
US20110281999A1 (en) 2011-11-17
JP2012508312A (ja) 2012-04-05
WO2010054897A1 (de) 2010-05-20
DE102008043658A1 (de) 2010-05-20
EP2346915A1 (de) 2011-07-27
US8816011B2 (en) 2014-08-26
JP5546550B2 (ja) 2014-07-09
AU2009315876A1 (en) 2010-05-20
EP2346915B1 (de) 2013-12-04
CN102216356A (zh) 2011-10-12
BRPI0921206A2 (pt) 2016-02-23

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