CN102181220A - Novel environment-friendly waterborne baking varnish for coiled material - Google Patents
Novel environment-friendly waterborne baking varnish for coiled material Download PDFInfo
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- CN102181220A CN102181220A CN 201110021202 CN201110021202A CN102181220A CN 102181220 A CN102181220 A CN 102181220A CN 201110021202 CN201110021202 CN 201110021202 CN 201110021202 A CN201110021202 A CN 201110021202A CN 102181220 A CN102181220 A CN 102181220A
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Abstract
A novel environment-friendly waterborne baking varnish for coiled materials is applicable to the replacement of solvent-based coatings used by coiled material manufacturers. The components comprises, by weight: 300-400 of waterborne polyester resin; 300-350 of water; 50-100 of amino resin; 150-200 of pigments and fillers; 0.5-1 of wetting agents; 1-2 of defoaming agents; 3-5 of dispersants; 10-20 of propylene glycol methyl ether; 10-20 of propylene glycol butyl ether; 2 of leveling agents. Compared with solvent-based products used in existing coiled material industry, the product mainly uses water as a dispersion medium, and the used cosolvent belongs to propylene glycol ether which is a friendly organic solvent for human body, so the product is environment friendly. The bodies of constructors are protected from invasion of poisonous volatile compounds, and the performance indices of the product, such as luster, impact resistance, solvent resistance, weatherability, T-bend, adhesion, hardness and the like, are comparable to the performance of solvent-based coatings.
Description
Technical field
The present invention relates to a kind of industrial water-borne coatings
Background technology
Coil coating application colour coated plate has become very big industry abroad, and the development of domestic colour coated plate in recent years is very rapid.At present, the coil coating technology mainly develops to extra long life, product functionization and environmentally friendly direction, and promotes the technical progress of color-painted steel strip and the continuous expansion of Application Areas.
The base material of coil coating has cold-rolled steel sheet, hot-dip galvanizing sheet steel, electrogalvanizing steel plate, aluminium zinc plate and aluminium sheet etc., and thickness is between 0.1～0.5mm.
In more than ten years in the past, the colored steel industry of China is grown out of nothing, actual working rate wretched insufficiency, and the excessive competition of colored steel industry faces low-end market, and high-end market needs the difficult situation of a large amount of imports.Domestic also being in the continuous process that enlarges of coloured coating plate Application Areas, generally, the demand in market is still vigorous.Coloured coating plate for building accounting on international color paint sheet market is 60%～70% heavily, and China accounts for more than 90%, though Application Areas is in expansion as can be seen, building is still main users.The production capacity total amount has been higher than the desired consumption demand, and high-grade color steel is more and more looked at by Chinese building material market parent, and household electrical appliances are increasing year by year with the demand of color steel, and have given new function, as antimicrobial surface.Household electrical appliances are very big with plate market, and refrigerator, air-conditioning, washing machine, refrigerator etc. take very big market, and domestic color steel will capture this market also need descend some time, but market is huge.
Existing coil coating can be divided into three major types: (1) priming paint: priming paint is divided into polyester-amino priming paint according to the film-forming resin difference, polyester-polyurethane priming paint, epoxy-amino priming paint, epoxy-polyurethane priming paint, (2) finish paint: use oil-free polyester resin.Crosslinking curing uses methyl-etherified aminoresin.(3) back side lacquer: use at the back side at the coil plate, can be coated with or do not prime, therefore requiring has good sticking power, though over-all properties requires not as good as the finish paint height, is better but adopt the resin manufacture identical with finish paint.
Although coil painting has many advantages, as increasingly automated, efficient is high, steady quality etc., the organic volatile in the coating (VOC) is after baking, through collecting burning, heat utilization ratio reaches more than 97%, is a kind of coating process of environment-friendly type.But,,, therefore reduce VOC even zero VOC is one of developing direction of environment-friendly type coil coating along with people improve the cognition of own healthy living and work because the solvent-borne type liquid coating need consume a large amount of organic solvents.
Summary of the invention
VOC content height at the existence of solvent-borne type coiled material baking vanish, big to person injury, coating uses later, and machine cleans difficulty, along with oil price raises, the organic solvent price is ascended to heaven, and causes enterprise to clean the disadvantage that cost further strengthens again, the invention provides a kind of novel environment-friendly water-based polyester coiled material baking vanish prescription, this kind product meets the requirement of country to the environment-friendly property of product, meets enterprise and produces needs, effectively replace solvents type coating
For achieving the above object, technical solution of the present invention is:
A kind of novel environment-friendly water-based polyester coiled material baking vanish prescription, as dispersion agent, its each set of dispense ratio is: aqueous polyester resin 300-400 with water for it; Water 300-350; Aminoresin 50-100; Color stuffing 150-200; Wetting agent 0.5-1; Defoamer 1-2; Dispersion agent 3-5; Propylene glycol monomethyl ether 10-20; Propylene glycol butyl ether 10-20; Flow agent 2.
The technique scheme advantage is:
, nontoxic behind the film curing moisture evaporation with water to the person as dispersion agent, as clean-out system, can clean cost with water for enterprise reduces, substitute organic solvent, and then reduce the organic solvent usage quantity more.This kind product does not also contain heavy metal, is beneficial to health of human body more, and its paint film is at gloss, shock resistance, and anti-solvent, weathering resistance, T is curved, adheres to, and reaches the solvent based coating performance on the indexs such as hardness.On depositing, owing to make water, do not fire and do not possess chemically reactive as dispersion agent, stable storing, safe and reliable.
Description of drawings
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Embodiment
A kind of novel environment-friendly water-based polyester coiled material baking vanish prescription, as dispersion agent, its each set of dispense ratio is: aqueous polyester resin 300-400 with water for it; Water 300-350; Aminoresin 50-100; Color stuffing 150-200; Wetting agent 0.5-1; Defoamer 1-2; Dispersion agent 3-5; Propylene glycol monomethyl ether 10-20; Propylene glycol butyl ether 10-20; Flow agent 2.
The present invention adopts the solvent-borne type baking vanish contrast of waterborne polyester baking vanish and 1000 grams of 1000g, comprises aqueous polyester resin 400 in this group 1000g waterborne polyester baking vanish; Water 310; Aminoresin 80; Color stuffing 170; Wetting agent 1; Defoamer 2; Dispersion agent 5; Propylene glycol monomethyl ether 15; Propylene glycol butyl ether 15; Flow agent 2.Two kinds of product performance contrasts see the following form:
Conventional construction test: 200 ℃ of construction temperatures, relative humidity 50%, experimental result sees the following form
Performance comparison
| Test subject | The waterborne polyester baking vanish | The solvent-borne type baking vanish |
| Shock-resistant | 35kg | 40kg |
| Sticking power | 1 grade | 1 grade |
| Water tolerance | Good | Good |
| Alcohol resistance | Good | Good |
| Temperature tolerance | Well | Well |
| Scratch resistance | Good | Good |
| Glossiness | Gao Guang | Gao Guang |
| Fullness ratio | Well | Good |
| Froth breaking | Well | Well |
| Levelling property | Good | Good |
| Dispersed | Well | Well |
| Anti-heavy property | Well | Well |
| VOC content | Very low | Very high |
| Shelf lives | 12 | 12 |
| Viscosity | 65 | 60 |
Claims (9)
1. a novel environment-friendly water-based baking vanish formulation ratio is: water-base resin 300-400; Water 300-350; Aminoresin 50-100; Color stuffing 150-200; Wetting agent 0.5-1; Defoamer 1-2; Dispersion agent 3-5; Propylene glycol monomethyl ether 10-20; Propylene glycol butyl ether 10-20; Flow agent 2.
2. a kind of according to claim 1 novel environment-friendly water-based enamel polyester paint, its water-base resin is an aqueous polyester resin, molecular weight is at 8000-10000.
3. a kind of according to claim 1 novel environment-friendly water-based enamel polyester paint, its aminoresin are one or more mixing in half methyl-etherified aminoresin, methyl-etherified aminoresin, the butyl ether aminoresin.
4. a kind of according to claim 1 novel environment-friendly water-based enamel polyester paint, color stuffing are one or more mixing in Rutile type Titanium Dioxide, anatase thpe white powder, organobentonite, the ultra-fine barium sulfate.
5. a kind of according to claim 1 novel environment-friendly water-based enamel polyester paint, its wetting agent is an alkylphenol-polyethenoxy alcohol.
6. a kind of according to claim 1 novel environment-friendly water-based enamel polyester paint, its dispersion agent are one or more mixing in sodium salt dispersion agent, the ammonium salt dispersion agent.
7. a kind of according to claim 1 novel environment-friendly water-based enamel polyester paint, its propylene glycol monomethyl ether that uses is technical grade.
8. a kind of according to claim 1 novel environment-friendly water-based enamel polyester paint, the propylene glycol butyl ether that it uses is technical grade.
9. a kind of according to claim 1 novel environment-friendly water-based enamel polyester paint, its practical flow agent are one or more mixing in polyurethane-type flow agent, acrylic type flow agent, fluorine carbon flow agent, the organosilicon flow agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110021202 CN102181220A (en) | 2011-01-19 | 2011-01-19 | Novel environment-friendly waterborne baking varnish for coiled material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110021202 CN102181220A (en) | 2011-01-19 | 2011-01-19 | Novel environment-friendly waterborne baking varnish for coiled material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102181220A true CN102181220A (en) | 2011-09-14 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201110021202 Pending CN102181220A (en) | 2011-01-19 | 2011-01-19 | Novel environment-friendly waterborne baking varnish for coiled material |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103382357A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Impact resistant paint used for metal equipment and preparation method thereof |
| CN103666212A (en) * | 2013-12-27 | 2014-03-26 | 天津市瑞宝绿色纳米涂料有限公司 | Water-based metal package barrel color paint and preparing method of color paint |
| CN104073129A (en) * | 2014-07-27 | 2014-10-01 | 广西梧州龙鱼漆业有限公司 | Water-base finish paint for precoating coil |
| CN105038533A (en) * | 2015-07-06 | 2015-11-11 | 上海民同涂料有限公司 | Aqueous baking varnish coating specially used for antitheft doors, and preparation method thereof |
| CN105542630A (en) * | 2016-01-22 | 2016-05-04 | 立邦工业涂料(上海)有限公司 | Waterborne coil coating polyester rear face paint and preparation method thereof |
| CN105778729A (en) * | 2016-03-04 | 2016-07-20 | 宁波市鄞州浩洋水性涂料厂 | Water-based vacuum coating primer and preparation method thereof |
| CN106118399A (en) * | 2016-07-01 | 2016-11-16 | 太仓市金新涂料有限公司 | A kind of high-strength abrasion-proof modified poly ester amino-stoving varnish and preparation method thereof |
| CN106609097A (en) * | 2015-10-26 | 2017-05-03 | 天津市新丽华色材有限责任公司 | Metallic paint formula |
| CN106634472A (en) * | 2016-12-19 | 2017-05-10 | 钦州市高新技术产业服务中心 | Resin baking varnish and preparation method |
| CN106634473A (en) * | 2016-12-27 | 2017-05-10 | 淄博汇和水性漆科技有限公司 | Water-based steel barrel baking varnish and preparation method thereof |
| CN106634115A (en) * | 2016-12-18 | 2017-05-10 | 钦州市科学技术开发中心 | Water-based baking varnish |
| CN106752615A (en) * | 2016-12-19 | 2017-05-31 | 钦州市高新技术产业服务中心 | A kind of lac varnish high and preparation method |
| CN106833241A (en) * | 2016-12-19 | 2017-06-13 | 钦州市高新技术产业服务中心 | A kind of bloom environmental protection paint and preparation method |
| CN108395797A (en) * | 2018-04-28 | 2018-08-14 | 湖州富美材料科技有限公司 | A kind of aqueous amino-stoving varnish |
| CN108587466A (en) * | 2018-04-28 | 2018-09-28 | 苏州新颖新材料科技股份有限公司 | A kind of superhard chromatic metallic plate of water-based paint |
| CN114921157A (en) * | 2022-06-29 | 2022-08-19 | 深圳市深赛尔股份有限公司 | Water-based polyester coil steel coating and preparation method thereof |
| CN115322659A (en) * | 2022-09-11 | 2022-11-11 | 房辉 | Preparation method of water-based paint |
| CN115403993A (en) * | 2022-09-11 | 2022-11-29 | 房辉 | Water-based paint composition |
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| WO1993006166A1 (en) * | 1991-09-18 | 1993-04-01 | Transcontinental Marketing Group Inc. | One coat protective system for a surface |
| CN101550311A (en) * | 2009-05-07 | 2009-10-07 | 杭州传化涂料有限公司 | Aqueous finish paint used for coiled material |
| CN101575479A (en) * | 2009-06-02 | 2009-11-11 | 华南理工大学 | Mono-component aqueous metal baking paint and preparation method thereof |
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2011
- 2011-01-19 CN CN 201110021202 patent/CN102181220A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO1993006166A1 (en) * | 1991-09-18 | 1993-04-01 | Transcontinental Marketing Group Inc. | One coat protective system for a surface |
| CN101550311A (en) * | 2009-05-07 | 2009-10-07 | 杭州传化涂料有限公司 | Aqueous finish paint used for coiled material |
| CN101575479A (en) * | 2009-06-02 | 2009-11-11 | 华南理工大学 | Mono-component aqueous metal baking paint and preparation method thereof |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103382357A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Impact resistant paint used for metal equipment and preparation method thereof |
| CN103666212A (en) * | 2013-12-27 | 2014-03-26 | 天津市瑞宝绿色纳米涂料有限公司 | Water-based metal package barrel color paint and preparing method of color paint |
| CN103666212B (en) * | 2013-12-27 | 2015-11-04 | 天津市瑞宝绿色纳米涂料有限公司 | A kind of water-based metal pail pack divides colored paint and preparation method thereof |
| CN104073129A (en) * | 2014-07-27 | 2014-10-01 | 广西梧州龙鱼漆业有限公司 | Water-base finish paint for precoating coil |
| CN105038533A (en) * | 2015-07-06 | 2015-11-11 | 上海民同涂料有限公司 | Aqueous baking varnish coating specially used for antitheft doors, and preparation method thereof |
| CN105038533B (en) * | 2015-07-06 | 2017-07-11 | 上海民同涂料有限公司 | A kind of special-purpose aqueous baking varnish coating of antitheft door and preparation method thereof |
| CN106609097A (en) * | 2015-10-26 | 2017-05-03 | 天津市新丽华色材有限责任公司 | Metallic paint formula |
| CN105542630A (en) * | 2016-01-22 | 2016-05-04 | 立邦工业涂料(上海)有限公司 | Waterborne coil coating polyester rear face paint and preparation method thereof |
| CN105542630B (en) * | 2016-01-22 | 2019-08-30 | 立邦工业涂料(上海)有限公司 | A kind of aqueous coil coating polyester back paint and preparation method thereof |
| CN105778729A (en) * | 2016-03-04 | 2016-07-20 | 宁波市鄞州浩洋水性涂料厂 | Water-based vacuum coating primer and preparation method thereof |
| CN106118399A (en) * | 2016-07-01 | 2016-11-16 | 太仓市金新涂料有限公司 | A kind of high-strength abrasion-proof modified poly ester amino-stoving varnish and preparation method thereof |
| CN106634115A (en) * | 2016-12-18 | 2017-05-10 | 钦州市科学技术开发中心 | Water-based baking varnish |
| CN106634472A (en) * | 2016-12-19 | 2017-05-10 | 钦州市高新技术产业服务中心 | Resin baking varnish and preparation method |
| CN106752615A (en) * | 2016-12-19 | 2017-05-31 | 钦州市高新技术产业服务中心 | A kind of lac varnish high and preparation method |
| CN106833241A (en) * | 2016-12-19 | 2017-06-13 | 钦州市高新技术产业服务中心 | A kind of bloom environmental protection paint and preparation method |
| CN106634473A (en) * | 2016-12-27 | 2017-05-10 | 淄博汇和水性漆科技有限公司 | Water-based steel barrel baking varnish and preparation method thereof |
| CN108587466A (en) * | 2018-04-28 | 2018-09-28 | 苏州新颖新材料科技股份有限公司 | A kind of superhard chromatic metallic plate of water-based paint |
| CN108395797A (en) * | 2018-04-28 | 2018-08-14 | 湖州富美材料科技有限公司 | A kind of aqueous amino-stoving varnish |
| CN114921157A (en) * | 2022-06-29 | 2022-08-19 | 深圳市深赛尔股份有限公司 | Water-based polyester coil steel coating and preparation method thereof |
| CN115322659A (en) * | 2022-09-11 | 2022-11-11 | 房辉 | Preparation method of water-based paint |
| CN115403993A (en) * | 2022-09-11 | 2022-11-29 | 房辉 | Water-based paint composition |
| CN115403993B (en) * | 2022-09-11 | 2023-08-08 | 浙江嘉怡生物科技有限公司 | Water-based paint composition |
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Application publication date: 20110914 |