CN106634472A - Resin baking varnish and preparation method - Google Patents
Resin baking varnish and preparation method Download PDFInfo
- Publication number
- CN106634472A CN106634472A CN201611179785.9A CN201611179785A CN106634472A CN 106634472 A CN106634472 A CN 106634472A CN 201611179785 A CN201611179785 A CN 201611179785A CN 106634472 A CN106634472 A CN 106634472A
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- parts
- resin
- amino resin
- fat
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09D161/32—Modified amine-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses resin baking varnish and a preparation method. The resin baking varnish is prepared from the following formula ingredients in parts by mass: 40 to 45 parts of aqueous polyester resin, 40 to 45 parts of semi-methylated amino resin, 40 to 45 parts of methylated amino resin, 30 to 35 parts of butylated amino resin, 30 to 35 parts of tert-butyl peroxybenzoate, 10 to 15 parts of initiators, 10 to 15 parts of titanium white, 10 to 15 parts of chrome yellow, 5 to 10 parts of iron blue, 5 to 10 parts of cadmium red, 3 to 6 parts of cadmium yellow, 3 to 6 parts of lithopone, 3 to 4 parts of thickening agents, 3 to 4 parts of HD 1 water solution, 1 to 2 parts of xylene, 1 to 2 parts of butyl acetate benzene and 1 to 2 parts of methyl acetate benzene. The resin baking varnish has a good waterproof property.
Description
Technical field
The present invention relates to technical field of chemical paint, in particular to a kind of resin baking vanish and preparation method.
Background technology
The species that existing market is painted is various, wherein high lac varnish is favored with its excellent glossiness by everybody.Pass
The high lac varnish of system is, with acrylic resin or polyurethane as base-material, to be aided with that various pigment, solvent, additive are refined to be formed, although
Its paint film toughness and wear-resisting, heat-resisting, resistance to persistence, glossiness are all relatively good, but its Water-proof and oil-proof, antifouling three anti-property
Energy and resistance to chemical corrosion are relatively poor, and this largely limits the range of application of high lac varnish, while shortening
The service life of high lac varnish.At present to there is antifouling property poor for paint, is covered with dust all over using coating surface after a period of time, then Jing
The drip washing of rainwater is crossed, the problem of many striped traces is left on surface.
The content of the invention
For the problems referred to above, the invention provides a kind of resin baking vanish and preparation method.
For achieving the above object, the present invention provides following technical scheme：
A kind of resin baking vanish, is made up of following mass fraction formula components：
40～45 parts of aqueous polyester resin, 40～45 parts of half Amino resin fat, Amino resin fat 40～
45 parts, 30～35 parts of butylated amino resin, 30～35 parts of peroxidized t-butyl perbenzoate, 10～15 parts of initiator, titanium white 10
～15 parts, 10～15 parts of chrome yellow, 5～10 parts of barba hispanica, 5～10 parts of cadmium red, 3～6 parts of cadmium yellow, 3～6 parts of lithopone, thickener 3～
1～2 part of 4 parts, 3～4 parts of the HD-1 aqueous solution, 1～2 part of dimethylbenzene, 1～2 part of butyl acetate benzene and methyl acetate benzene.
Further, it is made up of following mass fraction formula components：
40 parts of aqueous polyester resin, 40 parts of half Amino resin fat, 40 parts of Amino resin fat, butyl ether ammonia
30 parts of base resin, 30 parts of peroxidized t-butyl perbenzoate, 10 parts of initiator, 10 parts of titanium white, 10 parts of chrome yellow, 5 parts of barba hispanica, cadmium red 5
Part, 3 parts of cadmium yellow, 3 parts of lithopone, 3 parts of thickener, 3 parts of the HD-1 aqueous solution, 1 part of dimethylbenzene, 1 part of butyl acetate benzene and acetic acid first
1 part of ester benzene.
Further, it is made up of following mass fraction formula components：
45 parts of aqueous polyester resin, 45 parts of half Amino resin fat, 45 parts of Amino resin fat, butyl ether ammonia
35 parts of base resin, 35 parts of peroxidized t-butyl perbenzoate, 15 parts of initiator, 15 parts of titanium white, 15 parts of chrome yellow, 10 parts of barba hispanica, cadmium red
10 parts, 6 parts of cadmium yellow, 6 parts of lithopone, 4 parts of thickener, 4 parts of the HD-1 aqueous solution, 2 parts of dimethylbenzene, 2 parts of butyl acetate benzene and acetic acid
2 parts of methyl esters benzene.
Further, it is made up of following mass fraction formula components：
43 parts of aqueous polyester resin, 43 parts of half Amino resin fat, 42 parts of Amino resin fat, butyl ether ammonia
33 parts of base resin, 32 parts of peroxidized t-butyl perbenzoate, 14 parts of initiator, 12 parts of titanium white, 12 parts of chrome yellow, 9 parts of barba hispanica, cadmium red 8
Part, 4 parts of cadmium yellow, 4 parts of lithopone, 4 parts of thickener, 3 parts of the HD-1 aqueous solution, 2 parts of dimethylbenzene, 1 part of butyl acetate benzene and acetic acid first
2 parts of ester benzene.
Further：Preparation method of the present invention has following steps：
Step one：By aqueous polyester resin, half Amino resin, Amino resin, butylated amino resin
Stirring at low speed 1.2～1.5 hours in mixer are put into, are sufficiently mixed, then heated 1.5～2 hours and dry, heating-up temperature is 80
～90 DEG C, make intermediate blend 1；
Step 2：Peroxidized t-butyl perbenzoate and initiator are added in intermediate blend 1, and temperature is heated to
100～120 DEG C so that mixture reacts, the reaction time is 7～8 hours, makes intermediate blend 2；
Step 3：Titanium white, chrome yellow, barba hispanica, cadmium red, cadmium yellow and lithopone are added into intermediate blend 2, is stirred using mixer
Mixing is mixed, mixing time is 30～45 minutes, makes intermediate blend 3；
Step 4, thickener and the HD-1 aqueous solution are slowly added in intermediate blend 3, are well mixed, and are made middle mixed
Compound 4；
Step 5, by intermediate blend 4, dimethylbenzene, butyl acetate and methyl acetate stirring mixing 30 in mixer is added
～45 minutes, make finished product.
The invention has the beneficial effects as follows：
The lacquer type organic coating of the present invention has good water-resisting property；
The lacquer type organic coating of the present invention has good glossiness；
The lacquer type organic coating of the present invention has good UV resistant performance；
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment one：
A kind of resin baking vanish, is made up of following mass fraction formula components：40～45 parts of aqueous polyester resin, half methyl-etherified
40～45 parts of amino resins fat, 40～45 parts of Amino resin fat, 30～35 parts of butylated amino resin, benzoyl peroxide first
30～35 parts of tert-butyl acrylate, 10～15 parts of initiator, 10～15 parts of titanium white, 10～15 parts of chrome yellow, 5～10 parts of barba hispanica, cadmium red 5～
10 parts, 3～6 parts of cadmium yellow, 3～6 parts of lithopone, 3～4 parts of thickener, 3～4 parts of the HD-1 aqueous solution, 1～2 part of dimethylbenzene, acetic acid
1～2 part of 1～2 part of butyl ester benzene and methyl acetate benzene.
Embodiment two：
A kind of resin baking vanish, is made up of following mass fraction formula components：40 parts of aqueous polyester resin, half methyl-etherified amino
40 parts of resin ester, 40 parts of Amino resin fat, 30 parts of butylated amino resin, 30 parts of peroxidized t-butyl perbenzoate, draw
Send out 10 parts of agent, 10 parts of titanium white, 10 parts of chrome yellow, 5 parts of barba hispanica, 5 parts of cadmium red, 3 parts of cadmium yellow, 3 parts of lithopone, 3 parts of thickener, HD-1 water
1 part of 3 parts of solution, 1 part of dimethylbenzene, 1 part of butyl acetate benzene and methyl acetate benzene.
Embodiment three：
A kind of resin baking vanish, is made up of following mass fraction formula components：45 parts of aqueous polyester resin, half methyl-etherified amino
45 parts of resin ester, 45 parts of Amino resin fat, 35 parts of butylated amino resin, 35 parts of peroxidized t-butyl perbenzoate, draw
Send out 15 parts of agent, 15 parts of titanium white, 15 parts of chrome yellow, 10 parts of barba hispanica, 10 parts of cadmium red, 6 parts of cadmium yellow, 6 parts of lithopone, 4 parts of thickener, HD-1
2 parts of 4 parts of the aqueous solution, 2 parts of dimethylbenzene, 2 parts of butyl acetate benzene and methyl acetate benzene.
Example IV：
A kind of resin baking vanish, is made up of following mass fraction formula components：43 parts of aqueous polyester resin, half methyl-etherified amino
43 parts of resin ester, 42 parts of Amino resin fat, 33 parts of butylated amino resin, 32 parts of peroxidized t-butyl perbenzoate, draw
Send out 14 parts of agent, 12 parts of titanium white, 12 parts of chrome yellow, 9 parts of barba hispanica, 8 parts of cadmium red, 4 parts of cadmium yellow, 4 parts of lithopone, 4 parts of thickener, HD-1 water
2 parts of 3 parts of solution, 2 parts of dimethylbenzene, 1 part of butyl acetate benzene and methyl acetate benzene.
Embodiment five：
A kind of resin baking vanish its preparation method comprises the steps：
Step one：By aqueous polyester resin, half Amino resin, Amino resin, butylated amino resin
Stirring at low speed 1.2～1.5 hours in mixer are put into, are sufficiently mixed, then heated 1.5～2 hours and dry, heating-up temperature is 80
～90 DEG C, make intermediate blend 1；
Step 2：Peroxidized t-butyl perbenzoate and initiator are added in intermediate blend 1, and temperature is heated to
100～120 DEG C so that mixture reacts, the reaction time is 7～8 hours, makes intermediate blend 2；
Step 3：Titanium white, chrome yellow, barba hispanica, cadmium red, cadmium yellow and lithopone are added into intermediate blend 2, is stirred using mixer
Mixing is mixed, mixing time is 30～45 minutes, makes intermediate blend 3；
Step 4, thickener and the HD-1 aqueous solution are slowly added in intermediate blend 3, are well mixed, and are made middle mixed
Compound 4；
Step 5, by intermediate blend 4, dimethylbenzene, butyl acetate and methyl acetate stirring mixing 30 in mixer is added
～45 minutes, make finished product.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity those skilled in the art should
Using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (5)
1. a kind of resin baking vanish, it is characterised in that：It is made up of following mass fraction formula components：
40～45 parts of aqueous polyester resin, 40～45 parts of half Amino resin fat, 40～45 parts of Amino resin fat,
30～35 parts of butylated amino resin, 30～35 parts of peroxidized t-butyl perbenzoate, 10～15 parts of initiator, titanium white 10～15
Part, 10～15 parts of chrome yellow, 5～10 parts of barba hispanica, 5～10 parts of cadmium red, 3～6 parts of cadmium yellow, 3～6 parts of lithopone, 3～4 parts of thickener,
1～2 part of 3～4 parts of the HD-1 aqueous solution, 1～2 part of dimethylbenzene, 1～2 part of butyl acetate benzene and methyl acetate benzene.
2. a kind of resin baking vanish according to claim 1, it is characterised in that：It is made up of following mass fraction formula components：
40 parts of aqueous polyester resin, 40 parts of half Amino resin fat, 40 parts of Amino resin fat, fourth etherified amino tree
30 parts of fat, 30 parts of peroxidized t-butyl perbenzoate, 10 parts of initiator, 10 parts of titanium white, 10 parts of chrome yellow, 5 parts of barba hispanica, 5 parts of cadmium red, cadmium
Yellow 3 parts, 3 parts of lithopone, 3 parts of thickener, 3 parts of the HD-1 aqueous solution, 1 part of dimethylbenzene, 1 part of butyl acetate benzene and methyl acetate benzene 1
Part.
3. a kind of resin baking vanish according to claim 1, it is characterised in that：It is made up of following mass fraction formula components：
45 parts of aqueous polyester resin, 45 parts of half Amino resin fat, 45 parts of Amino resin fat, fourth etherified amino tree
35 parts of fat, 35 parts of peroxidized t-butyl perbenzoate, 15 parts of initiator, 15 parts of titanium white, 15 parts of chrome yellow, 10 parts of barba hispanica, 10 parts of cadmium red,
6 parts of cadmium yellow, 6 parts of lithopone, 4 parts of thickener, 4 parts of the HD-1 aqueous solution, 2 parts of dimethylbenzene, 2 parts of butyl acetate benzene and methyl acetate benzene
2 parts.
4. a kind of resin baking vanish according to claim 1, it is characterised in that：It is made up of following mass fraction formula components：
43 parts of aqueous polyester resin, 43 parts of half Amino resin fat, 42 parts of Amino resin fat, fourth etherified amino tree
33 parts of fat, 32 parts of peroxidized t-butyl perbenzoate, 14 parts of initiator, 12 parts of titanium white, 12 parts of chrome yellow, 9 parts of barba hispanica, 8 parts of cadmium red, cadmium
Yellow 4 parts, 4 parts of lithopone, 4 parts of thickener, 3 parts of the HD-1 aqueous solution, 2 parts of dimethylbenzene, 1 part of butyl acetate benzene and methyl acetate benzene 2
Part.
5. the preparation method of a kind of resin baking vanish according to claim 1, it is characterised in that：Comprise the steps：
Step one：Aqueous polyester resin, half Amino resin, Amino resin, butylated amino resin are put into
Stirring at low speed 1.2～1.5 hours, are sufficiently mixed in mixer, then heat 1.5～2 hours and dry, and heating-up temperature is 80～90
DEG C, make intermediate blend 1；
Step 2：Peroxidized t-butyl perbenzoate and initiator are added in intermediate blend 1, and temperature is heated into 100～
120 DEG C so that mixture reacts, the reaction time is 7～8 hours, makes intermediate blend 2；
Step 3：Titanium white, chrome yellow, barba hispanica, cadmium red, cadmium yellow and lithopone are added into intermediate blend 2, it is mixed using mixer stirring
Close, mixing time is 30～45 minutes, makes intermediate blend 3；
Step 4, thickener and the HD-1 aqueous solution are slowly added in intermediate blend 3, are well mixed, and make intermediate blend
4；
Step 5, by intermediate blend 4, dimethylbenzene, butyl acetate and methyl acetate stirring mixing 30～45 in mixer is added
Minute, make finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611179785.9A CN106634472A (en) | 2016-12-19 | 2016-12-19 | Resin baking varnish and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611179785.9A CN106634472A (en) | 2016-12-19 | 2016-12-19 | Resin baking varnish and preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106634472A true CN106634472A (en) | 2017-05-10 |
Family
ID=58833879
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611179785.9A Pending CN106634472A (en) | 2016-12-19 | 2016-12-19 | Resin baking varnish and preparation method |
Country Status (1)
| Country | Link |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002307A (en) * | 2009-08-31 | 2011-04-06 | 无锡市金箭造漆有限公司 | Water-based precoated coiled material coating finish paint and preparation method thereof |
| CN102181220A (en) * | 2011-01-19 | 2011-09-14 | 天津滨新涂料有限公司 | Novel environment-friendly waterborne baking varnish for coiled material |
| CN103865341A (en) * | 2012-12-18 | 2014-06-18 | 东莞市长安东阳光铝业研发有限公司 | Waterborne FEVE (chlorotrifluoroethylene copolymer) fluorocarbon coating and preparation method thereof |
-
2016
- 2016-12-19 CN CN201611179785.9A patent/CN106634472A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002307A (en) * | 2009-08-31 | 2011-04-06 | 无锡市金箭造漆有限公司 | Water-based precoated coiled material coating finish paint and preparation method thereof |
| CN102181220A (en) * | 2011-01-19 | 2011-09-14 | 天津滨新涂料有限公司 | Novel environment-friendly waterborne baking varnish for coiled material |
| CN103865341A (en) * | 2012-12-18 | 2014-06-18 | 东莞市长安东阳光铝业研发有限公司 | Waterborne FEVE (chlorotrifluoroethylene copolymer) fluorocarbon coating and preparation method thereof |
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Application publication date: 20170510 |
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