CN106752615A - A kind of lac varnish high and preparation method - Google Patents

A kind of lac varnish high and preparation method Download PDF

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Publication number
CN106752615A
CN106752615A CN201611179786.3A CN201611179786A CN106752615A CN 106752615 A CN106752615 A CN 106752615A CN 201611179786 A CN201611179786 A CN 201611179786A CN 106752615 A CN106752615 A CN 106752615A
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parts
acid
ultra
organobentonite
lac varnish
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CN201611179786.3A
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Inventor
戚炎月
丘泰西
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Qinzhou Hi Tech Industry Service Center
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Qinzhou Hi Tech Industry Service Center
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Priority to CN201611179786.3A priority Critical patent/CN106752615A/en
Publication of CN106752615A publication Critical patent/CN106752615A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1535—Five-membered rings
    • C08K5/1539—Cyclic anhydrides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of lac varnish high and preparation method, it is made up of following mass fraction formula components：40~45 parts of xylene solvent, 20~25 parts of perfluoro hexyl ethyl propylene acid esters, 20~25 parts of acrylic acid, 15~20 parts of methacrylic acid, 15~20 parts of methyl methacrylate, 15~20 parts of butyl acrylate, 5~10 parts of trimellitic anhydride, 5~7 parts of rutile type titanium white, 5~7 parts of anatase thpe white powder, 3~4 parts of organobentonite, 3~4 parts of ultra-fine barium sulfate, lac varnish high of the invention have good grease proofness.

Description

A kind of lac varnish high and preparation method
Technical field
The present invention relates to chemical material technical field, in particular to a kind of lac varnish high and preparation method.
Background technology
Paint is widely used in the life of people and industrial production, plays the work of protection, decoration, mark and other specific uses With being the indispensable material in the world today.The species that existing market is painted is various, wherein lac varnish high is with its excellent gloss Property is favored by everybody.Traditional lac varnish high be with acrylic resin or polyurethane as base-material, be aided with various pigment, solvent, Additive is refined to be formed, although its paint film toughness and wear-resisting, heat-resisting, resistance to persistence, glossiness are all relatively good, but it is anti- Water, grease proofing, antifouling NBC protective performance and resistance to chemical corrosion are relatively poor, and this largely limits lac varnish high Range of application, while shortening the service life of lac varnish high.To there is oil preventing performance poor for paint at present, makes in some special industries The problem being restricted in.
The content of the invention
Regarding to the issue above, the invention provides a kind of lac varnish high and preparation method.
To achieve the above object, the present invention provides following technical scheme：
A kind of lac varnish high, is made up of following mass fraction formula components：
40~45 parts of xylene solvent, 20~25 parts of perfluoro hexyl ethyl propylene acid esters, 20~25 parts of acrylic acid, methyl-prop 15~20 parts of olefin(e) acid, 15~20 parts of methyl methacrylate, 15~20 parts of butyl acrylate, 5~10 parts of trimellitic anhydride, golden red 5~7 parts of stone-type titanium dioxide, 5~7 parts of anatase thpe white powder, 3~4 parts of organobentonite, 3~4 parts of ultra-fine barium sulfate.
Further, it is made up of following mass fraction formula components：
40 parts of xylene solvent, 20 parts of perfluoro hexyl ethyl propylene acid esters, 20 parts of acrylic acid, 15 parts of methacrylic acid, first 15 parts of base methyl acrylate, 15 parts of butyl acrylate, 5 parts of trimellitic anhydride, 5 parts of rutile type titanium white, anatase thpe white powder 5 Part, 3 parts of organobentonite, 3 parts of ultra-fine barium sulfate.
Further, it is made up of following mass fraction formula components：
45 parts of xylene solvent, 25 parts of perfluoro hexyl ethyl propylene acid esters, 25 parts of acrylic acid, 20 parts of methacrylic acid, first 20 parts of base methyl acrylate, 20 parts of butyl acrylate, 10 parts of trimellitic anhydride, 7 parts of rutile type titanium white, anatase thpe white powder 7 parts, 4 parts of organobentonite, 4 parts of ultra-fine barium sulfate.
Further, it is made up of following mass fraction formula components：
43 parts of xylene solvent, 23 parts of perfluoro hexyl ethyl propylene acid esters, 23 parts of acrylic acid, 17 parts of methacrylic acid, first 17 parts of base methyl acrylate, 16 parts of butyl acrylate, 8 parts of trimellitic anhydride, 6 parts of rutile type titanium white, anatase thpe white powder 6 Part, 3 parts of organobentonite, 4 parts of ultra-fine barium sulfate.
Further：Preparation method of the present invention has following steps：
Step one：Under nitrogen protection, will in xylene solvent mix add agitator in, then sequentially add perfluor oneself Base ethyl propylene acid esters, acrylic acid, methacrylic acid, methyl methacrylate and butyl acrylate, and stirred under normal temperature condition Mix 1~2 hour, be made intermediate blend 1；
Step 2, by trimellitic anhydride addition intermediate blend 1, is then cooled to 150~160 DEG C of reactions 1.5~2 small When, it is made intermediate blend 2；
Step 3：During rutile type titanium white, anatase thpe white powder, organobentonite, ultra-fine barium sulfate are sequentially added Between in mixture 2, stirring mixing is made finished product.
The beneficial effects of the invention are as follows：
1. lac varnish high of the invention has good grease proofness；
2. lac varnish high of the invention has good glossiness；
3. lac varnish high of the invention has good UV resistant performance.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
Embodiment one：
A kind of lac varnish high, is made up of following mass fraction formula components：40~45 parts of xylene solvent, perfluoro hexyl ethyl 20~25 parts of acrylate, 20~25 parts of acrylic acid, 15~20 parts of methacrylic acid, 15~20 parts of methyl methacrylate, third 15~20 parts of olefin(e) acid butyl ester, 5~10 parts of trimellitic anhydride, 5~7 parts of rutile type titanium white, 5~7 parts of anatase thpe white powder, have 3~4 parts of machine bentonite, 3~4 parts of ultra-fine barium sulfate.
Embodiment two：
A kind of lac varnish high, is made up of following mass fraction formula components：40 parts of xylene solvent, perfluoro hexyl ethyl propylene 20 parts of acid esters, 20 parts of acrylic acid, 15 parts of methacrylic acid, 15 parts of methyl methacrylate, 15 parts of butyl acrylate, trimellitic acid 5 parts of acid anhydride, 5 parts of rutile type titanium white, 5 parts of anatase thpe white powder, 3 parts of organobentonite, 3 parts of ultra-fine barium sulfate.
Embodiment three：
A kind of lac varnish high, is made up of following mass fraction formula components：45 parts of xylene solvent, perfluoro hexyl ethyl propylene 25 parts of acid esters, 25 parts of acrylic acid, 20 parts of methacrylic acid, 20 parts of methyl methacrylate, 20 parts of butyl acrylate, trimellitic acid 10 parts of acid anhydride, 7 parts of rutile type titanium white, 7 parts of anatase thpe white powder, 4 parts of organobentonite, 4 parts of ultra-fine barium sulfate.
Example IV：
A kind of lac varnish high, is made up of following mass fraction formula components：43 parts of xylene solvent, perfluoro hexyl ethyl propylene 23 parts of acid esters, 23 parts of acrylic acid, 17 parts of methacrylic acid, 17 parts of methyl methacrylate, 16 parts of butyl acrylate, trimellitic acid 8 parts of acid anhydride, 6 parts of rutile type titanium white, 6 parts of anatase thpe white powder, 3 parts of organobentonite, 4 parts of ultra-fine barium sulfate.
Embodiment five：
A kind of lac varnish its preparation method high comprises the following steps：
Step one：Under nitrogen protection, will in xylene solvent mix add agitator in, then sequentially add perfluor oneself Base ethyl propylene acid esters, acrylic acid, methacrylic acid, methyl methacrylate and butyl acrylate, and stirred under normal temperature condition Mix 1~2 hour, be made intermediate blend 1；
Step 2, by trimellitic anhydride addition intermediate blend 1, is then cooled to 150~160 DEG C of reactions 1.5~2 small When, it is made intermediate blend 2；
Step 3：During rutile type titanium white, anatase thpe white powder, organobentonite, ultra-fine barium sulfate are sequentially added Between in mixture 2, stirring mixing is made finished product.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined May be appreciated other embodiment.

Claims (5)

1. a kind of lac varnish high, it is characterised in that：It is made up of following mass fraction formula components：
40~45 parts of xylene solvent, 20~25 parts of perfluoro hexyl ethyl propylene acid esters, 20~25 parts of acrylic acid, methacrylic acid 15~20 parts, 15~20 parts of methyl methacrylate, 15~20 parts of butyl acrylate, 5~10 parts of trimellitic anhydride, rutile-type 5~7 parts of titanium dioxide, 5~7 parts of anatase thpe white powder, 3~4 parts of organobentonite, 3~4 parts of ultra-fine barium sulfate.
2. a kind of lac varnish high according to claim 1, it is characterised in that：It is made up of following mass fraction formula components：
40 parts of xylene solvent, 20 parts of perfluoro hexyl ethyl propylene acid esters, 20 parts of acrylic acid, 15 parts of methacrylic acid, methyl-prop 15 parts of e pioic acid methyl ester, 15 parts of butyl acrylate, 5 parts of trimellitic anhydride, 5 parts of rutile type titanium white, 5 parts of anatase thpe white powder, 3 parts of organobentonite, 3 parts of ultra-fine barium sulfate.
3. a kind of lac varnish high according to claim 1, it is characterised in that：It is made up of following mass fraction formula components：
45 parts of xylene solvent, 25 parts of perfluoro hexyl ethyl propylene acid esters, 25 parts of acrylic acid, 20 parts of methacrylic acid, methyl-prop 20 parts of e pioic acid methyl ester, 20 parts of butyl acrylate, 10 parts of trimellitic anhydride, 7 parts of rutile type titanium white, 7 parts of anatase thpe white powder, 4 parts of organobentonite, 4 parts of ultra-fine barium sulfate.
4. a kind of lac varnish high according to claim 1, it is characterised in that：It is made up of following mass fraction formula components：
43 parts of xylene solvent, 23 parts of perfluoro hexyl ethyl propylene acid esters, 23 parts of acrylic acid, 17 parts of methacrylic acid, methyl-prop 17 parts of e pioic acid methyl ester, 16 parts of butyl acrylate, 8 parts of trimellitic anhydride, 6 parts of rutile type titanium white, 6 parts of anatase thpe white powder, 3 parts of organobentonite, 4 parts of ultra-fine barium sulfate.
5. the preparation method of a kind of lac varnish high according to claim 1, it is characterised in that：Comprise the following steps：
Step one：Under nitrogen protection, will mix in xylene solvent in addition agitator, then sequentially add perfluoro hexyl second Base acrylate, acrylic acid, methacrylic acid, methyl methacrylate and butyl acrylate, and under normal temperature condition stirring 1~ 2 hours, it is made intermediate blend 1；
Step 2, by trimellitic anhydride addition intermediate blend 1, is then cooled to 150~160 DEG C and reacts 1.5~2 hours, It is made intermediate blend 2；
Step 3：Rutile type titanium white, anatase thpe white powder, organobentonite, ultra-fine barium sulfate are sequentially added middle mixed In compound 2, stirring mixing is made finished product.
CN201611179786.3A 2016-12-19 2016-12-19 A kind of lac varnish high and preparation method Pending CN106752615A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101875813A (en) * 2010-08-11 2010-11-03 自贡拓利化工有限公司 High temperature resistant anticorrosion top coat
CN102181220A (en) * 2011-01-19 2011-09-14 天津滨新涂料有限公司 Novel environment-friendly waterborne baking varnish for coiled material
CN102250280A (en) * 2011-05-20 2011-11-23 锦州惠发天合化学有限公司 Perfluoro alkyl ethyl acrylic ester-modified single-component acrylic resin and preparation method as well as application thereof
CN102627899A (en) * 2012-04-13 2012-08-08 阜新恒通氟化学有限公司 Preparation process for fluorine-containing high light paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101875813A (en) * 2010-08-11 2010-11-03 自贡拓利化工有限公司 High temperature resistant anticorrosion top coat
CN102181220A (en) * 2011-01-19 2011-09-14 天津滨新涂料有限公司 Novel environment-friendly waterborne baking varnish for coiled material
CN102250280A (en) * 2011-05-20 2011-11-23 锦州惠发天合化学有限公司 Perfluoro alkyl ethyl acrylic ester-modified single-component acrylic resin and preparation method as well as application thereof
CN102627899A (en) * 2012-04-13 2012-08-08 阜新恒通氟化学有限公司 Preparation process for fluorine-containing high light paint

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Application publication date: 20170531