CN103666212B - A kind of water-based metal pail pack divides colored paint and preparation method thereof - Google Patents
A kind of water-based metal pail pack divides colored paint and preparation method thereof Download PDFInfo
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- CN103666212B CN103666212B CN201310754347.0A CN201310754347A CN103666212B CN 103666212 B CN103666212 B CN 103666212B CN 201310754347 A CN201310754347 A CN 201310754347A CN 103666212 B CN103666212 B CN 103666212B
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Abstract
The present invention relates to a kind of water-based metal pail pack and divide colored paint and preparation method thereof, this color separation enamel-cover draws together dark-colored paint and tinted paint: this tinted paint is prepared by the raw material comprising following parts by weight: deionized water, defoamer, dispersion agent, water-reducible polyester resin, titanium dioxide, permanent yellow, process white, waterborne organic silicon flow agent, anti-sudden strain of a muscle rust agent and water-compatible amino resin; This dark-colored paint is prepared by the raw material comprising following parts by weight: the one in deionized water, defoamer, dispersion agent, water-reducible polyester resin, process white, titanium dioxide, phthalocyanine blue or phthalocyanine green, water soluble acrylic acid flow agent, anti-sudden strain of a muscle rust agent and water-compatible amino resin.The present invention take water as thinner, does not add any organic solvent, saves petroleum resources, reduces airborne release, preserves the ecological environment, to HUMAN HEALTH fanout free region.
Description
Technical field
The present invention relates to paint field, relate to a kind of water-based metal pail pack specifically and divide colored paint and preparation method thereof.
Technical background
Metallic packing pail divides colored paint mostly to adopt solvent-based paints in the market, it contains a large amount of volatile organic compounds (VOC), these organic compound are mainly containing the benzene,toluene,xylene etc. human body being caused to great damage, these objectionable impuritiess evaporate in air goes, not only cause the wasting of resources, severe contamination is caused to air simultaneously.Along with the raising of people's environmental consciousness, the requirement increasingly stringent of Environmental protection, researches and develops low VOC even the aqueous environments friendly coating of Diamond Search and to be inevitable developing direction.
Research and develop water-based metal pail pack and divide colored paint, first will accomplish that two kinds of color paints are wet and touch wet spray, objectionable intermingling, impermeable mutually, the line of delimitation of drying latter two color is clear.Traditional paint does a point colored paint, the evaporation rate of organic solvent can be utilized to control the surface drying speed of paint, reach a point chromatic effect.And the solvent of water-miscible paint is water, the evaporation rate of water is slow, so wet when water-miscible paint does color separation touch wet spray, mutual bleeding is very serious, and this is also the technological difficulties that water-based metal pail pack divides colored paint.
Summary of the invention
The invention provides a kind of water-based metal pail pack and divide colored paint, so-called point of colored paint is exactly the paint of two kinds of different colours, and two kinds of one, colors be dark, another is light color.Spraying is taked to wet and is touched wet spray, needs solution two kinds of mutual nonbleeding of color, and after paint film oven dry, the division is clearly demarcated.The present invention adopts two kinds of color paints to use dissimilar auxiliary agent, and a kind of color uses organosilicon flow agent, and another kind of color uses vinylformic acid flow agent, solves water-based metal pail pack and divides that colored paint is wet touches the mutual bleeding problem of wet spray.
For achieving the above object, technical scheme of the present invention is:
A kind of water-based metal pail pack divides colored paint, and this color separation enamel-cover draws together dark-colored paint and tinted paint: this tinted paint is prepared by the raw material comprising following parts by weight: deionized water 15 ~ 20 parts, defoamer 0.1 ~ 0.5 part, dispersion agent 2 ~ 5 parts, water-reducible polyester resin 40 ~ 60 parts, titanium dioxide 15 ~ 20 parts, permanent yellow 0 ~ 2 part, process white 5 ~ 15 parts, waterborne organic silicon flow agent 0.5 ~ 1 part, anti-sudden strain of a muscle rust agent 0.5 ~ 1 part and water-compatible amino resin 5 ~ 15 parts; This dark-colored paint is prepared by the raw material comprising following parts by weight: the one 5 ~ 10 parts in deionized water 15 ~ 20 parts, defoamer 0.1 ~ 0.5 part, dispersion agent 2 ~ 5 parts, water-reducible polyester resin 40 ~ 60 parts, titanium dioxide 0 ~ 10 part, process white 5 ~ 15 parts, phthalocyanine blue or phthalocyanine green, water soluble acrylic acid flow agent 0.5 ~ 1 part, anti-sudden strain of a muscle rust agent 0.5 ~ 1 part and water-compatible amino resin 5 ~ 15 parts.
Particularly,
This tinted paint is prepared by the method comprised the steps: (1) by material deionized water 15 ~ 20 parts, defoamer 0.1 ~ 0.5 part, dispersion agent 2 ~ 5 parts, water-reducible polyester resin 20 ~ 30 parts, titanium dioxide 15 ~ 20 parts, permanent yellow 0 ~ 2 part, process white 5 ~ 15 parts, add join paint cylinder in stir; (2) step (1) gained solution is ground to fineness≤20um by shredder, then solution is drawn back join paint cylinder in; (3) under agitation, join in paint cylinder and add material water-reducible polyester resin 20 ~ 30 parts, waterborne organic silicon flow agent 0.5 ~ 1 part, the agent 0.5 ~ 1 part of anti-sudden strain of a muscle rust, water-compatible amino resin 5 ~ 15 parts successively, stir; (4) filtered by step (3) gained solution, equivalent is packed.I.e. obtained tinted paint.
This dark-colored paint is prepared by the method comprised the steps: (1) by the one 5 ~ 10 parts in material deionized water 15 ~ 20 parts, defoamer 0.1 ~ 0.5 part, dispersion agent 2 ~ 5 parts, water-reducible polyester resin 20 ~ 30 parts, titanium dioxide 0 ~ 10 part, process white 5 ~ 15 parts, phthalocyanine blue or phthalocyanine green, add join paint cylinder in stir; (2) step (1) gained solution is ground to fineness≤20um by shredder, then solution is drawn back join paint cylinder in; (3) under agitation, join in paint cylinder and add material water-reducible polyester resin 20 ~ 30 parts, water soluble acrylic acid flow agent 0.5 ~ 1 part, anti-sudden strain of a muscle rust agent 0.5 ~ 1 part, water-compatible amino resin 5 ~ 15 parts successively, stir; (4) filtered by step (3) gained solution, equivalent is packed, i.e. obtained dark-colored paint.
Described number is parts by weight.
Particularly, present invention also offers the preparation method that above-mentioned water-based metal pail pack divides colored paint, this water-based metal pail pack color separation enamel-cover draws together dark-colored paint and tinted paint:
The preparation method of this tinted paint, comprise the steps: (1) by material deionized water 15 ~ 20 parts, defoamer 0.1 ~ 0.5 part, dispersion agent 2 ~ 5 parts, water-reducible polyester resin 20 ~ 30 parts, titanium dioxide 15 ~ 20 parts, permanent yellow 0 ~ 2 part, process white 5 ~ 15 parts, add join paint cylinder in stir; (2) step (1) gained solution is ground to fineness≤20um by shredder, then solution is drawn back join paint cylinder in; (3) under agitation, join in paint cylinder and add material water-reducible polyester resin 20 ~ 30 parts, waterborne organic silicon flow agent 0.5 ~ 1 part, the agent 0.5 ~ 1 part of anti-sudden strain of a muscle rust, water-compatible amino resin 5 ~ 15 parts successively, stir; (4) filtered by step (3) gained solution, equivalent is packed.I.e. obtained tinted paint;
The preparation method of this dark-colored paint, comprises the steps:: (1) by the one 5 ~ 10 parts in material deionized water 15 ~ 20 parts, defoamer 0.1 ~ 0.5 part, dispersion agent 2 ~ 5 parts, water-reducible polyester resin 20 ~ 30 parts, titanium dioxide 0 ~ 10 part, process white 5 ~ 15 parts, phthalocyanine blue or phthalocyanine green, add join paint cylinder in stir; (2) step (1) gained solution is ground to fineness≤20um by shredder, then solution is drawn back join paint cylinder in; (3) under agitation, join in paint cylinder and add material water-reducible polyester resin 20 ~ 30 parts, water soluble acrylic acid flow agent 0.5 ~ 1 part, anti-sudden strain of a muscle rust agent 0.5 ~ 1 part, water-compatible amino resin 5 ~ 15 parts successively, stir; (4) filtered by step (3) gained solution, equivalent is packed, i.e. obtained dark-colored paint.
The instrument of preparation process (2) the detection fineness of described dark-colored paint and tinted paint is Hegman grind gage.
Preparation process (4) the filtering net aperture used of described dark-colored paint and tinted paint is 200 orders.
The whole production process of described dark-colored paint and tinted paint controls below 50 DEG C.
The preparation process step (1) of described dark-colored paint and tinted paint and the water-reducible polyester resin consumption equivalent of step (3).
Compared with the solvent-based paints that market uses, the present invention has following advantage:
The present invention take water as thinner, does not add any organic solvent, saves petroleum resources, reduces airborne release, preserves the ecological environment, to HUMAN HEALTH fanout free region.
The present invention utilizes the principle of two kinds of auxiliary agents not mutual tolerance, solves the color separation problem of water-based metal pail pack paint.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, but do not limit protection scope of the present invention.
Embodiment 1
White metal pail pack divides a preparation method for colored paint, comprises the steps:
Under 500r/min agitation condition, join in paint cylinder and add deionized water 20 parts, BYK-020 (defoamer) 0.2 part, BYK-190 (dispersion agent) 2 parts, RD-1050H water-reducible polyester resin 22.5 parts successively, R-902 titanium dioxide 20 parts, 801A process white 10 parts is added again after stirring, continue to stir, enter sand mill and be ground to fineness≤20um;
Solution qualified for fineness is drawn back and joins in paint cylinder, again under 500r/min agitation condition, add RD-1050H water-reducible polyester resin 22.5 parts, SF-9090 water-based flow agent (waterborne organic silicon flow agent) 1 part, the agent 0.6 part of RAYBO-60 anti-sudden strain of a muscle rust, 10 parts, M-03 aminoresin, stir again 30min white water-borne metallic packing pail divides colored paint, whole production process controls below 50 DEG C.
This white water-borne metallic packing pail divides colored paint, and be sprayed on the tinplate of cleaning, polishing, after 160 DEG C/10min is dried, test performance is in table 1.
Embodiment 2
Light yellow metallic packing pail divides a preparation method for colored paint, comprises the steps:
Under 500r/min agitation condition, join in paint cylinder and add deionized water 20 parts, BYK-020 (defoamer) 0.2 part, BYK-190 (dispersion agent) 2 parts, RD-1050H water-reducible polyester resin 22.5 parts successively, R-902 titanium dioxide 20 parts, 801A process white 10 parts, OP-206 permanent yellow 0.5 part is added again after stirring, continue to stir, enter sand mill and be ground to fineness≤20um;
Solution qualified for fineness is drawn back and joins in paint cylinder, again under 500r/min agitation condition, add RD-1050H water-reducible polyester resin 22.5 parts, SF-9090 water-based flow agent (waterborne organic silicon flow agent) 1 part, the agent 0.6 part of RAYBO-60 anti-sudden strain of a muscle rust, 10 parts, M-03 aminoresin, stir again 30min light yellow water-based metal pail pack divides colored paint, whole production process controls below 50 DEG C.
This light yellow water-based metal pail pack divides colored paint, and be sprayed on the tinplate of cleaning, polishing, after 160 DEG C/10min is dried, test performance is in table 1.
Table 1: light water-based metal pail pack divides colored paint detected result
Embodiment 3
In blue water-based metallic packing pail divide the preparation method of colored paint, comprise the steps:
Under 500r/min agitation condition, join in paint cylinder and add deionized water 20 parts, BYK-020 (defoamer) 0.2 part, BYK-190 (dispersion agent) 3 parts, RD-1050H water-reducible polyester resin 22.5 parts successively, R-902 titanium dioxide 10 parts, 801A process white 10 parts, 15:3 phthalocyanine blue 10 parts is added again after stirring, continue to stir, enter sand mill and be ground to fineness≤20um;
Solution qualified for fineness is drawn back and joins in paint cylinder, again under 500r/min agitation condition, add RD-1050H water-reducible polyester resin 22.5 parts, the agent 0.6 part of flow agent DAPRO U-99 (water soluble acrylic acid flow agent) 1 part, RAYBO-60 anti-sudden strain of a muscle rust, 10 parts, M-03 aminoresin, stir again 30min in blue water-based metallic packing pail divide colored paint, whole production process controls below 50 DEG C.
In this, blue water-based metallic packing pail divides colored paint, and be sprayed on the tinplate of cleaning, polishing, after 160 DEG C/10min is dried, test performance is in table 2.
Embodiment 4
Green water-based metal pail pack divides a preparation method for colored paint, comprises the steps:
Under 500r/min agitation condition, join in paint cylinder and add deionized water 20 parts, BYK-020 (defoamer) 0.2 part, BYK-190 (dispersion agent) 3 parts, RD-1050H water-reducible polyester resin 22.5 parts successively, R-902 titanium dioxide 10 parts, 801A process white 10 parts, phthalocyanine green 10 parts is added again after stirring, continue to stir, enter sand mill and be ground to fineness≤20um;
Solution qualified for fineness is drawn back and joins in paint cylinder, again under 500r/min agitation condition, add RD-1050H water-reducible polyester resin 22.5 parts, the agent 0.6 part of flow agent DAPRO U-99 (water soluble acrylic acid flow agent) 1 part, RAYBO-60 anti-sudden strain of a muscle rust, 10 parts, M-03 aminoresin, stir again 30min Green water-based metal pail pack divides colored paint, whole production process controls below 50 DEG C.
This Green water-based metal pail pack divides colored paint, and be sprayed on the tinplate of cleaning, polishing, after 160 DEG C/10min is dried, test performance is in table 2.
Table 2: dark water-based metal pail pack divides colored paint detected result
Conclusion: embodiment 1,2,3,4 color paint is through color separation construction application, and meet a point color standard, its physical and chemical index reaches the standard-required of solvent-based paints completely.
Embodiment 1,3 water-based metal pail pack divides colored paint, very clear in the wet line of delimitation touching two kinds of colors in wet spraying process, do not interpenetrate, and the hardness of paint film, sticking power, tint retention, resistance to acids and bases, oil-proofness and non-corrosibility reach solvent-based paints standard completely.
Embodiment 2,4 water-based metal pail pack divides colored paint, very clear in the wet line of delimitation touching two kinds of colors in wet spraying process, do not interpenetrate, and the hardness of paint film, sticking power, tint retention, resistance to acids and bases, oil-proofness and non-corrosibility reach solvent-based paints standard completely.
Number mentioned in embodiment 1-4 is parts by weight.
Raw material supply company involved in embodiment of the present invention 1-4 is:
SF-9090 water-based flow agent-Guangdong Biaomei Silicon and Fluoride New Materials Co., Ltd.;
This ELEMENTIS of flow agent DAPRO U-99-hamming;
BYK-020 defoamer-German Bi Ke company;
BYK-190 dispersion agent-German Bi Ke company;
15:3 phthalocyanine blue-Tianjin Ran Huaba factory;
R-902 titanium dioxide-Dupont;
Innovative material company limited is closed in 801A-process white-Hunan;
Phthalocyanine green-Zhejiang Prov Baihe Chemical Holding Group Co., Ltd;
OP-206 permanent yellow-Zhejiang Prov Baihe Chemical Holding Group Co., Ltd;
RD-1050H water-reducible polyester resin-Anshan Runde Fine Chemicals Co., Ltd.;
M-03 aminoresin-Korea S Shanghai eight common root International Trading Company Ltd.
Claims (6)
1. water-based metal pail pack divides a colored paint, it is characterized in that: this color separation enamel-cover draws together dark-colored paint and tinted paint: this tinted paint is prepared by the raw material comprising following parts by weight: deionized water 15 ~ 20 parts, defoamer 0.1 ~ 0.5 part, dispersion agent 2 ~ 5 parts, water-reducible polyester resin 40 ~ 60 parts, titanium dioxide 15 ~ 20 parts, permanent yellow 0 ~ 2 part, process white 5 ~ 15 parts, waterborne organic silicon flow agent 0.5 ~ 1 part, anti-sudden strain of a muscle rust agent 0.5 ~ 1 part and water-compatible amino resin 5 ~ 15 parts; This dark-colored paint is prepared by the raw material comprising following parts by weight: the one 5 ~ 10 parts in deionized water 15 ~ 20 parts, defoamer 0.1 ~ 0.5 part, dispersion agent 2 ~ 5 parts, water-reducible polyester resin 40 ~ 60 parts, titanium dioxide 0 ~ 10 part, process white 5 ~ 15 parts, phthalocyanine blue or phthalocyanine green, water soluble acrylic acid flow agent 0.5 ~ 1 part, anti-sudden strain of a muscle rust agent 0.5 ~ 1 part and water-compatible amino resin 5 ~ 15 parts.
2. water-based metal pail pack divides colored paint according to claim 1, it is characterized in that: described tinted paint is prepared by the method comprised the steps: (1) by material deionized water 15 ~ 20 parts, defoamer 0.1 ~ 0.5 part, dispersion agent 2 ~ 5 parts, water-reducible polyester resin 20 ~ 30 parts, titanium dioxide 15 ~ 20 parts, permanent yellow 0 ~ 2 part, process white 5 ~ 15 parts, add join paint cylinder in stir; (2) step (1) gained solution is ground to fineness≤20 μm by shredder, then solution is drawn back join paint cylinder in; (3) under agitation, join in paint cylinder and add material water-reducible polyester resin 20 ~ 30 parts, waterborne organic silicon flow agent 0.5 ~ 1 part, the agent 0.5 ~ 1 part of anti-sudden strain of a muscle rust, water-compatible amino resin 5 ~ 15 parts successively, stir; (4) filtered by step (3) gained solution, equivalent is packed, i.e. obtained tinted paint.
3. according to claim 1 or 2, water-based metal pail pack divides colored paint, it is characterized in that: described dark-colored paint is prepared by the method comprised the steps: (1) by the one 5 ~ 10 parts in material deionized water 15 ~ 20 parts, defoamer 0.1 ~ 0.5 part, dispersion agent 2 ~ 5 parts, water-reducible polyester resin 20 ~ 30 parts, titanium dioxide 0 ~ 10 part, process white 5 ~ 15 parts, phthalocyanine blue or phthalocyanine green, add join paint cylinder in stir; (2) step (1) gained solution is ground to fineness≤20 μm by shredder, then solution is drawn back join paint cylinder in; (3) under agitation, join in paint cylinder and add material water-reducible polyester resin 20 ~ 30 parts, water soluble acrylic acid flow agent 0.5 ~ 1 part, anti-sudden strain of a muscle rust agent 0.5 ~ 1 part, water-compatible amino resin 5 ~ 15 parts successively, stir; (4) filtered by step (3) gained solution, equivalent is packed, i.e. obtained dark-colored paint.
4. water-based metal pail pack divides a preparation method for colored paint, it is characterized in that: this water-based metal pail pack color separation enamel-cover draws together dark-colored paint and tinted paint:
The preparation method of this tinted paint, comprise the steps: (1) by material deionized water 15 ~ 20 parts, defoamer 0.1 ~ 0.5 part, dispersion agent 2 ~ 5 parts, water-reducible polyester resin 20 ~ 30 parts, titanium dioxide 15 ~ 20 parts, permanent yellow 0 ~ 2 part, process white 5 ~ 15 parts, add join paint cylinder in stir; (2) step (1) gained solution is ground to fineness≤20 μm by shredder, then solution is drawn back join paint cylinder in; (3) under agitation, join in paint cylinder and add material water-reducible polyester resin 20 ~ 30 parts, waterborne organic silicon flow agent 0.5 ~ 1 part, the agent 0.5 ~ 1 part of anti-sudden strain of a muscle rust, water-compatible amino resin 5 ~ 15 parts successively, stir; (4) filtered by step (3) gained solution, equivalent is packed, i.e. obtained tinted paint;
The preparation method of this dark-colored paint, comprise the steps: (1) by the one 5 ~ 10 parts in material deionized water 15 ~ 20 parts, defoamer 0.1 ~ 0.5 part, dispersion agent 2 ~ 5 parts, water-reducible polyester resin 20 ~ 30 parts, titanium dioxide 0 ~ 10 part, process white 5 ~ 15 parts, phthalocyanine blue or phthalocyanine green, add join paint cylinder in stir; (2) step (1) gained solution is ground to fineness≤20 μm by shredder, then solution is drawn back join paint cylinder in; (3) under agitation, join in paint cylinder and add material water-reducible polyester resin 20 ~ 30 parts, water soluble acrylic acid flow agent 0.5 ~ 1 part, anti-sudden strain of a muscle rust agent 0.5 ~ 1 part, water-compatible amino resin 5 ~ 15 parts successively, stir; (4) filtered by step (3) gained solution, equivalent is packed, i.e. obtained dark-colored paint.
5. water-based metal pail pack divides the preparation method of colored paint according to claim 4, it is characterized in that: the whole production process of described dark-colored paint and tinted paint controls below 50 DEG C.
6. water-based metal pail pack divides the preparation method of colored paint according to claim 4, it is characterized in that: the water-reducible polyester resin consumption equivalent of step (1) and step (3) in the preparation process of described dark-colored paint and tinted paint.
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CN102181220A (en) * | 2011-01-19 | 2011-09-14 | 天津滨新涂料有限公司 | Novel environment-friendly waterborne baking varnish for coiled material |
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DE19512428A1 (en) * | 1995-04-03 | 1996-10-10 | Wacker Chemie Gmbh | Organopolysiloxane / cyclodextrin complexes, their preparation and their use as additives in coating compositions |
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CN101139499A (en) * | 2007-10-29 | 2008-03-12 | 姚海军 | Aqueous automobile framework and automobile motorcycle wheel surface protection coating |
CN101575479A (en) * | 2009-06-02 | 2009-11-11 | 华南理工大学 | Mono-component aqueous metal baking paint and preparation method thereof |
CN102181220A (en) * | 2011-01-19 | 2011-09-14 | 天津滨新涂料有限公司 | Novel environment-friendly waterborne baking varnish for coiled material |
CN103160190A (en) * | 2011-12-08 | 2013-06-19 | 天津市新宇彩板有限公司 | Colorful steel plate paint containing polyacrylate levelling agent |
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