CN102167904B - 一种无卤阻燃纳米增强尼龙复合材料及其制备方法 - Google Patents
一种无卤阻燃纳米增强尼龙复合材料及其制备方法 Download PDFInfo
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- CN102167904B CN102167904B CN201110110736A CN201110110736A CN102167904B CN 102167904 B CN102167904 B CN 102167904B CN 201110110736 A CN201110110736 A CN 201110110736A CN 201110110736 A CN201110110736 A CN 201110110736A CN 102167904 B CN102167904 B CN 102167904B
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- halogen
- matrix material
- reinforced nylon
- nylon
- free flameproof
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- 239000004677 Nylon Substances 0.000 title claims abstract description 50
- 229920001778 nylon Polymers 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000003063 flame retardant Substances 0.000 title abstract description 35
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 31
- 239000002131 composite material Substances 0.000 title abstract description 5
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 14
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims abstract description 13
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims abstract description 13
- 229920002292 Nylon 6 Polymers 0.000 claims abstract description 7
- 229920002302 Nylon 6,6 Polymers 0.000 claims abstract description 7
- 239000000126 substance Substances 0.000 claims abstract description 5
- 238000012986 modification Methods 0.000 claims abstract description 3
- 230000004048 modification Effects 0.000 claims abstract description 3
- 239000011159 matrix material Substances 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 20
- 239000012752 auxiliary agent Substances 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 239000001205 polyphosphate Substances 0.000 claims description 17
- 235000011176 polyphosphates Nutrition 0.000 claims description 17
- 229920000877 Melamine resin Polymers 0.000 claims description 15
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 15
- 239000004615 ingredient Substances 0.000 claims description 14
- 239000003112 inhibitor Substances 0.000 claims description 12
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 239000011521 glass Substances 0.000 claims description 10
- 239000000314 lubricant Substances 0.000 claims description 9
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 9
- 229920002943 EPDM rubber Polymers 0.000 claims description 3
- 229920000577 Nylon 6/66 Polymers 0.000 claims description 3
- TZYHIGCKINZLPD-UHFFFAOYSA-N azepan-2-one;hexane-1,6-diamine;hexanedioic acid Chemical compound NCCCCCCN.O=C1CCCCCN1.OC(=O)CCCCC(O)=O TZYHIGCKINZLPD-UHFFFAOYSA-N 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical group [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 229920006124 polyolefin elastomer Polymers 0.000 claims description 3
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims 1
- 238000002203 pretreatment Methods 0.000 claims 1
- 238000012216 screening Methods 0.000 claims 1
- 238000010008 shearing Methods 0.000 claims 1
- 238000005303 weighing Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 20
- 229910052736 halogen Inorganic materials 0.000 abstract description 9
- 150000002367 halogens Chemical class 0.000 abstract description 9
- 238000002485 combustion reaction Methods 0.000 abstract description 8
- 239000002253 acid Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000005995 Aluminium silicate Substances 0.000 abstract 1
- 235000012211 aluminium silicate Nutrition 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000003365 glass fiber Substances 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 abstract 1
- 239000000779 smoke Substances 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 230000007613 environmental effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 239000003610 charcoal Substances 0.000 description 4
- 229920006351 engineering plastic Polymers 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
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Abstract
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CN201110110736A CN102167904B (zh) | 2011-04-29 | 2011-04-29 | 一种无卤阻燃纳米增强尼龙复合材料及其制备方法 |
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CN201110110736A CN102167904B (zh) | 2011-04-29 | 2011-04-29 | 一种无卤阻燃纳米增强尼龙复合材料及其制备方法 |
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CN102167904B true CN102167904B (zh) | 2012-10-10 |
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Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102417728B (zh) * | 2011-11-24 | 2014-01-22 | 上海日之升新技术发展有限公司 | 纳米阻燃pa66复合材料及其制备方法 |
CN103642208A (zh) * | 2013-11-18 | 2014-03-19 | 安徽宜万丰电器有限公司 | 一种汽车塑料件用纳米高岭土改性尼龙6材料 |
CN104072981A (zh) * | 2014-07-14 | 2014-10-01 | 苏州创佳塑胶有限公司 | 无卤阻燃聚酰胺材料及其制备方法 |
CN104130574A (zh) * | 2014-08-19 | 2014-11-05 | 南通瑞隆新材料有限公司 | 一种阻燃尼龙pa66改性工程塑料的制备方法 |
CN104448781B (zh) * | 2014-12-23 | 2017-04-19 | 上海至正道化高分子材料股份有限公司 | 一种电动汽车充电电缆用无卤阻燃电缆料及其制备方法 |
CN104974503A (zh) * | 2015-06-23 | 2015-10-14 | 苏州博利迈新材料科技有限公司 | 隔热型汽车用纳米pa复合材料及其制备方法 |
CN105670282A (zh) * | 2016-04-05 | 2016-06-15 | 南京利华工程塑料有限公司 | 高阻燃无卤非增强聚酰胺材料及其制备方法 |
CN106497039A (zh) * | 2016-11-04 | 2017-03-15 | 马鞍山市华能电力线路器材有限责任公司 | 一种疏水阻燃型玻纤增强pa66电力金具材料及其制备方法 |
CN107129679A (zh) * | 2017-05-16 | 2017-09-05 | 上海长园电子材料有限公司 | 增韧改性阻燃尼龙波纹管 |
CN107936297A (zh) * | 2017-11-22 | 2018-04-20 | 江苏利思德新材料有限公司 | 玻纤增强尼龙用无卤阻燃复配体系及其在无卤阻燃玻纤增强尼龙材料中的应用 |
CN114752212A (zh) * | 2022-05-23 | 2022-07-15 | 江苏瑞美福新材料有限公司 | 一种阻燃环保尼龙6改性材料 |
CN115124832A (zh) * | 2022-07-12 | 2022-09-30 | 湖北合聚新材料有限公司 | 无卤膨胀阻燃尼龙66组合物、尼龙66复合材料及其制备方法 |
CN116751450A (zh) * | 2023-06-02 | 2023-09-15 | 南京利华工程塑料有限公司 | 一种阻燃尼龙及其制备方法 |
Citations (1)
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CN101613527A (zh) * | 2009-07-29 | 2009-12-30 | 东莞市意普万工程塑料有限公司 | 一种耐醇解尼龙复合材料及其制备方法 |
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JP2004285176A (ja) * | 2003-03-20 | 2004-10-14 | Toray Ind Inc | オイル周り部品 |
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CN101613527A (zh) * | 2009-07-29 | 2009-12-30 | 东莞市意普万工程塑料有限公司 | 一种耐醇解尼龙复合材料及其制备方法 |
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Address after: 523808, Guangdong City, Dongguan province Songshan Lake Science and Technology Industrial Park, the northern industrial city small science and Technology Enterprise Park 4 Applicant after: Dongguan Epone Nylon Sci & Tech Co., Ltd. Address before: 523808, Guangdong City, Dongguan province Songshan Lake Science and Technology Industrial Park, the northern industrial city small science and Technology Enterprise Park 4 Applicant before: Dongguan Yipuwan Engineering Plastic Co., Ltd. |
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Free format text: CORRECT: APPLICANT; FROM: DONGGUAN EPONE ENGINEERING PLASTIC CO., LTD. TO: DONGGUAN EPONE NYLON SCI. + TECH. CO., LTD. |
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Address after: Room 312, ITT plant, No.5, Gongye North 4th Road, Songshanhu high tech Industrial Development Zone, Dongguan City, Guangdong Province Patentee after: Chendong Yipuwan New Materials (Guangdong) Co., Ltd. Address before: 523808, Guangdong City, Dongguan province Songshan Lake Science and Technology Industrial Park, the northern industrial city small science and Technology Enterprise Park 4 Patentee before: Dongguan Epone Nylon Sci & Tech Co., Ltd. |
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Effective date of registration: 20210903 Address after: No.12, jingsan Road, Zengjiang street, Zengcheng District, Guangzhou, Guangdong 511300 Patentee after: GUANGZHOU CHENDONG NEW MATERIALS Co.,Ltd. Patentee after: Chendong Yipuwan New Materials (Guangdong) Co.,Ltd. Address before: 523000 room 312, ITT workshop, No.5, Gongye North 4th Road, Songshanhu high tech Industrial Development Zone, Dongguan City, Guangdong Province Patentee before: Chendong Yipuwan New Materials (Guangdong) Co.,Ltd. |