CN102119197A - 一种不需要全氟化合物或不包含任何氟元素的超疏水气凝胶 - Google Patents
一种不需要全氟化合物或不包含任何氟元素的超疏水气凝胶 Download PDFInfo
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- CN102119197A CN102119197A CN200980125283XA CN200980125283A CN102119197A CN 102119197 A CN102119197 A CN 102119197A CN 200980125283X A CN200980125283X A CN 200980125283XA CN 200980125283 A CN200980125283 A CN 200980125283A CN 102119197 A CN102119197 A CN 102119197A
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- super
- gel
- hydrophobic
- polysilicates
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- 230000003075 superhydrophobic effect Effects 0.000 title claims abstract description 90
- 229910052731 fluorine Inorganic materials 0.000 title description 6
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 11
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- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 claims description 12
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- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
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- GLISZRPOUBOZDL-UHFFFAOYSA-N 3-bromopropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCBr GLISZRPOUBOZDL-UHFFFAOYSA-N 0.000 claims description 2
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 claims description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 2
- FPOSCXQHGOVVPD-UHFFFAOYSA-N chloromethyl(trimethoxy)silane Chemical compound CO[Si](CCl)(OC)OC FPOSCXQHGOVVPD-UHFFFAOYSA-N 0.000 claims description 2
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 claims description 2
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- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 2
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- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 claims description 2
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- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 30
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Applications Claiming Priority (3)
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| US7714508P | 2008-06-30 | 2008-06-30 | |
| US61/077145 | 2008-06-30 | ||
| PCT/US2009/049208 WO2010002859A2 (en) | 2008-06-30 | 2009-06-30 | A superhydrophobic aerogel that does not require per-fluoro compounds or contain any fluorine |
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| Publication Number | Publication Date |
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| CN102119197A true CN102119197A (zh) | 2011-07-06 |
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Country Status (8)
| Country | Link |
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| US (2) | US9040435B2 (https=) |
| EP (1) | EP2294152B1 (https=) |
| JP (1) | JP2011526835A (https=) |
| KR (1) | KR20110042268A (https=) |
| CN (1) | CN102119197A (https=) |
| AU (1) | AU2009267062A1 (https=) |
| CA (1) | CA2727920A1 (https=) |
| WO (1) | WO2010002859A2 (https=) |
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| CN106752214A (zh) * | 2017-01-13 | 2017-05-31 | 吉林大学 | 一种基于非连续性润湿性改良的仿生防结冰表面 |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1724353A (zh) * | 2005-07-15 | 2006-01-25 | 清华大学 | 以稻壳灰为原料制备疏水性二氧化硅气凝胶的方法 |
| CN1865136A (zh) * | 2005-05-19 | 2006-11-22 | 同济大学 | 表面活性可调的纳米多孔二氧化硅气凝胶及其制备方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA823554B (en) * | 1981-06-19 | 1983-03-30 | Dow Corning Ltd | Siloxane compositions and process for treatment of materials |
| JPS59170157A (ja) * | 1983-03-18 | 1984-09-26 | Toray Silicone Co Ltd | プライマ−組成物 |
| US4701508A (en) | 1984-12-14 | 1987-10-20 | Mitsui Sekiyu Kagaku Kogyo Kabushiki Kaisha | Solvent soluble fluorine-containing polymer, coating composition containing the same and coating process thereof |
| JP4772953B2 (ja) * | 2000-09-08 | 2011-09-14 | 東レ・ダウコーニング株式会社 | 水性塗料組成物、およびその製造方法 |
| JP2004527626A (ja) * | 2001-05-01 | 2004-09-09 | ダウ・コ−ニング・コ−ポレ−ション | 保護コーティング組成物 |
| JP4947855B2 (ja) * | 2001-07-31 | 2012-06-06 | 東レ・ダウコーニング株式会社 | 皮膜形成性シリコーン樹脂組成物 |
| EP1479738A1 (en) * | 2003-05-20 | 2004-11-24 | DSM IP Assets B.V. | Hydrophobic coatings comprising reactive nano-particles |
| JP4384898B2 (ja) | 2003-11-28 | 2009-12-16 | 日油株式会社 | 撥水撥油性被膜の製造方法 |
| EP1717278A1 (en) * | 2005-04-26 | 2006-11-02 | Nuplex Resins B.V. | Coated particles and coating compositions comprising coated particles |
| JP4953426B2 (ja) | 2005-06-09 | 2012-06-13 | ペンタックスリコーイメージング株式会社 | シリカエアロゲル膜の製造方法 |
| US20060292345A1 (en) * | 2005-06-14 | 2006-12-28 | Dave Bakul C | Micropatterned superhydrophobic silica based sol-gel surfaces |
| BRPI0808993B1 (pt) | 2007-03-16 | 2018-12-04 | Cabot Corp | método de fabricação de partículas de aerogel |
| CN102119197A (zh) * | 2008-06-30 | 2011-07-06 | Stc.Unm公司 | 一种不需要全氟化合物或不包含任何氟元素的超疏水气凝胶 |
-
2009
- 2009-06-30 CN CN200980125283XA patent/CN102119197A/zh active Pending
- 2009-06-30 EP EP20090774310 patent/EP2294152B1/en not_active Not-in-force
- 2009-06-30 WO PCT/US2009/049208 patent/WO2010002859A2/en not_active Ceased
- 2009-06-30 KR KR1020107029367A patent/KR20110042268A/ko not_active Withdrawn
- 2009-06-30 AU AU2009267062A patent/AU2009267062A1/en not_active Abandoned
- 2009-06-30 CA CA2727920A patent/CA2727920A1/en not_active Abandoned
- 2009-06-30 JP JP2011516803A patent/JP2011526835A/ja active Pending
- 2009-06-30 US US13/121,166 patent/US9040435B2/en not_active Expired - Fee Related
-
2015
- 2015-04-03 US US14/678,533 patent/US20150240123A1/en not_active Abandoned
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1865136A (zh) * | 2005-05-19 | 2006-11-22 | 同济大学 | 表面活性可调的纳米多孔二氧化硅气凝胶及其制备方法 |
| CN1724353A (zh) * | 2005-07-15 | 2006-01-25 | 清华大学 | 以稻壳灰为原料制备疏水性二氧化硅气凝胶的方法 |
Non-Patent Citations (2)
| Title |
|---|
| 李伟: "溶胶-凝胶法制备二氧化硅气凝胶纳米材料的研究", 《中国优秀博硕士学位论文全文数据库（硕士） 工程科技I辑》 * |
| 陈一民等: "SiO2气凝胶制备及疏水改性研究", 《宇航材料工艺》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643029A (zh) * | 2012-04-24 | 2012-08-22 | 奇瑞汽车股份有限公司 | 憎水修饰剂及其修饰的憎水玻璃、憎水玻璃的制备方法 |
| CN106752214A (zh) * | 2017-01-13 | 2017-05-31 | 吉林大学 | 一种基于非连续性润湿性改良的仿生防结冰表面 |
| CN106752214B (zh) * | 2017-01-13 | 2020-01-31 | 吉林大学 | 一种基于非连续性润湿性改良的仿生防结冰表面 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2011526835A (ja) | 2011-10-20 |
| US20150240123A1 (en) | 2015-08-27 |
| KR20110042268A (ko) | 2011-04-26 |
| EP2294152A2 (en) | 2011-03-16 |
| AU2009267062A1 (en) | 2010-01-07 |
| EP2294152A4 (en) | 2011-06-29 |
| WO2010002859A3 (en) | 2010-05-14 |
| US9040435B2 (en) | 2015-05-26 |
| US20120040577A1 (en) | 2012-02-16 |
| CA2727920A1 (en) | 2010-01-07 |
| WO2010002859A2 (en) | 2010-01-07 |
| EP2294152B1 (en) | 2012-11-14 |
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