CN102113133B - 光伏玻璃叠层制品和层状制品 - Google Patents

光伏玻璃叠层制品和层状制品 Download PDF

Info

Publication number
CN102113133B
CN102113133B CN200980126048.4A CN200980126048A CN102113133B CN 102113133 B CN102113133 B CN 102113133B CN 200980126048 A CN200980126048 A CN 200980126048A CN 102113133 B CN102113133 B CN 102113133B
Authority
CN
China
Prior art keywords
equal
glassy layer
photovoltaic
less
glass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN200980126048.4A
Other languages
English (en)
Other versions
CN102113133A (zh
Inventor
D·F·道森-埃利
S·E·德马蒂诺
L·L·赫路克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Corning Inc
Original Assignee
Corning Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Corning Inc filed Critical Corning Inc
Publication of CN102113133A publication Critical patent/CN102113133A/zh
Application granted granted Critical
Publication of CN102113133B publication Critical patent/CN102113133B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02—Details
    • H01L31/0216—Coatings
    • H01L31/02161—Coatings for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02167—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10082—Properties of the bulk of a glass sheet
    • B32B17/101—Properties of the bulk of a glass sheet having a predetermined coefficient of thermal expansion [CTE]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10082—Properties of the bulk of a glass sheet
    • B32B17/10091—Properties of the bulk of a glass sheet thermally hardened
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10082—Properties of the bulk of a glass sheet
    • B32B17/10119—Properties of the bulk of a glass sheet having a composition deviating from the basic composition of soda-lime glass, e.g. borosilicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/0004—Cutting, tearing or severing, e.g. bursting; Cutter details
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06—Joining glass to glass by processes other than fusing
    • C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/0256—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
    • H01L31/0264—Inorganic materials
    • H01L31/028—Inorganic materials including, apart from doping material or other impurities, only elements of Group IV of the Periodic System
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/0256—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
    • H01L31/0264—Inorganic materials
    • H01L31/0296—Inorganic materials including, apart from doping material or other impurities, only AIIBVI compounds, e.g. CdS, ZnS, HgCdTe
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/036—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/036—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes
    • H01L31/0392—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes including thin films deposited on metallic or insulating substrates ; characterised by specific substrate materials or substrate features or by the presence of intermediate layers, e.g. barrier layers, on the substrate
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/036—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes
    • H01L31/0392—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes including thin films deposited on metallic or insulating substrates ; characterised by specific substrate materials or substrate features or by the presence of intermediate layers, e.g. barrier layers, on the substrate
    • H01L31/03923—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes including thin films deposited on metallic or insulating substrates ; characterised by specific substrate materials or substrate features or by the presence of intermediate layers, e.g. barrier layers, on the substrate including AIBIIICVI compound materials, e.g. CIS, CIGS
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042—PV modules or arrays of single PV cells
    • H01L31/0445—PV modules or arrays of single PV cells including thin film solar cells, e.g. single thin film a-Si, CIS or CdTe solar cells
    • H01L31/046—PV modules composed of a plurality of thin film solar cells deposited on the same substrate
    • H01L31/0468—PV modules composed of a plurality of thin film solar cells deposited on the same substrate comprising specific means for obtaining partial light transmission through the module, e.g. partially transparent thin film solar modules for windows
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042—PV modules or arrays of single PV cells
    • H01L31/048—Encapsulation of modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/006—Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00—Integration of renewable energy sources in buildings
    • Y02B10/10—Photovoltaic [PV]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/541—CuInSe2 material PV cells

Landscapes

  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Inorganic Chemistry (AREA)
  • Sustainable Energy (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Photovoltaic Devices (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

本发明描述了用于例如光伏器件的叠层制品和层状制品，例如低碱玻璃和/或低钠的叠层制品和层状制品。

Description

光伏玻璃叠层制品和层状制品
本专利申请要求2008年5月30日提交的美国临时专利申请第61/057344号的优先权。
背景技术
技术领域
本发明的实施方式涉及叠层制品和层状制品，更具体来说涉及可以用于例如光伏器件的低碱玻璃和/或低钠的叠层制品和层状制品。
背景技术
光伏器件中对自然光的控制和利用是一个问题，例如如何最大程度提高光伏器件的效率。
光伏器件必须满足一些安全标准，经历一些机械强度测试，例如碎屑冲击测试和破裂后的弯曲循环。如果能够提高机械强度，光伏器件可以从中获益，例如能够耐受环境条件。
用于光伏应用的功能材料通常被施加于钠钙玻璃基板。在一些应用中，通常对基板涂覆阻挡层，以尽可能减少碱金属(例如钠)从基板扩散入功能材料中的问题。但是，阻挡层中的任何破裂，例如划痕，都会使得钠或碱金属能够进入功能材料中，这取决于功能材料的组成，会影响所述功能材料的应用。钠钙玻璃中的缺陷，例如气泡、划痕、夹杂物，也会影响功能材料的应用。
玻璃强度可能取决于所处的温度、长宽比、板尺寸、刚度和负荷持续时间。可以通过退火、热强化和/或完全回火制备叠层玻璃，以获得另外的优点，例如提高的抗弯曲负荷能力，提高的抗冲性或提高的抗热应力能力。
优选能够获得具有以下性质的叠层制品和层状制品：其中可以尽可能减少或预期或控制碱金属扩散和/或钠扩散，并且能够尽可能提高机械强度。
发明概述
叠层制品和层状制品能够解决上述常规的叠层制品和层状制品的一个或多个缺点，并且能够提供以下的一个或多个优点：尽可能减少或预期或控制碱金属和/或钠从玻璃扩散入功能材料，减少玻璃中的缺陷，增大透明度并且尽可能减轻重量。
一个实施方式涉及一种制品，其包含：
应变点等于或高于500℃的玻璃层；
设置在所述玻璃层上的光伏功能材料；
基板，其包含玻璃、聚合物、或它们的组合，基板的厚度大于所述玻璃层的厚度；以及
设置在所述基板与玻璃层之间或者基板与光伏功能材料之间的叠置层。
在以下的详细描述中提出了本发明的附加特征和优点，其中的部分特征和优点对本领域的普通技术人员而言由所述内容而容易理解，或按文字描述和其权利要求书以及附图中所述实施本发明而被认识。
应理解前面的一般性描述和以下的详细描述都只是对本发明的示例，用来提供理解要求保护的本发明的性质和特性的总体评述或框架。
包括的附图提供了对本发明的进一步理解，附图被结合在本说明书中并构成说明书的一部分。附图图示说明了本发明的一个或多个实施方式，并与说明书一起用来说明本发明的原理和操作。
附图简要说明
仅通过以下详述或与附图一起可更好地理解本发明。
图1是根据本发明一个实施方式的制品的示意图。
图2是根据本发明一个实施方式的制品的示意图。
图3是根据本发明一个实施方式的制品的示意图。
发明详述
下面详细参考本发明的各种实施方式，这些实施方式的例子在附图中示出。只要可能，在所有附图中使用相同的附图标记来表示相同或类似的部分。
在本文中，根据光伏电池的结构，术语“基板”可以用来描述基板或者覆板(superstrate)。例如，如果当所述基板在组装入光伏电池的时候，位于光伏电池的光入射侧，则所述基板是覆板。所述覆板可以为光伏材料提供保护，使其免受冲击和环境降解，同时允许太阳光谱中合适的波长透过。另外，可以将多个光伏电池设置成光伏模块。光伏器件可以表示电池、模块、或同时包括此二者。
图1和图2所示的一个实施方式分别为制品100和200，其包含：
应变点等于或高于500℃的玻璃层12；
设置在所述玻璃层上的光伏功能材料10；
基板16，其包含玻璃、聚合物、或它们的组合，基板的厚度大于所述玻璃层的厚度；以及
设置在所述基板与玻璃层之间或者基板与光伏功能材料之间的叠置层14。
根据一些实施方式，所述玻璃层的厚度等于或小于4.0毫米，例如等于或小于3.5毫米，例如等于或小于3.2毫米，例如等于或小于3.0毫米，例如等于或小于2.5毫米，例如等于或小于2.0毫米，例如等于或小于1.9毫米，例如等于或小于1.8毫米，例如等于或小于1.5毫米，例如等于或小于1.1毫米，例如0.5-2.0毫米，例如0.5-1.1毫米，例如0.7-1.1毫米。尽管有一些示例性的厚度，但是玻璃层的厚度可以包括0.1毫米至最高达4.0毫米(包括4.0毫米)范围内任意小数的数值。
在一个实施方式中，所述玻璃层是可卷起的。在一个实施方式中，所述玻璃是可下拉的。例如，所述玻璃可以狭缝拉制或熔融拉制。根据另一个实施方式，所述玻璃可以通过浮法成形。
所述玻璃层的性质，例如可成形性，CTE，应变点，将取决于玻璃的组成。
在一个实施方式中，所述玻璃层的应变点等于或高于500℃，例如等于或高于540℃，或例如为500-600℃。
所述玻璃层可以具有较低的热膨胀系数(CTE)，例如等于或小于50×10-7/℃，例如等于或小于35×10-7/℃。根据一个实施方式，所述玻璃层的CTE为20×10-7/℃至50×10-7/℃，例如为20×10-7/℃至35×10-7/℃。在一个实施方式中，所述玻璃层的热膨胀系数为30×10-7/℃至90×10-7/℃。在一些实施方式中，所述玻璃的热膨胀系数等于或大于50×10-7，例如等于或大于60×10-7，例如等于或大于70×10-7，例如等于或大于80×10-7。在一个实施方式中，所述玻璃的应变点为50×10-7至90×10-7。
在一个实施方式中，所述光伏功能材料包含二硒化铜铟镓(CIGS)。在一个实施方式中，所述光伏功能材料包含二硒化铜铟镓(GIGS)，玻璃层的热膨胀系数为30×10-7/℃至90×10-7/℃。
在一个实施方式中，所述玻璃层的热膨胀系数为60×10-7/℃至90×10-7/℃。
在一个实施方式中，所述光伏功能材料包括碲化镉。在一个实施方式中，所述光伏功能材料包含碲化镉，玻璃层的热膨胀系数为60×10-7/℃至90×10-7/℃。
在一个实施方式中，所述玻璃层的热膨胀系数为30×10-7/℃至60×10-7/℃。
在一个实施方式中，所述玻璃层是透明的。
在一些实施方式中，所述叠置层可以包含选自以下的材料：聚乙烯醇缩丁醛，可UV固化的树脂，热塑性塑料，热塑性离子型塑料，聚碳酸酯，聚氨酯，可UV固化的聚合物，硅酮，以及它们的组合。
在一个实施方式中，所述光伏功能材料包括硅。所述硅可以是晶态的、纳米晶体，无定形的，或者这些情况的组合。
在一个实施方式中，所述基板是透明的。
另一个实施方式涉及一种制品，其包含：
透明玻璃层，其包含等于或小于10重量％的碱金属氧化物，所述透明玻璃层的厚度为0.5-4毫米；
设置在所述透明玻璃层上的光伏功能材料；
基板，其包含玻璃、聚合物、或它们的组合，基板的厚度大于所述透明玻璃层的厚度；以及
叠置层，其包含选自以下的材料：聚乙烯醇缩丁醛，可UV固化的树脂，热塑性塑料，热塑性离子型塑料，聚碳酸酯，聚氨酯，可UV固化的聚合物，硅酮，以及它们的组合，所述叠置层设置在所述基板与透明玻璃层之间或者基板与光伏功能材料之间。
另一个实施方式涉及一种制品，其包含：
透明玻璃层，其包含等于或小于10重量％的氧化钠，所述透明玻璃层的厚度为0.5-4毫米；
设置在所述透明玻璃层上的光伏功能材料；
基板，其包含玻璃、聚合物、或它们的组合，基板的厚度大于所述透明玻璃层的厚度；以及
叠置层，其包含选自以下的材料：聚乙烯醇缩丁醛，可UV固化的树脂，热塑性塑料，热塑性离子型塑料，聚碳酸酯，聚氨酯，可UV固化的聚合物，硅酮，以及它们的组合，所述叠置层设置在所述基板与透明玻璃层之间或者基板与光伏功能材料之间。
根据一个实施方式，所述基板包含玻璃、聚合物或它们的组合。例如所述基板可以包含选自以下的材料：浮法玻璃、可熔融成形的玻璃、钠钙玻璃、塑料、聚碳酸酯、以及它们的组合。
所述光伏功能材料可包括单层或多层。所述光伏功能材料可以包括多层，例如一个或多个电极层，一个或多个对电极层，一个或多个离子传导层。在一些实施方式中，所述层可以包含固体无机材料。
根据一个实施方式，所述玻璃层中的碱金属氧化物含量为25重量％，例如等于或小于10重量％，例如等于或小于9重量％，例如等于或小于8重量％，例如等于或小于5重量％，例如等于或小于0.5重量％。在一个实施方式中，所述碱金属氧化物的含量为0.1-10％。尽管有一些示例性的碱金属氧化物含量，但是玻璃层的碱金属氧化物含量可以包括0至最高达10重量％(包括10重量％)范围内任意小数的数值。
根据一个实施方式，所述玻璃层中的氧化钠含量等于或小于10重量％，例如等于或小于9重量％，例如等于或小于8重量％，例如等于或小于5重量％，例如等于或小于0.5重量％。在一个实施方式中，所述氧化钠的含量为大于0重量％至10重量％，例如为0.1-10重量％。尽管有一些示例性的氧化钠含量，但是玻璃层的氧化钠含量可以包括0至最高达10重量％(包括10重量％)范围内任意小数的数值。
根据一些实施方式，所述制品的构型可以例如如图1和图2所示，但是，本发明也可以采用其它的构型。例如，所述叠置层可以设置在所述基板与玻璃层之间或者基板与光伏功能材料之间。
图3的另一个实施方式显示了一种制品300，其包括：玻璃层18，其应变点等于或高于500℃；设置在所述玻璃层上的光伏功能材料20；以及保护层22，该保护层设置在光伏材料的未与玻璃层接触的表面上。根据一个实施方式，所述制品还包括连接保护层和玻璃层的密封材料24，使得保护层、玻璃层和密封材料组合在一起，封闭所述光伏材料。所述密封材料可以选自玻璃料、玻璃片和溅射玻璃。所述密封材料与保护层和玻璃层组合起来，可以尽可能减少光伏功能材料在例如运输过程中、制造光伏器件过程中、以及/或者在最终产品(例如用于开/关电网中的建筑物内的光伏电池或光伏模块)中的时候，暴露于环境而带来的不利影响。
在此实施方式中，所述光伏功能材料可以包括多个层，例如一个或多个电极层，一个或多个对电极层，一个或多个半导体材料，碲化镉，CIGS，无定形硅和/或晶体硅层。在一些实施方式中，所述层可以包含固体无机材料。
在此实施方式中，所述玻璃层的厚度可以等于或小于4.0毫米，例如等于或小于3.5毫米，例如等于或小于3.2毫米，例如等于或小于3.0毫米，例如等于或小于2.5毫米，例如等于或小于2.0毫米，例如等于或小于1.9毫米，例如等于或小于1.8毫米，例如等于或小于1.5毫米，例如等于或小于1.1毫米，例如0.5-2.0毫米，例如0.5-1.1毫米，例如0.7-1.1毫米。尽管有一些示例性的厚度，但是玻璃层的厚度可以包括0.1毫米至最高达4.0毫米(包括4.0毫米)范围内任意小数的数值。
所述玻璃层可以具有较低的热膨胀系数(CTE)，例如等于或小于50×10-7/℃，例如等于或小于35×10-7/℃。根据一个实施方式，所述玻璃层的CTE为20×10-7/℃至50×10-7/℃，例如为20×10-7/℃至35×10-7/℃。在一个实施方式中，所述玻璃层的热膨胀系数为30×10-7/℃至90×10-7/℃。在一些实施方式中，所述玻璃的热膨胀系数等于或大于50×10-7，例如等于或大于60×10-7，例如等于或大于70×10-7，例如等于或大于80×10-7。在一个实施方式中，所述玻璃的应变点为50×10-7至90×10-7。
所述保护层可以提供化学耐久性或机械耐久性。所述保护层可以是溅射的玻璃层或玻璃片，例如透明的玻璃层或玻璃片。根据一些实施方式，所述保护层的厚度可以等于或小于4.0毫米，例如等于或小于3.5毫米，例如等于或小于3.2毫米，例如等于或小于3.0毫米，例如等于或小于2.5毫米，例如等于或小于2.0毫米，例如等于或小于1.9毫米，例如等于或小于1.8毫米，例如等于或小于1.5毫米，例如等于或小于1.1毫米，例如0.5-2.0毫米，例如0.5-1.1毫米，例如0.7-1.1毫米。尽管有一些示例性的厚度，但是保护层的厚度可以包括0.1毫米至最高达4.0毫米(包括4.0毫米)范围内任意小数的数值。
所述保护层可以具有较低的热膨胀系数(CTE)，例如等于或小于50×10-7/℃，例如等于或小于35×10-7/℃。根据一个实施方式，所述保护层的CTE为20×10-7/℃至50×10-7/℃，例如为20×10-7/℃至35×10-7/℃。在一个实施方式中，所述保护层的热膨胀系数为30×10-7/℃至90×10-7/℃。
在一些实施方式中，所述保护层是透明的。
将涂覆有材料的薄的低CTE的低碱或低钠玻璃与厚的钠钙玻璃层叠，能够进行工艺改进和尽可能降低成本。低CTE、低碱和/或低钠的玻璃是耐久性的，相对于钠钙玻璃具有更高的透明度，可以在制备的时候具有极少的缺陷，例如用于电视机的显示器玻璃应用。
根据一个实施方式，可以通过很多层叠方法中的一种，使用聚乙烯醇缩丁醛叠层将0.5-2.0毫米、例如0.7-1.1毫米的低CTE的低碱、例如低钠玻璃与小于6毫米的钠钙玻璃层叠。根据为了满足相关机械强度指标所需的强度，可以对所述钠钙玻璃进行退火、热强化(HS)和/或完全回火(FT)。
在此实施例中，钠钙玻璃提供了强度方面的效果，其可以被退火、热强化(通常退火玻璃的两倍强度)和/或完全回火(通常退火玻璃的四倍强度)，以提供额外的机械强度。低CTE、低碱(例如低钠)的玻璃通常仅能以退火的形式提供，因此在此实施例中，基板钠钙玻璃为叠置的制品提供提高的强度。
根据本发明，玻璃层提供了以下的一个或多个优点：低碱和/或低钠玻璃减少了对钠钙玻璃上阻挡层的需求(为了尽可能减少钠/碱金属扩散)；低碱或低钠玻璃提高了有机涂层或无机涂层的性能，例如光伏性能；低碱或低钠玻璃能够在高温下进行加工；低碱或低钠玻璃可以在涂覆之后进行切割。薄的低碱玻璃或低钠玻璃重量轻，尽可能减少了低CTE、低碱或低钠产品相关的成本。
叠层可以提供以下的一个或多个优点：耐候性/抗自然灾害能力，耐久性，设计灵活性，安装方便，以及制造方便。可以通过叠层来将薄玻璃与各种基板叠置。
本发明的叠层的制品和层状制品可以用于例如建筑物上的屋顶应用(商用和住家)以及开-关电网应用的光伏器件。
例如，所述叠层的制品和层状制品可以结合作为光伏器件的外部、中部或内部基板或覆板。
对本领域的普通技术人员而言，显而易见的是，可以在不偏离本发明的精神或范围的情况下对本发明进行各种修改和变动。因此，本发明意图覆盖对本发明的修改和变动，只要这些修改和变动在所附权利要求及其等同方案的范围之内即可。

Claims (5)

1.一种光伏制品，其包括:
应变点等于或高于500℃的玻璃层，所述玻璃层包含大于0到10重量％的碱金属氧化物;
设置在所述玻璃层上的光伏功能材料;
基板，其包含玻璃、聚合物、或它们的组合，基板的厚度大于所述玻璃层的厚度;以及
设置在所述基板与玻璃层之间或者基板与光伏功能材料之间的叠置层。
2.如权利要求1所述的光伏制品,其特征在于，所述玻璃层的应变点等于或高于540℃。
3.如权利要求1所述的光伏制品,其特征在于，所述玻璃层的热膨胀系数为30×10-7/℃至90×10-7/℃。
4.如权利要求1所述的光伏制品,其特征在于，所述玻璃层的氧化钠含量等于或小于10重量％。
5.一种光伏制品，其包括:
应变点等于或高于500℃的玻璃层，所述玻璃层包含大于0到10重量％的碱金属氧化物;
设置在所述玻璃层上的光伏功能材料;
保护层，其设置在所述光伏功能材料的未与玻璃层接触的表面上。
CN200980126048.4A 2008-05-30 2009-05-29 光伏玻璃叠层制品和层状制品 Active CN102113133B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US5734408P 2008-05-30 2008-05-30
US61/057,344 2008-05-30
PCT/US2009/003295 WO2009145909A1 (en) 2008-05-30 2009-05-29 Photovoltaic glass laminated articles and layered articles

Publications (2)

Publication Number Publication Date
CN102113133A CN102113133A (zh) 2011-06-29
CN102113133B true CN102113133B (zh) 2014-06-11

Family

ID=40875007

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200980126048.4A Active CN102113133B (zh) 2008-05-30 2009-05-29 光伏玻璃叠层制品和层状制品

Country Status (8)

Country Link
US (2) US20120037229A1 (zh)
EP (1) EP2311099A1 (zh)
JP (1) JP2011524270A (zh)
KR (1) KR20110021934A (zh)
CN (1) CN102113133B (zh)
AU (1) AU2009251825A1 (zh)
TW (1) TW201029194A (zh)
WO (1) WO2009145909A1 (zh)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9782949B2 (en) 2008-05-30 2017-10-10 Corning Incorporated Glass laminated articles and layered articles
ITCR20100013A1 (it) * 2010-04-21 2011-10-22 Marco Pietro Borrini Modulo fotovoltaico ventilato
WO2012102964A1 (en) * 2011-01-24 2012-08-02 Sage Electrochromics, Inc. Control system for electrochromic device
US20120192928A1 (en) * 2011-01-27 2012-08-02 Mark Francis Krol Laminated pv module package
US20120280368A1 (en) * 2011-05-06 2012-11-08 Sean Matthew Garner Laminated structure for semiconductor devices
BE1020460A3 (fr) * 2012-01-16 2013-10-01 Agc Glass Europe Vitrage photovoltaique.
KR101369166B1 (ko) * 2012-07-13 2014-03-24 한국에너지기술연구원 태양전지용 ｃｉｇｓ 광흡수층 형성 방법 및 ｃｉｇｓ 태양전지
US11352287B2 (en) 2012-11-28 2022-06-07 Vitro Flat Glass Llc High strain point glass
FR3012071B1 (fr) 2013-10-23 2021-01-01 Saint Gobain Verre feuillete mince
US11220076B2 (en) 2015-02-19 2022-01-11 Scienstry, Inc. Laminated switchable panel and methods for making and using
SG11201810963WA (en) 2016-06-08 2019-01-30 Agc Inc Light-dimming laminate and double glass
CN111788070A (zh) * 2018-03-05 2020-10-16 科思创德国股份有限公司 用于光透明解决方案的建筑构件

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4625070A (en) * 1985-08-30 1986-11-25 Atlantic Richfield Company Laminated thin film solar module
US4832755A (en) * 1987-08-11 1989-05-23 The Boeing Company Glass encapsulation of solar cell arrays to minimize voltage/plasma interaction effects in a space environment
US5059254A (en) * 1988-05-24 1991-10-22 Asahi Glass Company Ltd. Solar cell substrate and solar panel for automobile
US6329310B1 (en) * 1999-04-12 2001-12-11 Schott Glas Alkali-free aluminoborosilicate glass and uses thereof
DE10164273A1 (de) * 2001-12-27 2003-07-10 Solarwatt Solar Systeme Gmbh Photovoltaisches Solarmodul in Plattenform

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3671370A (en) * 1970-06-15 1972-06-20 Ppg Industries Inc Integral transparent safety glass armor unit
US4239555A (en) * 1979-07-30 1980-12-16 Mobil Tyco Solar Energy Corporation Encapsulated solar cell array
JPS5994882A (ja) * 1982-11-24 1984-05-31 Fuji Electric Corp Res & Dev Ltd 薄膜シリコン太陽電池
US4554259A (en) 1984-05-08 1985-11-19 Schott Glass Technologies, Inc. Low expansion, alkali-free borosilicate glass suitable for photomask applications
US4814297A (en) * 1987-04-01 1989-03-21 Corning Glass Works Strengthened glass article and method
JP2674087B2 (ja) * 1988-05-24 1997-11-05 旭硝子株式会社 曲面形状を有する太陽電池用ガラス基板及びその製造方法並びに太陽電池
US5557462A (en) * 1995-01-17 1996-09-17 Guardian Industries Corp. Dual silver layer Low-E glass coating system and insulating glass units made therefrom
US6061177A (en) * 1996-12-19 2000-05-09 Fujimoto; Kenneth Noboru Integrated computer display and graphical input apparatus and method
JPH11116258A (ja) * 1997-10-07 1999-04-27 Nippon Sheet Glass Co Ltd 合わせガラスおよびこれを用いたガラス窓構造
WO1999021707A1 (en) * 1997-10-24 1999-05-06 Agfa-Gevaert Naamloze Vennootschap A laminate comprising a thin borosilicate glass substrate as a constituting layer
US6287674B1 (en) 1997-10-24 2001-09-11 Agfa-Gevaert Laminate comprising a thin borosilicate glass substrate as a constituting layer
US6248948B1 (en) * 1998-05-15 2001-06-19 Canon Kabushiki Kaisha Solar cell module and method of producing the same
AU2001259451A1 (en) * 2000-05-04 2001-11-12 Schott Donnelly Llc Chromogenic glazing
WO2003068501A1 (en) * 2002-02-13 2003-08-21 Agp Europe Gmbh Anti spalling glass construction
US7176528B2 (en) * 2003-02-18 2007-02-13 Corning Incorporated Glass-based SOI structures
FR2857617B1 (fr) * 2003-07-16 2006-10-27 Saint Gobain Vitrage de securite fonctionnalise
DE102004022629B9 (de) * 2004-05-07 2008-09-04 Schott Ag Gefloatetes Lithium-Aluminosilikat-Flachglas mit hoher Temperaturbeständigkeit, das chemisch und thermisch vorspannbar ist und dessen Verwendung
JP2006049768A (ja) * 2004-08-09 2006-02-16 Showa Shell Sekiyu Kk Ｃｉｓ系化合物半導体薄膜太陽電池及び該太陽電池の光吸収層の製造方法
JP5101038B2 (ja) 2006-05-19 2012-12-19 株式会社フジクラ 電極基板の製造方法、電極基板の評価方法
JP5808069B2 (ja) * 2007-02-16 2015-11-10 日本電気硝子株式会社 太陽電池用ガラス基板
JP5158561B2 (ja) * 2007-04-13 2013-03-06 日本電気硝子株式会社 積層体及びそれを用いた太陽電池

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4625070A (en) * 1985-08-30 1986-11-25 Atlantic Richfield Company Laminated thin film solar module
US4832755A (en) * 1987-08-11 1989-05-23 The Boeing Company Glass encapsulation of solar cell arrays to minimize voltage/plasma interaction effects in a space environment
US5059254A (en) * 1988-05-24 1991-10-22 Asahi Glass Company Ltd. Solar cell substrate and solar panel for automobile
US6329310B1 (en) * 1999-04-12 2001-12-11 Schott Glas Alkali-free aluminoborosilicate glass and uses thereof
DE10164273A1 (de) * 2001-12-27 2003-07-10 Solarwatt Solar Systeme Gmbh Photovoltaisches Solarmodul in Plattenform

Also Published As

Publication number Publication date
KR20110021934A (ko) 2011-03-04
EP2311099A1 (en) 2011-04-20
CN102113133A (zh) 2011-06-29
AU2009251825A1 (en) 2009-12-03
WO2009145909A1 (en) 2009-12-03
JP2011524270A (ja) 2011-09-01
TW201029194A (en) 2010-08-01
US20160207289A1 (en) 2016-07-21
US20120037229A1 (en) 2012-02-16

Similar Documents

Publication Publication Date Title
CN102113133B (zh) 光伏玻璃叠层制品和层状制品
JP5620479B2 (ja) 積層ガラス板およびその使用
TWI497732B (zh) 物理鋼化玻璃、太陽能電池上蓋板、太陽能電池背板結構及太陽能電池板
KR20170118256A (ko) 박막 태양전지판 및 그 제조 방법
CN101552305A (zh) 薄膜光伏电池及其制造方法以及薄膜光电模块
CN102916067A (zh) 一种建材型双面玻璃光伏构件及其制造方法
CN202205777U (zh) 一种建材型双面玻璃光伏构件
WO2014180282A1 (zh) 太阳能汽车天窗及其制作方法
Blieske et al. Glass and other encapsulation materials
US20090205702A1 (en) Solar panel and associated method
CN105633182A (zh) 一种双玻璃光伏组件
KR20100006205A (ko) Ｃｉｇｓ 태양전지 모듈 및 그 제조방법
CN104134717B (zh) 太阳能电池组件的制造方法
CN102280505A (zh) 光伏模块的背板
TWI599059B (zh) 弧彎透光組件、其用途及其製作方法
JP2014068005A (ja) 太陽電池モジュール
CN206758445U (zh) 轻型自清洁光伏组件
WO2012127742A1 (ja) 太陽電池モジュールおよびその製造方法
US20140299180A1 (en) Multi-junction photovoltaic modules incorporating ultra-thin flexible glass
EP2383796A1 (en) Solar cell module
CN216450661U (zh) 光伏组件
CN208284485U (zh) 一种轻量化双面电池组件
CN210296395U (zh) 一种曲面太阳能天窗
JP4338159B2 (ja) 薄膜系太陽電池モジュール
Pern Pv module encapsulation–materials, process, and reliability

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant