CN102104154B - 含氮过渡金属微生物燃料电池催化剂及其制备方法 - Google Patents
含氮过渡金属微生物燃料电池催化剂及其制备方法 Download PDFInfo
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- CN102104154B CN102104154B CN2011100213678A CN201110021367A CN102104154B CN 102104154 B CN102104154 B CN 102104154B CN 2011100213678 A CN2011100213678 A CN 2011100213678A CN 201110021367 A CN201110021367 A CN 201110021367A CN 102104154 B CN102104154 B CN 102104154B
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- transition metal
- catalyst
- preparation
- fuel cell
- nitrogenous
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- 239000003054 catalyst Substances 0.000 title claims abstract description 32
- 229910052723 transition metal Inorganic materials 0.000 title claims abstract description 28
- -1 Nitrogenous transition metal Chemical class 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 230000000813 microbial effect Effects 0.000 title abstract description 5
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims abstract description 9
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims abstract description 6
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims abstract description 6
- 150000003624 transition metals Chemical class 0.000 claims abstract description 5
- 239000000446 fuel Substances 0.000 claims description 21
- 230000002906 microbiologic effect Effects 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 5
- 238000000197 pyrolysis Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims description 4
- 230000004913 activation Effects 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000002738 chelating agent Substances 0.000 claims description 4
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims description 4
- 239000000428 dust Substances 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000012018 catalyst precursor Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 230000009467 reduction Effects 0.000 abstract description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 8
- 239000001301 oxygen Substances 0.000 abstract description 8
- 229910052760 oxygen Inorganic materials 0.000 abstract description 8
- 239000007789 gas Substances 0.000 abstract description 7
- 230000003197 catalytic effect Effects 0.000 abstract description 6
- 239000013522 chelant Substances 0.000 abstract description 2
- 238000010668 complexation reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 238000005303 weighing Methods 0.000 description 6
- 229910052786 argon Inorganic materials 0.000 description 4
- 206010013786 Dry skin Diseases 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000008139 complexing agent Substances 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000008055 phosphate buffer solution Substances 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 238000004502 linear sweep voltammetry Methods 0.000 description 1
- 150000002678 macrocyclic compounds Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Catalysts (AREA)
Abstract
Description
Claims (1)
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Application Number | Priority Date | Filing Date | Title |
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CN2011100213678A CN102104154B (zh) | 2011-01-19 | 2011-01-19 | 含氮过渡金属微生物燃料电池催化剂及其制备方法 |
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CN2011100213678A CN102104154B (zh) | 2011-01-19 | 2011-01-19 | 含氮过渡金属微生物燃料电池催化剂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN102104154A CN102104154A (zh) | 2011-06-22 |
CN102104154B true CN102104154B (zh) | 2013-07-03 |
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CN2011100213678A Expired - Fee Related CN102104154B (zh) | 2011-01-19 | 2011-01-19 | 含氮过渡金属微生物燃料电池催化剂及其制备方法 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103170355B (zh) * | 2012-11-01 | 2015-10-21 | 周德璧 | 一种应用于空气电池的空气电极金属氮化物催化剂制备方法 |
CN110474059B (zh) * | 2018-05-11 | 2021-04-27 | 中国科学院化学研究所 | 一种固相宏量合成非贵金属氧还原催化剂的方法、催化剂及其应用 |
CN109107596A (zh) * | 2018-08-20 | 2019-01-01 | 河南师范大学 | 活性金属和氮元素共掺杂的碳纳米酶的制备方法及其作为纳米生物探针检测过氧化氢的应用 |
CN113178589B (zh) * | 2021-04-12 | 2022-08-16 | 武汉氢能与燃料电池产业技术研究院有限公司 | 一种微生物燃料电池阴极、其制备方法和微生物燃料电池 |
-
2011
- 2011-01-19 CN CN2011100213678A patent/CN102104154B/zh not_active Expired - Fee Related
Non-Patent Citations (3)
Title |
---|
Cicero W.B.Bezerra,et al..Novel carbon-supported Fe-N electrocatalysts synthesized through heat treatment of iron tripyridyl triazine complexes for the PEM fuel cell oxygen reduction reaction.《ElectrochimicaActa》.2008,第53卷7703-7710. * |
Hui-Juan Zhang,et al..Influence of heat treatment on the activity and structure of CoTETA/C catalysts for oxygen reduction reaction.《Electrochimica Acta》.2009,第55卷1107-1112. * |
Peter Aelterman,et al..Microbial fuel cells operated with iron-chelated air cathodes.《Electrochimica Acta》.2009,第54卷5754-5760. * |
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Inventor after: Huang Xia Inventor after: Wang Li Inventor after: Liang Peng Inventor after: Wei Jincheng Inventor after: Xia Xue Inventor after: Zhang Fang Inventor after: BRUCE E.LOGAN Inventor before: Huang Xia Inventor before: Wang Li Inventor before: Liang Peng Inventor before: Wei Jincheng |
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