CN102097592A - Laminated composite solar battery - Google Patents
Laminated composite solar battery Download PDFInfo
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- CN102097592A CN102097592A CN 201010562295 CN201010562295A CN102097592A CN 102097592 A CN102097592 A CN 102097592A CN 201010562295 CN201010562295 CN 201010562295 CN 201010562295 A CN201010562295 A CN 201010562295A CN 102097592 A CN102097592 A CN 102097592A
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- 239000002131 composite material Substances 0.000 title claims abstract description 13
- 239000010410 layer Substances 0.000 claims abstract description 112
- 239000004065 semiconductor Substances 0.000 claims abstract description 19
- 238000003475 lamination Methods 0.000 claims abstract description 18
- 239000012044 organic layer Substances 0.000 claims abstract description 12
- 230000007704 transition Effects 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims description 32
- 239000010409 thin film Substances 0.000 claims description 13
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 9
- 229910021417 amorphous silicon Inorganic materials 0.000 claims description 8
- 229920000547 conjugated polymer Polymers 0.000 claims description 8
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 229910003472 fullerene Inorganic materials 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000004020 conductor Substances 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 239000010931 gold Substances 0.000 claims description 4
- -1 poly oxide Substances 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 3
- 239000004642 Polyimide Substances 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- KTSFMFGEAAANTF-UHFFFAOYSA-N [Cu].[Se].[Se].[In] Chemical compound [Cu].[Se].[Se].[In] KTSFMFGEAAANTF-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 3
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 239000003973 paint Substances 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920001721 polyimide Polymers 0.000 claims description 3
- 229920001021 polysulfide Polymers 0.000 claims description 3
- 239000005077 polysulfide Substances 0.000 claims description 3
- 150000008117 polysulfides Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 238000009331 sowing Methods 0.000 claims description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 3
- 229910001887 tin oxide Inorganic materials 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 17
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000000758 substrate Substances 0.000 abstract description 2
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 239000002346 layers by function Substances 0.000 abstract 1
- 230000005693 optoelectronics Effects 0.000 description 6
- 238000010276 construction Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- GPXJNWSHGFTCBW-UHFFFAOYSA-N Indium phosphide Chemical compound [In]#P GPXJNWSHGFTCBW-UHFFFAOYSA-N 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Inorganic materials O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
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- Photovoltaic Devices (AREA)
Abstract
The invention discloses a laminated composite solar battery, which consists of eleven different functional layers, namely a transparent substrate, a cathode layer, a polar organic layer, a first light sensitive layer, a semi-transparent anode layer, a P-type semiconductor layer, a P-N transition layer, a N-type semiconductor layer, a transparent conductive layer, a second light sensitive layer and a non-conductive light reflecting layer, wherein the transparent anode layer is reticular; a plurality of ways, including the lamination of an organic solar battery and an inorganic solar battery, are simultaneously adopted for enhancing the photoelectric conversion efficiency of battery, thus the solar energy is fully utilized, the skillful lamination of the organic and inorganic solar batteries is realized, and production costs are equalized while the maximal photoelectric conversion efficiency is exerted; the structure of the second light sensitive layer and the non-conductive light reflecting layer is adopted for repeatedly making use of the sunlight, so secondary photoelectric conversion of the organic solar battery is reinforced and the conversion efficiency of the overall battery can reach over 35%.
Description
Technical field
The invention belongs to technical field of solar, particularly a kind of solar cell that adopts laminated construction to improve solar photovoltaic conversion efficient.
Background technology
Solar energy is desirable new forms of energy, it has inexhaustible advantage, also be clean energy resource simultaneously, do not produce any environmental pollution. in the middle of effective utilization of solar energy, big sun can opto-electronic conversion be with fastest developing speed, most active in the last few years research field.At present, solar cell mainly is divided into crystal silicon solar energy battery, inorganic thin film solar cell, organic solar batteries and DSSC.Wherein the crystal silicon solar energy battery electricity conversion is the highest, reaches 18%; The inorganic thin film solar cell is below 11%, and organic solar batteries is then at 6%-7%, but organic solar batteries has characteristics such as production technology is simple, the cost of raw material is cheap.
Chinese patent ZL200810051527.1 discloses a kind of stacking polymer thin-film solar cell of parallel-connection structure, and this solar cell adopts the high-work-function metal gold, silver to extract the hole as translucent anode.The anode both sides are adopted with P type metal oxide molybdenum trioxide or tungsten oxide and are connected up and down sub-battery photosensitive layer structure internal electric field as hole transmission layer, improve carrier collection efficient.The photosensitive layer of two sub-batteries up and down in the laminated cell is respectively the mixture of different conjugated polymer of absorption region and fullerene derivate composition.Two sub-batteries connect in parallel, and the short-circuit current density of lamination solar cell is two sub-battery short circuit current density sums up and down.This stacking polymer thin-film solar cell by adopt the different conjugated polymer of absorption region improved effectively to effective absorption of sunlight and realized short circuit current effectively be increased to 15 milliamperes/square centimeter, thereby the energy conversion efficiency that has improved polymer thin-film solar cell is up to 3.36%.This patent has adopted a kind of laminated construction, and the solar cell of realization belongs to organic solar batteries, owing to there is not well to bring into play the advantage of laminated construction, the energy conversion efficiency of solar cell is up to 3.36%, belongs to reduced levels.At present, no matter be scientific research institution or manufacture of solar cells producer, all for how improving the photoelectric conversion efficiency effort of battery.
Summary of the invention
The objective of the invention is solar cell laminated construction principle with reference to Chinese patent ZL200810051527.1, by being formed structure, solar cell further optimizes, introduce the fusion principle of organic solar batteries and inorganic thin film solar cell, by both mutual supplement with each other's advantages, realize a kind of brand new solar energy battery.
The present invention adopts following scheme to realize:
A kind of lamination composite solar battery is characterized in that comprising:
Transparency carrier: material is glass or plastics;
Cathode layer: its material is tin indium oxide or tin oxide;
The polarity organic layer: material is one of Merlon, polyacrylic acid, polymethylacrylic acid, poly oxide, polysulfide, polyamide, polyester, polyurethane, polyimides
First photosensitive layer: material is the blend of conjugated polymer and fullerene;
Translucent anode layer: material is a kind of in metallic gold, nickel and the silver;
P type semiconductor layer: material is P type amorphous silicon hydride or P type multi-element compounds;
P-N transition zone: the copper indium diselenide of material for mixing and sowing;
N type semiconductor layer: material is N type amorphous silicon hydride or N type multi-element compounds;
Transparency conducting layer: material is a kind of in the zinc oxide of indium tin oxide, zinc oxide or doped aluminium;
Cathode layer, polarity organic layer, first photosensitive layer and translucent anode layer form first successively the loom battery; Translucent anode, p type semiconductor layer, P-N transition zone, n type semiconductor layer and transparency conducting layer form the second inorganic thin film battery of touching successively; First has the loom battery and the second inorganic thin film battery of touching to form composite solar battery by translucent anode layer lamination.
Further optimize, also have second photosensitive layer, material is the blend of conjugated polymer and fullerene; Also have non-conductive reflector layer, material is the glass microballoon reflectorised paint that has added high index of refraction; Second photosensitive layer is striden layer with first photosensitive layer by electric conductor and is connected.
Further optimize, in order to improve the sunlight utilance, the more sunlight second inorganic thin film battery of touching is transformed, it is netted that anode layer is.
Lamination composite solar battery in sum has following characteristics and remarkable result:
(1) contrast Chinese patent ZL200810051527.1, the 3rd layer of the present invention is polarity organic layer (referenced patent is " the first sub-battery electron transport layer " for the 3rd layer), this polarity organic layer can increase the density of photocurrent of 20%-40% at least; The the 6th to eight layer of the present invention is respectively p type semiconductor layer, P-N transition zone, n type semiconductor layer (and referenced patent is " translucent anode ", " the second sub-battery hole transmission layer ", " the second sub-battery photosensitive layer "), so the structure of entire cell has world of difference; What ZL200810051527.1 adopted in addition is the lamination of two organic solar batteries, and the present invention is the lamination that adopts an organic solar batteries and an inorganic solar cell, realize the mutual supplement with each other's advantages between two kinds of batteries, both obtained good opto-electronic conversion performance, simultaneously also balanced production cost;
(2) the present invention also has second photosensitive layer and non-conductive reflector layer; Realize to penetrate at last the surplus light reflection of the sun of battery by the conduction reflector layer, and further excite the optoelectronic induction of second photosensitive layer; Second photosensitive layer is striden layer with first photosensitive layer by electric conductor and is connected, and further improves the photoelectric conversion efficiency that machine battery is arranged.
(3) realized the ingenious lamination of organic solar batteries and inorganic solar cell, the meshed anode layer more helps sunlight and arrives inorganic solar cell simultaneously.
Description of drawings
Fig. 1 is the hierarchy schematic diagram of solar cell of the present invention;
Fig. 2 is the structural representation that the present invention has the solar cell of eleventh floor composition;
Fig. 3 is that the surplus light of the sun is reflected and realizes the schematic diagram of recycling.
Fig. 4 is the structural representation of meshed anode layer.
Embodiment
Embodiment one:
With reference to figure 1, the invention scheme of present embodiment, the lamination composite solar battery is made up of nine difference in functionality layers.Be transparency carrier 1, cathode layer 2, polarity organic layer 3, first photosensitive layer 4, translucent anode layer 5, p type semiconductor layer 6, P-N transition zone 7, n type semiconductor layer 8, transparency conducting layer 9 successively; Wherein:
Cathode layer 2: its material is preferably tin indium oxide or tin oxide; Cathode layer 2 can form with any conventional method, for example vapour deposition, sputter etc.; Cathode layer 2 thickness are between 150～600nm.
Polarity organic layer 3: material is preferably one of Merlon, polyacrylic acid, polymethylacrylic acid, poly oxide, polysulfide, polyamide, polyester, polyurethane, polyimides, perhaps the combination of two or more among them.Polarity organic layer 3 contains a kind of polarity macromolecule of polar functional group at least, and its can increase on the one hand the density of photocurrent of 20%-40% at least, more can flat cathode layer 2; The thickness of polarity organic layer 3 is preferably between 50～250nm.
First photosensitive layer 4: material is preferably the blend of conjugated polymer and fullerene; It contains two kinds of compositions at least first photosensitive layer 4, comprises electron donor and electron acceptor; Wherein conjugated polymer can adopt polyacetylene as electron donor; Electron acceptor adopts the cyano group phenylene ethylene.First photosensitive layer, 4 thickness are between 30～150nm.
Translucent anode layer 5: material is preferably a kind of in metallic gold, nickel and the silver, must have light transmission preferably; Translucent anode layer 5 preferred network structures (with reference to shown in Figure 4); Can adopt but be not limited to spraying, silk screen printing, ink jet printing mode and form.
P type semiconductor layer 6: material is preferably P type amorphous silicon hydride (P-a-Si:H) or P type multi-element compounds such as aluminium is sowed nitrogen, aluminium is sowed arsenic etc.; P type semiconductor layer 6 thickness are between 100～130nm;
P-N transition zone 7: material is preferably the copper indium diselenide of mixing and sowing, and thickness is between 20～40nm;
N type semiconductor layer 8: material is preferably N type amorphous silicon hydride (N-a-Si:H) or the nitrogenize of N type multi-element compounds is sowed or indium phosphide is sowed, and thickness is between 100～130nm
Transparency conducting layer 9: material is a kind of in the zinc oxide of indium tin oxide, zinc oxide or doped aluminium; Between 120～300nm.
With reference to figure 1, cathode layer 2, polarity organic layer 3, first photosensitive layer 4 and translucent anode layer 5 form first successively the loom battery again; Translucent anode 5, p type semiconductor layer 6, P-N transition zone 7, n type semiconductor layer 8 and transparency conducting layer 9 form the second inorganic thin film battery of touching successively; First has the loom battery and the second inorganic thin film battery of touching to form composite solar battery by translucent anode layer 5 laminations.
Embodiment two:
Embodiment two is the further optimization of doing on the existing basis of embodiment one.Wherein difference is: with reference to figure 2 and 3, the translucent anode layer 5 of lamination composite solar battery also has second photosensitive layer, 10, the second photosensitive layers 10 and formation method, thickness can be implemented with reference to first photosensitive layer 4; Second photosensitive layer 10 also has non-conductive reflector layer 12, and material can select to have added the glass microballoon reflectorised paint of high index of refraction, forms by modes such as sprayings.Second photosensitive layer 10 is striden layer with first photosensitive layer 4 by electric conductor (as silverskin) and is connected.With reference to figure 3, the surplus light of the sun is reflected after arriving non-conductive reflector layer 12, further excites the optoelectronic induction of second photosensitive layer 10; Second photosensitive layer 10 and 4 actings in conjunction of first photosensitive layer further improve the photoelectric conversion efficiency that machine battery is arranged;
Present embodiment has adopted multipath to improve the photoelectric conversion efficiency of battery, lamination comprising organic solar batteries and inorganic solar cell makes full use of solar energy, realizes the ingenious superimposed of organic and inorganic solar cell, bring into play maximum opto-electronic conversion performance simultaneously, the balanced production cost; Adopt second photosensitive layer 10 and non-conductive reflector layer 12 structures, the pre-light of the sun is reused, strengthen the secondary opto-electronic conversion of organic solar batteries, realize that the conversion efficiency of integral battery door can reach more than 35%.
Claims (3)
1. lamination composite solar battery is characterized in that comprising:
Transparency carrier (1): material is glass or plastics;
Cathode layer (2): its material is tin indium oxide or tin oxide;
Polarity organic layer (3): material is one of Merlon, polyacrylic acid, polymethylacrylic acid, poly oxide, polysulfide, polyamide, polyester, polyurethane, polyimides;
First photosensitive layer (4): material is the blend of conjugated polymer and fullerene;
Translucent anode layer (5): material is a kind of in metallic gold, nickel and the silver;
P type semiconductor layer (6): material is P type amorphous silicon hydride or P type multi-element compounds;
P-N transition zone (7): the copper indium diselenide of material for mixing and sowing;
N type semiconductor layer (8): material is N type amorphous silicon hydride or N type multi-element compounds;
Transparency conducting layer (9): material is a kind of in the zinc oxide of indium tin oxide, zinc oxide or doped aluminium;
Cathode layer (2), polarity organic layer (3), first photosensitive layer (4) and translucent anode layer (5) form first successively the loom battery; Translucent anode (5), p type semiconductor layer (6), P-N transition zone (7), n type semiconductor layer (8) and transparency conducting layer (9) form the second inorganic thin film battery of touching successively; First has the loom battery and the second inorganic thin film battery of touching to form composite solar battery by translucent anode layer (5) lamination.
2. lamination composite solar battery according to claim 1 is characterized in that: also have second photosensitive layer (10), material is the blend of conjugated polymer and fullerene; Also have non-conductive reflector layer (12), material is the glass microballoon reflectorised paint that has added high index of refraction; Second photosensitive layer (10) is striden layer with first photosensitive layer (4) by electric conductor and is connected.
3. lamination composite solar battery according to claim 1 and 2 is characterized in that: translucent anode layer (5) is netted.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201010562295 CN102097592B (en) | 2010-11-22 | 2010-11-22 | Laminated composite solar battery |
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| CN 201010562295 CN102097592B (en) | 2010-11-22 | 2010-11-22 | Laminated composite solar battery |
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| CN102097592B CN102097592B (en) | 2012-11-21 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102623643A (en) * | 2012-03-31 | 2012-08-01 | 中国科学院半导体研究所 | Process for producing anti-configuration polymer solar cell using plasmon effect |
| CN102856498A (en) * | 2011-06-28 | 2013-01-02 | 海洋王照明科技股份有限公司 | Parallel type polymer solar cell and preparation method thereof |
| CN104241529A (en) * | 2013-06-17 | 2014-12-24 | 宁波大学 | Laminated organic solar battery and manufacturing method thereof |
| CN111341915A (en) * | 2020-05-19 | 2020-06-26 | 季华实验室 | Method for manufacturing organic crystal solar cell device and photoelectric equipment |
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2010
- 2010-11-22 CN CN 201010562295 patent/CN102097592B/en not_active Expired - Fee Related
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102856498A (en) * | 2011-06-28 | 2013-01-02 | 海洋王照明科技股份有限公司 | Parallel type polymer solar cell and preparation method thereof |
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| CN102623643A (en) * | 2012-03-31 | 2012-08-01 | 中国科学院半导体研究所 | Process for producing anti-configuration polymer solar cell using plasmon effect |
| CN104241529A (en) * | 2013-06-17 | 2014-12-24 | 宁波大学 | Laminated organic solar battery and manufacturing method thereof |
| CN111341915A (en) * | 2020-05-19 | 2020-06-26 | 季华实验室 | Method for manufacturing organic crystal solar cell device and photoelectric equipment |
| CN111341915B (en) * | 2020-05-19 | 2020-09-01 | 季华实验室 | Method for manufacturing organic crystal solar cell device and photoelectric equipment |
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| CN102097592B (en) | 2012-11-21 |
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