CN102067862A - Ipconazole-containing bactericidal composition - Google Patents
Ipconazole-containing bactericidal composition Download PDFInfo
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Abstract
The invention discloses an ipconazole-containing bactericidal composition. The bactericidal composition comprises an active ingredient A and an active ingredient B, wherein the active ingredient A is ipconazole; the active ingredient B is one selected from carbendazim, thiophanate methyl, probenazole, prochloraz, imazalil and triflumizole; the weight percentage ratio of the active ingredient A to the active ingredient B is (1-40):(1-80); and auxiliary agents and excipients are added into the active ingredients to prepare wettable powder, water dispersible granules, suspensions or suspoemulsion. The bactericidal composition is used for preventing and controlling rice blast, bakanae disease, leaf mold, cladosporium cucumerinum, ring spot, alternaria leaf spot, anthracnose, spot anthracnose and powdery mildew, is resistant to rain wash and has an obvious synergistic effect.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of kind of the application of the bactericidal composition of bacterium azoles on crop pest that contain.
Technical background
Plant the bacterium azoles, English name: ipconazole, molecular formula: C
18H
24ClN
3O, chemical name: the methyl 2-[(4-chlorphenyl)]-5-(1-isopropyl)-1-(1H-1,2,4-triazol-1-yl methyl) cyclopentanol.
Planting the bacterium azoles is triazole bactericidal agent, and ergosterol biosynthesis inhibitor is mainly used in the seed-borne disease of preventing and treating paddy rice and other crops, and, provide and tag and two kinds of mechanism of action of interior suction, thereby effectively remove cause of disease, prevent that seed from rotting, wither, dampinging off.
Plant the agent of bacterium azoles list and use for a long time, disease is developed immunity to drugs, cause the problem that dosage strengthens, preventive effect reduces, the lasting period shortens, be unfavorable for environment sustainable development.And that the active ingredient of the different mechanisms of action is carried out is composite, is to delay the disease method commonly used that develops immunity to drugs, and according to the effect in the production application, judge this composite be synergistic effect or antagonism.Complex role is more significantly filled a prescription, and can obviously improve preventive effect, reduces the dosage of agricultural chemicals greatly, also can enlarge fungicidal spectrum, improves germicidal efficiency.It is different with the effective active composition B mechanism of action to plant the bacterium azoles, mutually composite have good synergistic effect within the specific limits, and about plant bacterium azoles and carbendazim, thiophanate-methyl, probenazole, Prochloraz, but mould azoles, fluorine bacterium azoles is relevant composite, does not see relevant report at present at home and abroad as yet.
Summary of the invention
The objective of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good bactericidal composition that contains kind of bacterium azoles and effective active composition B.
The present invention is achieved through the following technical solutions:
A kind of kind of bactericidal composition of bacterium azoles that contains, it is characterized in that: the percentage by weight of A, two kinds of active components of B is 1～40%: 1～80%, described A component is kind of a bacterium azoles, and the B component is selected from carbendazim, thiophanate-methyl, probenazole, Prochloraz, press down a kind of in mould azoles, the fluorine bacterium azoles.
Described kind of the bacterium azoles bactericidal composition that contains, it is characterized in that: the percentage by weight of wherein planting bacterium azoles and effective active composition B is 1～35%: 5～70%.
The described bactericidal composition that contains kind of bacterium azoles and carbendazim is characterized in that: the percentage by weight of wherein planting bacterium azoles and carbendazim is 5～30%: 10～60%.
The described bactericidal composition that contains kind of bacterium azoles and thiophanate-methyl is characterized in that: the percentage by weight of wherein planting bacterium azoles and thiophanate-methyl is 5～30%: 10～60%.
The described bactericidal composition that contains kind of bacterium azoles and probenazole is characterized in that: the percentage by weight of wherein planting bacterium azoles and probenazole is 5～30%: 10～50%.
The described bactericidal composition that contains kind of bacterium azoles and Prochloraz is characterized in that: the percentage by weight of wherein planting bacterium azoles and Prochloraz is 5～30%: 10～50%.
Described kind of bacterium azoles and the bactericidal composition that presses down mould azoles of containing is characterized in that: wherein planting the bacterium azoles is 5～30%: 10～50% with the percentage by weight that presses down mould azoles.
The described bactericidal composition that contains kind of bacterium azoles and fluorine bacterium azoles is characterized in that: the percentage by weight of wherein planting bacterium azoles and fluorine bacterium azoles is 5～30%: 5～40%.
Described kind of the bactericidal composition of bacterium azoles that contains, wherein the effective active component content accounts for 1～95% of gross weight, is preferably 20～80%.
Described kind of the bactericidal composition of bacterium azoles that contains is made wetting powder, water dispersible granules, suspending agent or suspension emulsion.
When making wetting powder, composition comprises following constituent content: plant bacterium azoles 1～40%, effective active composition B 1～80%, dispersant 3～10%, wetting agent 2～10%, filler 8～93%.
To plant bacterium azoles, effective active composition B, dispersant, wetting agent, filler mixing, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into the wetting powder product of the present composition.
When making water dispersible granules, composition comprises following constituent content: plant bacterium azoles 1～40%, effective active composition B 1～80%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, filler 8～93%.
Kind of a bacterium azoles, effective active composition B, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes present composition water dispersible granules product.
Comprise following constituent content when composition is made suspending agent: kind bacterium azoles 1～20%, active ingredient B 1～40%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, antifreeze 0～8%, stabilizing agent 0%～3%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze in the above-mentioned formulation material are mixed through high speed shear, add kind of a bacterium azoles, active ingredient B, ball milling is 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, makes present composition suspending agent product.
Comprise following constituent content when composition is made suspension emulsion: plant bacterium azoles 1～20%, effective active composition B 1～40%, emulsifier 2～12%, dispersant 2～10%, defoamer 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear, add the former medicine of effective active composition B, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make effective active composition B suspending agent, to plant then the former medicine of bacterium azoles, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make present composition suspension emulsion product.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, during the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described disintegrant is selected from: one or more in sodium bicarbonate, sodium carbonate, bentonite, urea, ammonium sulfate, the aluminium chloride.
Described binding agent is selected from: one or more in gelatin, melon glue, gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, the polyvinyl alcohol.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, the polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (as capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described emulsifier is selected from: agricultural newborn 500# (alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming newborn 400# (benzyl dimethyl phenol polyoxy ethyl ether), farming newborn 600# (phenyl phenol polyoxy ethyl ether), Nongru-700 # (alkylphenol-formaldehyde resin polyoxy ethyl ether), farming newborn 36# (phenethyl fluosite polyoxy ethyl ether), farming newborn 1600# (phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), farming newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether), farming newborn 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), in the AEO series (the pure APEO of fat) one or more.
Described stabilizing agent is selected from: one or more in BHT, triphenyl phosphite, epoxychloropropane, tributyl phosphate, triethanolamine, diethanol amine, the monoethanolamine.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Beneficial effect of the present invention: (1) present composition effective active composition kind bacterium azoles and effective active composition B belong to the bactericide of two kinds of different mechanisms of action, and both are mixed mutually and can produce conflict; (2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single agent, and dosage is little; (3) the present invention not with an organic solvent is not difficult for producing poisoning, is convenient to transportation and storage; (4) present composition has enlarged fungicidal spectrum, and diseases such as crop rice blast, bakanae disease, leaf mold, scab, ring spot, spot defoliation, anthracnose, anthrachose of grape, powdery mildew are all had special efficacy.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.
Application Example one
1 66% kind of bacterium azoles carbendazol wettable powder of example
Kind bacterium azoles 6%, carbendazim 60%, lignosulfonates 7%, spaonin powder 5%, precipitated calcium carbonate add to 100%, and mixture carries out comminution by gas stream, makes 66% kind of bacterium azoles carbendazol wettable powder.
2 80% kinds of bacterium azoles carbendazol wettable powders of example
Kind bacterium azoles 10%, carbendazim 70%, alkyl benzene sulfonate calcium salt 6%, wetting and penetrating agent F 5%, white carbon add to 100%, and mixture carries out comminution by gas stream, makes 80% kind of bacterium azoles carbendazol wettable powder.
3 63% kinds of bacterium azoles carbendazim water dispersing granules of example
Kind of bacterium azoles 3%, carbendazim 60%, silkworm excrement 5%, polyoxyethylene carboxylate 7%, sodium carbonate 1.5%, attapulgite add to 100%, mixed 63% kind of bacterium azoles carbendazim water dispersing granule.
4 70% kinds of bacterium azoles carbendazim water dispersing granules of example
Kind of bacterium azoles 5%, carbendazim 65%, Nekal BX 4%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, bentonite add to 100%, mixed 70% kind of bacterium azoles carbendazim water dispersing granule.
5 22% kinds of bacterium azoles carbendazim of example suspending agent
Kind of bacterium azoles 2%, carbendazim 20%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 8%, neopelex 7%, silicone compound 0.3%, methylcellulose 1.7%, triethylene glycol 1.2%, deionized water add to 100%, mixed 22% kind of bacterium azoles carbendazim suspending agent.
6 30% kinds of bacterium azoles carbendazim of example suspending agent
Kind of bacterium azoles 5%, carbendazim 25%, polycarboxylate 7%, silkworm excrement 6%, silicone oil 0.2%, PAA 1.1%, glycerine 1.3%, deionized water add to 100%, mixed 30% kind of bacterium azoles carbendazim suspending agent.
7 15% kinds of bacterium azoles carbendazim of example suspension emulsion
Plant bacterium azoles 5%, carbendazim 10%, the phonetic formaldehyde condensation products sulphate 8% of alkylphenol-polyethenoxy, wetting and penetrating agent F 6%, sodium phosphate trimer 1.3%, 600# phosphate 8%, propane diols 1.5%, C
8～10Aliphatic alcohols 0.1%, water add to 100%, through mixed 15% kind of bacterium azoles carbendazim suspension emulsion.
8 42% kinds of bacterium azoles carbendazim of example suspension emulsion
Kind of bacterium azoles 7%, carbendazim 35%, aliphatic amine polyoxyethylene are phonetic 6%, lauryl sodium sulfate 5%, polyvinylpyrrolidone 1.3%, tween series 6%, polyethylene glycol 1.2%, silicone compound 0.4%, water add to 100%, through mixed 42% kind of bacterium azoles carbendazim suspension emulsion.
9 64% kinds of bacterium azoles thiophanate-methyls of example wetting powder
Kind of bacterium azoles 4%, thiophanate-methyl 60%, aliphatic amine polyoxyethylene are phonetic 7%, silkworm excrement 6%, diatomite add to 100%, and mixture carries out comminution by gas stream, makes 64% kind of bacterium azoles thiophanate-methyl wetting powder.
10 75% kinds of bacterium azoles thiophanate-methyls of example wetting powder
Kind bacterium azoles 15%, thiophanate-methyl 60%, polycarboxylate 6%, spaonin powder 5%, starch add to 100%, and mixture carries out comminution by gas stream, makes 75% kind of bacterium azoles thiophanate-methyl wetting powder.
11 55% kinds of bacterium azoles thiophanate-methyls of example water dispersible granules
Kind of bacterium azoles 5%, thiophanate-methyl 50%, lignosulfonates 8%, wetting and penetrating agent F6%, bentonite add to 100%, mixed 55% kind of bacterium azoles thiophanate-methyl water dispersible granules.
12 80% kinds of bacterium azoles thiophanate-methyls of example water dispersible granules
Kind of bacterium azoles 10%, thiophanate-methyl 70%, alkyl benzene sulfonate calcium salt 6%, lauryl sodium sulfate 4%, aluminium chloride 1.3%, diatomite add to 100%, mixed 80% kind of bacterium azoles thiophanate-methyl water dispersible granules.
13 10% kinds of bacterium azoles thiophanate-methyls of example suspending agent
Kind of bacterium azoles 5%, thiophanate-methyl 5%, the phonetic formaldehyde condensation products sulphate 8% of alkylphenol-polyethenoxy, Nekal BX 6%, silicone compound 0.5%, methylcellulose 1.2%, diethylene glycol (DEG) 1.4%, deionized water add to 100%, mixed 10% kind of bacterium azoles thiophanate-methyl suspending agent.
14 48% kinds of bacterium azoles thiophanate-methyls of example suspending agent
Plant bacterium azoles 3%, thiophanate-methyl 45%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 7%, soapberry powder 6%, C
8～10Aliphatic alcohols 0.3%, polyvinylpyrrolidone 1.5%, diethylene glycol (DEG) 1.3%, deionized water add to 100%, mixed 48% kind of bacterium azoles thiophanate-methyl suspending agent.
15 6% kinds of bacterium azoles thiophanate-methyls of example suspension emulsion
Plant bacterium azoles 1%, thiophanate-methyl 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, Nekal BX 6%, xanthans 1.1%, OP series phosphate 8%, glycerine 1.2%, C
10～20Saturated fat acids 0.1%, water add to 100%, through mixed 6% kind of bacterium azoles thiophanate-methyl suspension emulsion.
16 36% kinds of bacterium azoles thiophanate-methyls of example suspension emulsion
Kind of bacterium azoles 6%, thiophanate-methyl 30%, alkyl benzene sulfonate calcium salt 6%, lauryl sodium sulfate 5%, gum Arabic 1.3%, agricultural newborn 1600#6%, polyethylene glycol 1.2%, silicone compound 0.3%, water add to 100%, through mixed 36% kind of bacterium azoles thiophanate-methyl suspension emulsion.
17 50% kinds of bacterium azoles probenazoles of example wetting powder
Kind bacterium azoles 10%, probenazole 40%, polycarboxylate 6%, soapberry powder 4%, attapulgite add to 100%, and mixture carries out comminution by gas stream, makes 50% kind of bacterium azoles probenazole wetting powder.
18 70% kinds of bacterium azoles probenazoles of example wetting powder
Kind bacterium azoles 20%, probenazole 50%, naphthalene sulfonic acid-formaldehyde condensation product 8%, silkworm excrement 7%, diatomite add to 100%, and mixture carries out comminution by gas stream, makes 70% kind of bacterium azoles probenazole wetting powder.
19 60% kinds of bacterium azoles probenazoles of example water dispersible granules
Kind of bacterium azoles 5%, probenazole 55%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, soapberry powder 5%, bentonite add to 100%, mixed 60% kind of bacterium azoles probenazole water dispersible granules.
20 72% kinds of bacterium azoles probenazoles of example water dispersible granules
Kind of bacterium azoles 8%, probenazole 64%, polyoxyethylene carboxylate 7%, wetting and penetrating agent F6%, ammonium sulfate 1.3%, starch add to 100%, mixed 72% kind of bacterium azoles probenazole water dispersible granules.
21 25% kinds of bacterium azoles probenazoles of example suspending agent
Kind of bacterium azoles 5%, probenazole 20%, ester polyoxyethylene are phonetic 6%, spaonin powder 5%, silicone oil 0.4%, gelatin 1.3%, triethylene glycol 1.6%, deionized water add to 100%, mixed 25% kind of bacterium azoles probenazole suspending agent.
22 40% kinds of bacterium azoles probenazoles of example suspending agent
Plant bacterium azoles 10%, probenazole 30%, alkylnaphthalene sulfonate 7%, soapberry powder 6%, C
8～10Aliphatic alcohols 0.2%, xanthans 1.3%, ethylene glycol 1.4%, deionized water add to 100%, mixed 40% kind of bacterium azoles probenazole suspending agent.
23 8% kinds of bacterium azoles probenazoles of example suspension emulsion
Plant bacterium azoles 4%, probenazole 4%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, wetting and penetrating agent F 6%, methylcellulose 1.2%, Nongru-700 #8%, polyethylene glycol 1.1%, C
10～20Saturated fat acids 0.4%, water add to 100%, through mixed 8% kind of bacterium azoles probenazole suspension emulsion.
24 35% kinds of bacterium azoles probenazoles of example suspension emulsion
Kind of bacterium azoles 7%, probenazole 28%, the phonetic formaldehyde condensation products sulphate 6% of alkylphenol-polyethenoxy, lauryl sodium sulfate 5%, PAA 1.3%, agricultural newborn 34#6%, glycerine 1.6%, silicone compound 0.2%, water add to 100%, through mixed 35% kind of bacterium azoles probenazole suspension emulsion.
25 54% kinds of bacterium azoles Prochlorazs of example wetting powder
Kind bacterium azoles 8%, Prochloraz 46%, alkyl benzene sulfonate calcium salt 7%, Nekal BX 5%, diatomite add to 100%, and mixture carries out comminution by gas stream, makes 54% kind of bacterium azoles Prochloraz wetting powder.
26 70% kinds of bacterium azoles Prochlorazs of example wetting powder
Kind of bacterium azoles 10%, Prochloraz 60%, alkylphenol-polyethenoxy are phonetic 6%, spaonin powder 4%, precipitated calcium carbonate add to 100%, and mixture carries out comminution by gas stream, makes 70% kind of bacterium azoles Prochloraz wetting powder.
27 51% kinds of bacterium azoles Prochlorazs of example water dispersible granules
Kind of bacterium azoles 3%, Prochloraz 48%, octylphenol polyethylene oxyethylene group ether sulfate 8%, silkworm excrement 7%, bentonite add to 100%, mixed 51% kind of bacterium azoles Prochloraz water dispersible granules.
28 75% kinds of bacterium azoles Prochlorazs of example water dispersible granules
Kind of bacterium azoles 5%, Prochloraz 70%, lignosulfonates 7%, lauryl sodium sulfate 5%, sodium bicarbonate 1.1%, kaolin add to 100%, mixed 75% kind of bacterium azoles Prochloraz water dispersible granules.
29 12% kinds of bacterium azoles Prochlorazs of example suspending agent
Kind of bacterium azoles 6%, Prochloraz 6%, polyoxyethylene carboxylate 6%, soapberry powder 5%, silicone oil 0.4%, sodium phosphate trimer 1.2%, triethylene glycol 1.7%, deionized water add to 100%, mixed 12% kind of bacterium azoles Prochloraz suspending agent.
30 30% kinds of bacterium azoles Prochlorazs of example suspending agent
Plant bacterium azoles 10%, Prochloraz 20%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, Nekal BX 4%, C
8～10Aliphatic alcohols 0.2%, gum Arabic 1.4%, ethylene glycol 1.5%, deionized water add to 100%, mixed 30% kind of bacterium azoles Prochloraz suspending agent.
31 25% kinds of bacterium azoles Prochlorazs of example suspension emulsion
Kind bacterium azoles 5%, Prochloraz 20%, octylphenol polyethylene oxyethylene group ether sulfate 7%, wetting and penetrating agent F 6%, silicone oil 0.3%, PAA 1.2%, 600# phosphate 7%, glycerine 1.4%, water add to 100%, the aforementioned formula material is mixed, promptly make 25% kind of bacterium azoles Prochloraz suspension emulsion.
32 36% kinds of bacterium azoles Prochlorazs of example suspension emulsion
Kind bacterium azoles 6%, Prochloraz 30%, aryl phenol polyoxyethylene succinate sulfonate 6%, soapberry powder 5%, silicone compound 0.4%, methylcellulose 1.3%, tween series 8%, propane diols 1.1%, water add to 100%, the aforementioned formula material is mixed, promptly make 36% kind of bacterium azoles Prochloraz suspension emulsion.
33 50% kinds of bacterium azoles of example press down mould azoles wetting powder
Kind of bacterium azoles 10%, press down mould azoles 40%, polyoxyethylene carboxylate 7%, silkworm excrement 6%, attapulgite and add to 100%, mixture carries out comminution by gas stream, makes 50% kind of bacterium azoles and presses down mould azoles wetting powder.
34 75% kinds of bacterium azoles of example press down mould azoles wetting powder
Kind of bacterium azoles 15%, press down mould azoles 60%, lignosulfonates 8%, Nekal BX 7%, diatomite and add to 100%, mixture carries out comminution by gas stream, makes 75% kind of bacterium azoles and presses down mould azoles wetting powder.
35 45% kinds of bacterium azoles of example press down mould azoles water dispersible granules
Kind of bacterium azoles 5%, press down mould azoles 40%, alkyl benzene sulfonate calcium salt 7%, lauryl sodium sulfate 5%, bentonite and add to 100%, mixed that 45% kind of bacterium azoles press down mould azoles water dispersible granules.
36 70% kinds of bacterium azoles of example press down mould azoles water dispersible granules
Kind of bacterium azoles 20%, press down mould azoles 50%, naphthalene sulfonic acid-formaldehyde condensation product 6%, wetting and penetrating agent F 5%, urea 1.5%, starch and add to 100%, mixed that 70% kind of bacterium azoles press down mould azoles water dispersible granules.
37 10% kinds of bacterium azoles of example press down mould azole suspending agent
Kind of bacterium azoles 5%, press down mould azoles 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, wetting and penetrating agent F 6%, silicone oil 0.5%, xanthans 1.4%, propane diols 1.3%, deionized water and add to 100%, mixed that 10% kind of bacterium azoles press down mould azole suspending agent.
38 45% kinds of bacterium azoles of example press down mould azole suspending agent
Plant bacterium azoles 15%, press down mould azoles 30%, aryl phenol polyoxyethylene succinate sulfonate 7%, lauryl sodium sulfate 5%, C
8～10Aliphatic alcohols 0.2%, methylcellulose 1.2%, polyethylene glycol 1.1%, deionized water add to 100%, and be mixed that 45% kind of bacterium azoles presses down mould azole suspending agent.
39 25% kinds of bacterium azoles of example press down mould azoles suspension emulsion
Plant bacterium azoles 5%, press down mould azoles 20%, the phonetic formaldehyde condensation products sulphate 7% of alkylphenol-polyethenoxy, soapberry powder 6%, C
10～20Saturated fat acids 0.4%, PAA 1.3%, agricultural newborn 34#6%, diethylene glycol (DEG) 1.4%, water add to 100%, and the aforementioned formula material is mixed, and promptly make 25% kind of bacterium azoles and press down mould azoles suspension emulsion.
40 42% kinds of bacterium azoles of example press down mould azoles suspension emulsion
Kind of bacterium azoles 6%, press down mould azoles 36%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6%, Nekal BX 5%, silicone compound 0.1%, sodium phosphate trimer 1.1%, agricultural newborn 500#8%, triethylene glycol 1.4%, water and add to 100%, the aforementioned formula material is mixed, promptly make 42% kind of bacterium azoles and press down mould azoles suspension emulsion.
41 50% kinds of bacterium azoles triflumizole wettable powders of example
Kind bacterium azoles 25%, fluorine bacterium azoles 25%, alkyl benzene sulfonate calcium salt 7%, spaonin powder 5%, kaolin add to 100%, and mixture carries out comminution by gas stream, makes 50% kind of bacterium azoles triflumizole wettable powder.
42 70% kinds of bacterium azoles triflumizole wettable powders of example
Kind bacterium azoles 30%, fluorine bacterium azoles 40%, lignosulfonates 8%, silkworm excrement 7%, attapulgite add to 100%, and mixture carries out comminution by gas stream, makes 70% kind of bacterium azoles triflumizole wettable powder.
43 55% kinds of bacterium azoles triflumizole water dispersants of example
Kind of bacterium azoles 5%, fluorine bacterium azoles 50%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, wetting and penetrating agent F 5%, bentonite add to 100%, mixed 55% kind of bacterium azoles triflumizole water dispersant.
44 70% kinds of bacterium azoles triflumizole water dispersants of example
Kind of bacterium azoles 10%, fluorine bacterium azoles 60%, alkylphenol-polyethenoxy are phonetic 8%, lauryl sodium sulfate 7%, ammonium sulfate 1.2%, diatomite add to 100%, mixed 70% kind of bacterium azoles triflumizole water dispersant.
45 20% kinds of bacterium azoles fluorine of example bacterium azole suspending agent
Kind of bacterium azoles 10%, fluorine bacterium azoles 10%, lignosulfonates 8%, Nekal BX 6%, silicone oil 0.5%, xanthans 1.1%, diethylene glycol (DEG) 1.3%, deionized water adds to 100%, mixed 20% kind of bacterium azoles fluorine bacterium azole suspending agent.
46 42% kinds of bacterium azoles fluorine of example bacterium azole suspending agent
Kind of bacterium azoles 35%, fluorine bacterium azoles 7%, octylphenol polyethylene oxyethylene group ether sulfate 6%, soapberry powder 5%, silicone compound 0.3%, glycerine 1.2%, deionized water adds to 100%, mixed 42% kind of bacterium azoles fluorine bacterium azole suspending agent.
47 16% kinds of bacterium azoles fluorine of example bacterium azoles suspension emulsion
Plant bacterium azoles 8%, fluorine bacterium azoles 8%, alkyl benzene sulfonate calcium salt 7%, neopelex 6%, melon glue 1.2%, ethylene glycol 1.5%, C
8～10Aliphatic alcohols 0.2%, OP series phosphate 8%, water add to 100%, mixed 16% kind of bacterium azoles fluorine bacterium azoles suspension emulsion.
48 36% kinds of bacterium azoles fluorine of example bacterium azoles suspension emulsion
Plant bacterium azoles 6%, fluorine bacterium azoles 30%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, wetting and penetrating agent F 7%, polyvinylpyrrolidone 1.4%, triethylene glycol 1.5%, C
10～20Saturated fat acids 0.4%, agricultural newborn 400#6%, water add to 100%, mixed 36% kind of bacterium azoles fluorine bacterium azoles suspension emulsion.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect, on this basis, carry out field trial again.
It is composite to the crop pest Toxicity Determination to plant bacterium azoles and active component B (B is selected from carbendazim, thiophanate-methyl, probenazole, Prochloraz, presses down a kind of of mould azoles, fluorine bacterium azoles).
After the effective inhibition concentration scope of each medicament was determined in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament the crop germ.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively active component kind bacterium azoles and B (carbendazim, thiophanate-methyl, probenazole, Prochloraz, press down a kind of in mould azoles, the fluorine bacterium azoles) shared ratio in combination;
A is kind of a bacterium azoles;
B is carbendazim, thiophanate-methyl, probenazole, Prochloraz, press down a kind of in mould azoles, the fluorine bacterium azoles.
Application Example two:
It is composite to the rice blast Toxicity Determination to plant bacterium azoles and carbendazim.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining kind of a bacterium azoles, carbendazim active compound and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table a kind of bacterium azoles, carbendazim and composite toxicity test analysis of results table thereof to rice blast
As shown in Table 1, plant bacterium azoles, carbendazim EC to rice blast
50Be respectively 0.75mg/L and 16.08mg/L.Plant bacterium azoles and carbendazim proportioning at 40: 1 to 1: 80 o'clock, synergy ratio SR is all greater than 1.5, illustrating that kind of bacterium azoles and carbendazim were mixed in the scope at 40: 1 to 1: 80 all shows synergistic effect, especially when the two proportioning during at 1: 1 to 1: 20, synergistic effect is more obviously outstanding, synergy ratio SR maximum when kind of bacterium azoles and carbendazim percentage by weight are 1: 10 wherein, synergistic effect is the most obvious.
Application Example three
It is composite to the cladosporium leaf and fruit mould of tomato Toxicity Determination to plant bacterium azoles and thiophanate-methyl.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining kind of a bacterium azoles, the former medicine of thiophanate-methyl and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 2 kind of bacterium azoles, thiophanate-methyl and composite toxicity test analysis of results table thereof to cladosporium leaf and fruit mould of tomato
As shown in Table 2, plant bacterium azoles, thiophanate-methyl EC to cladosporium leaf and fruit mould of tomato
50Be respectively 0.71mg/L and 7.54mg/L.Plant bacterium azoles and thiophanate-methyl proportioning at 40: 1 to 1: 80 o'clock, synergy ratio SR is all greater than 1.5, illustrating that kind of bacterium azoles and thiophanate-methyl were mixed in the scope at 40: 1 to 1: 80 all shows synergistic effect, especially when the two proportioning during at 1: 1 to 1: 20, synergistic effect is more obviously outstanding, synergy ratio SR maximum when kind of bacterium azoles and thiophanate-methyl percentage by weight are 1: 10 wherein, synergistic effect is the most obvious.
Application Example four
It is composite to the ring rot of apple Toxicity Determination to plant bacterium azoles and probenazole.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining kind of a bacterium azoles, the former medicine of probenazole and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 3 kind of bacterium azoles, probenazole and composite toxicity test analysis of results table thereof to ring rot of apple
As shown in Table 3, plant bacterium azoles, probenazole EC to ring rot of apple
50Be respectively 0.73mg/L and 2.75mg/L.Plant bacterium azoles and probenazole proportioning at 40: 1 to 1: 80 o'clock, synergy ratio SR is all greater than 1.5, illustrating that kind of bacterium azoles and probenazole were mixed in the scope at 40: 1 to 1: 80 all shows synergistic effect, especially when the two proportioning during at 1: 1 to 1: 16, synergistic effect is more obviously outstanding, synergy ratio SR maximum when kind of bacterium azoles and probenazole percentage by weight are 1: 4 wherein, synergistic effect is the most obvious.
Application Example five:
It is composite to the bakanae disease of rice Toxicity Determination to plant bacterium azoles and Prochloraz.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining kind of a bacterium azoles, the former medicine of Prochloraz and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 4 kind of bacterium azoles, Prochloraz and composite toxicity test analysis of results table thereof to bakanae disease of rice
As shown in Table 4, plant bacterium azoles, Prochloraz EC to bakanae disease of rice
50Be respectively 0.68mg/L and 2.59mg/L.Plant bacterium azoles and Prochloraz proportioning at 40: 1 to 1: 80 o'clock, synergy ratio SR is all greater than 1.5, illustrating that kind of bacterium azoles and Prochloraz were mixed in the scope at 40: 1 to 1: 80 all shows synergistic effect, synergy ratio SR maximum when kind of bacterium azoles and Prochloraz percentage by weight are 1: 4 wherein, synergistic effect is the most obvious.
Application Example six
Plant the bacterium azoles and press down mould azoles composite to the anthracnose of orange Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: through the definite effective inhibition concentration scope of planting a bacterium azoles, pressing down the former medicine of mould azoles and the two different proportioning mixture of preliminary experiment.
Toxicity test result
Table 5 kind of bacterium azoles, press down mould azoles and composite toxicity test analysis of results table thereof to citrus anthracnose
As shown in Table 5, plant the bacterium azoles, press down the EC of mould azoles to anthracnose of orange
50Be respectively 0.76mg/L and 2.85mg/L.Plant the bacterium azoles and press down mould azoles proportioning at 40: 1 to 1: 80 o'clock, synergy ratio SR is all greater than 1.5, kind of bacterium azoles is described and presses down mould azoles and be mixed in the scope at 40: 1 to 1: 80 and all show synergistic effect, wherein when kind of bacterium azoles synergy ratio SR maximum when pressing down mould azoles percentage by weight and be 1: 4, synergistic effect is the most obvious.
Application Example seven
It is composite to the wheat powdery mildew Toxicity Determination to plant bacterium azoles and fluorine bacterium azoles.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of determining kind of a bacterium azoles, the former medicine of fluorine bacterium azoles and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 6 kind of bacterium azoles, fluorine bacterium azoles and composite toxicity test analysis of results table thereof to wheat powdery mildew
As shown in Table 6, plant bacterium azoles, fluorine bacterium azoles EC to wheat powdery mildew
50Be respectively 0.63mg/L and 0.72mg/L.Plant bacterium azoles and fluorine bacterium azoles proportioning at 40: 1 to 1: 80 o'clock, synergy ratio SR is all greater than 1.5, illustrating that kind of bacterium azoles and fluorine bacterium azoles were mixed in the scope at 40: 1 to 1: 80 all shows synergistic effect, especially when the two proportioning during at 10: 1 to 1: 10, synergistic effect is more obviously outstanding, synergy ratio SR maximum when kind of bacterium azoles and fluorine bacterium azoles percentage by weight are 1: 1 wherein, synergistic effect is the most obvious.
Eight kinds of bacterium azoles of Application Example and carbendazim and the composite control rice blast test of pesticide effectiveness thereof
This experimental establishment is in the Lianjiang County, Fujian Province, and test medicine is provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast 10% kind of bacterium azole suspending agent of medicament (commercial), 50% carbendazol wettable powder (commercial).
The investigation rice blast state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 7 kind of bacterium azoles, carbendazim and the composite control rice blast test of pesticide effectiveness thereof
As can be seen from Table 7, can effectively prevent and treat rice blast after kind bacterium azoles and carbendazim are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Nine kinds of bacterium azoles of Application Example and thiophanate-methyl and the composite cladosporium leaf and fruit mould of tomato test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Shouguang City, Shandong Province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast 10% kind of bacterium azole suspending agent of medicament (commercial), 70% thiophanate-methyl wetting powder (commercial).
The preceding investigation of medicine cladosporium leaf and fruit mould of tomato disease index, in the their early stage dispenser, dispenser for the second time after 10 days, dispenser is 2 times altogether, investigates disease indexs in 7 days, 14 days after the dispenser for the second time and calculates preventive effect.Experimental result is as follows:
Table 8 kind of bacterium azoles, thiophanate-methyl and the composite cladosporium leaf and fruit mould of tomato test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 8, can effectively prevent and treat cladosporium leaf and fruit mould of tomato after kind bacterium azoles and thiophanate-methyl are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Ten kinds of bacterium azoles of Application Example and probenazole and the composite ring rot of apple test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Weinan City Pucheng County, Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast 10% kind of bacterium azole suspending agent of medicament (commercial), 42% probenazole suspending agent (commercial).
The investigation ring rot of apple state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 9 kind of bacterium azoles, probenazole and the composite ring rot of apple test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 9, can effectively prevent and treat ring rot of apple after kind bacterium azoles and probenazole are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
11 kinds of bacterium azoles of Application Example and Prochloraz and the composite bakanae disease of rice test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in the Guangxi province Xingye County, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast 10% kind of bacterium azole suspending agent of medicament (commercial), 25% Prochloraz missible oil (commercial).
The preceding investigation of medicine bakanae disease of rice disease index, in the their early stage dispenser, dispenser for the second time after 10 days, dispenser is 2 times altogether, investigates disease indexs in 7 days, 14 days after the dispenser for the second time and calculates preventive effect.Experimental result is as follows:
Table 10 kind of bacterium azoles, Prochloraz and the composite bakanae disease of rice test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 10, can effectively prevent and treat bakanae disease of rice after kind bacterium azoles and Prochloraz are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
12 kinds of bacterium azoles of Application Example and but the mould azoles and the composite control anthracnose of orange test of pesticide effectiveness thereof
This experimental establishment is in Kai Xian, Chongqing City, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, and contrast 10% kind of bacterium azole suspending agent of medicament (commercial), 50% presses down mould azoles missible oil (commercial).
The investigation anthracnose of orange state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 11 kind of bacterium azoles, press down the mould azoles and the composite control anthracnose of orange test of pesticide effectiveness thereof
As can be seen from Table 11, plant the bacterium azoles and press down mould azoles and can effectively prevent and treat anthracnose of orange after composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
13 kinds of bacterium azoles of Application Example and fluorine bacterium azoles and the composite control wheat powdery mildew test of pesticide effectiveness thereof
This experimental establishment is in Fuyang City Linquan County, Anhui Province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast 10% kind of bacterium azole suspending agent of medicament (commercial), 30% triflumizole wettable powder (commercial).
The preceding investigation of medicine wheat powdery mildew disease index, in the their early stage dispenser, dispenser for the second time after 10 days, dispenser is 2 times altogether, investigates disease indexs in 7 days, 14 days after the dispenser for the second time and calculates preventive effect.Experimental result is as follows:
Table 12 kind of bacterium azoles, the composite control wheat powdery mildew of the fluorine bacterium azoles test of pesticide effectiveness
As can be seen from Table 12, can effectively prevent and treat wheat powdery mildew after kind bacterium azoles and fluorine bacterium azoles are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Claims (10)
1. one kind contains kind of the bactericidal composition of bacterium azoles, it is characterized in that: the percentage by weight of A, two kinds of active components of B is 1～40%: 1～80%, described active components A is kind of a bacterium azoles, and active component B is selected from carbendazim, thiophanate-methyl, probenazole, Prochloraz, press down a kind of in mould azoles, the fluorine bacterium azoles.
2. kind of the bactericidal composition of bacterium azoles that contains according to claim 1 is characterized in that: the percentage by weight of wherein planting bacterium azoles and effective active composition B is 1～35%: 5～70%.
3. kind of the bactericidal composition of bacterium azoles that contains according to claim 2, it is characterized in that: the percentage by weight of wherein planting bacterium azoles and carbendazim is 5～30%: 10～60%.
4. kind of the bactericidal composition of bacterium azoles that contains according to claim 2, it is characterized in that: the percentage by weight of wherein planting bacterium azoles and thiophanate-methyl is 5～30%: 10～60%.
5. kind of the bactericidal composition of bacterium azoles that contains according to claim 2, it is characterized in that: the percentage by weight of wherein planting bacterium azoles and probenazole is 5～30%: 10～50%.
6. kind of the bactericidal composition of bacterium azoles that contains according to claim 2, it is characterized in that: the percentage by weight of wherein planting bacterium azoles and Prochloraz is 5～30%: 10～50%.
7. kind of the bactericidal composition of bacterium azoles that contains according to claim 2 is characterized in that: wherein planting the bacterium azoles is 5～30%: 10～50% with the percentage by weight that presses down mould azoles.
8. kind of the bactericidal composition of bacterium azoles that contains according to claim 2 is characterized in that: the percentage by weight of wherein planting bacterium azoles and fluorine bacterium azoles is 5～30%: 5～40%.
9. kind of the bactericidal composition of bacterium azoles that contains according to claim 1, it is characterized in that: the formulation of microbicide compositions is: wetting powder, water dispersible granules, suspending agent or suspension emulsion.
10. kind of the bactericidal composition of bacterium azoles that contains according to claim 1 is used to prevent and treat disease on cereal crop, vegetables, the fruit tree.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102919252A (en) * | 2012-11-02 | 2013-02-13 | 江苏七洲绿色化工股份有限公司 | Sterilization composition containing cyproconazole and carbendazim |
| CN104604920A (en) * | 2013-11-05 | 2015-05-13 | 南京华洲药业有限公司 | Sterilization composition containing prochloraz nantokite and triazole bactericide as well as application thereof |
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| CN1030232A (en) * | 1987-06-30 | 1989-01-11 | 吴羽化学工业株式会社 | Novel pyrrole derivative and production method thereof and contain the agricultural of this pyrrole derivative and the chemical composition that gardening is used |
| EP0677246A1 (en) * | 1994-04-12 | 1995-10-18 | Kureha Kagaku Kogyo Kabushiki Kaisha | Fungicidal composition |
| JP2001302420A (en) * | 2000-04-28 | 2001-10-31 | Nippon Soda Co Ltd | Fungicide composition for agriculture and horticulture |
| CN102150678A (en) * | 2010-12-16 | 2011-08-17 | 陕西韦尔奇作物保护有限公司 | Sterilization composition containing prochloraz |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1030232A (en) * | 1987-06-30 | 1989-01-11 | 吴羽化学工业株式会社 | Novel pyrrole derivative and production method thereof and contain the agricultural of this pyrrole derivative and the chemical composition that gardening is used |
| EP0677246A1 (en) * | 1994-04-12 | 1995-10-18 | Kureha Kagaku Kogyo Kabushiki Kaisha | Fungicidal composition |
| JP2001302420A (en) * | 2000-04-28 | 2001-10-31 | Nippon Soda Co Ltd | Fungicide composition for agriculture and horticulture |
| CN102150678A (en) * | 2010-12-16 | 2011-08-17 | 陕西韦尔奇作物保护有限公司 | Sterilization composition containing prochloraz |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102919252A (en) * | 2012-11-02 | 2013-02-13 | 江苏七洲绿色化工股份有限公司 | Sterilization composition containing cyproconazole and carbendazim |
| CN104604920A (en) * | 2013-11-05 | 2015-05-13 | 南京华洲药业有限公司 | Sterilization composition containing prochloraz nantokite and triazole bactericide as well as application thereof |
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Address after: 715500 Pucheng County of Shaanxi Province agricultural base industrial park Applicant after: Shaanxi Meibang Pesticide Co., Ltd. Address before: 710075, C, 15 floor, Jinqiao International Plaza, science and technology road, hi tech Zone, Shaanxi, Xi'an Applicant before: Shaanxi Meibang Pesticide Co., Ltd. |
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Application publication date: 20110525 |