CN102369939A - Bactericidal combination containing fluopicolide and thiocarbamate compound - Google Patents
Bactericidal combination containing fluopicolide and thiocarbamate compound Download PDFInfo
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- CN102369939A CN102369939A CN2011103349716A CN201110334971A CN102369939A CN 102369939 A CN102369939 A CN 102369939A CN 2011103349716 A CN2011103349716 A CN 2011103349716A CN 201110334971 A CN201110334971 A CN 201110334971A CN 102369939 A CN102369939 A CN 102369939A
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- bacterium amine
- pyrrole bacterium
- fluorine pyrrole
- mancozeb
- zineb
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Abstract
The invention discloses a bactericidal combination containing a fluopicolide and thiocarbamate compound, which contains an active ingredient A and an ingredient B, wherein the active ingredient A is fluopicolide, the active ingredient B is any one of following bactericides: mancozeb, propineb, zineb and trioneb, and the weight ratio of the active ingredient A and the ingredient B is 50:1 to 1:80. The bactericidal combination containing the fluopicolide and thiocarbamate compound can prevent apple scab, epidemic diseases, downy mildew, powdery mildew, banded sclerotial blight, alternaria leaf spots, leaf spots, ring spots, rust diseases and anthracnose of crops, has an obvious synergistic effect and is highly safe to the crops; and the bactericidal combination additionally has the advantages of rainwater washing resistance, long-lasting pesticide effect, small dosage and the like.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of preparation and application that contains the bactericidal composition of two active components.
Background technology
Fluorine pyrrole bacterium amine, English name: fluopicolide, molecular formula: C
14H
8Cl
3F
3N
2O, chemical name: 2,6-two chloro-N-[(3-chloro-5-trifluoromethyl-2-pyridine radicals) methyl] benzamide.Fluorine pyrrole bacterium amine protectiveness is good, permeability is strong, and the true guiding principle fungus diseases of oomycetes is had higher biologically active, has good control efficiency.Can conduct from leaves of plants basal orientation blade tip direction.
No matter be fluorine pyrrole bacterium amine, zineb, Propineb, Carbatene, mancozeb or other efficient germicides; Long-term use separately; Disease is developed immunity to drugs, cause the problem that dosage strengthens, preventive effect reduces, the lasting period shortens, be unfavorable for environment sustainable development.And a kind ofly do not have the novel pesticide of cross resistance to prevent and treat pathogen if want newly developed, and then need screen 10,000～1.5 ten thousand compounds, expensive 1～1.5 hundred million dollar, the construction cycle is 6～10 years.And that the active ingredient of different effects mechanism is carried out is composite, is to delay the disease method commonly used that develops immunity to drugs, and according to the effect in the production application, judge this composite be synergistic effect or antagonism.Complex role is more significantly filled a prescription, and can obviously improve preventive effect, reduces the dosage of agricultural chemicals greatly, also can enlarge fungicidal spectrum, improves germicidal efficiency.
Fluorine pyrrole bacterium amine is different with the mechanism of action of mancozeb, Propineb, zineb, Carbatene, and each other composite have good synergistic effect within the specific limits.Composite about fluorine pyrrole bacterium amine and mancozeb, Propineb, zineb, Carbatene do not see relevant report at present at home and abroad as yet.
Summary of the invention
The long-term use of fluorine pyrrole bacterium amine list agent possibly bring degradation problem under resistance generation, the drug effect.The present invention proposes 1, the bactericidal composition of a kind of fluorine-containing pyrrole bacterium amine and thiocarbamates; The weight ratio of A, two kinds of active components of B is 50: 1～1: 80; Described A component is a fluorine pyrrole bacterium amine, and the B component is selected from a kind of in mancozeb, Propineb, zineb or the Carbatene.
Described bactericidal composition is characterized in that: the weight ratio of A, two kinds of active components of B is 40: 1～1: 70.
Described bactericidal composition is characterized in that: the weight ratio of A, two kinds of active components of B is 20: 1～1: 50, is preferably 10: 1～1: 40, more preferably 5: 1～1: 30.
Described bactericidal composition is characterized in that: the weight ratio of fluorine pyrrole bacterium amine and mancozeb is 1: 1～1: 20.
Described bactericidal composition is characterized in that: the weight ratio of fluorine pyrrole bacterium amine and Propineb is 1: 1～1: 20.
Described bactericidal composition is characterized in that: the weight ratio of fluorine pyrrole bacterium amine and zineb is 1: 1～1: 20.
Described bactericidal composition is characterized in that: the weight ratio of fluorine pyrrole bacterium amine and Carbatene is 1: 1～1: 20.
Amount of application when the content of active component depends on independent use in the present composition also depends on the mixed ratio and the synergistic effect degree of a kind of compound and another kind of compound, and the while is also relevant with the target fungi.Usually active weight percentage is 0.5～90% of a gross weight in the composition, and preferable is 5%～85%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 1～70% active substance by weight, preferably is 5～50%; Solid pharmaceutical preparation contains 5～85% active substance by weight, preferably is 10～80%.
At least contain a kind of surfactant in the bactericidal composition of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5～30% of a total formulation weight amount, and surplus is solid or liquid diluent.
The surfactant that bactericidal composition of the present invention is selected for use is known in those skilled in the art: can be selected from dispersant, wetting agent, thickener or the antifoaming agent one or more.According to different dosage form, can also contain stabilizing agent known in those skilled in the art, antifreeze etc. in the preparation.
Described dispersant is selected from alkylnaphthalene sulfonate; Two (alkyl) naphthalenesulfonate formaldehyde condensation compound; Naphthalene sulfonic acid-formaldehyde condensation product; Aryl phenol polyoxyethylene succinate sulfonate; Octylphenol polyethylene oxyethylene group ether sulfate; Polycarboxylate; Lignosulfonates; The alkylaryl APEO; Aliphatic alcohol polyethenoxy base ether; The phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy; Alkyl benzene sulfonate calcium salt; The naphthalene sulfonic acid-formaldehyde condensation product sodium salt; Alkylphenol-polyethenoxy is phonetic; Aliphatic amine polyoxyethylene is phonetic; Polyoxyethylene carboxylate; During the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, sldium lauryl sulfate, tea are withered, in the silkworm excrement, soapberry powder one or more.
Described disintegrant is selected from: one or more in sodium bicarbonate, sodium carbonate, bentonite, urea, ammonium sulfate, glucose, the aluminium chloride.
Described thickener is selected from: one or more in CMC, hydroxyethylcellulose, Magnesiumaluminumsilicate, gelatin, melon glue, gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, PVPP, polyethylene glycol, the polyvinyl alcohol.
Described antifreeze is selected from: one or more in glycerine, ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, the polyethylene glycol.
Described antifoaming agent is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (like capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described emulsifier is selected from: agricultural newborn 500# (alkyl benzene calcium sulfonate); OP series phosphate (NPE phosphate); 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate); Styrene polyoxyethylene ether ammonium sulfate salt; Alkyl biphenyl ether disulfonic acid magnesium salts; Triethanolamine salt; Farming newborn 400# (benzyl dimethyl phenol polyoxy ethyl ether); Farming newborn 600# (phenyl phenol polyoxy ethyl ether); Nongru-700 # (alkylphenol-formaldehyde resin polyoxy ethyl ether); Farming newborn 36# (phenethyl fluosite polyoxy ethyl ether); Farming newborn 1600# (phenethyl phenol polyoxy ethyl polypropylene-base ether); Ethylene oxide-propylene oxide block copolymer; OP series (NPE); By series (castor oil polyoxyethylene ether); Farming newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether); Farming newborn 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether); Sapn series (sorbitan monostearate); Tween series (sorbitan fatty acid ester APEO); In the AEO series (the pure APEO of fat) one or more.
Described stabilizing agent is selected from: one or more in BHT, triphenyl phosphite, epoxychloropropane, tributyl phosphate, triethanolamine, diethanol amine, the monoethanolamine.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention can be by the user before use through dilution or directly use.Its preparation can be by the preparation of common processing method, is about to active substance and after liquid flux or solid carrier mix, and adds in surfactant such as dispersant, stabilizing agent, wetting agent, adhesive, antifoaming agent, the stabilizing agent etc. one or more again.
Bactericidal composition of the present invention can be processed into acceptable forms on any agricultural chemicals on demand.Wherein comparatively preferably wetting powder, water dispersible granules, suspending agent or suspension emulsion;
When processing wetting powder, composition comprises following constituent content: fluorine pyrrole bacterium amine 1～50%, effective active composition B 1～80%, dispersant 5～10%, wetting agent 2～10%, filler 8～91%.
The former medicine of fluorine pyrrole bacterium amine, the former medicine of effective active composition B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into the wetting powder product of the present composition.
When processing water dispersible granules, composition comprises following constituent content: fluorine pyrrole bacterium amine 1～50%, effective active composition B 1～80%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, binding agent 1～8%, filler 10～92%.
The former medicine of fluorine pyrrole bacterium amine, the former medicine of effective active composition B, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, add other auxiliary agents such as binding agent again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that article are quantitatively sent the fluidized bed granulation dryer to, makes the water dispersible granules product of the present composition.
When processing suspending agent, composition comprises following constituent content: fluorine pyrrole bacterium amine 1～30%, effective active composition B 1～50%, dispersant 2～10%; Wetting agent 2～10%; Antifoaming agent 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%; Stabilizing agent 0.05～3%, deionized water adds to 100%.
Dispersant, wetting agent, antifoaming agent, thickener, antifreeze in the above-mentioned formulation material are mixed through high speed shear; Add the former medicine of fluorine pyrrole bacterium amine, the former medicine of effective active composition B; Ball milling is 2～3 hours in ball mill; Make diameter of particle all below 51 μ m, make the suspending agent product of the present composition.
Comprise following constituent content when composition is processed suspension emulsion: fluorine pyrrole bacterium amine 1～30%, effective active composition B 1～50%, emulsifier 2～12%, dispersant 2～10%, antifoaming agent 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, water add to 100%.
Dispersant, antifoaming agent, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear; Add the former medicine of effective active composition B; Ball milling is 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, makes effective active composition B suspending agent; Then with the former medicine of fluorine pyrrole bacterium amine, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make the suspension emulsion product of the present composition.
The described bactericidal composition that contains fluorine pyrrole bacterium amine and active component B is used for preventing and treating disease due to the germ of child Gammaproteobacteria, Basidiomycetes and Fungi Imperfecti; For example can be used for many kinds of crops: fruit tree, wheat, cucumber, grape, vegetables and flowers and paddy rice, preventing and treating Basidiomycetes, Ascomycetes and the microbial plant disease of deuteromycetes pathogeny especially has good preventive effect to plant diseases such as the microbial disease of basidiomycetes, imperfect fungus and ascus such as scab, eqpidemic disease, downy mildew, powdery mildew, spot defoliation, leaf spot, ring spot, rust, anthracnose.
Beneficial effect of the present invention: (1) is owing to the mechanism of action of single agent in the said composition is different; The problem that does not have cross resistance; So; The application of said composition can reach and delay drug-fast generation of pathogen and development, and the result of use that helps to prolong this medicament reduces the purpose that pesticide resistance produces probability.(2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single agent, and dosage is little; (3) with an organic solvent dosage is few in the present invention, is difficult for producing poisoning, is convenient to transportation and storage, has improved safety, and being mixed will be lower, safer to the influence of environment.(4) present composition has enlarged fungicidal spectrum, and plant diseases such as scab, eqpidemic disease, downy mildew, powdery mildew, banded sclerotial blight, spot defoliation, leaf spot, ring spot, rust, anthracnose are had special efficacy.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Embodiment
The present invention is explained further that the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
Application implementation example one
Instance 1 41% fluorine pyrrole bacterium amine mancozeb wettable powder
Fluorine pyrrole bacterium amine 40%, mancozeb 1%, lignosulfonates 10%, tea are withered 6%, attapulgite adds to 100%, and mixture carries out comminution by gas stream, makes 41% fluorine pyrrole bacterium amine mancozeb wettable powder.
Instance 2 70% fluorine pyrrole bacterium amine mancozeb wettable powders
Fluorine pyrrole bacterium amine 10%, mancozeb 60%, ester polyoxyethylene are phonetic 6%, lauryl sodium sulfate 5%, bentonite add to 100%, and mixture carries out comminution by gas stream, makes 70% fluorine pyrrole bacterium amine mancozeb wettable powder.
Instance 3 81% fluorine pyrrole bacterium amine mancozeb wettable powders
Fluorine pyrrole bacterium amine 1%, mancozeb 80%, alkylnaphthalene sulfonate 5%, neopelex 4%, white carbon add to 100%, and mixture carries out comminution by gas stream, make 81% fluorine pyrrole bacterium amine mancozeb wettable powder.
Instance 4 48% fluorine pyrrole bacterium amine mancozeb water dispersible granules
Fluorine pyrrole bacterium amine 3%, mancozeb 45%, polycarboxylate 7%, soapberry powder 5%, sodium carbonate 2%, diatomite add to 100%, the mixed 48% fluorine pyrrole bacterium amine mancozeb water dispersible granule that gets.
Instance 5 55% fluorine pyrrole bacterium amine mancozeb water dispersible granules
Fluorine pyrrole bacterium amine 5%, mancozeb 50%, polyoxyethylene carboxylate 6%, wetting and penetrating agent F 5%, ammonium sulfate 2.5%, kaolin add to 100%, the mixed 55% fluorine pyrrole bacterium amine mancozeb water dispersible granule that gets.
Instance 6 80% fluorine pyrrole bacterium amine mancozeb water dispersible granules
Fluorine pyrrole bacterium amine 10%, mancozeb 70%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, silkworm excrement 3%, bentonite add to 100%, the mixed 80% fluorine pyrrole bacterium amine mancozeb water dispersible granule that gets.
Instance 7 21% fluorine pyrrole bacterium amine mancozeb suspending agents
Fluorine pyrrole bacterium amine 1%, mancozeb 20%, lignosulfonates 7%, sldium lauryl sulfate 3%, silicone oil 0.3%, xanthans 0.7%, propane diols 2.5%, deionized water add to 100%, the mixed 21% fluorine pyrrole bacterium amine mancozeb suspending agent that gets.
Instance 8 30% fluorine pyrrole bacterium amine mancozeb suspending agents
Fluorine pyrrole bacterium amine 5%, mancozeb 25%, polycarboxylate 6%, soapberry powder 4%, C
8～10Aliphatic alcohols 0.1%, methylcellulose 0.8%, polyethylene glycol 3%, deionized water add to 100%, the mixed 30% fluorine pyrrole bacterium amine mancozeb suspending agent that gets.
Instance 9 44% fluorine pyrrole bacterium amine mancozeb suspending agents
Fluorine pyrrole bacterium amine 4%, mancozeb 40%, aryl phenol polyoxyethylene succinate sulfonate 8%, spaonin powder 5%, silicone oil 0.4%, polyvinyl alcohol 1.1%, glycerine 2.4%, deionized water add to 100%, the mixed 44% fluorine pyrrole bacterium amine mancozeb suspending agent that gets.
Instance 10 11% fluorine pyrrole bacterium amine mancozeb suspension emulsions
Fluorine pyrrole bacterium amine 10%, mancozeb 1%, aliphatic amine polyoxyethylene are phonetic 5%, lauryl sodium sulfate 4%, C
10～20Saturated fat acids 0.2%, hydroxyethylcellulose 0.8%, sorbitan monostearate 6%, ethylene glycol 2%, water add to 100%, and the aforementioned formula material is mixed, and promptly make 11% fluorine pyrrole bacterium amine mancozeb suspension emulsion.
Instance 11 12% fluorine pyrrole bacterium amine mancozeb suspension emulsions
Fluorine pyrrole bacterium amine 6%, mancozeb 6%, alkyl benzene sulfonate calcium salt 9%, soapberry powder 5%, silicone compound 0.5%, Magnesiumaluminumsilicate 1.2%, phenyl phenol polyoxy ethyl ether phosphate 7%, triethylene glycol 2.8%, water add to 100%; The aforementioned formula material is mixed, promptly make 12% fluorine pyrrole bacterium amine mancozeb suspension emulsion.
Instance 12 45% fluorine pyrrole bacterium amine mancozeb suspension emulsions
Fluorine pyrrole bacterium amine 5%, mancozeb 40%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 5%, Nekal BX 4%, sorbitan fatty acid ester APEO 6%, xanthans 0.9%, propane diols 2%, silicone 0.1%, water add to 100%, through the mixed 45% fluorine pyrrole bacterium amine mancozeb suspension emulsion that gets.
Instance 13 55% fluorine pyrrole bacterium amine Wettable propineb powders
Fluorine pyrrole bacterium amine 5%, Propineb 50%, polycarboxylate 8%, sldium lauryl sulfate 5%, kaolin add to 100%, and mixture carries out comminution by gas stream, make 55% fluorine pyrrole bacterium amine Wettable propineb powder.
Instance 14 63% fluorine pyrrole bacterium amine Wettable propineb powders
Fluorine pyrrole bacterium amine 3%, Propineb 60%, lignosulfonates 6%, silkworm excrement 4%, diatomite add to 100%, and mixture carries out comminution by gas stream, make 63% fluorine pyrrole bacterium amine Wettable propineb powder.
Instance 15 80% fluorine pyrrole bacterium amine Wettable propineb powders
Fluorine pyrrole bacterium amine 10%, Propineb 70%, aliphatic amine polyoxyethylene are phonetic 7%, lauryl sodium sulfate 5%, attapulgite add to 100%, and mixture carries out comminution by gas stream, makes 80% fluorine pyrrole bacterium amine Wettable propineb powder.
Instance 16 81% fluorine pyrrole bacterium amine Wettable propineb powders
Fluorine pyrrole bacterium amine 1%, Propineb 80%, alkylnaphthalene sulfonate 6%, wetting and penetrating agent F 4%, white carbon add to 100%, and mixture carries out comminution by gas stream, make 81% fluorine pyrrole bacterium amine Wettable propineb powder.
Instance 17 36% fluorine pyrrole bacterium amine Propineb water dispersible granules
The phonetic formaldehyde condensation products sulphate of fluorine pyrrole bacterium amine 6%, Propineb 30%, alkylphenol-polyethenoxy 9%, Nekal BX 4%, urea 2.7%, starch add to 100%, mixed 36% fluorine pyrrole bacterium amine Propineb water dispersible granules.
Instance 18 45% fluorine pyrrole bacterium amine Propineb water dispersible granules
Fluorine pyrrole bacterium amine 5%, Propineb 40%, lignosulfonates 7%, spaonin powder 5%, aluminium chloride 3%, bentonite add to 100%, the mixed 45% fluorine pyrrole bacterium amine Propineb water dispersible granules that gets.
Instance 19 70% fluorine pyrrole bacterium amine Propineb water dispersible granules
Fluorine pyrrole bacterium amine 10%, Propineb 60%, naphthalene sulfonic acid-formaldehyde condensation product 8%, soapberry powder 4%, sodium carbonate 2.5%, kaolin add to 100%, the mixed 70% fluorine pyrrole bacterium amine Propineb water dispersible granules that gets.
Instance 20 80% fluorine pyrrole bacterium amine Propineb water dispersible granules
Fluorine pyrrole bacterium amine 5%, Propineb 75%, alkyl benzene sulfonate calcium salt 5%, wetting and penetrating agent F4%, ammonium sulfate 2%, white carbon add to 100%, the mixed 80% fluorine pyrrole bacterium amine Propineb water dispersible granules that gets.
Instance 21 42% fluorine pyrrole bacterium amine Zineb wettable powders
Fluorine pyrrole bacterium amine 40%, zineb 2%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, spaonin powder 3%, precipitated calcium carbonate add to 100%, and mixture carries out comminution by gas stream, make 42% fluorine pyrrole bacterium amine Zineb wettable powder.
Instance 22 60% fluorine pyrrole bacterium amine Zineb wettable powders
Fluorine pyrrole bacterium amine 10%, zineb 50%, ester polyoxyethylene are phonetic 7%, neopelex 6%, bentonite add to 100%, and mixture carries out comminution by gas stream, makes 60% fluorine pyrrole bacterium amine Zineb wettable powder.
Instance 23 78% fluorine pyrrole bacterium amine Zineb wettable powders
Fluorine pyrrole bacterium amine 3%, zineb 75%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, tea are withered 4%, kaolin adds to 100%, and mixture carries out comminution by gas stream, makes 78% fluorine pyrrole bacterium amine Zineb wettable powder.
Instance 24 48% fluorine pyrrole bacterium amine water dispersion granules agent of dithane
Fluorine pyrrole bacterium amine 8%, zineb 40%, lignosulfonates 8%, lauryl sodium sulfate 6%, urea 3%, diatomite add to 100%, the mixed 48% fluorine pyrrole bacterium amine water dispersion granules agent of dithane that gets.
Instance 25 55% fluorine pyrrole bacterium amine water dispersion granules agent of dithane
Fluorine pyrrole bacterium amine 5%, zineb 50%, octylphenol polyethylene oxyethylene group ether sulfate 6%, Nekal BX 4%, ammonium sulfate 3%, attapulgite add to 100%, the mixed 55% fluorine pyrrole bacterium amine water dispersion granules agent of dithane that gets.
Instance 26 75% fluorine pyrrole bacterium amine water dispersion granules agent of dithane
Fluorine pyrrole bacterium amine 10%, zineb 65%, alkyl benzene sulfonate calcium salt 8%, wetting and penetrating agent F 5%, sodium bicarbonate 2%, bentonite add to 100%, the mixed 75% fluorine pyrrole bacterium amine water dispersion granules agent of dithane that gets.
Instance 27 20% fluorine pyrrole bacterium amine zineb suspending agents
Fluorine pyrrole bacterium amine 2%, zineb 18%, polycarboxylate 6%, soapberry powder 4%, C
8～10Aliphatic alcohols 0.2%, xanthans 1%, ethylene glycol 2.8%, deionized water add to 100%, the mixed 20% fluorine pyrrole bacterium amine zineb suspending agent that gets.
Instance 28 33% fluorine pyrrole bacterium amine zineb suspending agents
Fluorine pyrrole bacterium amine 3%, zineb 30%, lignosulfonates 3%, neopelex 4%, silicone oil 0.2%, Magnesiumaluminumsilicate 0.7%, glycerine 2.5%, deionized water add to 100%, the mixed 33% fluorine pyrrole bacterium amine zineb suspending agent that gets.
Instance 29 48% fluorine pyrrole bacterium amine zineb suspending agents
Fluorine pyrrole bacterium amine 8%, zineb 40%, polycarboxylate 8%, neopelex 5%, silicone oil 0.1%, polyvinylpyrrolidone 0.9%, ethylene glycol 3%, deionized water add to 100%, the mixed 48% fluorine pyrrole bacterium amine zineb suspending agent that gets.
Instance 30 10% fluorine pyrrole bacterium amine zineb suspension emulsions
Fluorine pyrrole bacterium amine 5%, zineb 5%, aryl phenol polyoxyethylene succinate sulfonate 6%, lauryl sodium sulfate 3%, silicone compound 0.2%, Magnesiumaluminumsilicate 0.8%, propane diols 3%, agricultural newborn 1600#9%, water add to 100%; The aforementioned formula material is mixed, promptly make 10% fluorine pyrrole bacterium amine zineb suspension emulsion.
Instance 31 22% fluorine pyrrole bacterium amine zineb suspension emulsions
Fluorine pyrrole bacterium amine 20%, zineb 2%, alkyl benzene sulfonate calcium salt 6%, neopelex 4%, PAA 0.3%, hydroxyethylcellulose 0.7%, diethylene glycol (DEG) 2.7%, agricultural newborn 500#8%, water add to 100%; The aforementioned formula material is mixed, promptly make 22% fluorine pyrrole bacterium amine zineb suspension emulsion.
Instance 32 45% fluorine pyrrole bacterium amine zineb suspension emulsions
Fluorine pyrrole bacterium amine 5%, zineb 40%, polycarboxylate 8%, wetting and penetrating agent F 4%, Magnesiumaluminumsilicate 1.2%, glycerine 3%, C
8～10Aliphatic alcohols 0.5%, castor oil polyoxyethylene ether 6%, water add to 100%, through the mixed 45% fluorine pyrrole bacterium amine zineb suspension emulsion that gets.
Instance 33 66% fluorine pyrrole bacterium amine thioneb wettable powders
Fluorine pyrrole bacterium amine 6%, Carbatene 60%, naphthalene sulfonic acid-formaldehyde condensation product 8%, wetting and penetrating agent F 6%, diatomite add to 100%, and mixture carries out comminution by gas stream, make 66% fluorine pyrrole bacterium amine thioneb wettable powder.
Instance 34 70% fluorine pyrrole bacterium amine thioneb wettable powders
Fluorine pyrrole bacterium amine 10%, Carbatene 60%, lignosulfonates 6%, soapberry powder 5%, kaolin add to 100%, and mixture carries out comminution by gas stream, make 70% fluorine pyrrole bacterium amine thioneb wettable powder.
Instance 35 81% fluorine pyrrole bacterium amine thioneb wettable powders
Fluorine pyrrole bacterium amine 1%, Carbatene 80%, alkyl benzene sulfonate calcium salt 7%, lauryl sodium sulfate 5%, white carbon add to 100%, and mixture carries out comminution by gas stream, make 81% fluorine pyrrole bacterium amine thioneb wettable powder.
Instance 36 44% fluorine pyrrole bacterium amine Carbatene water dispersible granules
Fluorine pyrrole bacterium amine 4%, Carbatene 40%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6%, wetting and penetrating agent F 5%, aluminium chloride 3%, attapulgite add to 100%, the mixed 44% fluorine pyrrole bacterium amine Carbatene water dispersible granules that gets.
Instance 37 65% fluorine pyrrole bacterium amine Carbatene water dispersible granules
Fluorine pyrrole bacterium amine 10%, Carbatene 55%, polyoxyethylene carboxylate 8%, lauryl sodium sulfate 6%, ammonium sulfate 2%, kaolin add to 100%, the mixed 65% fluorine pyrrole bacterium amine Carbatene water dispersible granules that gets.
Instance 38 80% fluorine pyrrole bacterium amine Carbatene water dispersible granules
Fluorine pyrrole bacterium amine 5%, Carbatene 75%, naphthalene sulfonic acid-formaldehyde condensation product 6%, neopelex 4%, bentonite add to 100%, the mixed 80% fluorine pyrrole bacterium amine Carbatene water dispersible granules that gets.
Instance 39 10% fluorine pyrrole bacterium amine Carbatene suspending agents
Fluorine pyrrole bacterium amine 5%, Carbatene 5%, octylphenol polyethylene oxyethylene group ether sulfate 6%, sldium lauryl sulfate 4%, C
10～20Saturated fat acids 0.1%, hydroxyethylcellulose 1%, ethylene glycol 3%, deionized water adds to 100%, the mixed 10% fluorine pyrrole bacterium amine Carbatene suspending agent that gets.
Instance 40 30% fluorine pyrrole bacterium amine Carbatene suspending agents
The phonetic formaldehyde condensation products sulphate of fluorine pyrrole bacterium amine 3%, Carbatene 27%, alkylphenol-polyethenoxy 7%, neopelex 4%, silicone oil 0.3%, polyvinylpyrrolidone 0.9%, diethylene glycol (DEG) 2.8%; Deionized water adds to 100%, the mixed 30% fluorine pyrrole bacterium amine Carbatene suspending agent that gets.
Instance 41 36% fluorine pyrrole bacterium amine Carbatene suspending agents
Fluorine pyrrole bacterium amine 4%, Carbatene 32%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, neopelex 3%, silicone oil 0.2%, sodium phosphate trimer 0.8%, polyethylene glycol 2.1%; Deionized water adds to 100%, the mixed 36% fluorine pyrrole bacterium amine Carbatene suspending agent that gets.
Instance 42 11% fluorine pyrrole bacterium amine Carbatene suspension emulsions
Fluorine pyrrole bacterium amine 1%, Carbatene 10%, lignosulfonates 8%, wetting and penetrating agent F 5%, silicone 0.5%, ethylene glycol 2.6%, xanthans 1.2%, alkylphenol-formaldehyde resin polyoxy ethyl ether 7%; Water adds to 100%, the mixed 11% fluorine pyrrole bacterium amine Carbatene suspension emulsion that gets.
Instance 43 20% fluorine pyrrole bacterium amine Carbatene suspension emulsions
Fluorine pyrrole bacterium amine 5%, Carbatene 15%, polyoxyethylene carboxylate 7%, lauryl sodium sulfate 5%, silicone oil 0.2%, propane diols 2%, Magnesiumaluminumsilicate 1.1%, styrene polyoxyethylene ether ammonium sulfate salt 8%; Water adds to 100%, the mixed 20% fluorine pyrrole bacterium amine Carbatene suspension emulsion that gets.
Instance 44 33% fluorine pyrrole bacterium amine Carbatene suspension emulsions
Fluorine pyrrole bacterium amine 30%, Carbatene 3%, the ester polyoxyethylene is phonetic 6%, neopelex 4%, xanthans 0.7%, agricultural newborn 33#6%, C
8～10Aliphatic alcohols 0.1%, glycerine 3%, water add to 100%, the mixed 33% fluorine pyrrole bacterium amine Carbatene suspension emulsion that gets.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect, on this basis, carry out field trial again.
Fluorine pyrrole bacterium amine and active component B (active component B is selected from a kind of of mancozeb, Propineb, zineb, Carbatene) are composite to the crop pest Toxicity Determination.
After the effective inhibition concentration scope of each medicament was confirmed in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament the crop germ.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is following:
Wherein: a, b are respectively active component fluorine pyrrole bacterium amine and active component B (mancozeb, Propineb, Carbatene, zineb) shared ratio in combination;
A is a fluorine pyrrole bacterium amine;
B is a kind of in mancozeb, Propineb, zineb, the Carbatene.
Practice example two:
Fluorine pyrrole bacterium amine and mancozeb are composite to the potato late blight Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of confirming fluorine pyrrole bacterium amine, the former medicine of mancozeb and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 1 fluorine pyrrole bacterium amine, mancozeb and composite toxicity test analysis of results table thereof to potato late blight
Can know that by table 1 fluorine pyrrole bacterium amine, mancozeb are to the EC of potato late blight
50Be respectively 1.87mg/L and 28.95mg/L.The virulence of fluorine pyrrole bacterium amine is higher than the virulence of mancozeb.Fluorine pyrrole bacterium amine and mancozeb proportioning were at 50: 1 to 1: 80 o'clock; Synergy ratio SR is all greater than 1.5; Explaining that fluorine pyrrole bacterium amine and mancozeb were mixed in the scope at 50: 1 to 1: 80 all shows synergistic effect; Especially when the two proportioning during at 1: 1 to 1: 20; Synergistic effect is more obviously outstanding, synergy ratio SR maximum when fluorine pyrrole bacterium amine and mancozeb weight ratio are 1: 10 wherein, and synergistic effect is the most obvious; Test is found; When the proportioning of fluorine pyrrole bacterium amine and mancozeb during at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20,1: 21,1: 22,1: 23,1: 24,1: 25 to wheat rust, banded sclerotial blight, vegetables downy mildew, black spot of fruit tree, ring spot, spot defoliation, anthracnose; Synergistic effect is obvious, and synergy ratio is all greater than 1.5.
Practice example three
Fluorine pyrrole bacterium amine and Propineb are composite to the cucumber downy mildew Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of confirming fluorine pyrrole bacterium amine, the former medicine of Propineb and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 2 fluorine pyrrole bacterium amine, Propineb and composite toxicity test analysis of results table thereof to cucumber downy mildew
Can know that by table 2 fluorine pyrrole bacterium amine, Propineb are to the EC of cucumber downy mildew
50Be respectively 2.04mg/L and 28.15mg/L.The virulence of fluorine pyrrole bacterium amine is higher than the virulence of Propineb.Fluorine pyrrole bacterium amine and Propineb proportioning were at 50: 1 to 1: 80 o'clock; Synergy ratio SR is all greater than 1.5; Explaining that fluorine pyrrole bacterium amine and Propineb were mixed in the scope at 50: 1 to 1: 80 all shows synergistic effect; Especially when the two proportioning during at 1: 1 to 1: 20; Synergistic effect is more obviously outstanding, synergy ratio SR maximum when fluorine pyrrole bacterium amine and Propineb weight ratio are 1: 10 wherein, and synergistic effect is the most obvious; Test is found; When the proportioning of fluorine pyrrole bacterium amine and Propineb during at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20,1: 21,1: 22,1: 23,1: 24,1: 25 to wheat rust, banded sclerotial blight, powdery mildew, vegetables downy mildew, eqpidemic disease, black spot of fruit tree, ring spot, spot defoliation, anthracnose; Synergistic effect is obvious, and synergy ratio is all greater than 1.5.
Practice example four
Fluorine pyrrole bacterium amine and zineb are composite to the early blight of tomato Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of confirming fluorine pyrrole bacterium amine, the former medicine of zineb and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 3 fluorine pyrrole bacterium amine, zineb and composite toxicity test analysis of results table thereof to early blight of tomato
Can know that by table 3 fluorine pyrrole bacterium amine, zineb are to the EC of early blight of tomato
50Be respectively 2.12mg/L and 27.93mg/L.The virulence of fluorine pyrrole bacterium amine is higher than the virulence of zineb.Fluorine pyrrole bacterium amine and zineb proportioning were at 50: 1 to 1: 80 o'clock; Synergy ratio SR is all greater than 1.5; Explaining that fluorine pyrrole bacterium amine and zineb were mixed in the scope at 50: 1 to 1: 80 all shows synergistic effect; Especially when the two proportioning during at 1: 1 to 1: 20, synergistic effect is more obviously outstanding, wherein synergy ratio SR maximum when fluorine pyrrole bacterium amine and zineb weight ratio are 1: 10; Synergistic effect is the most obvious; Test finds, when the proportioning of fluorine pyrrole bacterium amine and zineb during at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20,1: 21,1: 22,1: 23,1: 24,1: 25 to wheat rust, banded sclerotial blight, powdery mildew, crop downy mildew, eqpidemic disease; The synergistic effect of fruit tree ring spot is obvious, and synergy ratio is all greater than 1.5.
Practice example five
Fluorine pyrrole bacterium amine and Carbatene are composite to the apple anthracnose Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of confirming fluorine pyrrole bacterium amine, the former medicine of Carbatene and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 4 fluorine pyrrole bacterium amine, Carbatene and composite toxicity test analysis of results table thereof to apple anthracnose
Can know that by table 4 fluorine pyrrole bacterium amine, Carbatene are to the EC of apple anthracnose
50Be respectively 1.89mg/L and 26.45mg/L.The virulence of fluorine pyrrole bacterium amine is higher than the virulence of Carbatene.Fluorine pyrrole bacterium amine and Carbatene proportioning were at 50: 1 to 1: 80 o'clock; Synergy ratio SR is all greater than 1.5; Explaining that fluorine pyrrole bacterium amine and Carbatene were mixed in the scope at 50: 1 to 1: 80 all shows synergistic effect; Especially when the two proportioning during at 1: 1 to 1: 20; Synergistic effect is more obviously outstanding, synergy ratio SR maximum when fluorine pyrrole bacterium amine and Carbatene weight ratio are 1: 10 wherein, and synergistic effect is the most obvious; Test is found; When the proportioning of fluorine pyrrole bacterium amine and Carbatene during at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20,1: 21,1: 22,1: 23,1: 24,1: 25 to wheat rust, powdery mildew, banded sclerotial blight, vegetables downy mildew, eqpidemic disease, black spot of fruit tree, ring spot, spot defoliation, shot hole; Synergistic effect is obvious, and synergy ratio is all greater than 1.5.
Application implementation example hexafluoro pyrrole bacterium amine and the mancozeb and the composite potato late blight test of pesticide effectiveness of preventing and treating thereof
This EE is in Yian County, Qiqihaer City, Heilongjiang Province, and test medicine is provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 687.5 grams per liter fluorine pyrrole bacterium amine propamocarb suspending agents (commercial), 80% mancozeb wettable powder (commercial).
The investigation potato late blight state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 10 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the second time.Experimental result is as follows:
Table 5 fluorine pyrrole bacterium amine, mancozeb and the composite potato late blight test of pesticide effectiveness of preventing and treating thereof
Can find out that by table 5 can effectively prevent and treat potato late blight after fluorine pyrrole bacterium amine and mancozeb are composite, control efficiency all is superior to the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects; Simultaneously to wheat rust, vegetables downy mildew, the preventive effect of the common diseases of crop such as black spot of fruit tree, ring spot, spot defoliation, anthracnose is all more than 95%; Be superior to single agent preventive effect, synergistic effect is obvious.
Application implementation example seven fluorine pyrrole bacterium amine and the Propineb and the composite control cucumber downy mildew test of pesticide effectiveness thereof
This EE is the Weinan City Linwei District in Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 687.5 grams per liter fluorine pyrrole bacterium amine propamocarb suspending agents (commercial), 70% Wettable propineb powder (commercial).
The preceding investigation of medicine cucumber downy mildew disease index, in the their early stage dispenser, dispenser for the second time after 10 days, dispenser is 2 times altogether, investigates disease indexs in 7 days, 15 days, 30 days after the dispenser for the second time and calculates preventive effect.Experimental result is as follows:
Table 6 fluorine pyrrole bacterium amine, Propineb and the composite control cucumber downy mildew test of pesticide effectiveness thereof
Can find out that by table 6 can effectively prevent and treat cucumber downy mildew after fluorine pyrrole bacterium amine and Propineb are composite, control efficiency all is superior to the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects; Simultaneously to wheat rust, powdery mildew, vegetables downy mildew, eqpidemic disease, the preventive effect of the common diseases of crop such as black spot of fruit tree, ring spot, spot defoliation, anthracnose is all more than 95%; Be superior to single agent preventive effect, synergistic effect is obvious.
Application implementation example octafluoro pyrrole bacterium amine and the zineb and the composite early blight of tomato test of pesticide effectiveness of preventing and treating thereof
This EE is Changan District in the Xian City, Shanxi Province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 687.5 grams per liter fluorine pyrrole bacterium amine propamocarb suspending agents (commercial), 80% Zineb wettable powder (commercial).
The investigation early blight of tomato state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the second time.Experimental result is as follows:
Table 7 fluorine pyrrole bacterium amine, zineb and the composite early blight of tomato test of pesticide effectiveness of preventing and treating thereof
Can find out that by table 7 can effectively prevent and treat early blight of tomato after fluorine pyrrole bacterium amine and zineb are composite, control efficiency all is superior to the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects; Simultaneously to wheat rust, banded sclerotial blight, powdery mildew, vegetables downy mildew, eqpidemic disease, the preventive effect of the common diseases of crop such as black spot of fruit tree, ring spot, shot hole is all more than 95%; Be superior to single agent preventive effect, synergistic effect is obvious.
Application implementation example nine fluorine pyrrole bacterium amine and the Carbatene and the composite control apple anthracnose test of pesticide effectiveness thereof
This EE is in Liquan County, Xianyang, Shanxi province city, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 687.5 grams per liter fluorine pyrrole bacterium amine propamocarb suspending agents (commercial), 70% Carbatene water dispersible granules (commercial).
The preceding investigation of medicine apple anthracnose disease index, in the their early stage dispenser, dispenser for the second time after 10 days, dispenser is 2 times altogether, investigates disease indexs in 7 days, 15 days, 30 days after the dispenser for the second time and calculates preventive effect.Experimental result is as follows:
Table 8 fluorine pyrrole bacterium amine, Carbatene and the composite control apple anthracnose test of pesticide effectiveness thereof
Can find out that by table 8 can effectively prevent and treat apple anthracnose after fluorine pyrrole bacterium amine and Carbatene are composite, control efficiency all is superior to the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects; Simultaneously to powdery mildew, banded sclerotial blight, vegetables downy mildew, eqpidemic disease; The preventive effect of the common diseases of crop such as black spot of fruit tree, ring spot, spot defoliation, shot hole is superior to single agent preventive effect all more than 95%, and synergistic effect is obvious.
Claims (9)
1. the bactericidal composition of fluorine-containing pyrrole bacterium amine and thiocarbamates compound; It is characterized in that: the weight ratio of A, two kinds of active components of B is 50: 1～1: 80; Described A component is a fluorine pyrrole bacterium amine, and the B component is selected from a kind of in mancozeb, Propineb, zineb or the Carbatene.
2. bactericidal composition according to claim 1 is characterized in that: the weight ratio of A, two kinds of active components of B is 40: 1～1: 70.
3. bactericidal composition according to claim 2 is characterized in that: the weight ratio of fluorine pyrrole bacterium amine and mancozeb is 1: 1～1: 20.
4. bactericidal composition according to claim 2 is characterized in that: the weight ratio of fluorine pyrrole bacterium amine and Propineb is 1: 1～1: 20.
5. bactericidal composition according to claim 2 is characterized in that: the weight ratio of fluorine pyrrole bacterium amine and zineb is 1: 1～1: 20.
6. bactericidal composition according to claim 2 is characterized in that: the weight ratio of fluorine pyrrole bacterium amine and Carbatene is 1: 1～1: 20.
7. bactericidal composition according to claim 1 is characterized in that: composition is processed wetting powder, water dispersible granules, suspending agent or suspension emulsion.
8. bactericidal composition according to claim 1 is characterized in that: bactericidal composition is used to prevent and treat the application of the plant disease of fruit tree, wheat, vegetables, flowers and paddy rice.
9. application according to claim 8 is characterized in that: described plant disease comprises scab, eqpidemic disease, downy mildew, powdery mildew, banded sclerotial blight, spot defoliation, leaf spot, ring spot, rust, anthracnose.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103120169A (en) * | 2011-11-18 | 2013-05-29 | 深圳诺普信农化股份有限公司 | Sterilizing composition containing fluopicolide |
| CN103155932A (en) * | 2013-03-27 | 2013-06-19 | 北京燕化永乐农药有限公司 | Sterilizing compound |
| CN103385245A (en) * | 2012-05-11 | 2013-11-13 | 陕西韦尔奇作物保护有限公司 | Bactericidal composition comprising tiadinil and thiocarbamate |
| CN103518741A (en) * | 2012-07-06 | 2014-01-22 | 陕西美邦农药有限公司 | Fluopyram-containing high-efficiency bactericidal composition |
| CN107258803A (en) * | 2017-06-19 | 2017-10-20 | 陕西先农生物科技有限公司 | Composition pesticide of containing fluopicolide and Carbatene and preparation method thereof |
| CN108812673A (en) * | 2013-09-02 | 2018-11-16 | 张通 | A kind of composition pesticide of fluorine-containing ether bacterium amide |
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| EP2245934A2 (en) * | 2007-09-12 | 2010-11-03 | Bayer CropScience AG | Post-harvest treatment |
| CN102204537A (en) * | 2011-05-05 | 2011-10-05 | 青岛海利尔药业有限公司 | Antibacterial composition containing fluopicolide and ethofenprox |
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| CN1301645C (en) * | 2001-10-23 | 2007-02-28 | 拜尔农科股份有限公司 | Fungicidal composition based on at least one pyridylmethylbenzamide derivatives and at least on dithiocarbamate derivative |
| EP2245934A2 (en) * | 2007-09-12 | 2010-11-03 | Bayer CropScience AG | Post-harvest treatment |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103120169A (en) * | 2011-11-18 | 2013-05-29 | 深圳诺普信农化股份有限公司 | Sterilizing composition containing fluopicolide |
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| CN103518741A (en) * | 2012-07-06 | 2014-01-22 | 陕西美邦农药有限公司 | Fluopyram-containing high-efficiency bactericidal composition |
| CN103155932A (en) * | 2013-03-27 | 2013-06-19 | 北京燕化永乐农药有限公司 | Sterilizing compound |
| CN108812673A (en) * | 2013-09-02 | 2018-11-16 | 张通 | A kind of composition pesticide of fluorine-containing ether bacterium amide |
| CN107258803A (en) * | 2017-06-19 | 2017-10-20 | 陕西先农生物科技有限公司 | Composition pesticide of containing fluopicolide and Carbatene and preparation method thereof |
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