CN101998883B - 含钯催化剂及其在选择性氢化中的应用 - Google Patents

含钯催化剂及其在选择性氢化中的应用 Download PDF

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CN101998883B
CN101998883B CN200880113931.5A CN200880113931A CN101998883B CN 101998883 B CN101998883 B CN 101998883B CN 200880113931 A CN200880113931 A CN 200880113931A CN 101998883 B CN101998883 B CN 101998883B
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catalyst
palladium
carrier
volume
particle
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CN101998883A (zh
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L·费希尔
C·佩蒂特-克莱尔
C·托马佐
L·索比尔
C·弗唐
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IFP Energies Nouvelles IFPEN
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0211—Impregnation using a colloidal suspension
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/40—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/394—Metal dispersion value, e.g. percentage or fraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN200880113931.5A 2007-10-29 2008-10-24 含钯催化剂及其在选择性氢化中的应用 Active CN101998883B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0707699A FR2922784B1 (fr) 2007-10-29 2007-10-29 Catalyseur comprenant du palladium et son application en hydrogenation selective
FR07/07699 2007-10-29
PCT/FR2008/001506 WO2009092879A2 (fr) 2007-10-29 2008-10-24 Catalyseur comprenant du palladium et son application hydrogenation selective

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CN101998883A CN101998883A (zh) 2011-03-30
CN101998883B true CN101998883B (zh) 2014-01-29

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Country Link
US (1) US8637719B2 (enExample)
EP (1) EP2214818B1 (enExample)
JP (1) JP5281091B2 (enExample)
CN (1) CN101998883B (enExample)
FR (1) FR2922784B1 (enExample)
WO (1) WO2009092879A2 (enExample)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2922784B1 (fr) 2007-10-29 2011-05-13 Inst Francais Du Petrole Catalyseur comprenant du palladium et son application en hydrogenation selective
WO2011107565A1 (en) * 2010-03-05 2011-09-09 Shell Internationale Research Maatschappij B.V. Hydrogenation catalyst
FR2991197B1 (fr) * 2012-05-31 2014-08-22 IFP Energies Nouvelles Catalyseur comprenant du palladium et de l'argent et son application en hydrogenation selective
FR2990882B1 (fr) * 2012-05-24 2015-05-15 IFP Energies Nouvelles Procede de preparation d'un catalyseur a base d'un metal du groupe viii et contenant du silicium et procede d'hydrogenation selective mettant en oeuvre ledit catalyseur
FR2993795B1 (fr) * 2012-07-25 2016-01-08 IFP Energies Nouvelles Procede de preparation de catalyseurs a base de particules metalliques de dispersion controlee
CN104001526B (zh) * 2014-06-13 2016-04-13 西南化工研究设计院有限公司 一种用于醋酸加氢制乙醇的催化剂及制备方法
JP6565019B2 (ja) * 2015-11-17 2019-08-28 株式会社三井Ｅ＆Ｓマシナリー 触媒の製造方法、触媒、および触媒の使用
US10752563B2 (en) 2016-03-31 2020-08-25 Zeon Corporation Hydrogenation method
FR3051684B1 (fr) * 2016-05-30 2020-09-04 Ifp Energies Now Catalyseur d'hydrogenation selective comprenant un support extrude
FR3051685B1 (fr) * 2016-05-30 2018-06-08 IFP Energies Nouvelles Procede de preparation d'un catalyseur d'hydrogenation selective .
FR3059253B1 (fr) * 2016-11-29 2020-01-17 IFP Energies Nouvelles Catalyseur d'hydrogenation selective d'une coupe d'hydrocarbures c3.
FR3059252B1 (fr) * 2016-11-29 2018-11-16 IFP Energies Nouvelles Catalyseur d’hydrogenation selective de coupes c3 de vapocraquage et/ou de craquage catalytique
WO2018207038A1 (en) 2017-05-10 2018-11-15 Sabic Global Technologies B.V. Systems and methods for isoprene purification
US10981149B2 (en) * 2019-03-18 2021-04-20 Uop Llc Dehydrogenation catalyst with optimum modifier profile index
FR3099387B1 (fr) 2019-07-31 2021-10-29 Ifp Energies Now Catalyseur comprenant une phase active de nickel repartie en croute
FR3099388B1 (fr) 2019-07-31 2021-07-16 Ifp Energies Now Catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute et un alliage nickel cuivre
FR3099391B1 (fr) 2019-07-31 2021-10-29 Ifp Energies Now Catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute
FR3099389B1 (fr) 2019-07-31 2021-07-16 Ifp Energies Now Catalyseur comprenant une phase active de nickel soufre repartie en croute
FR3099386B1 (fr) 2019-07-31 2021-07-16 Ifp Energies Now Catalyseur comprenant une phase active de nickel repartie en croute et un alliage nickel cuivre
FR3110867B1 (fr) 2020-05-29 2022-07-01 Ifp Energies Now Procede de preparation d’un catalyseur comprenant une phase active de nickel repartie en croute obtenu a partir de sels fondus
FR3110862A1 (fr) 2020-05-29 2021-12-03 IFP Energies Nouvelles Procede de preparation d’un catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute
FR3110865A1 (fr) 2020-05-29 2021-12-03 IFP Energies Nouvelles Procede de preparation d’un catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute et un alliage nickel cuivre
FR3110866B1 (fr) 2020-05-29 2022-07-01 Ifp Energies Now Procede de preparation d’un catalyseur comprenant une phase active de nickel repartie en croute
FR3110863A1 (fr) 2020-05-29 2021-12-03 IFP Energies Nouvelles Procede de preparation d’un catalyseur comprenant une phase active de nickel repartie en croute obtenu a partir de sels fondus et un alliage nickel cuivre
FR3110864B1 (fr) 2020-05-29 2022-07-01 Ifp Energies Now Procede de preparation d’un catalyseur comprenant une phase active de nickel repartie en croute et un alliage nickel cuivre
CN115069246B (zh) * 2021-03-15 2023-08-15 中国石油化工股份有限公司 一种负载型银催化剂及其制备方法和应用
FR3125439B1 (fr) 2021-07-22 2025-10-31 Ifp Energies Now Procede de preparation d’un catalyseur comprenant une phase active de nickel repartie en croute via impregnation d’hexanol
FR3125440A1 (fr) 2021-07-22 2023-01-27 IFP Energies Nouvelles Procede de preparation d’un catalyseur comprenant une phase active de nickel repartie en croute via impregnation d’heptanol
TWI806307B (zh) * 2021-12-24 2023-06-21 光洋應用材料科技股份有限公司 鈀觸媒與其製作方法
FR3132646A1 (fr) 2022-02-14 2023-08-18 IFP Energies Nouvelles Catalyseur comprenant une phase active de palladium et de cuivre
FR3132647A1 (fr) 2022-02-14 2023-08-18 IFP Energies Nouvelles Procede de preparation d’un catalyseur comprenant une phase active de palladium et de cuivre
FR3150965B1 (fr) 2023-07-10 2025-06-27 Ifp Energies Now Catalyseur comprenant du cuivre et un element de la colonne iiia
FR3150966A1 (fr) 2023-07-10 2025-01-17 IFP Energies Nouvelles Procede d’hydrogenation mettant en œuvre un catalyseur comprenant du cuivre et un element de la colonne iiia
FR3151508A1 (fr) 2023-07-28 2025-01-31 IFP Energies Nouvelles Procédé de préparation d’un catalyseur comprenant une phase active de nickel repartie en croute via imprégnation de décanol
FR3151509A1 (fr) 2023-07-28 2025-01-31 IFP Energies Nouvelles Procédé de préparation d’un catalyseur comprenant une phase active de nickel repartie en croute via imprégnation d’acide hexanoïque ou d’acide heptanoïque

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Publication number Publication date
CN101998883A (zh) 2011-03-30
JP2011500327A (ja) 2011-01-06
FR2922784A1 (fr) 2009-05-01
US20100236986A1 (en) 2010-09-23
US8637719B2 (en) 2014-01-28
JP5281091B2 (ja) 2013-09-04
FR2922784B1 (fr) 2011-05-13
WO2009092879A3 (fr) 2010-02-25
EP2214818B1 (fr) 2019-05-08
WO2009092879A2 (fr) 2009-07-30
EP2214818A2 (fr) 2010-08-11

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