CN101981083B - 在缩聚反应中显示优越的活性和选择性的基于钛的催化剂 - Google Patents

在缩聚反应中显示优越的活性和选择性的基于钛的催化剂 Download PDF

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Publication number
CN101981083B
CN101981083B CN200980111155XA CN200980111155A CN101981083B CN 101981083 B CN101981083 B CN 101981083B CN 200980111155X A CN200980111155X A CN 200980111155XA CN 200980111155 A CN200980111155 A CN 200980111155A CN 101981083 B CN101981083 B CN 101981083B
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China
Prior art keywords
catalyzer
titanium
acid
heteroaryl
aryl
Prior art date
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Expired - Fee Related
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CN200980111155XA
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English (en)
Chinese (zh)
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CN101981083A (zh
Inventor
延斯-彼得·魏格纳
福尔克马尔·弗尔谢尔
迪特马·伦克尔
罗尔夫·艾克特
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Equipolymers GmbH
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Equipolymers GmbH
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Publication of CN101981083A publication Critical patent/CN101981083A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN200980111155XA 2008-03-28 2009-03-23 在缩聚反应中显示优越的活性和选择性的基于钛的催化剂 Expired - Fee Related CN101981083B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US7223008P 2008-03-28 2008-03-28
US61/072,230 2008-03-28
PCT/IB2009/000574 WO2009118600A2 (en) 2008-03-28 2009-03-23 A new titanium-based catalyst showing excellent activity and selectivity in polycondensation reactions

Publications (2)

Publication Number Publication Date
CN101981083A CN101981083A (zh) 2011-02-23
CN101981083B true CN101981083B (zh) 2013-07-10

Family

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Family Applications (1)

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CN200980111155XA Expired - Fee Related CN101981083B (zh) 2008-03-28 2009-03-23 在缩聚反应中显示优越的活性和选择性的基于钛的催化剂

Country Status (15)

Country Link
US (3) US20110077379A1 (enExample)
EP (2) EP2479205B1 (enExample)
JP (2) JP5739322B2 (enExample)
CN (1) CN101981083B (enExample)
BR (1) BRPI0907076A2 (enExample)
CY (2) CY1114093T1 (enExample)
DK (2) DK2262846T3 (enExample)
ES (2) ES2531884T3 (enExample)
HR (2) HRP20130735T1 (enExample)
HU (1) HUE024110T2 (enExample)
PL (2) PL2479205T3 (enExample)
PT (2) PT2479205E (enExample)
SI (1) SI2479205T1 (enExample)
TW (2) TWI495659B (enExample)
WO (1) WO2009118600A2 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102875786A (zh) * 2011-07-12 2013-01-16 常州化学研究所 聚酯制备用多齿配体螯合钛系催化剂的合成方法与应用
ES2599165T3 (es) * 2012-10-29 2017-01-31 Uhde Inventa-Fischer Gmbh Procedimiento para la preparación de un poliéster o un copoliéster de alto peso molecular así como mezclas poliméricas que los contienen
FR3054551B1 (fr) * 2016-07-29 2019-08-02 Roquette Freres Composition polymere comprenant un polyester thermoplastique
CN106866712A (zh) * 2017-01-11 2017-06-20 江苏科技大学 用于耐高温水性涂料的金属离子交联剂及制备方法
CN114075238B (zh) * 2020-08-19 2023-11-17 中国石油化工股份有限公司 一种钛酸四丁二醇酯的制备方法
EP4101817A1 (en) 2021-06-11 2022-12-14 Clariant International Ltd New titanium catalyst for the polyester manufacturing process

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4260735A (en) * 1980-02-12 1981-04-07 Allied Chemical Corporation Catalytic process for preparation of polyesters
CN1261608A (zh) * 1998-12-23 2000-08-02 辛科研究有限公司 制备聚酯树脂的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5946258B2 (ja) 1976-10-05 1984-11-12 帝人株式会社 ポリエステルの製造方法
DE3300315A1 (de) 1983-01-07 1984-07-12 Dynamit Nobel Ag, 5210 Troisdorf Verfahren zur herstellung von hellfarbigen polyestern unter verwendung von titankatalysatoren
BR9202121A (pt) 1991-06-03 1993-02-02 Polyplastics Co Processo para a preparacao de um poliester e composicao de resina de poliester
IT1271309B (it) 1994-12-21 1997-05-27 Enichem Spa Catalizzatori di policondensazione per la sintesi di polietilene tereftalato
TW354305B (en) 1994-12-22 1999-03-11 Eastman Chem Co Production of particular polyesters using a novel catalyst system
GB9610939D0 (en) 1996-05-24 1996-07-31 Ici Plc Process for preparing a copolyester
JP4806855B2 (ja) * 2001-03-27 2011-11-02 東レ株式会社 ポリブチレンテレフタレートの製造法
US20050009687A1 (en) * 2003-05-02 2005-01-13 Verkade John G. Titanium alkoxide catalysts for polymerization of cyclic esters and methods of polymerization
US20050215425A1 (en) 2004-03-26 2005-09-29 Clair Jerry D S Esterification catalyst and process therewith

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4260735A (en) * 1980-02-12 1981-04-07 Allied Chemical Corporation Catalytic process for preparation of polyesters
CN1261608A (zh) * 1998-12-23 2000-08-02 辛科研究有限公司 制备聚酯树脂的方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘兴汉等.手征性杂氮钛三环化合物的合成.《高等学校化学学报》.1989,第10卷(第12期),第1257-1259页. *

Also Published As

Publication number Publication date
JP5739322B2 (ja) 2015-06-24
WO2009118600A2 (en) 2009-10-01
TW200940595A (en) 2009-10-01
EP2479205B1 (en) 2014-12-17
US20140024798A1 (en) 2014-01-23
CY1117278T1 (el) 2017-04-26
EP2262846A2 (en) 2010-12-22
JP2011515554A (ja) 2011-05-19
PT2479205E (pt) 2015-02-09
CN101981083A (zh) 2011-02-23
DK2262846T3 (da) 2013-06-03
US20110077379A1 (en) 2011-03-31
EP2262846B9 (en) 2013-08-21
PT2262846E (pt) 2013-07-15
US20120316316A1 (en) 2012-12-13
ES2424983T3 (es) 2013-10-10
JP2013216907A (ja) 2013-10-24
CY1114093T1 (el) 2016-07-27
JP5739481B2 (ja) 2015-06-24
DK2479205T3 (en) 2015-02-02
HRP20150054T1 (hr) 2015-04-10
SI2479205T1 (sl) 2015-04-30
US8440782B2 (en) 2013-05-14
WO2009118600A3 (en) 2009-12-03
EP2262846B1 (en) 2013-05-15
TW201412819A (zh) 2014-04-01
HUE024110T2 (en) 2016-02-29
ES2531884T3 (es) 2015-03-20
PL2479205T3 (pl) 2015-05-29
EP2479205A1 (en) 2012-07-25
TWI495659B (zh) 2015-08-11
BRPI0907076A2 (pt) 2019-09-24
HRP20130735T1 (en) 2013-10-11
PL2262846T3 (pl) 2013-10-31
TWI487728B (zh) 2015-06-11

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Granted publication date: 20130710

Termination date: 20160323