CN101905998B - Method for preparing special fertilizer containing organic iron element for artificial side slope soil - Google Patents
Method for preparing special fertilizer containing organic iron element for artificial side slope soil Download PDFInfo
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- CN101905998B CN101905998B CN201010220669A CN201010220669A CN101905998B CN 101905998 B CN101905998 B CN 101905998B CN 201010220669 A CN201010220669 A CN 201010220669A CN 201010220669 A CN201010220669 A CN 201010220669A CN 101905998 B CN101905998 B CN 101905998B
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- iron element
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- organic iron
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 25
- 239000002689 soil Substances 0.000 title claims abstract description 24
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title abstract description 3
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 9
- 210000003608 fece Anatomy 0.000 claims abstract description 8
- 239000003415 peat Substances 0.000 claims abstract description 7
- 239000008139 complexing agent Substances 0.000 claims abstract description 5
- 241000255789 Bombyx mori Species 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 4
- 229960000892 attapulgite Drugs 0.000 claims abstract description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 4
- 239000011790 ferrous sulphate Substances 0.000 claims abstract description 4
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 4
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 4
- 239000010457 zeolite Substances 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 239000005696 Diammonium phosphate Substances 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 4
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 4
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 4
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 3
- 208000006558 Dental Calculus Diseases 0.000 claims description 3
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000004021 humic acid Substances 0.000 claims description 3
- 239000004571 lime Substances 0.000 claims description 3
- 235000015097 nutrients Nutrition 0.000 claims description 3
- 239000002426 superphosphate Substances 0.000 claims description 3
- 101100008044 Caenorhabditis elegans cut-1 gene Proteins 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 2
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 3
- 206010022971 Iron Deficiencies Diseases 0.000 abstract description 2
- 201000010099 disease Diseases 0.000 abstract description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 2
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- -1 catalytic promoter Substances 0.000 abstract 1
- 235000013365 dairy product Nutrition 0.000 abstract 1
- 239000010871 livestock manure Substances 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 238000005728 strengthening Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000020774 essential nutrients Nutrition 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004162 soil erosion Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention provides a method for preparing special fertilizer containing organic iron element for artificial slope soil. The fertilizer is prepared by processing the following raw materials of ferrous sulfate, complexing agent, catalytic promoter, mixture containing peat or/and algal residue or/and silkworm excreta or/and dairy manure, attapulgite powder, zeolite powder, bentonite, diatomite powder, plant ash and chemical fertilizer under certain condition. The fertilizer has obvious effects on strengthening the effectivity of artificial side slope soil iron element, controlling the physiological disease caused by plant iron deficiency, improving the physicochemical characteristic of artificial side slope soil, and promoting the growth and development of plants.
Description
Technical field
The present invention relates to a kind of fertilizer, be meant a kind of preparation method who contains the fertilizer special for slope artificial soil of organic iron element especially.
Background technology
China is a mountain region big country, and the mountain area accounts for 69% of China's land territory total area.The formed a large amount of bare side slopings of engineering construction such as the road in mountain area, water power, mine; Become the special habitats of a serious degradation because of the tectal stripping damage of original soil vegetative cover; Cause a large amount of secondary barrens occurring and producing serious soil erosion phenomenon, caused the very big destruction of ecotope.On the bare side sloping surface of a wound, rebuild the essential measure that artificial soil has become protecting slope ecology, Revegetation, the artificial side slope soil of widespread use forms (like Chinese patent ZL02104143.1) by feedstock production such as natural soils, fertilizer, vegetable fibre, sticker, an agent, water-holding agents usually.Fertilizer provides the plant essential nutrient element, keeps good soil character, the important substance of the function of increasing soil fertility, and it can not only nutrient plant, promote plant metabolism, and can also regulate soil reaction, improve Soil structure, fertilizing soil.Ferro element is the necessary trace element of plant; In guaranteeing the plant normal growth growth course, play the physiological action of equal importance with macroelement; Organic iron element can overcome and is easy to generate oxidation, antagonism, adverse consequences that deposition caused after the inorganic iron element is used; It is stable to have fertilizer efficiency, is prone to by plant absorbing the utilization ratio advantages of higher.Yet, have fertilizer used in the artificial side slope soil process for preparation high organic iron element of validity for want of now, it is not ideal enough with the effect of Revegetation to cause artificial side slope soil to be fostered and apply fertilizer.
Summary of the invention
The object of the present invention is to provide a kind of preparation method who contains the fertilizer special for slope artificial soil of organic iron element; To overcome the deficiency that prior art exists; Have characteristics such as raw material is easy to get, production cost is low, stable performance, lasting fertilizer effect, biological effectiveness height, to the validity that strengthens the artificial side slope soil ferro element, physiological disease that control plant iron deficiency causes, improve the artificial side slope soil physicochemical property, promote that growth and development of plants aspect effect is remarkable.
The objective of the invention is to realize that through following technical scheme a kind of preparation method who contains the fertilizer special for slope artificial soil of organic iron element carries out according to following steps:
1. be that 5%～30% complexing agent is put into reaction kettle with weight percentages of components, add weight percentages of components and be 10%～40% catalyst aid, 30～90 ℃ of reactions 0.5～6 hour down.Wherein, complexing agent is at least a in humic acid, valonex, the Hydrocerol A, and catalyst aid is a kind of or two kinds in water, methyl alcohol, ethanol, the ydrogen peroxide 50.Then, be that 35%～65% ferrous sulfate adds in the reaction kettle with weight percentages of components again, under 65～110 ℃, carry out the mixture that complex reaction in 0.5～6 hour obtains organic iron element, be sample 1;
2. with a kind of in the peat of water cut 1%～15%, algae-residue, silkworm faeces, the cow dung or two kinds; Press composition weight 15～45: 30～65: 1～10: 5～25: 1～10 with industrial attapulgite, industrial zeolite powder, industrial wilkinite, industrial diatomite in powder, agricultural with plant ash: 0～5 mixed is even, is sample 2.
3. get that weight percentages of components is respectively 1%～10% sample 1,3%～17% sample 2,75%～95% chemical fertilizer makes the finished product through compound.
Wherein, the various effective elements of chemical fertilizer in the weight percentages of components of pure nutrient are: nitrogen 5%～25%, Vanadium Pentoxide in FLAKES 2%～20%, potassium oxide 2%～25%.Various effective elements in the chemical fertilizer are provided by following substances respectively: nitrogen be taken from urea or/and ammonium sulfate or/and diammonium phosphate, phosphorus are taken from superphosphate of lime diammonium phosphate or/and potassium primary phosphate, potassium are taken from vitriolate of tartar Repone K or/and potassium primary phosphate.
Embodiment
Below in conjunction with embodiment the present invention is further described.
Embodiment 1:
With weight percentages of components is that 5% humic acid, 10% valonex are put into reaction kettle; The adding weight percentages of components is 30% water; Reacted 1.5 hours down at 80 ℃; Be that 55% ferrous sulfate adds in the reaction kettle with weight percentages of components then, and under 90 ℃, carrying out complex reaction in 1 hour, to obtain the mixture of organic iron element subsequent use.With the peat of water cut behind the natural air drying 5%, with industrial attapulgite, industrial zeolite powder, industrial wilkinite, industrial diatomite in powder, agricultural with plant ash by composition weight 28: 50: 5: 10: 5: 2 mixed makes evenly that to contain the peat mixture subsequent use.At last, get mixture that weight percentages of components is respectively 5% organic iron element, 10% contain peat mixture, 30% urea, 30% superphosphate of lime, 25% vitriolate of tartar make the finished product through compound.
Embodiment 2:
Schedule of operation is identical with embodiment 1 during preparation.Just the water cut to raw-material kind, quantity and solvent temperature, reaction times and peat, algae-residue, silkworm faeces, cow dung changes in the scope of schedule of operation defined of the present invention, still is prepared into a kind of fertilizer special for slope artificial soil that contains organic iron element of the present invention equally.
Claims (2)
1. preparation method who contains the fertilizer special for slope artificial soil of organic iron element is characterized in that carrying out according to following steps:
1. be that 5%～30% complexing agent is put into reaction kettle with weight percentages of components, add weight percentages of components and be 10%～40% catalyst aid, 30～90 ℃ of reactions 0.5～6 hour down; Wherein, complexing agent is at least a in humic acid, valonex, the Hydrocerol A, and catalyst aid is a kind of or two kinds in water, methyl alcohol, ethanol, the ydrogen peroxide 50; Then, be that 35%～65% ferrous sulfate adds in the reaction kettle with weight percentages of components again, under 65～110 ℃, carry out the mixture that complex reaction in 0.5～6 hour obtains organic iron element, be sample 1;
2. with a kind of in the peat of water cut 1%～15%, algae-residue, silkworm faeces, the cow dung or two kinds; Press composition weight 15～45: 30～65: 1～10: 5～25: 1～10 with industrial attapulgite, industrial zeolite powder, industrial wilkinite, industrial diatomite in powder, agricultural with plant ash: 0～5 mixed is even, is sample 2;
3. get that weight percentages of components is respectively 1%～10% sample 1,3%～17% sample 2,75%～95% chemical fertilizer makes the finished product through compound.
2. according to the said a kind of preparation method who contains the fertilizer special for slope artificial soil of organic iron element of claim 1, the various effective elements that it is characterized in that chemical fertilizer in the weight percentages of components of pure nutrient are: nitrogen 5%～25%, Vanadium Pentoxide in FLAKES 2%～20%, potassium oxide 2%～25%; Various effective elements in the chemical fertilizer are provided by following substances respectively: nitrogen be taken from urea or/and ammonium sulfate or/and diammonium phosphate, phosphorus are taken from superphosphate of lime diammonium phosphate or/and potassium primary phosphate, potassium are taken from vitriolate of tartar Repone K or/and potassium primary phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010220669A CN101905998B (en) | 2010-07-08 | 2010-07-08 | Method for preparing special fertilizer containing organic iron element for artificial side slope soil |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010220669A CN101905998B (en) | 2010-07-08 | 2010-07-08 | Method for preparing special fertilizer containing organic iron element for artificial side slope soil |
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| Publication Number | Publication Date |
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| CN101905998A CN101905998A (en) | 2010-12-08 |
| CN101905998B true CN101905998B (en) | 2012-10-17 |
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| CN201010220669A Expired - Fee Related CN101905998B (en) | 2010-07-08 | 2010-07-08 | Method for preparing special fertilizer containing organic iron element for artificial side slope soil |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2558502B1 (en) * | 2014-07-30 | 2016-11-15 | Universidad De Jaén | Fajina for plant regeneration |
| CN106010556A (en) * | 2016-05-31 | 2016-10-12 | 山东胜伟园林科技有限公司 | Bamboo charcoal nanopowder-containing penetration resisting material, and method for planting blueberries in saline and alkaline land by using penetration resisting material |
| CN109134088A (en) * | 2018-10-22 | 2019-01-04 | 四川大学 | A kind of dedicated organic iron fertilizer preparation method of engineering wound-surface soil remediation |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1762916A (en) * | 2005-08-26 | 2006-04-26 | 四川大学 | Organic iron fertilizer |
| CN101391918A (en) * | 2008-11-07 | 2009-03-25 | 四川大学 | Compound fertilizer special for slope artificial soil |
| CN101391930A (en) * | 2008-11-07 | 2009-03-25 | 四川大学 | Slope artificial soil conditioner with water retention role |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003096452A (en) * | 2001-07-19 | 2003-04-03 | Soruteko Kk | Composition for soil consisting of industrial waste |
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- 2010-07-08 CN CN201010220669A patent/CN101905998B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1762916A (en) * | 2005-08-26 | 2006-04-26 | 四川大学 | Organic iron fertilizer |
| CN101391918A (en) * | 2008-11-07 | 2009-03-25 | 四川大学 | Compound fertilizer special for slope artificial soil |
| CN101391930A (en) * | 2008-11-07 | 2009-03-25 | 四川大学 | Slope artificial soil conditioner with water retention role |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2003-96452A 2003.04.03 |
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| Publication number | Publication date |
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| CN101905998A (en) | 2010-12-08 |
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Granted publication date: 20121017 |