CN101899785A - Method for dyeing with lacquer and natural coloring matter and products thererof - Google Patents

Method for dyeing with lacquer and natural coloring matter and products thererof Download PDF

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Publication number
CN101899785A
CN101899785A CN2009102524481A CN200910252448A CN101899785A CN 101899785 A CN101899785 A CN 101899785A CN 2009102524481 A CN2009102524481 A CN 2009102524481A CN 200910252448 A CN200910252448 A CN 200910252448A CN 101899785 A CN101899785 A CN 101899785A
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dyeing
dye
tree
lacquer
colored
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CN101899785B (en
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赵凤周
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/34General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B61/00Dyes of natural origin prepared from natural sources, e.g. vegetable sources

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a method for tray dyeing of objects to be dyed and products produced thereby, the method is that secretion extracted from a lacuqer tree is processed into clear lacquer, secretion extracted from a Chinese wood-oil tree is machined into transparent tail oil, the clear lacquer and the tail oil are added into stone powder formed by crushing mineral matter with specific colors to mix so as to prepare mineral matter natural coloring matter, the coloring matter is dissolved in a dilution solvent extracted from a pine tree or a camphor tree to obtain the dye liquor where the objects to be dyed are of tray dyeing. The mineral natural coloring matter has the following effects: if cloth is dipped in the dilution dye liquor for a finite time, the clear lacquer and the tail oil as well as coloring matter pigment may be soaked into fibers of the objects to be dyed to absorb, the dyeing object has corrosion resistance, insect protection, bacteria repellancy and disinfection by means of the clear lacquer so as to protect the dyeing object to protect the human body; furthermore, the tail oil contain elastic coating film to protect the surface of the fiber, the color is sharp, the fiber surface has brightness, and the object will not be discolored and fade to improve durability and service life of the dyeing object.

Description

Use colouring method of lacquer and natural dye and products thereof
Technical field
The present invention relates to being colored thing (dress material, fabric, window paper, other natural fabrics) natural dye method of use mineral natural coloring matter and products thereof when dyeing, more particularly, relate to colouring method that uses lacquer and natural dye and products thereof, this method uses the resin that extracts from lacquer tree to be processed into the transparent colored varnish, and the resin that extracts from tung tree is processed into transparent bright oil, join in the color powder of fine stone that the mineral matter that has particular color is ground into, be hybridly prepared into natural dye, this dyestuff is dissolved in from the retarder thinner that pine tree or camphor tree are extracted is diluted to dye liquor, in this dye liquor, contaminate then and be colored thing.
Background technology
Used natural dye in several thousand, because of its raw material selecting and purchasing is restricted, the leaching process complexity of dyestuff, and in the dyeing operation complex procedures, need numerous labours, therefore along with the exploitation of chemical dye after 19th century, the use amount of natural dye reduces gradually.
But; along with the research and the recovery activity of the traditional dress as Korea S's national costume " Korea Spro's clothes " comes to life; and when emphasizing to protect environment and nature; solution is as the water pollution issue of chemical dye shortcoming; people have strengthened the concern to the more friendly vegetable colour of environment, in order to overcome the also change deeply in succession of research as the repeatability problem of natural dye shortcoming.
Before using the method that is dyeed by chemicals, traditional dress material dyeing skill and technique mainly is to use the material that obtains from nature, promptly uses vegetalitas, animality, mineral raw material to dye.
For example, vegetable dyes be with from the plant petals that has color, fruit, do, the material of extraction is used for dyestuff the root, leaf etc., as redness is to extract from the petal of safflower, yellow is to extract from the resin of fruit of cape jasmine or gamboge, blueness be subordinated to polygonaceae indigo plant do and leaf in extract, orange-yellow be subordinated to Zingiber root tuber of aromatic turmeric root and do in extract.
In addition, according to the difference of dye material, be divided into that safflower dyes, sapanwood dyes, fall dye, the fruit of Chinese magnoliavine is dyed, golden cypress is dyed, Cape jasmine dyes, root tuber of aromatic turmeric is dyed, the coptis is dyed, sophora flower dyes, hispid arthraxon dyes, birch-leaf pear dyes, Asian puccoon is dyed, indigo plant is dyed, indigo plant is dyed, redly multiple colouring method such as dye.
Above-mentioned colouring method is the colouring method of distinguishing according to the tone of dyeing, now illustrates existing several dyeing skill and technique.
Sapanwood dyes use from being called sapanwood or bush, sapanwood wood, and the liquid that the red composition that sapanwood, red wood, wood are red, extract in the tree of many wood decocts dyes.When needing dense light red, use the alum mordant dyeing; When needing navy blue, use the ferric acetate mordant dyeing.
Falling to dye and be also referred to as rubia and dye, is the colouring method as the another kind of dye yielding herb of orchil.The climing yellowish red color that has of this rubia, its fibrous root just is used as medicinal material and dyestuff since ancient times.This dyestuff is colouring method trouble, dissolving difficulty, must uses the representative mordant dye of mordant (alum).When kapok (calico) was dyeed, elder generation handled with alum after carrying out mordant dyeing with alkali lye again.
With the mordant dyeing that alkali lye carries out mordant dyeing, at first will be colored thing and in cold alkali lye, soak and leave standstill.Rubia is carried at about 50~60 ℃ Shui Zhongshui, will be colored thing then and soak also of short duration leaving standstill once more, just can dye the redness that has distinct yellow well.To obtain brown if replace alkali lye to carry out mordant dyeing with the iron mordant dyeing.
Redness is dyed red dye or redness of the skin or complexion dyes that be otherwise known as, with safflower, sapanwood, fall and use when (rubia) etc. dyes redness.With the red batch of safflower, promptly safflower dyes, and is that petal is direct, perhaps in the solution after the petal fermentation is sieved, adds hot water and removes yellow juice.Add alkali lye then, discard initial water, add hot water again and obtain water extract.When this solution becomes redness, add fruit of Chinese magnoliavine juice, make dye liquor, dye till reaching the concentration that needs under 50~60 ℃ the condition cloth being dipped to.Further, when wanting to dye peony, the sediment of safflower and fruit of Chinese magnoliavine liquid is dried, make powder dyeing.
The fruit of Chinese magnoliavine is dyed, be to be the colouring method of raw material with the fruit of Chinese magnoliavine, Schizandra is in the wood section of the company climing property shrub of falling leaves, its fruit has tart flavour, bitter taste, pungent, one-tenth flavor, five kinds of tastes of sweet taste, this method at first is diluted with water to suitable concentration with fruit of Chinese magnoliavine leach cooking liquid, make dye liquor, then cloth is put into dye liquor and boiled and dye.The fruit of Chinese magnoliavine is the dyestuff that uses when dying redness.
The dyeing of Yellow series is to be that raw material carries out yellow dyeing with plants such as root tuber of aromatic turmeric, the coptis, sophora flower, golden cypress, cape jasmine, hispid arthraxon, birch-leaf pears, it is that bark with Chinese corktree dries in the sun that golden cypress is dyed, carry with cold water water, dye for one night being colored thing immersion in the solution that water proposes, add alkali lye again.If carry out golden cypress again and dye after indigo plant dyes carrying out, then can obtain green product dyed thereby.
It is the dyestuff that also can dye without mordant that Cape jasmine dyes, and the fruit that will belong to the cape jasmine of rubia section dries, water is carried, and this water is proposed the adding acid of solution decoction back dye.Be mainly used in dyeing as linens such as shroud.
Root tuber of aromatic turmeric is dyed the raw material that is to use the India's tradition cooking " curry " that is called as root tuber of aromatic turmeric or turmeric, the direct dyes that dye.The root of Zingiber perennial plant root tuber of aromatic turmeric is discerped, dyeed with its water extract.
Except that above-mentioned dyeing raw material and colouring method, also have plurality of raw materials and, omit related description here with the dyeing skill and technique of these raw materials.
But the staining technique of above-mentioned use vegetable matter, its shortcoming are, can only use unique staining technique to dye according to the difference of dye materials, and be therefore different with the chemical staining method that dyes with same procedure; Colouring method is different because of the difference of raw material, therefore very trouble and inconvenience; Use vegetable raw material as dyestuff, though the therefore beautiful vividness of the color attenuation that easily comes off, if the clothes after the long preservation dyeing, then clothes is vulnerable to the insect damage of moth and so on, and can fade, decolour because of washing to cause continually.
Relative in this, use the colouring method of mineral material, when having washing bleaching level than vegetable dyes lack, dark advantage, repeatability is poor, the raw material of dyestuff obtains difficulty, the high shortcoming of price but have simultaneously.
The present invention is in order to solve the problem that above-mentioned existing colouring method brings, and provides the inventor constantly to grope repeatedly through the several years and the result that finishes.
Summary of the invention
The problem that invention will solve
The object of the present invention is to provide a kind of colouring method that uses mineral natural coloring matter and products thereof, this method will be colored thing and dye with mineral natural coloring matter, thereby give product dyed thereby anticorrosion and insect protected, bactericidal action, and dyeing is bright dense, color is difficult for decolouring, do not produce environmental pollution fully, especially, the invention provides a kind of colouring method that uses lacquer and natural dye and products thereof, this method uses the resin that extracts from lacquer tree to be processed into the transparent colored varnish, and the resin that extracts from tung tree is processed into transparent bright oil, joining the mineral matter that has particular color is ground in the color powder of fine stone, be hybridly prepared into mineral natural coloring matter, this mineral natural coloring matter be diluted in from the retarder thinner of pine tree or camphor tree extraction dye.
The means of dealing with problems
Colouring method of use lacquer of the present invention and natural dye and products thereof, operation by the 1st stage, the 2nd stage, the 3rd stage and the 4th stage is finished, described the 1st stage will be in the time will being colored thing and dyeing with natural dye, prepare retarder thinner for the pigment stripping that makes natural dye, this retarder thinner is to add the water distillation to the resin that extracts from pine, perhaps adds the water distillation and make to the resin that extracts from camphor tree; Described the 2nd stage for respectively the tung tree fruit is pressed resin slowly boil and make transparent bright oil, and make with extra care the ultraviolet ray of back irradiation certain hour from the raw lacquer that lacquer tree is extracted and make the transparent colored varnish, be mixed in the color powder of stone that the mineral matter that has particular color is ground into, make mineral natural coloring matter; Described the 3rd stage will be colored thing and contaminate certain hour in this dye liquor for above-mentioned natural dye is diluted to dye liquor in the retarder thinner in the 1st stage; Described the 4th stage is taken out dry certain hour for the thing that is colored after will contaminating from dye liquor.
The invention effect
Natural dye of the present invention, it has following effect: if contaminate certain hour in the dye liquor that dress material is diluted at the mixed diluting solvent, then the resin of resin of lacquer tree (colored varnish) and tung tree (bright oil) composition and coloring matter can soak in the fiber that is colored thing and be absorbed,, insect protected anticorrosion and antibiotic and bactericidal action by the colored varnish had, not only protect product dyed thereby, also to the human body beneficial; And film by the elasticity that tung tree resin is had and to protect fiber surface, make color clear, and fiber surface is glossy, even frequent washing can not decoloured yet, be faded, improves durability, prolongs the life-span that is colored thing.
The specific embodiment
Below colouring method of use lacquer of the present invention and natural dye and products thereof is elaborated.
Natural dye of the present invention is made of the color powder of stone, mineral natural coloring matter and retarder thinner.The color powder of described stone is that the mineral matter pulverizing that has particular color forms; Described mineral natural coloring matter is to add binding agent and cohesive force with regulation in the color powder of stone; Described retarder thinner is when the pigment of natural dye and binding agent are discharged, the concentration and the viscosity of regulating dye liquor.
The color powder of stone of the present invention, wear into the atomic thin powder of 2500 orders with being distributed in the natural mineral matter that has particular color with ball mill, the particle diameter of the color powder of stone preferably, make pigment that the color powder of stone had can by retarder thinner fully and to greatest extent stripping be ground into atomic thin degree.
In the color powder of stone, add the color dyestuff, and the viscosity that is contained by lacquer and bright oil (binding agent) with cohere composition the effect of waterproof, insect protected, anticorrosion, desinsection and mordant dyeing be provided to the product dyed thereby that is colored.
As the application examples of binding agent of the present invention, adopt the resin of lacquer tree and the resin of tung tree (Aleuritesfordi Hemsi) fruit.
Lacquer tree is in a single day injured, will flow out resin in order to protect wound from lacquer tree, and this resin is called as raw lacquer.Raw lacquer is the canescence emulsion liquid, and laccol (urushiol) accounts for 70%, in addition also contains rubber mass (4~8%), nitrogen substance (2~3%), laccase (laccase) and moisture (10~20%).
The characteristics of raw lacquer are, initial stage has canescence, after after a while, because deterioration blackening gradually, and opaque, viscosity increases, special odor is arranged, especially, because of it has waterproof, insect protected, anticorrosion, desinsection and mordant dyeing effect, therefore be mainly used in the coating of woodenware and handicraft and conclude material.
Raw lacquer is that the different multiple composition of chemical property is separated in bark tissue, when haveing a superficial wound, the composite latex state that contains a large amount of laccols, moisture and polysaccharides, but this state is not a homogeneous, contain excessive laccase, harden rapidly at the environment lower surface of low humidity.
When painting to woodwork, the one-tenth of above-mentioned raw lacquer is grouped into, and what produce easily that polymerization rapidly causes becomes the lacquer fold of shortcoming of filming, and can produce film variable color and by the UV-induced deterioration of filming of the lacquer that is caused by a large amount of polysaccharides.
Use the coating of raw lacquer, even through several thousand, lacquer is filmed and also can be kept former state, is the traditional coating of excellent in te pins of durability, now also is used to require in the product of strong durability.
Because filming, lacquer in various organic solvents, do not corrode fully, have strong chemical resistance, therefore also be developed as requiring the multiduty industry coating such as pipe arrangement equipment of the industry of strong corrosion resistant with coating, oil tank, petroleum pipeline, liquefied natural gas (LNG) storage tank, chemical plant.
Raw lacquer is made transparent method is, to from the resin (hereinafter referred to as raw lacquer) that lacquer tree is extracted, remove foreign matter and impurity, about 2 hours ultraviolet limit stirring raw lacquer is shone on the limit then, by deterioration color is become transparent (hereinafter referred to as the colored varnish), but keep original character by a large amount of polysaccharides.What ultraviolet lamp used is medical ultraviolet lamp.
Giving birth to tung oil is the oils of extracting from the fruit of tung tree (also being known as paulownia), the fruit of tung tree is extracted shallow milky oil with compressor pressurizes, thereby form fast drying, viscosity height, thick and springy the filming in dry back, give birth to tung oil and have smoothing effect, be widely used as the ground paperboard in heated kang room and the oil of filming of umbrella paper since ancient times.Recently, give birth to tung oil and also be used as paint for building, varnish, the raw material of printing ink.
Living tung oil is made transparent method is, adds in container and gives birth to tung oil and boil (being called boiled wood oil), and milky living tung oil becomes transparent gradually, is referred to as bright oil.Even become bright oil from giving birth to tung oil, bright oil also can keep original physics, chemical property.
As previously mentioned, if with coloured raw lacquer and give birth to tung oil and sneak in the color powder of stone, then the color of the color powder of stone and raw lacquer and the color of giving birth to tung oil are obscured mutually, produce unpredicted color, therefore for obtain need color and use the colored varnish and transparent tung oil.
In the present invention, the summation of the colored varnish and bright oil is added by 18~22 weight portions (all the other be stone color powder), thereby makes natural dye, when the viscosity of this natural dye reaches in order to make bread with face, and the tack-free degree that face had that rubs up.
According to the additional proportion of the viscosity adjustment retarder thinner of above-mentioned natural dye, but the dilution ratio of natural dye is high more, and the stripping quantity of the colored varnish and bright oil is many more, and the flowability of dye liquor reduces, and dyeing efficient reduces.
In the present invention, the natural dye dilution ratio of relevant retarder thinner is pressed corresponding natural dye at least 0.5 weight portion of per 100 weight portions of retarder thinner, and maximum 45 weight portions dilute, and use the dye liquor after the dilution.
If the dilution ratio of natural dye surpasses 45 weight portions, then lacquer and bright oil component excessively stripping in dye liquor strengthens the viscosity of dye liquor, so the colored varnish that forms on product dyed thereby and the thickening of filming of bright oil, and prolong the drying time of product dyed thereby.
And, if with the color dyestuff of stone in retarder thinner by under the situation of diluting more than 60 weight portions, dye liquor viscosity strengthens, dye liquor can not fully soak in being colored thing, heterogeneity sometimes dyes.
In contrast, if with natural dye in retarder thinner by diluting below 0.5 weight portion, the stripping quantity of coloring matter reduces, the tone of dyeing also can blur and shoal.
Below to the pigment, the colored varnish and the bright oil component that are used for making natural dye in the dye liquor stripping, the preparation method of the retarder thinner of dye liquor concentration dilution is described.
The effect of retarder thinner is that the pigment of natural dye and lacquer stripping are come, and makes interface activation simultaneously so that pigment and paint branch and can easily soak in the fiber of dress material makes it can dye the tone of homogeneous.
In the present invention, can adopt any of turpentine oil or camphorated oil as retarder thinner, its preparation method is as described below.
About terebinthine preparation method be, with cutter the pine tree trunk cut out the V font, dig out spiral helicine groove, add the water of equivalent in the resin that flows out from breach, distillation is prepared from then.
Turpentine oil fragrance than rosin before distillation is stronger, but rosin only has minimal residue after distillation, has clear, colorless, and viscosity and water are similar.
Even turpentine oil is drunk also harmless, its rate of drying and water are than basic identical.Mainly gather in summer.
Camphorated oil is when the camphor tree trunk is injured, adds the water of equivalent to the resin that flows out from wound, and with the transparent liquid that its distillation makes, its rate of drying is slower than turpentine oil.And viscosity and turpentine oil are much at one, gather in summer equally.
Therefore because turpentine oil is faster than camphorated oil rate of drying, in air themperature low winter, preferably use turpentine oil as retarder thinner; In temperature high summer, preferably use camphorated oil as retarder thinner.
No matter select above-mentioned turpentine oil that makes and in the camphorated oil any one to make retarder thinner, can both make and paint branch and bright oil component stripping, pigment can both be dyed and be colored on the thing.
Above-mentioned retarder thinner with aequum, be that in turpentine oil and the camphorated oil any one joins in the dyeing tube, to wherein adding natural dye according to required ratio, the agitation and dilution solvent, make the natural dye dissolving, will be colored thing then and join in this dye liquor, rub with hand and be colored thing, stir while overturning with excellent, the pigment of dyestuff and the colored varnish and bright oil component are soaked in fiber dye.
Through behind the certain hour, taking-up is colored thing and makes its intensive drying, just can obtain being dyed the product dyed thereby of color of object.
The colouring method of the invention described above is put in order in order, as described below.
The 1st stage was the process of preparation retarder thinner, when dress material is dyeed with natural dye, in order to make coloring matter stripping and modulate retarder thinner in dye liquor, this retarder thinner is by isolating the crust of pine, and, perhaps in the camphor tree resin, add the camphorated oil retarder thinner that the water distillation makes to adding the turpentine oil retarder thinner that the water distillation makes in the resin that extracts from isolating.
The 2nd stage was the preparation process of natural dye, with the tung tree fruit press resin slowly boil and make transparent bright oil, and make with extra care the back irradiation ultraviolet radiation from the raw lacquer that lacquer tree is extracted and make the transparent colored varnish, be mixed in the former stone flour of the mineral matter with particular color and be broken in the color powder of fine stone the preparation natural dye.
The 3rd stage will be for will be colored the process that thing dyes, the retarder thinner that the 1st stage was made adds in the dye liquor tube, the natural dye that the 2nd stage of adding makes in this dye liquor tube is dissolved into dye liquor, will be colored thing and join in the dye liquor, contaminates certain hour (about 30 minutes).
The 4th stage, drying means did not have particular restriction in order to take out the dress material of contaminating and make its dry process in dye liquor.
The above-mentioned product dyed thereby that dyes with natural dye is painted branch by known heat treatment method neutralization, finishes dyeing.
The product dyed thereby that makes according to the method described above forms atomic filming carefully along with the deterioration of lacquer and the composition that contained of bright oil and sclerosis at the fiber surface of dress material.
As above-mentioned illustrated, colouring method according to use lacquer of the present invention and natural dye, product dyed thereby has anti-corrosive properties, insect protected, antibiotic property, bactericidal properties and antibiotic property effect because of painting branch, can prevent the damage that product dyed thereby is caused by insect, the luster effect that can also obtain to have because of the colored varnish and bright oil makes product dyed thereby have gloss in addition, bright, the decolouring and the dyeing product of variable color hardly, and anyone can both dye easily with unified method.

Claims (2)

1. use the colouring method of lacquer and natural dye, it is characterized in that, comprise following operation:
The 1st stage, in the time will being colored thing and dyeing with mineral natural coloring matter, modulate retarder thinner for the pigment stripping that makes dyestuff, this retarder thinner is by isolating the crust of pine tree, and after distilling after adding water in the resin that extracts from isolating, perhaps in the camphor tree resin, adding water, distill and make;
The 2nd stage, respectively the tung tree fruit is pressed resin slowly boil and make transparent bright oil, and make with extra care the back irradiation ultraviolet radiation from the raw lacquer that lacquer tree is extracted and make the transparent colored varnish, be mixed in the mineral matter that has specific color and pulverize in the color powder of the stone that forms, make natural dye;
The 3rd stage added natural dye and is diluted to dye liquor in the retarder thinner, will be colored thing and contaminate certain hour in this dye liquor; And,
In the 4th stage, be colored thing, dry certain hour after take out contaminating.
2. the product that is colored that method according to claim 1 makes.
CN2009102524481A 2009-05-29 2009-12-09 Method for dyeing with lacquer and natural coloring matter and products thererof Expired - Fee Related CN101899785B (en)

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CN102824998B (en) * 2012-08-29 2013-10-30 杭州余杭区中泰灵声乐器厂 Bamboo flute painting method
CN105256606A (en) * 2015-11-16 2016-01-20 张家界娄江生态农业开发有限公司 Natural raw lacquer dip-dyed varnished cloth making method and varnished cloth
CN105421099A (en) * 2015-11-30 2016-03-23 浙江辰鸿纺织品科技有限公司 Method for dyeing dacron fabric through natural dye
CN109235078A (en) * 2018-10-26 2019-01-18 张伟 A kind of natural plants textile dyestuff
CN115305741A (en) * 2022-08-23 2022-11-08 陈俊杰 Coating paint and preparation method thereof

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