CN103436135B - High tint permanence paint and application thereof - Google Patents
High tint permanence paint and application thereof Download PDFInfo
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- CN103436135B CN103436135B CN201310432019.9A CN201310432019A CN103436135B CN 103436135 B CN103436135 B CN 103436135B CN 201310432019 A CN201310432019 A CN 201310432019A CN 103436135 B CN103436135 B CN 103436135B
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Abstract
The present invention relates to a kind of high tint permanence paint and application thereof, this paint is made up of the component of following weight part: phenolic varnish 80-120 part, kerosene 100-400 part and boiled wood oil 15-40 part; Boiled wood oil is wherein made up of the component of following weight part again: raw tung oil 100 parts, native sub-0.1-1.0 part, yellow lead oxide 0.1-1.0 part and rosin 0.5-2 part.This paint reaches good synergy by the proportioning that each component is suitable, meet quick-drying, water-fast, insect protected, anti-mildew, not easily fall the performances such as paint while, also show good pigment adsorption, there is high tint permanence etc.After this paint is painted on implements surface, be easy to colouring thereon and not easily fade, the picture color drawn is vivid, and texture is good, be particularly suitable as the implements such as bamboo and wood products surface draw a picture before bottoming enamelled coating.
Description
Technical field
The present invention relates to a kind of paint, after particularly one is brushed on implements, the high tint permanence can carrying out thereon drawing a picture is painted and application.
Background technology
The skill that bamboo and wood products passes on as China, particularly bamboo wood painting products, in the age of pursuing ancient customs now or recover one's original simplicity, receive the very big welcome in market.In the drawing processing of bamboo wood painting products; first the enamelled coating being convenient to draw a picture on bamboo wood surface is brushed is needed; this enamelled coating both played certain protective role to bamboo and wood products, required that again the top layer after brushing has better tinctorial property, required that pigment adsorption performance is good, water-tolerant, not easily falls paint etc.
Boiled wood oil be the seed of euphorbia plant tung tree as raw material, after squeezing, obtained raw tung oil, then will give birth to tung oil after high temperature heat refining is polymerized, filters the covering with paint dry vegetable oil of gained by essence.Boiled wood oil has high-strength seepage force, enter the inside such as bamboo and wood products can with its combination, after film forming, system is more stable, can the corrosion of ultra-violet radiation resisting and soda acid, salt spray resistance and sea water immersion, stable coating effectively can also intercept infiltration and the infiltration of water molecules, realizes " lotus leaf effect " of top coat.Therefore, coat the performance that the goods after boiled wood oil have waterproof, insect protected, anti-mildew, working life increase, but also because it has stronger " lotus leaf effect ", poor to the absorption property of pigment, therefore after coating, also will draw a picture thereon just quite difficult.
Phenolic varnish (phenolicvarnish) are by pure phenolic resin or modified phenolic resins and dry vegetable oil after tempering, then add the formulated varnish such as siccative and solvent.The film light of phenolic varnish is hard, water-tolerant, resistance to boiling hot property are good, but more crisp, easy yellowing, the desirable bottoming enamelled coating before can not directly drawing a picture as implements surfaces such as bamboo and wood productses.
Known by analyzing above, if the advantage of boiled wood oil and phenolic varnish can be utilized simultaneously, and overcome their respective deficiencies, by proportioning suitable between the two and synergy, then can develop the desirable drop priming before the implements drawing such as a kind of applicable bamboo and wood products.The present invention is directed to the deficiencies in the prior art, carried out improving invention.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of high tint permanence paint, this paint meet quick-drying, water-fast, insect protected, anti-mildew, not easily fall the performances such as paint while, also show good pigment adsorption etc., have high tint permanence, after being painted on implements surface, performance of can painting is good.
For achieving the above object, the technical solution used in the present invention is as follows:
A high tint permanence paint, is made up of the component of following weight part: phenolic varnish 80-120 part, kerosene 100-400 part and boiled wood oil 15-40 part.
Further, described high tint permanence paint is made up of the component of following weight part: phenolic varnish 100 parts, kerosene 300 parts and boiled wood oil 25 parts.
Further, described phenolic varnish are soluble phenolic resin varnish, and oil content is 40-60%.Soluble phenolic resin is the resol made with various substituted phenol and formaldehyde condensation polymer, conventional p-phenyl phenol and p-tert-butylphenol manufacture, this resin do not need modification just can thermosol in oil.Soluble phenolic resin and siccative oil mixed refining soluble phenolic resin varnish, market has finished product sell.
Or described phenolic varnish are rosin modified phenolic resin varnish, oil content is 40-60%.Rosin modified phenolic resin is the macromolecule product carrying out chemical reaction generation with alkylphenol (if phenol, dihydroxyphenyl propane, PTBP p-tert-butylphenol, POP are to tert-octylphenol, PNP nonyl phenol and PDDP dodecyl phenol etc.), formaldehyde, polyvalent alcohol and rosin, due to the polynuclear plane feature of its uniqueness, there is good pigment wetting performance.Rosin modified phenolic resin and siccative oil mixed refining rosin modified phenolic resin varnish, market has finished product sell.
Described oil content is the mass percentage of grease in phenolic varnish.Described siccative oil is the triglyceride level with high degree of unsaturation and conjugated structure lipid acid, and main component is the glyceryl ester of the unsaturated fatty acids such as linolenic acid, linolic acid, and iodine number is more than 130.
Kerosene of the present invention is a class of oils, is obtained through fractionation or cracking by natural oil or artificial petroleum.Wherein, containing alkane 28-48%, aromatic hydrocarbons 20-50%, unsaturated hydrocarbons 1-6%, cyclic hydrocarbon 17-44%, carbonatoms is 10-16.In addition, a small amount of impurity is also had, as sulfide (mercaptan), colloid etc.
Described boiled wood oil divides two kinds: ripe pure tung oil and mixing boiled wood oil.The extracting process of skillful tung oil is that the seeds of a tung oil tree fry oil expression, and inartificial going adds any chemical composition, environment friendly and pollution-free.Mixing boiled wood oil boils in process, adds, into some siccative, to be more suitable for the preparation for painting.
In paint formulation of the present invention, phenolic varnish play styling, and kerosene is solvent, and boiled wood oil plays a part to dry up, insect protected, anti-mildew, during use, mix.
Another object of the present invention is to provide a kind of boiled wood oil, and this boiled wood oil fast drying, strong adhesion, glossiness are good, is particularly suitable for the preparation of described high tint permanence paint.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of boiled wood oil, is made up of the component of following weight part: raw tung oil 100 parts, native sub-0.1-1.0 part, yellow lead oxide 0.1-1.0 part and rosin 0.5-2 part.
Further, described boiled wood oil is made up of the component of following weight part: raw tung oil 100 parts, soil 0.24 part, yellow lead oxide 0.25 part and rosin 0.82 part.
Further, the preparation of described boiled wood oil comprises the following steps:
A, tung oil and soil will be given birth to mixing by filling a prescription, enduring the yellow lead oxide to adding formula ratio during 200-240 DEG C;
B, continue to endure the rosin to adding formula ratio during 260-290 DEG C;
C, after rosin melts completely, mix to obtain boiled wood oil.
Wherein, described native son has another name called pyrolusitum, is the ore of oxide-based mineral pyrolusite, is mainly Manganse Dioxide.Described yellow lead oxide (Lithargyrum) is commonly called as yellow lead, is plumbous oxide mineral, is mainly yellow lead oxide.Described rosin is that the oil that pine tree trunk inside is flowed out changes into watery through high temperature melting, the blocks of solid after dry and hard.Raw tung oil, rosin, soil and yellow lead oxide can be used as industrial chemicals or Chinese medicinal materials purchase obtains.Tung oil, under the synergy of rosin, soil and yellow lead oxide, can either be accelerated the rate of drying of tung oil, can increase again sticking power and the glossiness of tung oil simultaneously.
The present invention also aims to the application providing described high tint permanence paint, use the product painting effect of this high tint permanence paint preparation good, its application comprises:
Described high tint permanence paint is in the application preparing enamelled coating of can painting.This high tint permanence paint can be painted on implements surface that is bamboo, wooden or other similar quality, then carries out thereon painting or the operation such as printing and dyeing, has excellent picture effect.
The application of described high tint permanence paint in bamboo and wood products.This high tint permanence paint is particularly suitable as the bottoming enamelled coating before bamboo or wood-based product's decoration.This enamelled coating produces provide protection to bamboo and wood products on the one hand, has the high tint permanence of drawing on the other hand, as this paint is attached to bamboo curtain splint surface, can substantially reach the effect of drawing a picture on rice paper.
Advantageous Effects of the present invention is:
High tint permanence paint of the present invention, comprehensive employing phenolic varnish and the performance advantage of boiled wood oil in coating preparation, and reach good synergy with suitable proportioning, meet quick-drying, water-fast, insect protected, anti-mildew, not easily fall the performances such as paint while, also there is high tint permanence, show good pigment adsorption etc.After this paint is painted on implements surface, be easy to colouring thereon and not easily fade, the picture color drawn is vivid, and texture is good, be particularly suitable as the implements such as bamboo and wood products surface draw a picture before bottoming enamelled coating.
Boiled wood oil of the present invention, by the synergy of raw tung oil, rosin, soil and yellow lead oxide, and suitable preparation method, obtains fast drying, strong adhesion, boiled wood oil that glossiness is good, is particularly suitable for the preparation of described high tint permanence paint.
Embodiment
In order to make the object, technical solutions and advantages of the present invention clearly, below embodiments of the invention are described in detail.
Embodiment 1
Tung oil 1000g will be given birth to mix with soil 2.4g, and endure and add 2.5g yellow lead oxide to when 220 DEG C; Continue to endure and add 8.2g rosin to when 260 DEG C; Boiled wood oil is mixed to obtain after rosin melts completely.
Embodiment 2
Tung oil 1000g will be given birth to mix with soil 1.0g, and endure and add 10g yellow lead oxide to when 200 DEG C; Continue to endure and add 10g rosin to when 290 DEG C; Boiled wood oil is mixed to obtain after rosin melts completely.
Embodiment 3
Tung oil 1000g will be given birth to mix with soil 10g, and endure and add 1g yellow lead oxide to when 240 DEG C; Continue to endure and add 15g rosin to when 280 DEG C; Boiled wood oil is mixed to obtain after rosin melts completely.
Embodiment 4
Boiled wood oil prepared by 1000g soluble phenolic resin varnish (Zouping Yu Yang Chemical Co., Ltd. produces, oil content 46%), 3000g kerosene (Shanghai Haas too lubricating oil company limited is produced) and 250g embodiment 1 is mixed, obtains high tint permanence paint.
Embodiment 5
Boiled wood oil prepared by 1200g rosin modified phenolic resin varnish (Zouping Yu Yang Chemical Co., Ltd. produces, oil content 40%), 4000g kerosene (Shanghai Haas too lubricating oil company limited is produced) and 150g embodiment 2 is mixed, obtains high tint permanence paint.
Embodiment 6
Boiled wood oil prepared by 800g soluble phenolic resin varnish (Zouping Yu Yang Chemical Co., Ltd. produces, oil content 60%), 1000g kerosene (Shanghai Haas too lubricating oil company limited is produced) and 400g embodiment 3 is mixed, obtains high tint permanence paint.
The performance test of the high tint permanence paint of embodiment 7
To embodiment 4-6 obtain high tint permanence varnish, and in embodiment 4 use soluble phenolic resin varnish (control group 1) and embodiment 5 in use rosin modified phenolic resin varnish (control group 2) carry out performance test, test result is as shown in the table:
Note: in upper table, skinning, brushing property, time of drying, water tolerance are tested according to People's Republic of China's chemical industry standard " F01-1 phenolic varnish HG/T2238-1991 "; Paint film appearance is tested according to " alkyd varnish HG2453-1993 "; Water-intake rate is tested according to " paint film water-intake rate assay method HG2-1612-1985 ".
From test result, the brushing property of high tint permanence paint of the present invention, paint film appearance, time of drying and water tolerance index are approximate with phenolic varnish; Skinning index is better than phenolic varnish; Water-intake rate is obviously better than phenolic varnish, namely much better than to the adsorptivity of water-based paint.Prove thus, high tint permanence paint of the present invention remain phenolic varnish and boiled wood oil quick-drying, water-fast, insect protected, anti-mildew, not easily fall the advantages such as paint, further improve the hard easily crisp shortcoming of phenolic varnish, and there is the high tint permanence of excellence, after being painted on implements surface, performance of can painting is good.
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, those of ordinary skill in the art is to be understood that, can modify to technical scheme or equivalent replacement, and not departing from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of right of the present invention.
Claims (7)
1. one kind high tint permanence paint, is made up of the component of following weight part: rosin modified phenolic resin varnish 80-120 part of oil content to be the soluble phenolic resin varnish of 40-60% or oil content be 40-60%, kerosene 100-400 part and boiled wood oil 25-40 part.
2. high tint permanence paint according to claim 1, is characterized in that: be made up of the component of following weight part: phenolic varnish 100 parts, kerosene 300 parts and boiled wood oil 25 parts.
3. high tint permanence paint according to claim 1, is characterized in that: described boiled wood oil is made up of the component of following weight part: raw tung oil 100 parts, native sub-0.1-1.0 part, yellow lead oxide 0.1-1.0 part and rosin 0.5-2 part.
4. high tint permanence paint according to claim 3, is characterized in that: described boiled wood oil is made up of the component of following weight part: raw tung oil 100 parts, soil 0.24 part, yellow lead oxide 0.25 part and rosin 0.82 part.
5. the high tint permanence paint according to claim 3 or 4, is characterized in that: the preparation of described boiled wood oil comprises the following steps:
A, tung oil and soil will be given birth to mixing by filling a prescription, enduring the yellow lead oxide to adding formula ratio during 200-240 DEG C;
B, continue to endure the rosin to adding formula ratio during 260-290 DEG C;
C, after rosin melts completely, mix to obtain boiled wood oil.
6. the high tint permanence paint described in any one of Claims 1-4 is in the application preparing enamelled coating of can painting.
7. the application of high tint permanence paint in bamboo and wood products described in any one of Claims 1-4.
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| CN201310432019.9A CN103436135B (en) | 2013-09-22 | 2013-09-22 | High tint permanence paint and application thereof |
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| CN201310432019.9A CN103436135B (en) | 2013-09-22 | 2013-09-22 | High tint permanence paint and application thereof |
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| CN103436135B true CN103436135B (en) | 2015-11-18 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105017846A (en) * | 2015-07-29 | 2015-11-04 | 李可 | Preparation method capable of improving bonding strength of ink |
| CN106590417A (en) * | 2015-10-14 | 2017-04-26 | 池州市富光涂料有限公司 | Tung oil for primer of waterborne wood coatings and its construction technology |
| CN106147700B (en) * | 2016-08-02 | 2018-08-28 | 东莞市楚丰园环保科技有限公司 | A kind of gold size and preparation method thereof |
| CN112552818B (en) * | 2020-11-09 | 2022-05-13 | 钟宏云 | Bright oil, preparation method thereof and application of limestone land |
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| US3502495A (en) * | 1962-12-28 | 1970-03-24 | Toyo Kako Co Ltd | Printing resins with penetrating ink |
| CN1712480A (en) * | 2004-06-15 | 2005-12-28 | 凌旭 | Painting with tung oil as ground coat |
| CN1986662A (en) * | 2005-11-21 | 2007-06-27 | 罗震 | Paint composition for both writing and printing on smooth surface |
| CN101508760A (en) * | 2009-01-22 | 2009-08-19 | 中国印钞造币总公司 | Oil modified phenolic resin connection material and preparation thereof |
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Patent Citations (4)
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|---|---|---|---|---|
| US3502495A (en) * | 1962-12-28 | 1970-03-24 | Toyo Kako Co Ltd | Printing resins with penetrating ink |
| CN1712480A (en) * | 2004-06-15 | 2005-12-28 | 凌旭 | Painting with tung oil as ground coat |
| CN1986662A (en) * | 2005-11-21 | 2007-06-27 | 罗震 | Paint composition for both writing and printing on smooth surface |
| CN101508760A (en) * | 2009-01-22 | 2009-08-19 | 中国印钞造币总公司 | Oil modified phenolic resin connection material and preparation thereof |
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Effective date of registration: 20190731 Address after: 516000 Zhedongfeng Village, Xinwei Town, Huiyang District, Huizhou City, Guangdong Province Patentee after: HUIZHOU CHANGGUAN PAINT Co.,Ltd. Address before: 405200 Liangshan Road 578 Liangshan Street, Liangping County, Chongqing Patentee before: Liangpin County Yinsi Bamboo Curtain Co.,Ltd. |
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Effective date of registration: 20200624 Address after: 516200 dashantang Development Zone, Xinlian village, Huiyang District, Huizhou City, Guangdong Province Patentee after: HUIZHOU YINHAI PAINT Co.,Ltd. Address before: 516000 Zhedongfeng Village, Xinwei Town, Huiyang District, Huizhou City, Guangdong Province Patentee before: HUIZHOU CHANGGUAN PAINT Co.,Ltd. |
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Address after: 516000 Dashantang Development Zone, Xinlian Village, Xinwei Town, Huiyang District, Huizhou City, Guangdong Province Patentee after: Guangdong Xinge New Materials Co.,Ltd. Address before: 516200 dashantang Development Zone, Xinwei Town, Xinlian village, Huiyang District, Huizhou City, Guangdong Province Patentee before: HUIZHOU YINHAI PAINT Co.,Ltd. |