CN103436135A - High-coloring paint and application thereof - Google Patents
High-coloring paint and application thereof Download PDFInfo
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- CN103436135A CN103436135A CN2013104320199A CN201310432019A CN103436135A CN 103436135 A CN103436135 A CN 103436135A CN 2013104320199 A CN2013104320199 A CN 2013104320199A CN 201310432019 A CN201310432019 A CN 201310432019A CN 103436135 A CN103436135 A CN 103436135A
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Abstract
The invention relates to a high-coloring paint and an application thereof. The paint comprises the following components in parts by weight: 80-120 parts of phenolic varnish, 100-400 parts of coal oil and 15-40 parts of boiled wood oil, wherein the boiled wood oil comprises the following components in parts by weight: 100 parts of raw wood oil, 0.1-1.0 part of pyrolusitum pyrolusite, 0.1-1.0 part of lithargite and 0.5-2 parts of colophony. The paint disclosed by the invention achieves a good synergetic effect through the appropriate proportion of the components, meets the requirements for properties, namely quick drying, water resistance, insect prevention, mildew prevention, difficulty in paint drop, and the like, and has the advantages of good pigment adsorptivityabsorptivity, high coloring, and the like. After the paint is coated on the surfaces of utensils, the easiness for coloring and difficulty in decoloring on the paint are achieved, and drawn pictures are bright in color and have good tactile sensation, so that the paint is especially suitable for being used as an under coating varnish layer before the surfaces of the utensils, such as bamboo and wood products, are drawn.
Description
Technical field
The present invention relates to a kind of paint, particularly a kind of on implements after brushing, high tint permanence paint and the application thereof that can be drawn a picture thereon.
Background technology
Bamboo and wood products is as a skill of China's succession, and particularly bamboo wood painting products, in the age of pursuing ancient customs or recovering one's original simplicity now, be subject to the very big welcome in market.In the drawing processing of bamboo wood painting products; at first the enamelled coating that need to be convenient to draw a picture on the bamboo wood surface is brushed; this enamelled coating both played certain protective role to bamboo and wood products, and the top layer after require brushing again has better tinctorial property, required that the pigment adsorption performance is good, water-tolerant, was difficult for falling paint etc.
Boiled wood oil be the seed of euphorbia plant tung tree as raw material, after squeezing, make living tung oil, then will give birth to tung oil after the polymerization of high temperature heat refining, filter the covering with paint dry vegetable oil of gained by essence.Boiled wood oil has high-strength seepage force, enter the inside such as bamboo and wood products can with its combination, after film forming, system is more stable, but the corrosion of ultra-violet radiation resisting and soda acid, salt spray resistance and sea water immersion, stable coating can also effectively intercept infiltration and the infiltration of water molecules, realizes " lotus leaf effect " of top coat.Therefore, the performance that coat goods after boiled wood oil and there is waterproof, insect protected, anti-ly goes mouldy, increases working life, but also because it has stronger " lotus leaf effect ", poor to the absorption property of pigment, therefore, after coating, also will draw a picture with regard to difficult thereon.
Phenolic varnish (phenolic varnish) be by pure phenolic resin or modified phenolic resins and dry vegetable oil after tempering, then add the formulated varnish such as siccative and solvent.Hard, the water-tolerant of light of filming of phenolic varnish, anti-boiling hot property are good, but more crisp, easy yellowing, can not be directly as the implements surfaces such as the bamboo and wood products front desirable bottoming enamelled coating of drawing a picture.
Known by above analysis, if can utilize the advantage of boiled wood oil and phenolic varnish simultaneously, and overcome their deficiencies separately, suitable proportioning and the synergy by the two, can develop the desirable drop priming before the implements drawing such as a kind of applicable bamboo and wood products.The present invention is directed to the deficiencies in the prior art, carried out improving invention.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of high tint permanence paint, this paint meeting quick-drying, water-fast, insect protected, prevent going mouldy, being difficult for falling the performance such as paint in, also show good pigment adsorption etc., have high tint permanence, after being painted on the implements surface, the performance of can painting is good.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of high tint permanence paint, be comprised of the component of following weight part: phenolic varnish 80-120 part, kerosene 100-400 part and boiled wood oil 15-40 part.
Further, described high tint permanence paint is comprised of the component of following weight part: 25 parts of 100 parts of phenolic varnish, 300 parts of kerosene and boiled wood oils.
Further, described phenolic varnish are soluble phenolic resin varnish, and oil content is 40-60%.Soluble phenolic resin is the resol made from various substituted phenols and formaldehyde condensation polymer, p-phenyl phenol commonly used and p-tert-butylphenol manufacture, this resin do not need modification just can thermosol in oil.Soluble phenolic resin and siccative oil mixed refining soluble phenolic resin varnish, on market, have finished product to sell.
Perhaps, described phenolic varnish are rosin modified phenolic resin varnish, and oil content is 40-60%.Rosin modified phenolic resin is the macromolecule product that carries out the chemical reaction generation with alkylphenol (as phenol, dihydroxyphenyl propane, PTBP p-tert-butylphenol, POP to tert-octylphenol, PNP nonyl phenol and PDDP dodecyl phenol etc.), formaldehyde, polyvalent alcohol and rosin, due to its unique polynuclear plane feature, there is good pigment wetting performance.Rosin modified phenolic resin and siccative oil mixed refining rosin modified phenolic resin varnish, on market, have finished product to sell.
The quality percentage composition that described oil content is grease in phenolic varnish.Described siccative oil is the triglyceride level with high degree of unsaturation and conjugated structure lipid acid, the glyceryl ester that main component is the unsaturated fatty acidss such as linolenic acid, linolic acid, and iodine number is more than 130.
Kerosene of the present invention is a class of oils, by natural oil or artificial petroleum through fractionation or cracking and obtain.Wherein, contain alkane 28-48%, aromatic hydrocarbons 20-50%, unsaturated hydrocarbons 1-6%, cyclic hydrocarbon 17-44%, carbonatoms is 10-16.In addition, also has a small amount of impurity, as sulfide (mercaptan), colloid etc.
Described boiled wood oil divides two kinds: ripe pure tung oil and mixing boiled wood oil.The extracting process of skillful tung oil is that the seeds of a tung oil tree fry oil expression, and any chemical composition is added in inartificial going, environment friendly and pollution-free.Mix boiled wood oil and boil in process, add into some siccative, be more suitable for the preparation for paint.
In paint formulation of the present invention, phenolic varnish play styling, and kerosene is solvent, and boiled wood oil plays a part to dry up, insect protected, anti-going mouldy, and during use, mixes and gets final product.
Another object of the present invention is to provide a kind of boiled wood oil, and this boiled wood oil fast drying, strong adhesion, glossiness are good, is particularly suitable for the preparation of described high tint permanence paint.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of boiled wood oil is comprised of the component of following weight part: give birth to 100 parts of tung oil, native sub-0.1-1.0 part, yellow lead oxide 0.1-1.0 part and rosin 0.5-2 part.
Further, described boiled wood oil is comprised of the component of following weight part: give birth to 0.82 part of 100 parts of tung oil, 0.24 part of soil, 0.25 part of yellow lead oxide and rosin.
Further, the preparation of described boiled wood oil comprises the following steps:
A, will give birth to tung oil and mix by formula with soil, add the yellow lead oxide of formula ratio while enduring to 200-240 ℃;
B, add the rosin of formula ratio while continuing to endure to 260-290 ℃;
C, after melting fully, rosin mixes to obtain boiled wood oil.
Wherein, described native son has another name called pyrolusitum, is the ore of oxide-based mineral pyrolusite, is mainly Manganse Dioxide.Described yellow lead oxide (Lithargyrum) is commonly called as yellow lead, is plumbous oxide mineral, is mainly yellow lead oxide.It is watery that described rosin is that the inner oil flowed out of pine tree trunk changes into through high temperature melting, the blocks of solid after dry and hard.Give birth to tung oil, rosin, native son and yellow lead oxide and can be used as industrial chemicals or Chinese medicinal materials purchase acquisition.Tung oil, under rosin, native son and yellow lead oxide's synergy, can either be accelerated the rate of drying of tung oil, can increase again sticking power and the glossiness of tung oil simultaneously.
The present invention also aims to provide the application of described high tint permanence paint, use the product painting effect of this high tint permanence paint preparation good, its application comprises:
Described high tint permanence paint is in the application for preparing the enamelled coating of can painting.This high tint permanence paint can be painted on the implements surface of bamboo, wooden or other similar quality, then is painted thereon or the operation such as printing and dyeing, has excellent picture effect.
The application of described high tint permanence paint in bamboo and wood products.This high tint permanence paint is particularly suitable as the bottoming enamelled coating before bamboo or wood-based product's decoration.This enamelled coating produces provide protection to bamboo and wood products on the one hand, has on the other hand the high tint permanence of drawing, as this paint is attached to the bamboo curtain splint surface, can substantially reach the effect of drawing a picture on rice paper.
Useful technique effect of the present invention is:
High tint permanence paint of the present invention, comprehensive phenolic varnish and the performance advantage of boiled wood oil on coating preparation of adopting, and reach good synergy with suitable proportioning, meet quick-drying, water-fast, insect protected, anti-go mouldy, be difficult for falling the performance such as paint in, also there is high tint permanence, show good pigment adsorption etc.After this paint is painted on the implements surface, is easy to colouring thereon and is difficult for fading, the picture color of drawing is vivid, and texture is good, is particularly suitable as the bottoming enamelled coating before drawing a picture in the implements surface such as bamboo and wood products.
Boiled wood oil of the present invention, by giving birth to tung oil, rosin, native son and yellow lead oxide's synergy, and suitable preparation method, obtained fast drying, strong adhesion, boiled wood oil that glossiness is good, is particularly suitable for the preparation of described high tint permanence paint.
Embodiment
In order to make the purpose, technical solutions and advantages of the present invention clearer, below embodiments of the invention are described in detail.
Embodiment 1
To give birth to tung oil 1000g and mix with native sub-2.4g, add 2.5g yellow lead oxide while enduring to 220 ℃; Add 8.2g rosin while continuing to endure to 260 ℃; After melting fully, rosin mixes to obtain boiled wood oil.
Embodiment 2
To give birth to tung oil 1000g and mix with native sub-1.0g, add 10g yellow lead oxide while enduring to 200 ℃; Add 10g rosin while continuing to endure to 290 ℃; After melting fully, rosin mixes to obtain boiled wood oil.
Embodiment 3
To give birth to tung oil 1000g and mix with native sub-10g, add 1g yellow lead oxide while enduring to 240 ℃; Add 15g rosin while continuing to endure to 280 ℃; After melting fully, rosin mixes to obtain boiled wood oil.
Embodiment 4
1000g soluble phenolic resin varnish (the abundant work company limited of foreignizing in Zouping produces, oil content 46%), 3000g kerosene (Shanghai Haas too lubricating oil company limited is produced) and the boiled wood oil of 250g embodiment 1 preparation are mixed, obtain high tint permanence paint.
Embodiment 5
1200g rosin modified phenolic resin varnish (the abundant work company limited of foreignizing in Zouping produces, oil content 40%), 4000g kerosene (Shanghai Haas too lubricating oil company limited is produced) and the boiled wood oil of 150g embodiment 2 preparations are mixed, obtain high tint permanence paint.
Embodiment 6
800g soluble phenolic resin varnish (the abundant work company limited of foreignizing in Zouping produces, oil content 60%), 1000g kerosene (Shanghai Haas too lubricating oil company limited is produced) and the boiled wood oil of 400g embodiment 3 preparations are mixed, obtain high tint permanence paint.
The performance test of the high tint permanence paint of embodiment 7
The painted varnish of height that embodiment 4-6 is obtained, and the rosin modified phenolic resin varnish (control group 2) of use in the soluble phenolic resin varnish (control group 1) used in embodiment 4 and embodiment 5 carries out performance test, test result is as shown in the table:
Annotate: in upper table, skinning, brushing property, time of drying, water tolerance are tested according to People's Republic of China's chemical industry standard " F01-1 phenolic varnish HG/T2238-1991 "; Paint film appearance is tested according to " alkyd varnish HG2453-1993 "; Water-intake rate is tested according to " paint film water-intake rate assay method HG2-1612-1985 ".
From test result, brushing property, paint film appearance, time of drying and water tolerance index and the phenolic varnish of high tint permanence paint of the present invention are approximate; The skinning index is better than phenolic varnish; Water-intake rate obviously is better than phenolic varnish, much better than to the adsorptivity of water-based paint.Prove thus, high tint permanence paint of the present invention retained phenolic varnish and boiled wood oil quick-drying, water-fast, insect protected, anti-ly gone mouldy, has been difficult for falling the advantage such as paint, also improved the hard easily crisp shortcoming of phenolic varnish, and has the high tint permanence of excellence, after being painted on the implements surface, the performance of can painting is good.
Finally explanation is, above embodiment is only unrestricted in order to technical scheme of the present invention to be described, those of ordinary skill in the art is to be understood that, can modify or be equal to replacement technical scheme, and not breaking away from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of claim scope of the present invention.
Claims (10)
1. one kind high tint permanence paint, be comprised of the component of following weight part: phenolic varnish 80-120 part, kerosene 100-400 part and boiled wood oil 15-40 part.
2. high tint permanence paint according to claim 1, it is characterized in that: the component by following weight part forms: 25 parts of 100 parts of phenolic varnish, 300 parts of kerosene and boiled wood oils.
3. high tint permanence according to claim 1 is painted, and it is characterized in that: described phenolic varnish are soluble phenolic resin varnish, and oil content is 40-60%.
4. high tint permanence according to claim 1 is painted, and it is characterized in that: described phenolic varnish are rosin modified phenolic resin varnish, and oil content is 40-60%.
5. high tint permanence according to claim 1 is painted, and it is characterized in that: described boiled wood oil is comprised of the component of following weight part: give birth to 100 parts of tung oil, native sub-0.1-1.0 part, yellow lead oxide 0.1-1.0 part and rosin 0.5-2 part.
6. high tint permanence paint according to claim 5, it is characterized in that: described boiled wood oil is comprised of the component of following weight part: give birth to 0.82 part of 100 parts of tung oil, 0.24 part of soil, 0.25 part of yellow lead oxide and rosin.
7. according to the described high tint permanence paint of claim 5 or 6, it is characterized in that: the preparation of described boiled wood oil comprises the following steps:
A, will give birth to tung oil and mix by formula with soil, add the yellow lead oxide of formula ratio while enduring to 200-240 ℃;
B, add the rosin of formula ratio while continuing to endure to 260-290 ℃;
C, after melting fully, rosin mixes to obtain boiled wood oil.
8. the described high tint permanence paint of claim 1 to 6 any one is in the application for preparing the enamelled coating of can painting.
9. the application of the described high tint permanence paint of claim 1 to 6 any one in bamboo and wood products.
10. a boiled wood oil, be comprised of the component of following weight part: give birth to 100 parts of tung oil, native sub-0.1-1.0 part, yellow lead oxide 0.1-1.0 part and rosin 0.5-2 part; Its preparation method comprises the following steps:
A, will give birth to tung oil and mix by formula with soil, add the yellow lead oxide of formula ratio while enduring to 200-240 ℃;
B, add rosin while continuing to endure to 260-290 ℃;
C, after melting fully, rosin mixes to obtain boiled wood oil.
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| CN201310432019.9A CN103436135B (en) | 2013-09-22 | 2013-09-22 | High tint permanence paint and application thereof |
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| CN201310432019.9A CN103436135B (en) | 2013-09-22 | 2013-09-22 | High tint permanence paint and application thereof |
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| CN103436135A true CN103436135A (en) | 2013-12-11 |
| CN103436135B CN103436135B (en) | 2015-11-18 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105017846A (en) * | 2015-07-29 | 2015-11-04 | 李可 | Preparation method capable of improving bonding strength of ink |
| CN106147700A (en) * | 2016-08-02 | 2016-11-23 | 北京楚之园环保科技有限责任公司 | A kind of gold size and preparation method thereof |
| CN106590417A (en) * | 2015-10-14 | 2017-04-26 | 池州市富光涂料有限公司 | Tung oil for primer of waterborne wood coatings and its construction technology |
| CN112552818A (en) * | 2020-11-09 | 2021-03-26 | 钟宏云 | Bright oil, limestone ground and preparation method of bright oil and limestone ground preparation method |
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| NL302147A (en) * | 1962-12-28 | |||
| CN1712480A (en) * | 2004-06-15 | 2005-12-28 | 凌旭 | Painting with tung oil as ground coat |
| CN1986662A (en) * | 2005-11-21 | 2007-06-27 | 罗震 | Paint composition for both writing and printing on smooth surface |
| CN101508760B (en) * | 2009-01-22 | 2010-09-08 | 中国印钞造币总公司 | Oil modified phenolic resin connection material and preparation thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105017846A (en) * | 2015-07-29 | 2015-11-04 | 李可 | Preparation method capable of improving bonding strength of ink |
| CN106590417A (en) * | 2015-10-14 | 2017-04-26 | 池州市富光涂料有限公司 | Tung oil for primer of waterborne wood coatings and its construction technology |
| CN106147700A (en) * | 2016-08-02 | 2016-11-23 | 北京楚之园环保科技有限责任公司 | A kind of gold size and preparation method thereof |
| CN112552818A (en) * | 2020-11-09 | 2021-03-26 | 钟宏云 | Bright oil, limestone ground and preparation method of bright oil and limestone ground preparation method |
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| CN103436135B (en) | 2015-11-18 |
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Effective date of registration: 20190731 Address after: 516000 Zhedongfeng Village, Xinwei Town, Huiyang District, Huizhou City, Guangdong Province Patentee after: HUIZHOU CHANGGUAN PAINT Co.,Ltd. Address before: 405200 Liangshan Road 578 Liangshan Street, Liangping County, Chongqing Patentee before: Liangpin County Yinsi Bamboo Curtain Co.,Ltd. |
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Effective date of registration: 20200624 Address after: 516200 dashantang Development Zone, Xinlian village, Huiyang District, Huizhou City, Guangdong Province Patentee after: HUIZHOU YINHAI PAINT Co.,Ltd. Address before: 516000 Zhedongfeng Village, Xinwei Town, Huiyang District, Huizhou City, Guangdong Province Patentee before: HUIZHOU CHANGGUAN PAINT Co.,Ltd. |
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Address after: 516000 Dashantang Development Zone, Xinlian Village, Xinwei Town, Huiyang District, Huizhou City, Guangdong Province Patentee after: Guangdong Xinge New Materials Co.,Ltd. Address before: 516200 dashantang Development Zone, Xinwei Town, Xinlian village, Huiyang District, Huizhou City, Guangdong Province Patentee before: HUIZHOU YINHAI PAINT Co.,Ltd. |
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