CN101879163B - In vitro insecticidal shampoo for pet and preparation and application method thereof - Google Patents
In vitro insecticidal shampoo for pet and preparation and application method thereof Download PDFInfo
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- CN101879163B CN101879163B CN201010108415A CN201010108415A CN101879163B CN 101879163 B CN101879163 B CN 101879163B CN 201010108415 A CN201010108415 A CN 201010108415A CN 201010108415 A CN201010108415 A CN 201010108415A CN 101879163 B CN101879163 B CN 101879163B
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Abstract
The invention discloses an in vitro insecticidal shampoo for pets and a preparation and application method thereof. The in vitro insecticidal shampoo for pets comprises 0.1-10 part(s) by weight of insecticidal active ingredient, 3-18 parts by weight of solvent, 10-35 parts by weight of washing ingredient, 1-20 part(s) by weight of other assistants and 40-80 parts by weight of water, wherein the insecticidal active ingredient is mixture of rotenone and chlorantraniliprole. When the in vitro insecticidal preparation for pets is applied, in vitro parasites on the pets can be killed through medicated bath. The in vitro insecticidal preparation for pets can be used conveniently and has significant preventive effect on in vitro parasites harmful to the livestock or pets, such as ticks, fleas, lice, mites and the like.
Description
Technical field
The invention belongs to washing and insecticidal technology field; Be specifically related to a kind of medicament that parasites such as the outer cattle Ticks of pet body, demodicid mite, louse, flea is had prevention and killing action; A kind of outer Pesticidal shampoo of pet body of killing all kinds of pet body epizoas and having the effect of washing house pet fur concurrently that is exclusively used in of more specifically saying so, with and preparation and method for using.
Background technology
Along with the acceleration of Chinese society expanding economy and urbanization process, the upsurge of raising pets is surging forward in China city.But the thing followed is a pet body is easy to parasitic various insect outward, like louse, Ticks, demodicid mite and flea etc., also can carry the kind pathogenic bacteria sometimes, and the harm house pet is healthy, also possibly cause the cross infection of people, animal disease.For killing house pet parasite on one's body, modes such as that people use usually is oral, the various medicaments of injection.These modes have effect preferably to parasite, but most of insecticide toxicity is higher, and are dangerous to house pet.
Summary of the invention
The objective of the invention is to remedy the deficiency of prior art, provide a kind of pet body outer Pesticidal shampoo.
Another object of the present invention provides the method for preparing of said shampoo.
A further object of the invention provides the method for using of said shampoo.
The object of the invention is achieved through following technical proposals:
Provide a kind of pet body outer Pesticidal shampoo, comprise each component of following parts by weight:
0.1～10 part of active insecticidal components;
3～18 parts of solvents;
10～35 parts in cleaning ingredients or surfactant;
1～20 part of other auxiliary agent;
40～80 parts of distilled water.
Preferably, pet body is Pesticidal shampoo outward, comprises each component of following parts by weight:
1～7 part of active insecticidal components;
5～15 parts of solvents;
15～30 parts in cleaning ingredients or surfactant;
5～15 parts of other auxiliary agents;
45～70 parts of distilled water.
Said active insecticidal components is the mixture of rotenone (rotenone) and Rynaxypyr (chlorantraniliprole); Mixed proportion is that the mass ratio of rotenone and Rynaxypyr is 1～40: 1～40; The mass ratio that preferred mixed proportion is rotenone and Rynaxypyr is 1～10: 1～10, and more preferred version is that the mass ratio of rotenone and Rynaxypyr is 1～7: 1～7.
Said cleaning ingredients (or surfactant) mainly comprises one or more of following material: ammonium lauryl sulfate; Sodium lauryl sulphate; Brij30 ammonium sulfate; Dodecylbenzene sodium sulfonate; Calcium dodecyl benzene sulfonate; Fatty alcohol-polyoxyethylene ether series; Alkyl phenol formaldehyde resin polyoxyethylene ether; Phenethyl phenyl polyoxyethylene one polyethenoxy ether; C12 alkyl (EO) 3 ether sodium sulfates; Olefin sulfonic acid; Lauric acid amide of ethanol; Styryl phenyl polyoxyethylene ether; Castor oil polyoxyethylene ether; C12 alkyl betaine (BS-12) or NPE;
Said other auxiliary agent (washing assisant) mainly comprises following component: solvent, emulsifying agent, conditioner, antifreezing agent, anti-photodissociation agent, stabilizing agent and/or antioxidant etc., and specifically select for use conventional products to get final product according to routine techniques.
Preferably; Described solvent is selected from one or more of following compositions: methanol, acetone, Ketohexamethylene, N, dinethylformamide, benzene, xylene, naphthalane, gasoline, kerosene, machine oil, propylene glycol, propylene glycol, petroleum ether, ethyl acetate, isopropyl alcohol, acetone, dimethyl sulfoxide, butanediol, plants essential oil.
Described surfactant is selected from one or more of following compositions: surfactant is the tween series of nonionic, or the alkylsurfuric acid salt of anionic.
Described antifreezing agent is selected from one or more of following compositions: ethylene glycol, glycerol or ethanol.
Described anti-photodissociation agent is selected from one or more of following compositions: para-amino benzoic acid, Oleum Ricini, pyrogallic acid, citric acid, lignosulfonates, UV-P (2-(2 '-hydroxyl-5 '-aminomethyl phenyl) BTA), BP-12 (have another name called UV-531; UV-531) or BP-3 (having another name called UV-9,2-hydroxyl-4-methoxy benzophenone).
Described stabilizing agent is selected from one or more of following compositions: epoxidized soybean oil, epoxidized linseed.
Described antioxidant is selected from one or more of following compositions: vitamin E, vitamin C, beta-carotene, BHA, BHT, citric acid, methoxybenzene or P-hydroxybenzoic acid.
Described conditioner is chosen in following compositions a kind of several kinds: silicone oil, lanoline, CH3-(CH2)13N(CH3)2-O, ND conditioner, RB-4128 conditioner, trimethylolpropane, three hot decanoins, trimethyl glycine or glyceryl monooleate.
The present invention provides the method for preparing of the outer Pesticidal shampoo of said pet body simultaneously, may further comprise the steps:
(1) earlier with the former powder of rotenone or crystal and the former medicinal solvent dissolving of Rynaxypyr, adds emulsifying agent and stir, put into the hot water water-bath emulsifying agent is fully dissolved; Hot bath can be adopted the temperature about 50 ℃;
(2) cleaning ingredients is weighed up in proportion, add distilled water, put into the hot water water-bath and make the cleaning ingredients dissolving evenly, from hot bath, take out the cleaning ingredients aqueous solution, slowly be stirred to room temperature; Hot bath can be adopted the temperature about 60 ℃;
(3) limit whipping step (1) mixture, the limit evenly splashes into step (2) cleaning ingredients aqueous solution in step (1) mixture, stirs;
(4) add various other auxiliary agents according to the dosage form needs respectively with reference to routine techniques and obtain shampoo.
The present invention also provides the method for using of said shampoo, during use, drenches house pet hair on one's body with warm water earlier; Said shampoo is applied on one's body the house pet; And rub out and enrich foam, kept 15～20 minutes, clean with warm water washing again; Blot the water on the house pet health with bath towel, use drier.
The invention has the beneficial effects as follows:
Both are mixed rotenone (rotenone) and low toxicity ultra high efficiency insecticide Rynaxypyr (chlorantraniliprole) and can increase drug effect and do not see technology report as yet; More rotenone and Rynaxypyr are not mixed and are applied to kill the ectozoic reports of pet body such as demodicid mite, Ticks, flea, louse as the effective active composition; The present invention discovers; Adopt suitable proportioning, rotenone and Rynaxypyr mixture are applied to house pet, the pet body epizoa is had good toxic effect; Both are mixed to use and can reduce dosage, increase drug effect; Widen the scope of application of medicament, delay pest resistance to insecticide and take place.
The present invention selects for use the mixture of rotenone and Rynaxypyr (chlorantraniliprole) to be aided with auxiliary agent, confirms that suitable proportioning processes shampoo for pets; Make house pet reach prevention and treat verminal effect through daily dipping; And it is easy to use; Have no side effect, good disinsection effect is to people and pet safe.
The specific embodiment
Below in conjunction with specific embodiment further explain the present invention, the auxiliary agent of selecting for use is not given unnecessary details one by one in an embodiment, but does not therefore limit to the present invention.
The preparation and the use of the pest-resistant medicated shampoo of embodiment 1 house pet
Count by weight, prepare following each component:
A component: 5 parts of the former medicines of Rynaxypyr, the former powder of rotenone or crystal 5 part, 15 parts of solvent ethyl acetates, 5 parts of emulsifying agent phenethyl phenol polyoxyethylene poly-oxygen propylene aethers;
B component: 10 parts of detergent ingredients NPEs, 5 parts of auxiliary agent tea saponins, 50 parts of distilled water;
C component: 0.2 part of conditioner ND conditioner.
Preparation process is following:
(1) takes by weighing each component by consumption;
(2) earlier with the former powder of rotenone or crystal and the former medicinal solvent dissolving of Rynaxypyr, the adding emulsifying agent stirs, put into 50 ℃ of hot water water-baths make emulsifying agent fully dissolve A;
(3) detergent ingredients is weighed up in proportion, add distilled water, put into 60 ℃ of hot water water-baths and make the even B of getting of washing assisant dissolving;
(4) from hot bath, take out B, slowly stir, be cooled to room temperature;
(5) A is stirred on the limit, and the limit evenly splashes into middle A to the B that step (4) is cooled to room temperature, stir D.
(6) with among the adding D such as other auxiliary agent C component, slowly stirring gets final product.
When using the pest-resistant medicated shampoo of house pet, drench house pet hair on one's body with warm water earlier, said shampoo is applied on one's body the house pet; And rub out and enrich foam, kept 15～20 minutes, clean with warm water washing again; Blot the water on the house pet health with bath towel, use drier.
The preparation and the use of the pest-resistant medicated shampoo of embodiment 2 house pets
Count by weight, prepare following each component:
A component: 5 parts of the former medicines of Rynaxypyr, the former powder of rotenone or crystal 2 part, solvent N, 10 parts of dinethylformamides, 3 parts of emulsifying agent styryl phenyl polyoxyethylene ether;
B component: 10 parts of detergent ingredients AESAs, 0.5 part of auxiliary agent vitamin E, 60 parts of distilled water;
0.1 part of C component: UV-P.
Preparation process and method for using are with embodiment 1.
The preparation and the use of the pest-resistant medicated shampoo of embodiment 3 house pets
Count by weight, prepare following each component:
A component: 3 parts of the former medicines of Rynaxypyr, 1 part in former powder of rotenone or crystal, 8 parts of solvent formic acid dimethyl esters, 3 parts in emulsifier polyoxyethylene lauryl alcohol ammonium sulfate;
B component: 18 parts of detergent ingredients lauric acid amide of ethanol, 5 parts of glycerin, 70 parts of distilled water;
C component: 3 parts of epoxidized soybean oils.
Preparation process and method for using are with embodiment 1.
The preparation and the use of the pest-resistant medicated shampoo of embodiment 4 house pets
Count by weight, prepare following each component:
A component: 3 parts of the former medicines of Rynaxypyr, 0.5 part in former powder of rotenone or crystal, 12 parts of solvent cinnamon essential oils, 7 parts of emulsifying agent castor oil polyoxyethylene ethers;
B component: 25 parts of detergent ingredients C12 alkyl betaines, 5 parts of glycerin, 45 parts of distilled water;
C component: 1 part of citric acid.
Preparation process and method for using are with embodiment 1.
The preparation and the use of the pest-resistant medicated shampoo of embodiment 5 house pets
Count by weight, prepare following each component:
A component: 8 parts of the former medicines of Rynaxypyr, 0.5 part in former powder of rotenone or crystal, 12 parts of solvent methyl pyrrolidones, 8 parts of emulsifying agent styryl phenyl polyoxyethylene ether;
B component: 25 parts of detergent ingredients NPEs, 5 parts of ethylene glycol, 45 parts of distilled water;
C component: 1 part of RB-4128 conditioner.
Preparation process and method for using are with embodiment 1.
The preparation and the use of the pest-resistant medicated shampoo of embodiment 6 house pets
Count by weight, prepare following each component:
A component: 1 part of the former medicine of Rynaxypyr, 0.1 part in former powder of rotenone or crystal, 5 parts of solvent dimethyl sulfoxide, 6 parts of emulsifying agent aliphatic acid polyethenoxy ethers;
B component: 10 parts of detergent ingredients calcium dodecyl benzene sulfonates, 5 parts of ethylene glycol, 58 parts of distilled water;
C component: 1 part of RB-4128 conditioner.
Preparation process and method for using are with embodiment 1.
Embodiment 7 rotenone are tested the killing effect of boophilus microplus with the different proportionings of Rynaxypyr
Test method adopts the medicine infusion process of standard.Earlier determine general concentration range through trial test, all medicines all half-and-half are diluted to the variable concentrations gradient with distilled water, do not suck blood 10 of young Tickss of every group of boophilus microplus in test, 3 repetitions of every processing.Draw the 1ml medicine and add boophilus microplus and do not suck blood in the young Ticks, dipping 5s～10min with the medicine sucking-off, wipes away the medicinal liquid of dried Ticks body surface with filter paper, and being transferred to the bottom has in the drying basin of water, room temperature, and relative humidity remains on 80～85%.Behind the 24h, observe its death condition.Be provided with distilled water and normal control group in the test.If the mortality rate of matched group is used the Abbott formula correction 5～20%.Judge the dead boophilus microplus young Ticks of not sucking blood with following program: the one, direct observation, each limb inertia of boophilus microplus; The 2nd, under anatomical lens, it is movable to cannot see each limb of boophilus microplus; The 3rd, under anatomical lens, slightly contact with toothpick, it is movable also to cannot see each limb of boophilus microplus.The mortality rate computing formula:
Experimental result is seen table 1 and table 2:
The different proportionings with Rynaxypyr of table 1 rotenone are to the killing effect of cattle Ticks
A represents Rynaxypyr; B represents rotenone
Table 2 toxicity test result of calculation
A represents Rynaxypyr; B represents rotenone
With the shampoo in embodiment 1,2,3,4,5 and 6 is pet bathing.Administration the previous day is with 20 hard Tickss, 7 doggies (wherein as contrasting) on one's body in the parasitisms respectively.Calculate the use shampoo according to the amount of 10ml/5kg body weight, before the use, drench the hair that Canis familiaris L. goes up alone with warm water earlier; According to using dosage said shampoo is applied on one's body the house pet; And rub out and enrich foam, kept 15～20 minutes, clean with warm water washing again; Blot the water on the house pet health with bath towel, use drier.The Canis familiaris L. of contrast goes up alone only uses common bath solution for pet, and the inspection Canis familiaris L. goes up the quantity of hard Ticks alone behind the 24h, calculates prevention effect.Calculate control rate according to formula, the result is according to the criterion evaluation.
| Evaluation criterion | Control rate (%) |
| A | 100 |
| B | 99-90 |
| C | 89-80 |
| D | 79-50 |
| E | ＜50 |
Experimental result shows that the prevention effect of 1,2,3,4,5 and 6 pairs of Canis familiaris L. epizoite insects of the embodiment of the invention all reaches A.
Claims (4)
1. the outer Pesticidal shampoo of a pet body is characterized in that comprising each components of following parts by weight:
0.1～7 part of active insecticidal components;
5～15 parts of solvents;
15～30 parts in cleaning ingredients or surfactant;
5～15 parts of other auxiliary agents;
45～70 parts of distilled water;
Said active insecticidal components is the mixture of rotenone and Rynaxypyr; The mass ratio of said rotenone and Rynaxypyr is 1～10: 1～10;
Said cleaning ingredients or surfactant are one or more of following material: ammonium lauryl sulfate; Sodium lauryl sulphate; Brij30 ammonium sulfate; Dodecylbenzene sodium sulfonate; Calcium dodecyl benzene sulfonate; Alkyl phenol formaldehyde resin polyoxyethylene ether; Phenethyl phenyl polyoxyethylene one polyethenoxy ether; C12 alkyl (EO) 3 ether sodium sulfates; Olefin sulfonic acid; Lauric acid amide of ethanol; Styryl phenyl polyoxyethylene ether; Castor oil polyoxyethylene ether or NPE;
Said other auxiliary agent is one or more of following composition: emulsifying agent, solvent, conditioner, antifreezing agent, anti-photodissociation agent, stabilizing agent and/or antioxidant;
Described solvent is selected from one or more of following substances: methanol, acetone, Ketohexamethylene, N, dinethylformamide, benzene, xylene, naphthalane, gasoline, kerosene, machine oil, propylene glycol, propylene glycol, petroleum ether, ethyl acetate, isopropyl alcohol, acetone, dimethyl sulfoxide, butanediol, N-Methyl pyrrolidone or plants essential oil;
Described antifreezing agent is selected from one or more of following substances: ethylene glycol, glycerol, sorbitol, carbamide, sodium chloride or ethanol;
Described anti-photodissociation agent is selected from one or more of following substances: para-amino benzoic acid, Oleum Ricini, pyrogallic acid, citric acid, lignosulfonates, 2-(2 '-hydroxyl-5 '-aminomethyl phenyl) BTA, UV-531 or 2-hydroxyl-4-methoxy benzophenone;
Described stabilizing agent is selected from one or more of following substances: epoxidized soybean oil or epoxidized linseed;
Described antioxidant is selected from one or more of following substances: vitamin E, vitamin C, beta-carotene, citric acid, methoxybenzene or P-hydroxybenzoic acid;
Described conditioner is chosen from one or more of following substances: silicone oil, lanoline, CH3-(CH2)13N(CH3)2-O, trimethylolpropane, three hot decanoins, trimethyl glycine or glyceryl monooleate.
2. according to the outer Pesticidal shampoo of the said pet body of claim 1, the mass ratio that it is characterized in that said rotenone and Rynaxypyr is 1～7: 1～7.
3. the method for preparing of the outer Pesticidal shampoo of claim 1 or 2 said pet bodies is characterized in that may further comprise the steps:
(1) with rotenone and the former medicinal solvent dissolving of Rynaxypyr, adds emulsifying agent and stir, emulsifying agent is fully dissolved in water-bath;
(2) cleaning ingredients is weighed up in proportion, add distilled water, water-bath makes the cleaning ingredients dissolving evenly, from hot bath, takes out the cleaning ingredients aqueous solution, slowly is stirred to room temperature;
(3) limit whipping step (1) mixture, the limit evenly splashes into step (2) cleaning ingredients aqueous solution in step (1) mixture, stirs.
4. the method for using of the outer Pesticidal shampoo of claim 1 or 2 said pet bodies; It is characterized in that it being earlier to drench house pet hair on one's body, said shampoo is applied on one's body the house pet, and rubs out and enrich foam with warm water; Kept 15～20 minutes; Clean with warm water washing again, blot the water on the pet hair, dry up.
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| CN201010108415A CN101879163B (en) | 2010-02-08 | 2010-02-08 | In vitro insecticidal shampoo for pet and preparation and application method thereof |
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| CN201010108415A CN101879163B (en) | 2010-02-08 | 2010-02-08 | In vitro insecticidal shampoo for pet and preparation and application method thereof |
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| CN101879163B true CN101879163B (en) | 2012-10-10 |
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Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102085163B (en) * | 2011-01-24 | 2012-09-05 | 北京洛娃日化有限公司 | Mite-removing pet shampoo |
| CN102550573B (en) * | 2012-01-30 | 2013-10-30 | 华南理工大学 | Chlorantraniliprole and rotenone compound suspending agent and its preparation method |
| CN103462828A (en) * | 2013-08-27 | 2013-12-25 | 江苏轩驿生物科技有限公司 | Medicinal shampoo and production process thereof |
| CN103494764B (en) * | 2013-10-16 | 2014-12-03 | 南通市电梯部件业商会 | Healthcare mist spray for pet cat |
| CN104257591A (en) * | 2014-10-11 | 2015-01-07 | 邯郸学院 | Chinese herbal medicine pet shampoo capable of dispelling insects and removing acari and preparation method of pet shampoo |
| CN104352390A (en) * | 2014-10-29 | 2015-02-18 | 苗娥 | Traditional Chinese medicine bath liquid for pets and preparation method thereof |
| ES2711734T3 (en) * | 2015-02-17 | 2019-05-07 | Nippon Soda Co | Agrochemical composition |
| CN105412004B (en) * | 2015-12-03 | 2019-01-08 | 湖北美天生物科技股份有限公司 | It is a kind of for treating and protecting the antiparasitic composition of non-food stuff animal |
| CN106726911A (en) * | 2016-12-09 | 2017-05-31 | 陈忠燕 | A kind of lemon pet hair clean-care agent |
| CN109464345A (en) * | 2019-01-25 | 2019-03-15 | 湖北中博绿亚生物技术有限公司 | A kind of Tea Saponin lotion and preparation method thereof |
| CN110124040B (en) * | 2019-05-10 | 2021-05-25 | 金华市呗力水产养殖技术有限公司 | Compound preparation for preventing and treating parasites of aquatic animals |
| CN113367118A (en) * | 2021-05-14 | 2021-09-10 | 中国农业科学院上海兽医研究所(中国动物卫生与流行病学中心上海分中心) | Application of Chinese cinnamon essential oil |
| CN115720902A (en) * | 2021-09-01 | 2023-03-03 | 郑州赛科药业科技有限公司 | Traditional Chinese medicine spray for treating ectoparasites of pets |
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