CN101845289A - Double-component polyurethane foaming adhesive for attaching XPS and EPS walls and preparation method thereof - Google Patents
Double-component polyurethane foaming adhesive for attaching XPS and EPS walls and preparation method thereof Download PDFInfo
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- CN101845289A CN101845289A CN 201010187844 CN201010187844A CN101845289A CN 101845289 A CN101845289 A CN 101845289A CN 201010187844 CN201010187844 CN 201010187844 CN 201010187844 A CN201010187844 A CN 201010187844A CN 101845289 A CN101845289 A CN 101845289A
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- component polyurethane
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- polyurethane foaming
- foaming adhesive
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Abstract
The invention relates to a double-component polyurethane foaming adhesive for buildings. The foaming adhesive is dedicated for adhering polystyrene board (EPS), cement board (GRC) and extruded sheet (XPS) internal and external wall insulation boards. The double-component polyurethane foaming adhesive has controllable adhering time and has temperature resistance, cold resistance, hydrolysis resistance and strong adhesive power. When the double-component polyurethane foaming adhesive is adhered to the wall, a user can loose hand in time to assemble a fastener. Compared with the conventional adhesive, the double-component polyurethane foaming adhesive saves working hours and cost, also relates to energy saving of a building system and greatly reduces waste generated in the constructing process. A material of the invention is formed by mixing an A adhesive (a white material) with a B adhesive (a black material). The range of the mass ratio of the A adhesive to the B adhesive is wide. 100 parts by mass of A adhesive and 50 to 70 parts by mass of B adhesive can be attached and do not influence the bonding strength. The double-component polyurethane foaming adhesive can be operated in harsh environment of low temperature between minus 3 DEG C and 5 DEG C, but the walls must be dried. The A and B adhesives can be bonded after being mixed precisely and stirred uniformly. Under the condition that the wall is not flat slightly, microfoam of the double-component polyurethane foaming adhesive of the invention can help to fill in gaps between the boards and the wall to make the inside generate an isolation layer to more achieve the effects of insulating heat and preserving heat.
Description
Technical field
The invention belongs to building material technical field, relate to the polyurethane two-component foaming adhesive of used for adhering internal wall and external wall in a kind of building, the especially a kind of XPS in the building, dual-component polyurethane foamed glue of EPS warming plate binding cement body of wall of being exclusively used in.
Background technology
In recent years, along with the continuous propelling of Chinese architecture energy conservation, the development of External Thermal Insulation Technology for External, the present constructional method that generally adopts cement, EPS or XPS is at exterior wall processing paste heat-preserving laminate.Adhesive material adopts clay, linked network, nailing or the like more, and these adhesive materials its intensity rising setting time when construction is long, and its shortcoming is summarized as follows:
(1) generally use clay and epoxy type glue, bonding overlong time must be at 3 hours, and other clay just can reach certain intensity later on about 24 hours.Need a large amount of cement, mortar etc. during construction, when building high-rise building, it is consuming time that material is too much carried, and working efficiency is poor.
(2) the two component glue of above-mentioned epoxy cost an arm and a leg, and general clay drying, gel time are long, and intensity can't in time be come up, and causes construction not convenient, increases more cost of labor.
Summary of the invention
The object of the present invention is to provide a kind of dual-component polyurethane foamed glue, at benzene plate (EPS), extruded sheet (XPS), cement plate (GRC) and the special adhesive of exploitation.To solve shortcomings such as waste of material that conventional adhesive exists, complex procedures, contaminate environment, bonding force difference, dual-component polyurethane foamed glue of the present invention, controlled, heatproof of its stickup time, cold-resistant, hydrolysis, intensity height, strong adhesion, therefore the stickup condition of this glue is loose, has saved man-hour and cost.
Dual-component polyurethane foamed glue of the present invention is made up of A glue (little Huang) and B glue (tawny), and A glue and B glue are respectively urethane (polyol) polyether glycol combination formula and isocyanic ester (ISO) prescription, also can be called white material and black material respectively.The ratio range of A/B is wide, and proportioning can both be fitted between 50～70 parts in B glue in 100 parts in A glue, does not influence its bonding strength, and can still can operate under the low temperature between-3 ℃～5 ℃.During use, A glue and B glue are by the deal proportioning of index, and brushing can be bonded in metope on sheet material after evenly stirring.The little foaming of this adhesive tape has under the irregular situation slightly at body of wall, and little foaming can be filled up the gap of body of wall and sheet material, more can reach the effect of insulation, disconnected heat.
The white material of dual-component polyurethane foamed glue of the present invention and black material each component weight ratio prescription are as follows:
Polyether glycol 60% polyoxyethylene glycol 18%
Sorbyl alcohol 8% magnesium hydroxide 6%
1.4-two Zhong Ding amino-benzenes 1% 1.8 diazacyclo hendecenes 0.2%
Triethylene two tertiary amines 0.5% antioxidant 1%
Hydrolysis agent 0.5% silicone oil 0.3%
Water (H
2O) 0.5% glycerine 3%
TriMethylolPropane(TMP) 0.5% trolamine 0.5%
Polymethylene phenyl isocyanate 35%
Modified polyalcohol '-diphenylmethane diisocyanate 50%
Plasticizer (vinylbenzene) 15%
Embodiment
1, the white material of preparation (polyol)
Step 1: get 60% polyether glycol in advance with the polymerization of going ahead of the rest of triethylene two tertiary amines, glycerine raw material, temperature is even 18～25 ℃ of following high-speed stirring.
Step 2: in the polymerisate of step 1, add other composition sorbyl alcohol, TriMethylolPropane(TMP), trolamine, 1.8 diazacyclo hendecenes, magnesium hydroxide, silicone oil, antioxidant etc. by proportioning, heat to 40～50 ℃, and stir about 2～3 hours, promptly finish.
Step 3:, deposit in shady and cool place with the white material cooling back barrelling sealing that makes in the step 2.
2, the black material of preparation (ISO)
Step 1: the modified polyalcohol '-diphenylmethane diisocyanate with 50%, 35% polymethylene phenyl isocyanate, 15% plasticizer (vinylbenzene) are put into container.
Step 2: the starting material in the above-mentioned steps one are heated to 50～60 ℃, and stir in advance about 1 hour of reaction back to cooling, unload barreled and pack promptly and finish.
The white material and the black material that will prepare when 3, using are 1: 0.5～1: 0.7 uniform mixing by weight.
Claims (4)
1. dual-component polyurethane foamed glue, this two-component foaming adhesive is stirred by urethane (polyol) polyether glycol combination formula and isocyanic ester (ISO) prescription and forms, the weight ratio of urethane (polyol) polyether glycol combination formula and isocyanic ester (ISO) prescription is 1: 0.5～1: 0.7, it is characterized in that: the composition of described urethane (polyol) polyether glycol combination formula comprises 60% polyether glycol, 18% polyoxyethylene glycol, 8% sorbyl alcohol, 6% magnesium hydroxide, the two Zhong Ding amino-benzenes of 1% 1.4-, 0.2% 1.8 diazacyclo hendecenes, 0.5% triethylene two tertiary amines, 1% antioxidant, 0.5% hydrolysis agent, 0.3% silicone oil, 0.5% water (H
2O), 3% glycerine, 0.5% TriMethylolPropane(TMP), 0.5% trolamine; The composition of described isocyanic ester (ISO) prescription comprises 35% polymethylene phenyl isocyanate, 50% modified polyalcohol '-diphenylmethane diisocyanate and 15% plasticizer.
2. dual-component polyurethane foamed glue according to claim 1 is characterized in that described urethane (polyol) polyether glycol combination formula and described isocyanic ester (ISO) prescription generate by polymerization.
3. polyurethane two-component foaming adhesive according to claim 1 and 2 is characterized in that described plasticizer is a vinylbenzene.
4. polyurethane two-component foaming adhesive as claimed in claim 1 or 2, it is characterized in that: the preparation of urethane wherein (polyol) polyether glycol combination formula comprises:
Step 1: get 60% polyether glycol in advance with the polymerization of going ahead of the rest of triethylene two tertiary amines, glycerine raw material, temperature is even 18～25 ℃ of following high-speed stirring.
Step 2: in the polymerisate of step 1, add other composition sorbyl alcohol, TriMethylolPropane(TMP), trolamine, 1.8 diazacyclo hendecenes, magnesium hydroxide, silicone oil, antioxidant etc. by proportioning, heat to 40～50 ℃, and stir about 2～3 hours, promptly finish.
Step 3:, deposit in shady and cool place with the white material cooling back barrelling sealing that makes in the step 2.
The preparation of isocyanic ester wherein (ISO) prescription comprises:
Step 1: the modified polyalcohol '-diphenylmethane diisocyanate with 50%, 35% polymethylene phenyl isocyanate, 15% plasticizer (vinylbenzene) are put into container.
Step 2: the starting material in the above-mentioned steps one are heated to 50～60 ℃, and stir in advance about 1 hour of reaction back to cooling, unload barreled and pack promptly and finish.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010187844 CN101845289A (en) | 2010-06-01 | 2010-06-01 | Double-component polyurethane foaming adhesive for attaching XPS and EPS walls and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010187844 CN101845289A (en) | 2010-06-01 | 2010-06-01 | Double-component polyurethane foaming adhesive for attaching XPS and EPS walls and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101845289A true CN101845289A (en) | 2010-09-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010187844 Pending CN101845289A (en) | 2010-06-01 | 2010-06-01 | Double-component polyurethane foaming adhesive for attaching XPS and EPS walls and preparation method thereof |
Country Status (1)
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| CN (1) | CN101845289A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103266672A (en) * | 2013-05-30 | 2013-08-28 | 北京索利特新型建筑材料有限公司 | External wall heat preservation system and construction technology of recombination of polystyrene foam and heat preservation inorganic fireproof plate |
| CN106318308A (en) * | 2015-07-07 | 2017-01-11 | 盛德罗宝节能材料科技股份有限公司 | Early-strength polyurethane-epoxy resin composite adhesive for external drawing test |
| CN106634784A (en) * | 2016-11-09 | 2017-05-10 | 万华化学集团股份有限公司 | A two-component polyurethane foaming adhesive |
| CN112746752A (en) * | 2020-12-23 | 2021-05-04 | 南通瀚盟建设工程有限公司 | Multilayer composite heat-preservation, heat-insulation and fireproof construction process for outer wall |
| CN114410232A (en) * | 2022-03-21 | 2022-04-29 | 苏州富日川电子材料有限公司 | Application method of frameless laminating reworking glue and frameless laminating reworking glue |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003089505A1 (en) * | 2002-04-17 | 2003-10-30 | Bayer Materialscience Llc | Polyurethane or polyisocyanurate foams blown with hydrofluorocarbons and carbon dioxide |
| CN1807479A (en) * | 2005-12-16 | 2006-07-26 | 秦宇 | Modified polyurethane hard bubble and its uses |
| CN101614064A (en) * | 2009-07-23 | 2009-12-30 | 辽宁鼎力科技有限责任公司 | Artificial stone indoor and outdoor wall plastic plate and preparation method thereof |
| CN101688103A (en) * | 2007-07-12 | 2010-03-31 | 三井化学株式会社 | Adhesive, composite material containing the adhesive, and process for producing the composite material |
-
2010
- 2010-06-01 CN CN 201010187844 patent/CN101845289A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003089505A1 (en) * | 2002-04-17 | 2003-10-30 | Bayer Materialscience Llc | Polyurethane or polyisocyanurate foams blown with hydrofluorocarbons and carbon dioxide |
| CN1807479A (en) * | 2005-12-16 | 2006-07-26 | 秦宇 | Modified polyurethane hard bubble and its uses |
| CN101688103A (en) * | 2007-07-12 | 2010-03-31 | 三井化学株式会社 | Adhesive, composite material containing the adhesive, and process for producing the composite material |
| CN101614064A (en) * | 2009-07-23 | 2009-12-30 | 辽宁鼎力科技有限责任公司 | Artificial stone indoor and outdoor wall plastic plate and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103266672A (en) * | 2013-05-30 | 2013-08-28 | 北京索利特新型建筑材料有限公司 | External wall heat preservation system and construction technology of recombination of polystyrene foam and heat preservation inorganic fireproof plate |
| CN103266672B (en) * | 2013-05-30 | 2015-04-22 | 北京索利特新型建筑材料有限公司 | External wall heat preservation system and construction technology of recombination of polystyrene foam and heat preservation inorganic fireproof plate |
| CN106318308A (en) * | 2015-07-07 | 2017-01-11 | 盛德罗宝节能材料科技股份有限公司 | Early-strength polyurethane-epoxy resin composite adhesive for external drawing test |
| CN106634784A (en) * | 2016-11-09 | 2017-05-10 | 万华化学集团股份有限公司 | A two-component polyurethane foaming adhesive |
| CN112746752A (en) * | 2020-12-23 | 2021-05-04 | 南通瀚盟建设工程有限公司 | Multilayer composite heat-preservation, heat-insulation and fireproof construction process for outer wall |
| CN114410232A (en) * | 2022-03-21 | 2022-04-29 | 苏州富日川电子材料有限公司 | Application method of frameless laminating reworking glue and frameless laminating reworking glue |
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Application publication date: 20100929 |