CN102776961A - Grindable polyurethane composite board and manufacture method thereof - Google Patents

Grindable polyurethane composite board and manufacture method thereof Download PDF

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Publication number
CN102776961A
CN102776961A CN2012102851220A CN201210285122A CN102776961A CN 102776961 A CN102776961 A CN 102776961A CN 2012102851220 A CN2012102851220 A CN 2012102851220A CN 201210285122 A CN201210285122 A CN 201210285122A CN 102776961 A CN102776961 A CN 102776961A
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CN
China
Prior art keywords
foam polyurethane
polymer cement
hard
polyurethane
insulation layer
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Pending
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CN2012102851220A
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Chinese (zh)
Inventor
吴国成
丁建阳
战国明
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YANTAI SHUNDA POLYURETHANES CO Ltd
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YANTAI SHUNDA POLYURETHANES CO Ltd
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Application filed by YANTAI SHUNDA POLYURETHANES CO Ltd filed Critical YANTAI SHUNDA POLYURETHANES CO Ltd
Priority to CN2012102851220A priority Critical patent/CN102776961A/en
Publication of CN102776961A publication Critical patent/CN102776961A/en
Pending legal-status Critical Current

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  • Polyurethanes Or Polyureas (AREA)
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Abstract

The invention relates to a grindable polyurethane composite board which comprises a hard-foam polyurethane thermal insulation layer in the middle layer and polymer cement interface layers arranged on the upper surface and the lower surface of the hard-foam polyurethane thermal insulation layer, wherein the polymer cement interface layers are directly compounded on the upper surface and the lower surface of the hard-foam polyurethane thermal insulation layer during foaming of the hard-foam polyurethane thermal insulation layer, and the polymer cement interface layers are made of waterproof and fireproof materials which can be directly grinded. The grindable polyurethane composite board can be embellished and grinded in on-wall construction, has excellent waterproof thermal-insulation performance, is prominent in system fireproofing, reduces the requirement for wall surface evenness of foundation building walls, and is convenient to construct. The efficiency of the grindable polyurethane composite board is 1.5 times as high as an ordinary polyurethane composite board. The manufacture method of the grindable polyurethane composite board can perform continuous production in plants, is high in manufacture efficiency and saves a large amount of production cost and construction cost.

Description

Can grind Rigid foam polyurethane and production method thereof
Technical field
The present invention relates to the energy saving building material field, especially relate to a kind of low ground Rigid foam polyurethane and the production method thereof of construction wall planeness requirement.
Background technology
Along with the progressively enforcement of China's the 3rd step building energy conservation 65% target, polyurethane is as high-quality and efficient thermal-insulating waterproof material, and the application on body of wall, roofing also progressively enlarges, and has obtained good result of use.Outside external wall in the heat insulating work; Thin plastoring system be present history at most, the most ripe, the most widely used thermal-insulating waterproof of technology system; Rigid foam polyurethane is swift and violent as the insulation base material development in recent years of this system, but existing Rigid foam polyurethane plane materiel is harder, can not be as the polyphenyl plate levelling of polishing; Limit it in the relatively poor architectural application of wall leveling degree, also had a strong impact on the thin plastoring system efficiency of construction of Rigid foam polyurethane material simultaneously.
The sheet material of modifying of can polishing on the existing market has polyphenyl plate, polyurethane bare board etc.; But it does not have overlay coating; On the one hand with the poor adhesion of body of wall, the safety that wind suction prevention and antigravity are sheared can not get ensureing there is not the protection of inorganic surface layer on the other hand; Can not stop the attack of flame, the system fire line is poor.
Summary of the invention
The technical problem that the present invention solved provides a kind of Rigid foam polyurethane and production method thereof of grinding; The composite plate that adopts this method to make not only has excellent fire prevention, waterproof, heat-insulating property; Also strengthened caking property with body of wall; More outstanding is that plate surface can be modified polishing, greatly reduces the requirement to the construction wall planeness, has improved efficiency of construction simultaneously significantly.
In order to achieve the above object, the technical scheme of the present invention's employing is:
A kind of Rigid foam polyurethane that grinds comprises hard-foam polyurethane insulation layer that is positioned at the intermediate layer and the polymer cement boundary layer that is positioned at hard-foam polyurethane insulation layer upper and lower surface; Said polymer cement boundary layer is in the foaming process of hard-foam polyurethane insulation layer, directly to be compounded in said hard-foam polyurethane insulation layer upper and lower surface; Said polymer cement boundary layer employing can directly be polished and the material of waterproof fireproofing is processed.
The present invention is through the direct composition polymer cement interface layer on the foamed polyurethane layer two sides; Said polymer cement boundary layer employing can directly be polished and the material of waterproof fireproofing is processed; Make the surface of the Rigid foam polyurethane after processing directly to modify polishing, greatly reduce requirement, and composite plate is easy to body of wall bonding the construction wall planeness; Adhesion is high, is difficult for dropping; Also contain the waterproof fireproofing material simultaneously, have the excellent waterproof fireproof performance.Said can directly polish and the material of waterproof fireproofing is preferably processed by polymer gel material, inorganic powder and fire retardant; Said polymer gel material is one or more in polyacrylic resin, waterborne polyurethane resin, the EVA resin; Said inorganic powder is one or more in cement, river sand, quartz powder, dicalcium powder, the natural sand; Said fire retardant is one or more in TCEP, TCPP, TDCPP, DMMP, APP, triphenyl phosphate, antimony oxide, magnesium hydroxide, aluminium hydroxide, the silicon-series five-retardant.The consumption of wherein said polymer gel material can be adjusted between mass concentration 0.5-90%, to obtain the product of different stability, weatherability.The principle of allotment is as the criterion with the film or the layer structure that can form stable in properties.
There are not net material or facestock material in the Rigid foam polyurethane that grinds of the present invention, wherein said polymer cement boundary layer as skeleton.
Production method of grinding Rigid foam polyurethane of the present invention: can directly polish and the material of waterproof fireproofing can grind polymer cement interface coiled material being coated on the production line to produce on the carrier film of compatibility difference with it, the said polymer cement interface coiled material that grinds is said polymer cement boundary layer; Can grinding polymer cement interface coiled material then, to divide upper and lower faces to pass through tensile stress docile on the upper and lower carrier bar of the continuous foamed line of polyurethane; Again polyisocyanates and combination material mixture are cast in and grind between the coiled material above and below, polymer cement interface uncoiling and carry out continuous foamed; After the moulding outlet carrier film is taken off, processed and to grind Rigid foam polyurethane; Middle foaming layer is said hard-foam polyurethane insulation layer.
Aforementioned production method, wherein said can directly polish and the material of waterproof fireproofing is processed by polymer gel material, inorganic powder and fire retardant; Said polymer gel material is one or more in polyacrylic resin, waterborne polyurethane resin, the EVA resin; Said inorganic powder is one or more in cement, river sand, quartz powder, dicalcium powder, the natural sand; Said fire retardant is one or more in TCEP, TCPP, TDCPP, DMMP, APP, triphenyl phosphate, antimony oxide, magnesium hydroxide, aluminium hydroxide, the silicon-series five-retardant.
Aforementioned production method, wherein said carrier film are a kind of in polyolefin plastics film, release liners, the pad pasting kraft.
Aforementioned production method, wherein said combination material are one or both of combined polyether glycol, combination PEPA.
The Rigid foam polyurethane that grinds of the present invention can be modified polishing when last wall is constructed, and not only has excellent waterproof thermal-insulated performance; And the system fire prevention is outstanding; And reduced requirement to the foundation construction degree of plainness for wall surface, easy construction, efficient is 1.5 times of conventional polyurethanes composite plate construction.
Production method of grinding Rigid foam polyurethane of the present invention can adopt factory's serialization to produce; Production efficiency is high; A large amount of cost of production and construction cost have been saved; And sheet material in light weight, planeness is high, fireproof performance good, also can cut arbitrarily, can improve the efficiency of construction of thin plastoring system greatly.
Description of drawings
Fig. 1 is the structural representation that grinds Rigid foam polyurethane of the present invention.
The specific embodiment
For further specifying the present invention, specify in conjunction with following examples:
As shown in Figure 1, the ground Rigid foam polyurethane that the present invention produces according to production method is to constitute by three layers:
From sheet material one side to another side is can grind polymer cement boundary layer 2, hard-foam polyurethane layer 1, can grind polymer cement boundary layer 2 successively.
Its production method is: the first step is in harmonious proportion the mixture that forms with cement, polyacrylic acid emulsion, river sand, TCPP and suitable quantity of water and produces through coil production line on polypropylene plastic film that can to grind the coiled material rolling of polymer cement interface subsequent use; Second step can grind on the upper and lower carrier bar that polymer cement interface coiled material is tiled in continuous foamed line, and cast polyisocyanates and combined polyether mass ratio are the mixing material of 1.2:1, foaming between carrier bar.The sheet material of producing cutting cutting after slaking is pasted and is used.
The consumption of above-mentioned each raw material is the conventional amount used of this area, and wherein the consumption of polyacrylic acid emulsion can be adjusted between mass concentration 0.5-90%, to obtain the product of different stability, weatherability.The principle of allotment is as the criterion with the film or the layer structure that can form stable in properties.
Coil production line and continuous foamed production line are all ripe commercially available equipment, no longer describe here.
Above-described embodiment describes preferred implementation of the present invention; Be not that scope of the present invention is limited; Design under the prerequisite of spirit not breaking away from the present invention; Various distortion and improvement that the common engineers and technicians in this area make technical scheme of the present invention all should fall in the definite protection domain of claims of the present invention.

Claims (8)

1. one kind can be ground Rigid foam polyurethane, it is characterized in that: saidly grind the polymer cement boundary layer (2) that Rigid foam polyurethane comprises the hard-foam polyurethane insulation layer (1) that is positioned at the intermediate layer and is positioned at hard-foam polyurethane insulation layer (1) upper and lower surface; Said polymer cement boundary layer (2) is in the foaming process of hard-foam polyurethane insulation layer (1), directly to be compounded in said hard-foam polyurethane insulation layer (1) upper and lower surface; Said polymer cement boundary layer (2) employing can directly be polished and the material of waterproof fireproofing is processed.
2. the Rigid foam polyurethane that grinds according to claim 1 is characterized in that: do not have net material or facestock material as skeleton in the said polymer cement boundary layer (2).
3. the Rigid foam polyurethane that grinds according to claim 1 is characterized in that: said polymer cement boundary layer (2) is processed by polymer gel material, inorganic powder and fire retardant; Said polymer gel material is one or more in polyacrylic resin, waterborne polyurethane resin, the EVA resin; Said inorganic powder is one or more in cement, river sand, quartz powder, dicalcium powder, the natural sand; Said fire retardant is one or more in TCEP, TCPP, TDCPP, DMMP, APP, triphenyl phosphate, antimony oxide, magnesium hydroxide, aluminium hydroxide, the silicon-series five-retardant.
4. the Rigid foam polyurethane that grinds according to claim 3 is characterized in that: the mass ratio that said polymer gel material accounts for the raw material total amount is 0.5%~90%.
5. each described production method of grinding Rigid foam polyurethane of claim 1-4; It is characterized in that: can directly polish and the material of waterproof fireproofing can grind polymer cement interface coiled material being coated on the production line to produce on the carrier film of compatibility difference with it, the said polymer cement interface coiled material that grinds is said polymer cement boundary layer (2); Can grinding polymer cement interface coiled material then, to divide upper and lower faces to pass through tensile stress docile on the upper and lower carrier bar of the continuous foamed line of polyurethane; Again polyisocyanates and combination material mixture are cast in and grind between the coiled material above and below, polymer cement interface uncoiling and carry out continuous foamed; After the moulding outlet carrier film is taken off, processed and to grind Rigid foam polyurethane; Middle foaming layer is said hard-foam polyurethane insulation layer (1).
6. production method according to claim 5 is characterized in that: said can directly polish and the material of waterproof fireproofing is processed by polymer gel material, inorganic powder and fire retardant; Said polymer gel material is one or more in polyacrylic resin, waterborne polyurethane resin, the EVA resin; Said inorganic powder is one or more in cement, river sand, quartz powder, dicalcium powder, the natural sand; Said fire retardant is one or more in TCEP, TCPP, TDCPP, DMMP, APP, triphenyl phosphate, antimony oxide, magnesium hydroxide, aluminium hydroxide, the silicon-series five-retardant.
7. production method according to claim 5 is characterized in that: said carrier film is a kind of in polyolefin plastics film, release liners, the pad pasting kraft.
8. production method according to claim 5 is characterized in that: said combination material is one or both of combined polyether glycol, combination PEPA.
CN2012102851220A 2012-08-06 2012-08-06 Grindable polyurethane composite board and manufacture method thereof Pending CN102776961A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103046654A (en) * 2012-12-18 2013-04-17 烟台市顺达聚氨酯有限责任公司 Hard foam polyurethane phase-transition heat preservation composite board
CN104295035A (en) * 2014-09-22 2015-01-21 北京建筑材料科学研究总院有限公司 Rigid-foam polyurethane heat-preserving and decorating integration plate and manufacturing method thereof
CN112874113A (en) * 2021-01-08 2021-06-01 马金焕 Polyurethane composite board processing system and processing technology

Citations (7)

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Publication number Priority date Publication date Assignee Title
US6044604A (en) * 1996-09-23 2000-04-04 Bridgestone/Firestone, Inc. Composite roofing members having improved dimensional stability and related methods
CN1775521A (en) * 2005-12-08 2006-05-24 夏良强 Hard-foam polyurethane composite plate and its production process
CN101214750A (en) * 2008-01-15 2008-07-09 夏良强 Fire-resistant hard foamed polyurethane composite board and fire protection strip preparation method
CN201908367U (en) * 2011-01-05 2011-07-27 杭州安阳建材科技有限公司 Thermal insulation waterproof composite board
CN201952924U (en) * 2011-01-01 2011-08-31 夏良强 Hard bubble polyurethane composite plate
CN102173147A (en) * 2011-01-01 2011-09-07 夏良强 Modified hard bubble polyurethane composite plate and manufacturing method thereof
CN102587609A (en) * 2012-03-23 2012-07-18 烟台市顺达聚氨酯有限责任公司 Method for producing rigid foam polyurethane heat-insulation and decorative integrated plate

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6044604A (en) * 1996-09-23 2000-04-04 Bridgestone/Firestone, Inc. Composite roofing members having improved dimensional stability and related methods
CN1775521A (en) * 2005-12-08 2006-05-24 夏良强 Hard-foam polyurethane composite plate and its production process
CN101214750A (en) * 2008-01-15 2008-07-09 夏良强 Fire-resistant hard foamed polyurethane composite board and fire protection strip preparation method
CN201952924U (en) * 2011-01-01 2011-08-31 夏良强 Hard bubble polyurethane composite plate
CN102173147A (en) * 2011-01-01 2011-09-07 夏良强 Modified hard bubble polyurethane composite plate and manufacturing method thereof
CN201908367U (en) * 2011-01-05 2011-07-27 杭州安阳建材科技有限公司 Thermal insulation waterproof composite board
CN102587609A (en) * 2012-03-23 2012-07-18 烟台市顺达聚氨酯有限责任公司 Method for producing rigid foam polyurethane heat-insulation and decorative integrated plate

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103046654A (en) * 2012-12-18 2013-04-17 烟台市顺达聚氨酯有限责任公司 Hard foam polyurethane phase-transition heat preservation composite board
CN103046654B (en) * 2012-12-18 2015-05-13 烟台市顺达聚氨酯有限责任公司 Hard foam polyurethane phase-transition heat preservation composite board
CN104295035A (en) * 2014-09-22 2015-01-21 北京建筑材料科学研究总院有限公司 Rigid-foam polyurethane heat-preserving and decorating integration plate and manufacturing method thereof
CN104295035B (en) * 2014-09-22 2016-05-11 北京建筑材料科学研究总院有限公司 A kind of hard foam polyurethane heat insulation decoration integrated board and preparation method thereof
CN112874113A (en) * 2021-01-08 2021-06-01 马金焕 Polyurethane composite board processing system and processing technology
CN112874113B (en) * 2021-01-08 2023-04-07 山东昌源材料科技有限公司 Polyurethane composite board processing system and processing technology

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Application publication date: 20121114