CN101838579B - Special aluminum wire drawing oil used for aluminum wires and production method thereof - Google Patents

Special aluminum wire drawing oil used for aluminum wires and production method thereof Download PDF

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Publication number
CN101838579B
CN101838579B CN 201010142505 CN201010142505A CN101838579B CN 101838579 B CN101838579 B CN 101838579B CN 201010142505 CN201010142505 CN 201010142505 CN 201010142505 A CN201010142505 A CN 201010142505A CN 101838579 B CN101838579 B CN 101838579B
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oil
fatty acid
aluminum wire
parts
special
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CN101838579A (en
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王慧峰
李家雄
郑树磷
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Jiangsu Zhonghui Electrical Materials Co., Ltd.
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YICHUN DEYUAN XINMAO ALUMINUM INDUSTRY Co Ltd
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Abstract

The invention discloses special drawing oil used for aluminum wires and a production method thereof. The wire drawing oil comprises the following components in parts by weight: 800-962 parts of base oil and 38-200 parts of additive. The method comprises the following steps: (1) placing the base oil into a reactor for 2 hours at constant temperature of 120 DEG C; and (2) cooling the base oil to 40-60 DEG C, adding additive in proportion; stirring and mixing for 2 hours. The special aluminum wire drawing oil has good lubricating property, strong clean ability, strong aluminum powder sedimentation ability, and low requirement to the clean device, and is environmental friendly; in addition, residual lubricating oil on the aluminum wire prepared by the aluminum wire drawing oil of the invention can be cleared off through simple washing, and when the annealing temperature of more than 360 DEG C.

Description

Drawing oil special for aluminum wire and production method thereof
Technical field
The present invention relates to coiling group field, specifically, refer to a kind of lubricating oil and production method thereof of aluminum steel wire drawing special use.
Background technology
Along with the lasting of copper valency risen, swift and violent as the substitute aluminium enamel-covered wire development of copper enameled wire.In the aluminum steel drawing process, the zone of oxidation on aluminium surface is destroyed in wire-drawing die, if make use wire drawing oil, although there is inhibitor to exist, but the aluminum steel surface still can form aluminum oxide and aluminium hydroxide again, destroyed again in lower one drawing process, form more aluminium powder, be unfavorable for the processing of aluminium.And oiliness wire drawing oil can be with aluminium and air insulated, reduce oxidation and the aquation of aluminium, but the clean-up performance of oiliness wire drawing oil is relevant with wire drawing oil viscosity and additive with isolation performance, selects improperly, causes cleaning effect or lubricant effect or isolation effect bad.Oiliness wire drawing oil combined lubrication performance, the good stability of some reputable brand wire drawing oil manufacturers manufacturings both at home and abroad, but oil viscosity is large, cleaning effect is bad, and aluminium powder is difficult for precipitation.Existing Chinese patent application CN200810194863.1, it discloses a kind of low viscous aluminum wire drawing oil combination, be conducive to the cleaning of the precipitation of aluminium powder and wire-drawing frame, aluminium conductor, but environment friendly is poor.Another Chinese patent application: CN200810199127.5, it is to disclose a kind of environmentally friendly low viscosity aluminum wire drawing oil combination.But, to compare with the product of professional manufacturers, the combination of two kinds of low viscosity wire drawing oil exists oilness to hang down and the large problem of course of processing mist of oil equally.The bare aluminium wire cleaning surfaces difficulty that above several lubricating oil combination draws is large, requires high to cleaning device.
Summary of the invention
The object of the present invention is to provide the good and eco-friendly drawing oil special for aluminum wire of a kind of oilness.
Another object of the present invention is to provide a kind of method of producing drawing oil special for aluminum wire.
For achieving the above object, the present invention adopts following technical scheme:
A kind of drawing oil special for aluminum wire, it is comprised of base oil and additive, and each component concentration is respectively according to mass fraction: base oil 800-962 part, additive 38-200 part.
Above-mentioned base oil is that each component concentration is respectively according to mass fraction by fatty acid ester, mixed vegetable oil, polyol ester compositions of mixtures: fatty acid ester 412-600 part, mixed vegetable oil 150-400 part, polyol ester mixture 50-150 part.
Preferably, above-mentioned fatty acid ester is fatty acid methyl ester.
The boiling range of above-mentioned fatty acid methyl ester is 250-360 ℃, and preferred boiling range is 300-360 ℃, and in the time of most preferably, its boiling range is 300-350 ℃.
Acid number≤the 1mgKOH/g of above-mentioned mixed vegetable oil, preferably, its acid number≤0.4 (mgKOH/g).
Above-mentioned additive is by O, O-two-(dodecanol polyoxyethylene groups ether) thiophosphatephosphorothioate, defoamer, nano aluminium oxide, oxidation inhibitor and fatty acid amide form, each component concentration is respectively according to mass fraction: O, O-two-(dodecanol polyoxyethylene groups ether) thiophosphatephosphorothioate 10-50 part, defoamer 3-20 part, nano aluminium oxide 10-50 part, oxidation inhibitor 5-30 part, the fatty acid amide ratio is 10-50 part.
Above-mentioned nano aluminium oxide is the α nano aluminium oxide, its diameter<500mm.When it is preferred, the particle diameter<200nm of nano aluminium oxide, the diameter<100nm of nano aluminium oxide in the time of most preferably.
A kind of method of making above-mentioned drawing oil special for aluminum wire, the method may further comprise the steps:
(1) base oil is placed reactor, 120 ℃ of lower constant temperature 2 hours;
(2) base oil is cooled to 40-60 ℃, add in proportion additive, stir, mixed 2 hours.
After adopting said structure, this drawing oil special for aluminum wire, its lubricity is good, cleaning capacity strong, aluminium powder precipitation ability is strong,, environmental friendliness less demanding to washing unit.In addition, the sharp aluminum steel that uses aluminum wire drawing oil combination of the present invention to make, through simply washing, remaining lubricating oil can remove during annealing temperature more than 360 ℃ clean.
Embodiment
Embodiment one:
The invention discloses a kind of drawing oil special for aluminum wire, it is comprised of base oil and additive, wherein:
In the present embodiment, 800 parts of base oils, 200 parts of additives.
Base oil is by fatty acid ester, mixed vegetable oil and polyol ester compositions of mixtures; Each component concentration is respectively according to mass fraction: 412 parts of fatty acid esters, 150 parts of mixed vegetable oils, 150 parts in polyol ester mixture.Wherein:
Fatty acid ester is fatty acid methyl ester, and the boiling range of this fatty acid methyl ester is 250 ℃; The mixed vegetable oil preferred acid number is 1.0mgKOH/g.
Additive is by O, O-two-(dodecanol polyoxyethylene groups ether) thiophosphatephosphorothioate, defoamer, nano aluminium oxide, oxidation inhibitor and fatty acid amide form, each component concentration is respectively according to mass fraction: O, 10 parts of O-two-(dodecanol polyoxyethylene groups ether) thiophosphatephosphorothioate, 3 parts of defoamers, 50 parts of nano aluminium oxides, 30 parts in oxidation inhibitor, the fatty acid amide ratio is 50 parts.Nano aluminium oxide is the α nano aluminium oxide, and its diameter is 100mm.
The invention also discloses the method for the drawing oil special for aluminum wire of a kind of embodiment of manufacturing one, the method may further comprise the steps:
(1) above-mentioned base oil is placed reactor, 120 ℃ of lower constant temperature 2 hours;
(2) base oil is cooled to 40-60 ℃, add in proportion additive, stir, mixed 2 hours.
Embodiment two:
Compare with embodiment one, difference is:
The mass fraction of base oil and additive is respectively: 962 parts of base oils, 38 parts of additives.
Each component concentration of base oil is respectively according to mass fraction: 600 parts of fatty acid esters, 400 parts of mixed vegetable oils, 50 parts in polyol ester mixture.
The boiling range of fatty acid methyl ester wherein is 360 ℃.The acid number of mixed vegetable oil is 0.4mgKOH/g.
Each component concentration of additive is respectively according to mass fraction: O, and 50 parts of O-two-(dodecanol polyoxyethylene groups ether) thiophosphatephosphorothioate, 20 parts of defoamers, 10 parts of nano aluminium oxides, 5 parts in oxidation inhibitor, the fatty acid amide ratio is 10 parts.Nano aluminium oxide is the α nano aluminium oxide, and its diameter is 60mm.
Embodiment three:
Compare with embodiment one, difference is:
The mass fraction of base oil and additive is respectively: 800 parts of base oils, 200 parts of additives.
Each component concentration of base oil is respectively according to mass fraction: 500 parts of fatty acid esters, 300 parts of mixed vegetable oils, 100 parts in polyol ester mixture.
The boiling range of fatty acid methyl ester wherein is 300 ℃.The acid number of mixed vegetable oil is 0.3mgKOH/g.
Each component concentration of additive is respectively according to mass fraction: O, and 40 parts of O-two-(dodecanol polyoxyethylene groups ether) thiophosphatephosphorothioate, 15 parts of defoamers, 28 parts of nano aluminium oxides, 20 parts in oxidation inhibitor, the fatty acid amide ratio is 40 parts.Nano aluminium oxide is the α nano aluminium oxide, and its diameter is 200mm.
Embodiment four:
Compare with embodiment one, difference is:
The mass fraction of base oil and additive is respectively: 600 parts of base oils, 400 parts of additives.
Each component concentration of base oil is respectively according to mass fraction: 450 parts of fatty acid esters, 280 parts of mixed vegetable oils, 120 parts in polyol ester mixture.
The boiling range of fatty acid methyl ester wherein is 350 ℃.The acid number of mixed vegetable oil is 0.2mgKOH/g.
Each component concentration of additive is respectively according to mass fraction: O, and 35 parts of O-two-(dodecanol polyoxyethylene groups ether) thiophosphatephosphorothioate, 10 parts of defoamers, 35 parts of nano aluminium oxides, 18 parts in oxidation inhibitor, the fatty acid amide ratio is 38 parts.Nano aluminium oxide is the α nano aluminium oxide, and its diameter is 80mm.
Although described the present invention by this embodiment, those of ordinary skills know, surface patterns of the present invention and size have many distortion and variation and do not break away from spirit of the present invention, wish that appended claim comprises these distortion and variation and do not break away from spirit of the present invention.

Claims (7)

1. drawing oil special for aluminum wire, it is characterized in that: it is comprised of base oil and additive, and each component concentration is respectively according to mass fraction: base oil 800-962 part, additive 38-200 part;
Wherein, described base oil is that each component concentration is respectively according to mass fraction by fatty acid ester, mixed vegetable oil, polyol ester compositions of mixtures: fatty acid ester 412-600 part, mixed vegetable oil 150-400 part, polyol ester mixture 50-150 part;
Described additive is by O, O-two-(dodecanol polyoxyethylene groups ether) thiophosphatephosphorothioate, defoamer, nano aluminium oxide, oxidation inhibitor and fatty acid amide form, each component concentration is respectively according to mass fraction: O, O-two-(dodecanol polyoxyethylene groups ether) thiophosphatephosphorothioate 10-50 part, defoamer 3-20 part, nano aluminium oxide 10-50 part, oxidation inhibitor 5-30 part, the fatty acid amide ratio is 10-50 part.
2. drawing oil special for aluminum wire according to claim 1, it is characterized in that: described fatty acid ester is fatty acid methyl ester.
3. drawing oil special for aluminum wire according to claim 2, it is characterized in that: the boiling range of described fatty acid methyl ester is 250-360 ℃.
4. drawing oil special for aluminum wire according to claim 1 is characterized in that: the acid number≤1mgKOH/g of described mixed vegetable oil.
5. drawing oil special for aluminum wire according to claim 1 is characterized in that: the acid number≤0.4mgKOH/g of described mixed vegetable oil.
6. arbitrary described drawing oil special for aluminum wire according to claim 1-5, it is characterized in that: described nano aluminium oxide is the α nano aluminium oxide, its diameter<500mm.
7. method of making the arbitrary described drawing oil special for aluminum wire of claim 1-6, it is characterized in that: the method may further comprise the steps:
(1) base oil is placed reactor, 120 ℃ of lower constant temperature 2 hours;
(2) base oil is cooled to 40-60 ℃, add in proportion additive, stir, mixed 2 hours.
CN 201010142505 2010-03-31 2010-03-31 Special aluminum wire drawing oil used for aluminum wires and production method thereof Active CN101838579B (en)

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Publication number Priority date Publication date Assignee Title
CN103992856B (en) * 2014-04-25 2016-05-11 蚌埠市时代电子有限公司 The anti-oxidant efficient wire drawing oil of a kind of spacetabs type
CN103992868A (en) * 2014-04-25 2014-08-20 蚌埠市正园电子科技有限公司 High temperature resistant high speed wire drawing oil
CN103992862B (en) * 2014-04-25 2016-04-13 蚌埠市正园电子科技有限公司 A kind of oil of the wire drawing containing Yelkin TTS
CN103992867B (en) * 2014-04-25 2016-05-18 蚌埠市正园电子科技有限公司 A kind of anti-oxidant wire drawing oil containing origanum oil
CN105038922A (en) * 2015-06-25 2015-11-11 张勤洪 Drawing fluid for aluminum material
CN111180136B (en) * 2019-12-07 2021-11-09 安徽瑞之星电缆集团有限公司 Flexible stranded conductor manufacturing process and stranded conductor
CN112852529A (en) * 2021-01-25 2021-05-28 广西平果博导铝镁线缆有限公司 Formula of wire drawing oil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101386804A (en) * 2008-10-11 2009-03-18 佛山市威奇电工材料有限公司 Drawing oil special for aluminum wire and production process thereof
CN101397519A (en) * 2008-10-21 2009-04-01 无锡华能电缆有限公司 Drawing oil special for annealed aluminum wire and method for producing the same
CN101671598A (en) * 2009-09-24 2010-03-17 无锡巨丰复合线有限公司 Aluminum wire drawing lubricant

Family Cites Families (1)

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Publication number Priority date Publication date Assignee Title
WO2009148110A1 (en) * 2008-06-04 2009-12-10 三井化学株式会社 Lubricating oil composition and use of same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101386804A (en) * 2008-10-11 2009-03-18 佛山市威奇电工材料有限公司 Drawing oil special for aluminum wire and production process thereof
CN101397519A (en) * 2008-10-21 2009-04-01 无锡华能电缆有限公司 Drawing oil special for annealed aluminum wire and method for producing the same
CN101671598A (en) * 2009-09-24 2010-03-17 无锡巨丰复合线有限公司 Aluminum wire drawing lubricant

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Denomination of invention: Special drawing oil for aluminum wire and its production method

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Registration number: Y2020980009665