CN101830746A - Method for producing selenium-enriched organic fertilizer - Google Patents
Method for producing selenium-enriched organic fertilizer Download PDFInfo
- Publication number
- CN101830746A CN101830746A CN200910047269A CN200910047269A CN101830746A CN 101830746 A CN101830746 A CN 101830746A CN 200910047269 A CN200910047269 A CN 200910047269A CN 200910047269 A CN200910047269 A CN 200910047269A CN 101830746 A CN101830746 A CN 101830746A
- Authority
- CN
- China
- Prior art keywords
- raw material
- selenium
- organic fertilizer
- enriched organic
- powder raw
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 239000011669 selenium Substances 0.000 title claims abstract description 51
- 229910052711 selenium Inorganic materials 0.000 title claims abstract description 51
- 239000003895 organic fertilizer Substances 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 62
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 27
- 239000011707 mineral Substances 0.000 claims abstract description 26
- 239000004575 stone Substances 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 17
- 238000000498 ball milling Methods 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims description 26
- 239000003245 coal Substances 0.000 claims description 21
- 210000003608 fece Anatomy 0.000 claims description 6
- 239000010871 livestock manure Substances 0.000 claims description 6
- 244000144972 livestock Species 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 244000144977 poultry Species 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 5
- 238000012216 screening Methods 0.000 claims description 5
- 239000002689 soil Substances 0.000 abstract description 8
- 206010028980 Neoplasm Diseases 0.000 abstract description 5
- 201000011510 cancer Diseases 0.000 abstract description 5
- 230000036039 immunity Effects 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 238000003900 soil pollution Methods 0.000 abstract description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000006806 disease prevention Effects 0.000 abstract 1
- 238000000855 fermentation Methods 0.000 abstract 1
- 230000004151 fermentation Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 235000010755 mineral Nutrition 0.000 description 18
- 239000003337 fertilizer Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 4
- 239000011573 trace mineral Substances 0.000 description 4
- 235000013619 trace mineral Nutrition 0.000 description 4
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 235000021384 green leafy vegetables Nutrition 0.000 description 2
- 230000001228 trophic effect Effects 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
Landscapes
- Fertilizers (AREA)
Abstract
The invention relates to a method for producing a selenium-enriched organic fertilizer. The method comprises the following steps: respectively crushing selenium-containing gangue, selenium-containing medical stone and limonit, and ball milling into powdery raw material; then, mixing into mineral raw material in proportion, adding acetate to mix into acidified mineral raw material; finally, mixing the acidified mineral material and the biological organic fertilizer to ferment, and obtaining selenium-enriched organic fertilizer after well fermentation. The selenium-enriched organic fertilizer prepared by the method can prevent soil pollution, improve the soil structure and quality, and has adsorption and conversion functions on the heavy metal in the soil. The selenium-enriched organic fertilizer prepared by the method is a functional agricultural product. After people eat the functional agricultural product, the immunity of the human body can be adjusted, the physical health can be strengthened, and the effects of disease prevention, cancer prevention and cancer resistance can be achieved.
Description
Technical field
The present invention relates to a kind of manufacture method of fertilizer, relate in particular to a kind of manufacture method of selenium-enriched organic fertilizer.
Background technology
Chemical fertilizer has used over half a century in China, and the labour intensity that alleviates the peasant, the output that improves farm crop have been made very big contribution.But life-time service chemical fertilizer has also produced many problems, at first is environment to be produced pollute, and this pollution causes the health of human body is produced serious harm; Next is that chemical fertilizer often only contains the single fertilizer element, and life-time service can produce the trophic structure of soil and destroy, and then it is bad to have influence on the trophic structures of farm crop; The 3rd is that life-time service can produce destruction to the physical structure of soil, causes soil compaction, is not easy to cultivate.Therefore, in recent years, people progressively recover to use fertilizer again.But also there are problems in original farm manure and common fertilizer, and first available fertilizer composition ratio is not high, causes usage quantity bigger than normal, and labour intensity strengthens; Next is still to lack the necessary element of some crop growth in the fertilizer.In addition, along with the raising of people's living standard with to the concern of health, people generally wish to obtain that some can be regulated body immunity, builds up health, preventing disease, help the trace element selenium of cancer-resisting by food.Especially China is a serious country that lacks selenium, and it is to lack the selenium district that 72% soil is arranged, and the whole nation has 900,000,000 populations to live in scarce selenium state approximately.Owing to lack selenium, caused the occurred frequently of numerous disease.For example, China is one of higher country of cancer morbidity in the world, shows that after deliberation this is relevant with scarce selenium.
Summary of the invention
Purpose of the present invention exactly in order to address the above problem, provides a kind of manufacture method of selenium-enriched organic fertilizer.
In order to achieve the above object, the present invention has adopted following technical scheme: a kind of manufacture method of selenium-enriched organic fertilizer may further comprise the steps:
A, the selenium medical stone that contains that selenium coal gangue, Tai'an, Shandong produce that contains of getting that produced from the enshi respectively become coal gangue powder raw material, medical stone powder raw material and MUSYUSHI powder raw material with MUSYUSHI through screening, pulverizing, ball milling;
B, get steps A gained coal gangue powdery raw material 8-20 weight part, medical stone powder raw material 6-16 weight part and MUSYUSHI powder raw material 4-22 weight part and be mixed into mineral raw material;
C, step B gained mineral raw material added be equivalent to the acetum of this mineral raw material gross weight 1.5-2.5% weight and mix into the acidifying mineral raw material;
D, get step C gained acidifying mineral raw material 20-50 weight part and biological organic fertilizer 50-80 weight part and mix and ferment, promptly obtain the selenium-enriched organic fertilizer product behind the fermenting-ripening.
The granularity of coal gangue powdery raw material, medical stone powder raw material and the MUSYUSHI powder raw material described in the steps A is the 60-80 order.
The selenium content that contains the selenium coal gangue described in the steps A is 200-250mg/kg.
The concentration of the acetum described in the step C is 10-15mg/L.
Biological organic fertilizer described in the step D is a manure of livestock and poultry.
Proof adopts the selenium-enriched organic fertilizer of method manufacturing of the present invention to contain trace element and mineral substance such as selenium, strontium, zinc, calcium, iodine, magnesium, iron and silicon after testing, and wherein the selenium content of per kilogram organic fertilizer product can reach 30mg.
Adopt selenium-enriched organic fertilizer that method of the present invention makes through two various leaf vegetables of 50 mu of vegetable gardening fields and Sun Qiao modern agriculture district plantation on probation in Chuansha, Shanghai town, various leaf vegetables products detect through Chinese commodity inspection, selenium content all reach the people every day intake demand.
The manufacture method of selenium-enriched organic fertilizer of the present invention is owing to adopted by containing the selenium coal gangue, contain mineral raw material that selenium medical stone and MUSYUSHI form and it having been carried out acidification, carried out fermentative processing with fertilizer again then, coal gangue, medical stone, MUSYUSHI are fully activated, make wherein selenium element and other trace element obtain abundant release, the fertilizer of manufacturing can prevent soil pollution, the structure of improving the soil and quality, and the heavy metal in the soil is had absorption and transformation function.Thereby the farm crop that the selenium-enriched organic fertilizer kind of using method manufacturing of the present invention goes out are a kind of functional agricultural-food, and the people can regulate body immunity, build up health after having eaten this functional agricultural-food, and can reach the effect of preventing disease, cancer-resisting.
Embodiment
Embodiment 1
To become granularity with MUSYUSHI through screening, pulverizing, ball milling be 60-80 purpose coal gangue powdery raw material, medical stone powder raw material and MUSYUSHI powder raw material to the selenium medical stone that contains of getting respectively that coal gangue, Tai'an, Shandong that the selenium content that produces the enshi is 200-250mg/kg produces; Get 15 kilograms of coal gangue powdery raw materials, 10 kilograms of medical stone powder raw materials and MUSYUSHI powder raw material then and be mixed into mineral raw material for 10 kilograms; Adding 0.8 kilogram of concentration again in above-mentioned mineral raw material is the acetum of 12mg/L and mixes into the acidifying mineral raw material.Then above-mentioned acidifying mineral raw material and 65 kilograms of manure of livestock and poultry are mixed and ferment, promptly obtained a kind of selenium-enriched organic fertilizer product through 30-60 days behind the fermenting-ripening.
Embodiment 2
To become granularity with MUSYUSHI through screening, pulverizing, ball milling be 60-80 purpose coal gangue powdery raw material, medical stone powder raw material and MUSYUSHI powder raw material to the selenium medical stone that contains of getting respectively that coal gangue, Tai'an, Shandong that the selenium content that produces the enshi is 200-250mg/kg produces; Get 20 kilograms of coal gangue powdery raw materials, 6 kilograms of medical stone powder raw materials and MUSYUSHI powder raw material then and be mixed into mineral raw material for 20 kilograms; Adding 0.7 kilogram of concentration again in above-mentioned mineral raw material is the acetum of 15mg/L and mixes into the acidifying mineral raw material.Then above-mentioned acidifying mineral raw material and 54 kilograms of manure of livestock and poultry are mixed and ferment, promptly obtained a kind of selenium-enriched organic fertilizer product through 30-60 days behind the fermenting-ripening.
Embodiment 3
To become granularity with MUSYUSHI through screening, pulverizing, ball milling be 60-80 purpose coal gangue powdery raw material, medical stone powder raw material and MUSYUSHI powder raw material to the selenium medical stone that contains of getting respectively that coal gangue, Tai'an, Shandong that the selenium content that produces the enshi is 200-250mg/kg produces; Get 10 kilograms of coal gangue powdery raw materials, 16 kilograms of medical stone powder raw materials and MUSYUSHI powder raw material then and be mixed into mineral raw material for 5 kilograms; Adding 0.6 kilogram of concentration again in above-mentioned mineral raw material is the acetum of 10mg/L and mixes into the acidifying mineral raw material.Then above-mentioned acidifying mineral raw material and 70 kilograms of manure of livestock and poultry are mixed and ferment, promptly obtained a kind of selenium-enriched organic fertilizer product through 30-60 days behind the fermenting-ripening.
Claims (5)
1. the manufacture method of a selenium-enriched organic fertilizer is characterized in that, may further comprise the steps:
A, the selenium medical stone that contains that selenium coal gangue, Tai'an, Shandong produce that contains of getting that produced from the enshi respectively become coal gangue powder raw material, medical stone powder raw material and MUSYUSHI powder raw material with MUSYUSHI through screening, pulverizing, ball milling;
B, get steps A gained coal gangue powdery raw material 8-20 weight part, medical stone powder raw material 6-16 weight part and MUSYUSHI powder raw material 4-22 weight part and be mixed into mineral raw material;
C, step B gained mineral raw material added be equivalent to the acetum of this mineral raw material gross weight 1.5-2.5% weight and mix into the acidifying mineral raw material;
D, get step C gained acidifying mineral raw material 20-50 weight part and biological organic fertilizer 50-80 weight part and mix and ferment, promptly obtain the selenium-enriched organic fertilizer product behind the fermenting-ripening.
2. the manufacture method of selenium-enriched organic fertilizer as claimed in claim 1, it is characterized in that: the granularity of coal gangue powdery raw material, medical stone powder raw material and the MUSYUSHI powder raw material described in the steps A is the 60-80 order.
3. the manufacture method of selenium-enriched organic fertilizer as claimed in claim 1, it is characterized in that: the selenium content that contains the selenium coal gangue described in the steps A is 200-250mg/kg.
4. the manufacture method of selenium-enriched organic fertilizer as claimed in claim 1, it is characterized in that: the concentration of the acetum described in the step C is 10-15mg/L.
5. the manufacture method of selenium-enriched organic fertilizer as claimed in claim 1, it is characterized in that: the biological organic fertilizer described in the step D is a manure of livestock and poultry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100472694A CN101830746B (en) | 2009-03-09 | 2009-03-09 | Method for producing selenium-enriched organic fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100472694A CN101830746B (en) | 2009-03-09 | 2009-03-09 | Method for producing selenium-enriched organic fertilizer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101830746A true CN101830746A (en) | 2010-09-15 |
| CN101830746B CN101830746B (en) | 2012-06-27 |
Family
ID=42714990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100472694A Expired - Fee Related CN101830746B (en) | 2009-03-09 | 2009-03-09 | Method for producing selenium-enriched organic fertilizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101830746B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102731197A (en) * | 2011-04-07 | 2012-10-17 | 天门福临化工有限责任公司 | Preparation method of Kelangsong biological organic fertilizer |
| CN102757293A (en) * | 2012-08-06 | 2012-10-31 | 长沙福山农业科技有限公司 | Organic selenium-enzyme and preparation method thereof |
| CN103936504A (en) * | 2014-04-10 | 2014-07-23 | 中国水稻研究所 | Preparation method of micro-nano mineral selenium fertilizer |
| CN104710212A (en) * | 2013-12-13 | 2015-06-17 | 李峰 | Selenium-rich organic fertilizer and preparation method thereof |
| CN104761320A (en) * | 2015-03-30 | 2015-07-08 | 任春庆 | Wooden fish stone contained biological organic fertilizer |
| CN105016927A (en) * | 2015-07-31 | 2015-11-04 | 兴安宸亿工贸有限公司 | Method for preparing fertilizer by utilizing high-iron tailing slag |
| CN106007915A (en) * | 2016-05-13 | 2016-10-12 | 深圳市芭田生态工程股份有限公司 | Mineral substance containing bio-fertilizer and preparation method thereof |
| CN109650975A (en) * | 2019-02-27 | 2019-04-19 | 江苏原元生物工程有限公司 | A kind of vinasse of microbe-mediated, stalk, gangue first biological organic fertilizer production technology and system entirely |
| CN112110765A (en) * | 2020-09-16 | 2020-12-22 | 衢州市柯城区农业农村局 | Selenium-rich organic citrus fertilizer and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1579123A (en) * | 2003-08-11 | 2005-02-16 | 金德财 | Sllenium-riched organic fertilizer and producing method |
| CN1958521A (en) * | 2006-06-21 | 2007-05-09 | 彭祚全 | Method for preparing activated selenium composite additive |
-
2009
- 2009-03-09 CN CN2009100472694A patent/CN101830746B/en not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102731197A (en) * | 2011-04-07 | 2012-10-17 | 天门福临化工有限责任公司 | Preparation method of Kelangsong biological organic fertilizer |
| CN102731197B (en) * | 2011-04-07 | 2014-11-05 | 天门福临化工有限责任公司 | Preparation method of Kelangsong biological organic fertilizer |
| CN102757293A (en) * | 2012-08-06 | 2012-10-31 | 长沙福山农业科技有限公司 | Organic selenium-enzyme and preparation method thereof |
| CN102757293B (en) * | 2012-08-06 | 2013-10-23 | 长沙福山农业科技有限公司 | Organic selenium-enzyme and preparation method thereof |
| CN104710212A (en) * | 2013-12-13 | 2015-06-17 | 李峰 | Selenium-rich organic fertilizer and preparation method thereof |
| CN103936504A (en) * | 2014-04-10 | 2014-07-23 | 中国水稻研究所 | Preparation method of micro-nano mineral selenium fertilizer |
| CN103936504B (en) * | 2014-04-10 | 2015-12-30 | 中国水稻研究所 | A kind of preparation method of micro-nano mineral selenium fertilizer |
| CN104761320A (en) * | 2015-03-30 | 2015-07-08 | 任春庆 | Wooden fish stone contained biological organic fertilizer |
| CN105016927A (en) * | 2015-07-31 | 2015-11-04 | 兴安宸亿工贸有限公司 | Method for preparing fertilizer by utilizing high-iron tailing slag |
| CN106007915A (en) * | 2016-05-13 | 2016-10-12 | 深圳市芭田生态工程股份有限公司 | Mineral substance containing bio-fertilizer and preparation method thereof |
| CN109650975A (en) * | 2019-02-27 | 2019-04-19 | 江苏原元生物工程有限公司 | A kind of vinasse of microbe-mediated, stalk, gangue first biological organic fertilizer production technology and system entirely |
| CN112110765A (en) * | 2020-09-16 | 2020-12-22 | 衢州市柯城区农业农村局 | Selenium-rich organic citrus fertilizer and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101830746B (en) | 2012-06-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: JIN DECAI Free format text: FORMER OWNER: SHANGHAI YUANKANG SELENIUM BIOTECHNOLOGY CO., LTD. Effective date: 20140126 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 200434 LUWAN, SHANGHAI TO: 200435 ZHABEI, SHANGHAI |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20140126 Address after: 200435, room 29, No. 555, Lane 301, Wenxi Road, Shanghai, Zhabei District Patentee after: Jin Decai Address before: 200434, room 526, 405 Fuxing Road, Shanghai, Luwan District Patentee before: Shanghai Yuankang Selenium Biotechnology Co., Ltd. |
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| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120627 Termination date: 20140309 |