CN101735710B - 一种用于防伪装土黄色卷材涂料及其制备方法和应用 - Google Patents
一种用于防伪装土黄色卷材涂料及其制备方法和应用 Download PDFInfo
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- CN101735710B CN101735710B CN 200810203147 CN200810203147A CN101735710B CN 101735710 B CN101735710 B CN 101735710B CN 200810203147 CN200810203147 CN 200810203147 CN 200810203147 A CN200810203147 A CN 200810203147A CN 101735710 B CN101735710 B CN 101735710B
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- polyester
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- coil coating
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- 238000000576 coating method Methods 0.000 title claims abstract description 47
- 239000011248 coating agent Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 36
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 29
- 229920000877 Melamine resin Polymers 0.000 claims description 18
- 239000004640 Melamine resin Substances 0.000 claims description 18
- 229920000728 polyester Polymers 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 150000005690 diesters Chemical class 0.000 claims description 11
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000003849 aromatic solvent Substances 0.000 claims description 10
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims description 10
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 10
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 claims description 10
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical class COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 150000007513 acids Chemical class 0.000 claims description 9
- 229960005191 ferric oxide Drugs 0.000 claims description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- JHRDMNILWGIFBI-UHFFFAOYSA-N 6-diazenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(N=N)=N1 JHRDMNILWGIFBI-UHFFFAOYSA-N 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 238000011056 performance test Methods 0.000 claims description 7
- NVKTUNLPFJHLCG-UHFFFAOYSA-N strontium chromate Chemical compound [Sr+2].[O-][Cr]([O-])(=O)=O NVKTUNLPFJHLCG-UHFFFAOYSA-N 0.000 claims description 7
- 238000013019 agitation Methods 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 238000012856 packing Methods 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 239000002904 solvent Substances 0.000 abstract description 11
- 239000000049 pigment Substances 0.000 abstract description 9
- 229920003180 amino resin Polymers 0.000 abstract description 7
- 229910000831 Steel Inorganic materials 0.000 abstract description 4
- 239000010959 steel Substances 0.000 abstract description 4
- 239000012046 mixed solvent Substances 0.000 abstract description 3
- 239000001054 red pigment Substances 0.000 abstract description 3
- 239000004408 titanium dioxide Substances 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract description 2
- 238000010276 construction Methods 0.000 abstract description 2
- 239000001056 green pigment Substances 0.000 abstract description 2
- 238000004064 recycling Methods 0.000 abstract description 2
- 229920001225 polyester resin Polymers 0.000 abstract 2
- 239000004645 polyester resin Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000012958 reprocessing Methods 0.000 abstract 1
- 239000001052 yellow pigment Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 230000035939 shock Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000005070 sampling Methods 0.000 description 3
- IBMRTYCHDPMBFN-UHFFFAOYSA-N Mono-Me ester-Pentanedioic acid Natural products COC(=O)CCCC(O)=O IBMRTYCHDPMBFN-UHFFFAOYSA-N 0.000 description 2
- RFAFBXGYHBOUMV-UHFFFAOYSA-N calcium chromate Chemical compound [Ca+2].[O-][Cr]([O-])(=O)=O RFAFBXGYHBOUMV-UHFFFAOYSA-N 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- PWBLFPFEBXCQBP-UHFFFAOYSA-N 3-nonylnaphthalene-1,2-disulfonic acid Chemical class C1=CC=C2C(S(O)(=O)=O)=C(S(O)(=O)=O)C(CCCCCCCCC)=CC2=C1 PWBLFPFEBXCQBP-UHFFFAOYSA-N 0.000 description 1
- 239000004801 Chlorinated PVC Substances 0.000 description 1
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 1
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 description 1
- 229940083898 barium chromate Drugs 0.000 description 1
- 229940043232 butyl acetate Drugs 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical group CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
项目 | 指标 | 试验方法 |
粘度(察恩粘度4号杯),s | 28±2 | ASTMD4212 |
固体含量,% | ≥58 | GB/T1725 |
最高金属板温度(PMT),℃ | 224~249 | |
漆膜厚度,μm | 20±2 | GB/T1764 |
弯曲,T | ≤3 | ASTMD4145 |
光泽(60°) | ≤6 | ASTMD523 |
铅笔硬度 | HB~2H | ASTMD363 |
冲击强度,cm(J) | 101.60(9.04) | ASTMD2794 |
耐溶剂性(MEK),次 | ≥100 | NCCA II-18 |
ΔE*(CIE Lab) | ≤2.0 |
项目 | 指标 |
粘度(察恩粘度4号杯),s | 28 |
固体含量,% | ≥61 |
最高金属板温度(PMT),℃ | 232 |
漆膜厚度,μm | 20 |
弯曲,T | 2 |
光泽(60°) | 5 |
铅笔硬度 | F |
冲击强度,cm(J) | 101.60(9.04) |
耐溶剂性(MEK),次 | ≥100 |
ΔE*(CIE Lab) | 1.0 |
项目 | 指标 |
粘度(察恩粘度4号杯),s | 29 |
固体含量,% | ≥62 |
最高金属板温度(PMT),℃ | 249 |
漆膜厚度,μm | 20 |
弯曲,T | 3 |
光泽(60°) | 4.7 |
铅笔硬度 | H |
冲击强度,cm(J) | 101.60(9.04) |
耐溶剂性(MEK),次 | ≥100 |
ΔE*(CIE Lab) | 0.3 |
项目 | 指标 |
粘度(察恩粘度4号杯),s | 27 |
固体含量,% | ≥61 |
最高金属板温度(PMT),℃ | 224 |
漆膜厚度,μm | 20 |
弯曲,T | 3 |
光泽(60°) | 4.2 |
铅笔硬度 | F |
冲击强度,cm(J) | 101.60(9.04) |
耐溶剂性(MEK),次 | ≥100 |
ΔE*(CIE Lab) | 0.5 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200810203147 CN101735710B (zh) | 2008-11-21 | 2008-11-21 | 一种用于防伪装土黄色卷材涂料及其制备方法和应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200810203147 CN101735710B (zh) | 2008-11-21 | 2008-11-21 | 一种用于防伪装土黄色卷材涂料及其制备方法和应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101735710A CN101735710A (zh) | 2010-06-16 |
CN101735710B true CN101735710B (zh) | 2013-08-07 |
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CN 200810203147 Expired - Fee Related CN101735710B (zh) | 2008-11-21 | 2008-11-21 | 一种用于防伪装土黄色卷材涂料及其制备方法和应用 |
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Country | Link |
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CN (1) | CN101735710B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102443344B (zh) * | 2010-10-12 | 2014-03-19 | 苏州飞翔新材料研究院有限公司 | 一种混合溶剂及卷钢涂料组合物和卷钢材料的制备方法 |
CN102732123B (zh) * | 2012-07-04 | 2014-03-26 | 中昊北方涂料工业研究设计院有限公司 | 一种70℃~140℃多变色热色涂料 |
CN102925034A (zh) * | 2012-08-28 | 2013-02-13 | 唐山威克涂料化工有限公司 | 一种彩板表面涂层用木纹状面漆及制备方法 |
CN104031534B (zh) * | 2014-06-26 | 2016-09-07 | 立邦工业涂料(上海)有限公司 | 一种单涂聚酯涂料及其制备方法 |
CN112029358B (zh) * | 2020-09-16 | 2022-01-07 | Ppg涂料(天津)有限公司 | 水性面漆组合物 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1068133A (zh) * | 1991-06-18 | 1993-01-20 | 埃克森化学专利公司 | 以聚酯为基本组分有高比率颜料/粘合剂的涂料的组合物 |
CN1583911A (zh) * | 2004-05-27 | 2005-02-23 | 解居会 | 卷材面漆涂料及其制法 |
CN1710000A (zh) * | 2005-07-01 | 2005-12-21 | 刘才方 | 预涂金属卷材用低温固化聚酯面漆及其制备方法 |
-
2008
- 2008-11-21 CN CN 200810203147 patent/CN101735710B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1068133A (zh) * | 1991-06-18 | 1993-01-20 | 埃克森化学专利公司 | 以聚酯为基本组分有高比率颜料/粘合剂的涂料的组合物 |
CN1583911A (zh) * | 2004-05-27 | 2005-02-23 | 解居会 | 卷材面漆涂料及其制法 |
CN1710000A (zh) * | 2005-07-01 | 2005-12-21 | 刘才方 | 预涂金属卷材用低温固化聚酯面漆及其制备方法 |
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CN101735710A (zh) | 2010-06-16 |
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Owner name: SHANGHAI HUAYI FINE CHEMICAL INDUSTRY CO., LTD. Free format text: FORMER OWNER: SHANGHAI CHENHUA PAINT MFG. CO. Effective date: 20150505 |
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Free format text: CORRECT: ADDRESS; FROM: 200331 PUTUO, SHANGHAI TO: 201108 MINHANG, SHANGHAI |
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TR01 | Transfer of patent right |
Effective date of registration: 20150505 Address after: Minhang District town of Shanghai city in 201108 Patentee after: SHANGHAI HUAYI FINE CHEMICAL Co.,Ltd. Address before: 200331 No. 1167, Gulang Road, Shanghai, Putuo District Patentee before: Shanghai Chenhua Paint MFG. Co. |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130807 |