CN101731260B - L-terpineol synergist-containing beta-cypermethrin pesticide composition - Google Patents
L-terpineol synergist-containing beta-cypermethrin pesticide composition Download PDFInfo
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- CN101731260B CN101731260B CN200910114624.5A CN200910114624A CN101731260B CN 101731260 B CN101731260 B CN 101731260B CN 200910114624 A CN200910114624 A CN 200910114624A CN 101731260 B CN101731260 B CN 101731260B
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- terpineol
- cypermethrin
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- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 title claims abstract description 34
- 229940116411 terpineol Drugs 0.000 title claims abstract description 33
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 239000000575 pesticide Substances 0.000 title abstract description 11
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 7
- 241000238631 Hexapoda Species 0.000 claims description 14
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 14
- 239000002917 insecticide Substances 0.000 claims description 11
- 239000000470 constituent Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 7
- 230000000749 insecticidal effect Effects 0.000 claims description 7
- 239000003921 oil Substances 0.000 claims description 7
- 235000019198 oils Nutrition 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 210000000481 breast Anatomy 0.000 claims description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 6
- 239000000443 aerosol Substances 0.000 claims description 3
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 239000003350 kerosene Substances 0.000 claims description 3
- 239000004530 micro-emulsion Substances 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 230000002147 killing effect Effects 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- 235000013599 spices Nutrition 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 5
- 239000004495 emulsifiable concentrate Substances 0.000 claims 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 abstract description 10
- 230000002195 synergetic effect Effects 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 2
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- -1 alkyl phenol formaldehyde resin Chemical compound 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 239000005946 Cypermethrin Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 3
- 229960005424 cypermethrin Drugs 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 2
- 229940088601 alpha-terpineol Drugs 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000077 insect repellent Substances 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 description 1
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 244000299507 Gossypium hirsutum Species 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 108010052164 Sodium Channels Proteins 0.000 description 1
- 102000018674 Sodium Channels Human genes 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 235000004426 flaxseed Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 235000013847 iso-butane Nutrition 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001537 neural effect Effects 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229940117013 triethanolamine oleate Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an L-terpineol synergist-containing and beta-cypermethrin-containing synergistic pesticide composition, which is characterized in that: the pesticide composition consists of an active ingredient, a synergist and auxiliary materials, wherein the active ingredient is the beta-cypermethrin; and the synergist is the L-terpineol. The composition can overcome resistance of sanitary pests to the beta-cypermethrin, improves pesticide effect, reduces pesticide dosage, retards pesticide resistance of the pests and has less damage and pollution to ecological environment.
Description
Technical field:
The present invention relates to a kind of insecticides, the insecticides that to be specifically related to take beta-cypermethrin be active ingredient.
Technical background:
L-terpineol, also claims terpineol, has α, β, tri-kinds of isomer of γ, Shi You Chemical Industry Inst., Guangxi Zhuang Autonomous Region synthetic a kind of chemical products in 2002, have good deodorize, moistening and infiltration capacity.From 2003 to the present, Guangxi Chemical Inst. has carried out its synergistic activity research to various agricultural chemicals.Research shows, L-terpineol all shows certain synergistic effect to various bactericide and insecticide.Specifically see Chinese Patent Application No.: 03178548.4 open (bulletin) number: patentee: Chemical Industry Inst., Guangxi Zhuang Autonomous Region, inventor: Huang Kelin, Fan Xiaodan, Wang Guiying, Long Yuyan, this invention provide a kind of take containing australene, be that main turpentine oil is raw material, take low-carbon alcohols or ketone as solvent, adopting modification strongly acidic styrene type cation exchange resin is catalyzer, by fixed bed reactors, carry out catalysis hydration reaction, the method of one-step synthesis levogyrate alpha-terpineol, the weight ratio of catalyzer and australene is 1: 1～10, the mol ratio of australene and water is 1: 1.1～2, the mol ratio of water and solvent is 1: 0.1～0.9, reaction temperature is 70～100 ℃, reaction time is 5～13 hours, australene conversion ratio is more than 95%, levogyrate alpha-terpineol yield is more than 65%.
Beta-cypermethrin (beta-cypermethrin), beta-cypermethrin is a kind of pyrethroid insecticides, mainly by interacting and destroyed neural function with insect sodium channel.Biologically active is higher, is the efficient isomer of cypermethrin, has and tags and stomach poison function.Insecticidal spectrum is wide, the speed of knocking down is fast, and insecticidal activity is high compared with cypermethrin.Be applicable to prevent and treat insect and the sanitary insect pest in the various plants such as cotton, vegetables, fruit tree, tea tree, forest.
Yet through application for many years, some sanitary insect pests have produced certain resistance to beta-cypermethrin.The preventive effect of this medicine is more and more lower, and working concentration is just more and more higher, has caused the pollution of environment.For the insect of easy generation resistance, a kind of method be exploitation new with the new component of existing product without cross resistance.But the development cost of new active ingredient is high, and the cycle is long, and be unable to catch up with the speed that insect produces resistance.
The active ingredient of different cultivars is carried out composite, is to delay the better more common method that insect produces resistance.Also having another kind of method is to add synergist for the active ingredient that insect has produced resistance to it.Thereby greatly delay insect, producing resistance, extended the life-span of pesticide active ingredient, is a kind of important means of integrated control insect.Synergist using L-terpineol as beta-cypermethrin there is no people and reported.
Summary of the invention:
Main purpose of the present invention is that research has the best synergy proportioning of the L-terpineol of synergistic effect to it to beta-cypermethrin, to solve some sanitary insect pests, this medicine is produced to the problem of resistance, reduces its dosage, protection of the environment.
Technical scheme of the present invention is:
A kind of Synergistic insecticidal composition that contains L-terpineol and beta-cypermethrin, it is characterized in that: this insecticides is comprised of active ingredient, synergist and auxiliary material, described active ingredient is beta-cypermethrin, synergist is L-terpineol, and it can be missible oil, microemulsion, suspending agent, aqueous emulsion, propellant, aerosol and thermal fog that said composition is divided according to formulations of pesticide product.
Synergistic insecticidal composition active ingredient---beta-cypermethrin percentage by weight is 0.1%～20%, synergist---L-terpineol percentage by weight is 3%～15%.
Synergistic insecticidal composition of the present invention is by active ingredient beta-cypermethrin and synergist L-terpineol and auxiliary agent and carrier is composite forms.Wherein conventional auxiliary agent is as neopelex, calcium dodecyl benzene sulfonate, lauryl sodium sulfate, alkyl phenol formaldehyde resin polyoxyethylene ether, aliphatic alcohol sulfate, phenethyl phenol polyethenoxy ether, Nonyl pheno base ether, lignosulfonates, alkylbenzenesulfonate, alkylphenol polyoxyethylene, polyoxyethylene nonylphenol ether, alkyl ethyl sulfonate, alkylnaphthalene sulfonate formaldehyde condensation products and polycarboxylic acid, triethanolamine oleate or epoxidized vegetable oil are as epoxidized linseed, epoxidized soybean oil, toluene, dimethylbenzene, acetone, cyclohexanone, ethanol, deodorized kerosine, essence, deionized water, dimethyl ether, Compressed Gas or hydrocarbon compound are as propane, iso-butane, isopentane and composition thereof.
Insecticides provided by the present invention has the following advantages:
L-terpineol shows unique characteristics at aspects such as agriculture desinsection, sterilization and pesticide synergistic, mosquito repellents.Aspect domestic hygiene, L-terpineol has stronger mosquito repellent effect, and the germ of some harm humans health is also had to killing action.Because L-terpineol has no side effect to human body, will become a kind of novel green agricultural chemicals and domestic hygiene disinfectant, there is very large market potential, will produce good economy, society and environmental benefit.
By L-terpineol and efficient cypermethrin compounded, can overcome the resistance that sanitary insect pest produces beta-cypermethrin, improve drug effect, reduce the pesticide resistance that dosage delays insect, to the infringement of ecotope and less pollution.
Embodiment:
Below in conjunction with embodiment, the invention will be further described, but content of the present invention is not limited to this.
Embodiment 1:
By beta-cypermethrin 0.1g, L-terpineol 3g, deodorized kerosine 30g, spices 0.2g, stir and add inhalator jar, be finally pressed into hydrocarbon compound to 100g capping, obtain active constituent content and be 0.1% composition aerosol.
Embodiment 2:
By beta-cypermethrin 1g, L-terpineol 5g, cyclohexanone 18g, polyoxyethylene nonylphenol ether 8g, fatty alcohol-polyoxyethylene ether 12g, epoxidized soybean oil 5g, sorbierite 3g, join together in reactor, stir and dissolve completely, slowly add 48g deionized water, mix and blend 2 hours, obtains active constituent content and is 1% composite microemulsion.
Embodiment 3:
By beta-cypermethrin 5g, L-terpineol 5g, dimethylbenzene 10g, calcium dodecyl benzene sulfonate 6g, agriculture breast 602#9g, propane diols 1g, join together in reactor, stir and completely dissolve and obtain oil phase, in homogenizer (rotating speed is 4000～5000r/min) high shear situation, oil phase is slowly added in the water of formula ratio, after adding, continue to maintain above-mentioned rotating speed high shear 30～60min, obtain active constituent content and be 5% composition aqueous emulsion.
Embodiment 4:
By beta-cypermethrin 10g, L-terpineol 15g, calcium dodecyl benzene sulfonate 4g, agriculture breast 602#6g, add dimethylbenzene to 100g, join together in reactor, stir and dissolve completely, obtain active constituent content and be 10% composition missible oil.
Embodiment 5:
By beta-cypermethrin 20g, L-terpineol 10g, calcium dodecyl benzene sulfonate 4g, agriculture breast 602#6g, add dimethylbenzene to 100g, join together in reactor, stir and dissolve completely, obtain active constituent content and be 20% composition missible oil.
Application Example:
By indoor biometrics, we can determine that L-terpineol is to beta-cypermethrin synergy situation.According to the effective object of beta-cypermethrin, we select Groton bug as the raw object (medicine embrane method) of surveying.Concrete result of the test is as following table:
From the above-mentioned test of pesticide effectiveness, can find out that the synergist that the present invention adds can obviously increase the control efficiency of beta-cypermethrin to Groton bug.
Claims (5)
1. a method for producing insecticide that contains L-terpineol and beta-cypermethrin, it is characterized in that, by beta-cypermethrin 0.1g, the left terpineol 3g of family, deodorized kerosine 30g and spices 0.2g, stir and add inhalator jar, finally be pressed into hydrocarbon compound to 100g capping, obtain active constituent content and be 0.1% insect aerosol.
2. a method for producing insecticide that contains L-terpineol and beta-cypermethrin, it is characterized in that, by beta-cypermethrin 1g L-terpineol 5g, cyclohexanone 18g, Wang Ji phenol polyethenoxy ether 8g, fatty alcohol-polyoxyethylene ether 12g, epoxidized soybean oil 5g, sorbierite 3g, join together in reactor, stir and dissolve completely, slowly add 48g deionized water, mix and blend 2 hours, obtains active constituent content and is 1% pest killing micro emulsion.
3. a method for producing insecticide that contains L-terpineol and beta-cypermethrin, it is characterized in that, by beta-cypermethrin 5g, L-terpineol 5g, dimethylbenzene 10g, calcium dodecyl benzene sulfonate 6g, agriculture breast 602#9g and propane diols 1g, join together in reactor, stir and completely dissolve and obtain oil phase, at homogenizer rotating speed, be in 4000-5000r/min high shear situation, oil phase is slowly added in the water of formula ratio, after adding, continue to maintain above-mentioned rotating speed high shear 30-60min, obtain active constituent content and be 5% disinsection aqueous emulsion.
4. a method for producing insecticide that contains L-terpineol and beta-cypermethrin, it is characterized in that, by beta-cypermethrin 10g, L-terpineol 15g, calcium dodecyl benzene sulfonate 4g, agriculture breast 602#6g, add dimethylbenzene to 100g, join together in reactor, stir and dissolve completely, obtaining active constituent content and be 10% insecticidal emulsifiable concentrate.
5. a method for producing insecticide that contains L-terpineol and beta-cypermethrin, it is characterized in that, by beta-cypermethrin 20g, the left terpineol 10g of family, calcium dodecyl benzene sulfonate 4g and agriculture breast 602#6g, add dimethylbenzene to 100g, join together in reactor, stir and dissolve completely, obtaining active constituent content and be 20% insecticidal emulsifiable concentrate.
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| CN200910114624.5A CN101731260B (en) | 2009-12-11 | 2009-12-11 | L-terpineol synergist-containing beta-cypermethrin pesticide composition |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103535389B (en) * | 2013-10-27 | 2015-04-15 | 莫晟琼 | Plant source fruit tree insecticide |
| CN103688981A (en) * | 2013-11-29 | 2014-04-02 | 灵璧县通达化工厂 | Pesticide composition and preparation method thereof |
| CN104957161A (en) * | 2015-07-09 | 2015-10-07 | 广西兄弟农药厂(普通合伙) | Microemulsion containing emamectin benzoate and lufenuron |
| CN105104410B (en) * | 2015-08-18 | 2018-01-16 | 诺农(北京)国际生物技术有限公司 | A kind of composition of agricultural synergist and pyrethroid insecticides |
| CN105519524B (en) * | 2015-12-31 | 2018-07-27 | 广西三晶化工科技有限公司 | A kind of herbicidal composition and its preparation containing levogyrate alpha-terpineol |
| CN106172427B (en) * | 2016-06-30 | 2018-06-19 | 广西壮族自治区化工研究院 | A kind of Herbicidal combinations containing levogyrate alpha-terpineol |
| CN108308188B (en) * | 2018-04-18 | 2022-06-21 | 中国人民解放军海军特色医学中心 | Water-based insecticidal emulsion |
| CN109430264B (en) * | 2018-11-08 | 2021-04-30 | 广西化工研究院有限公司 | Bactericide composition containing terpene alcohol and chitosan, and preparation method and application thereof |
| CN116267916A (en) * | 2023-03-02 | 2023-06-23 | 河南金田地农化有限责任公司 | Hot fogging concentrate formula and application thereof |
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