CN103229782B - Pesticidal combination - Google Patents
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- CN103229782B CN103229782B CN201310156107.0A CN201310156107A CN103229782B CN 103229782 B CN103229782 B CN 103229782B CN 201310156107 A CN201310156107 A CN 201310156107A CN 103229782 B CN103229782 B CN 103229782B
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Abstract
The present invention relates to technical field of pesticide, in particular to Pesticidal combination.Pesticidal combination, according to weight parts, its composition comprises: Diacloden 0.1-60 part, chlopyrifos 0.1-60 part.The Pesticidal combination of the above embodiment of the present invention, Diacloden, its mechanism of action is similar to Imidacloprid, alternative suppression insect CNS nicotinic acetylcholine esterase acceptor, and then block the normal conduction of insect CNS, when causing insect to occur paralysis machine death not only have tag, stomach toxicity, systemic activity, and there is higher activity, better safety, wider insecticidal spectrum and the feature such as speed of action is fast, the lasting period is long.Chlopyrifos, can kill multiple chewing type and sucking pest; Mixed intermiscibility is good, can with multiple Mixture Use of Insecticides and synergistic effect is obvious.After Diacloden and chlorpyrifos mixture, have obvious synergistic effect, quick-acting is good, and the lasting period is long; The features such as insecticidal spectrum is wide.
Description
Technical field
The present invention relates to technical field of pesticide, in particular to Pesticidal combination.
Background technology
Citrus Huanglongbing pathogen is the common a kind of diseases of oranges and tangerines, and citrus psylla is the unique natural propagation medium of Citrus Huanglongbing pathogen; Citrus psylla has high biography characteristic of disease (the sick rate of biography of single wood louse is up to 70-80%), passes characteristic of disease (take food 5 hours and can pass poison) fast, and its adult can be flown; Therefore, in the process of control, kill the first important measures that citrus psylla is prevention and corntrol yellow twig.
But at present, the medicament being used for preventing and treating citrus psylla due to research is little, and therefore, the control of Citrus Huanglongbing pathogen is not also solved well.
Summary of the invention
The object of the present invention is to provide a kind of Pesticidal combination, to solve the above problems.
Provide a kind of Pesticidal combination in embodiments of the invention, its active ingredient comprises: Diacloden 0.1-60 part, chlopyrifos 0.1-60 part.
The Pesticidal combination of the above embodiment of the present invention, one of its composition, Diacloden, its chemical name is 3-(2-chloro-1,3-thiazole-5-ylmethyl)-5-methyl isophthalic acid, 3,5-oxadiazines-4-base fork (nitro) amine, be a kind of High-efficiency low-toxicity broad spectrum, be also second generation anabasine insecticide simultaneously; Its mechanism of action is similar to Imidacloprid, alternative suppresses insect CNS nicotinic acetylcholine esterase acceptor, and then blocks the normal conduction of insect CNS, dead when causing insect to occur paralysis machine.Its not only have tag, stomach toxicity, systemic activity, and there is the feature such as higher activity, better safety, wider insecticidal spectrum and speed of action is fast, lasting period length, to coleoptera, diptera, Lepidoptera, especially homoptera pest has high activity, effectively can prevent and treat the insect of the insects such as various aphid, leafhopper, plant hopper, aleyrodid, chafer larva, colorado potato beetle, nematode, ground beetle, leaf miner and knot polytype chemical pesticide generation resistance; Chlopyrifos, its chemical name is O, O-diethyl-O-(3,5,6-trichloro-2-pyridyl) thiophosphate, be thiophosphate insecticides, there is stomach toxicity, tag, fumigate triple role, multiple chewing type and sucking pest can be killed; Mixed intermiscibility is good, can with multiple Mixture Use of Insecticides and synergistic effect is obvious.After Diacloden and chlorpyrifos mixture, have obvious synergistic effect, quick-acting is good, and the lasting period is long; Insecticidal spectrum is wide, all has good control efficiency to rice hoppers, paddy stem borer, rice leaf roller, apple tree aphid, melon trialeurodes vaporariorum, diaphorina citri, leaf miner, especially good to diaphorina citri quick-acting, the lasting period is long.
Embodiment
Below by specific embodiment, the present invention is described in further detail.
Embodiment one
The Pesticidal combination that the embodiment of the present invention one provides comprises, Diacloden 0.1-60 part, chlopyrifos 0.1-60 part.
Diacloden, its chemical name is 3-(the chloro-1,3-thiazoles of 2--5-ylmethyl)-5-methyl isophthalic acid, 3,5-oxadiazines-4-base fork (nitro) amine, and be a kind of High-efficiency low-toxicity broad spectrum, be also second generation anabasine insecticide simultaneously; Its mechanism of action is similar to Imidacloprid, alternative suppresses insect CNS nicotinic acetylcholine esterase acceptor, and then blocks the normal conduction of insect CNS, dead when causing insect to occur paralysis machine.Its not only have tag, stomach toxicity, systemic activity, and there is the feature such as higher activity, better safety, wider insecticidal spectrum and speed of action is fast, lasting period length, to coleoptera, diptera, Lepidoptera, especially homoptera pest has high activity, effectively can prevent and treat the insect of the insects such as various aphid, leafhopper, plant hopper, aleyrodid, chafer larva, colorado potato beetle, nematode, ground beetle, leaf miner and knot polytype chemical pesticide generation resistance; Chlopyrifos, its chemical name is O, O-diethyl-O-(3,5,6-trichloro-2-pyridyl) thiophosphate, be thiophosphate insecticides, there is stomach toxicity, tag, fumigate triple role, multiple chewing type and sucking pest can be killed; Mixed intermiscibility is good, can with multiple Mixture Use of Insecticides and synergistic effect is obvious.After Diacloden and chlorpyrifos mixture, have obvious synergistic effect, quick-acting is good, and the lasting period is long; Insecticidal spectrum is wide, all has good control efficiency to rice hoppers, paddy stem borer, rice leaf roller, apple tree aphid, melon trialeurodes vaporariorum, diaphorina citri, leaf miner, especially good to diaphorina citri quick-acting, the lasting period is long.
In order to the effect making the Pesticidal combination of above-described embodiment better can play desinsection, present invention also offers following examples, following embodiment is the further increase and restriction made on the basis of embodiment one, now makes detailed explanation and elaboration:
On the basis of embodiment one, also comprise: one or more in dispersant 0.1-10 part, emulsifier 0.1-12 part, antifreezing agent 0.1-4 part, thickener 0.1-4 part, defoamer 0.1-2 part, solvent 25-99.7 part, wetting agent 0.1-10 part, disintegrant 0.1-6 part and filler 8-99.6 part;
In addition, optionally, after adding one or more auxiliary agents above-mentioned, can be made into the Pesticidal combination of multiple formulation, concrete, can be made into the formulations such as suspending agent, aqueous emulsion, water dispersible granules, microemulsion, wetting powder or missible oil.
Embodiment two
When the formulation of described Pesticidal combination is suspending agent, its component comprises: Diacloden 0.1-30 part, chlopyrifos 0.1-15 part, dispersant 0.1-10 part, emulsifier 0.1-10 part, antifreezing agent 0.1-4 part, thickener 0.1-4 part, defoamer 0.1-2 part, solvent 25-99.3 part.
Embodiment three
When the formulation of described Pesticidal combination is aqueous emulsion, its component comprises: Diacloden 0.1-25 part, chlopyrifos 0.1-20 part, dispersant 0.1-10 part, emulsifier 0.1-10 part, antifreezing agent 0.1-4 part, solvent 31-99.5 part.
Embodiment four
When the formulation of described Pesticidal combination is water dispersible granules, its component comprises: Diacloden 0.1-20 part, chlopyrifos 0.1-30 part, dispersant 0.1-10 part, emulsifier 0.1-10 part, wetting agent 0.1-10 part, disintegrant 0.1-6 part, thickener 0.1-4 part, defoamer 0.1-2 part, filler 8-92 part
Embodiment five
When the formulation of described Pesticidal combination is microemulsion, its component comprises: Diacloden 0.1-20 part, chlopyrifos 0.1-20 part, dispersant 0.1-10 part, wetting agent 0.1-10 part, antifreezing agent 0.1-4 part, solvent 36-99.5 part
Embodiment six
When the formulation of described Pesticidal combination is emulsifiable concentrate, its component comprises: Diacloden 0.1-20 part, chlopyrifos 0.1-25 part, emulsifier 0.1-12 part, solvent 43-99.7 part;
When the formulation of described Pesticidal combination is wetting powder, its component comprises: Diacloden 0.1-30 part, chlopyrifos 0.1-15 part, dispersant 0.1-10 part, wetting agent 0.1-10 part, filler 35-99.6 part.
It is to be noted, in above-mentioned all embodiments, described emulsifier is one or more in calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, thermally coupled distillation columns, polyoxyethylene carboxylate, polyoxyethylene aliphatic alcohol ether, alkyl polyoxyethylene sulfate salt, phenethyl phenol polyethenoxy ether;
Described solvent can be any one or more in dimethylbenzene, diesel oil, toluene, cyclohexanol, methyl alcohol, vegetable oil, turpentine oil, solvent naphtha, dimethyl formamide, ethanol, N-pyrrolidones, ethyl acetate equal solvent;
Wetting agent can be lauryl sodium sulfate, calcium dodecyl benzene sulfonate, methyl naphthalene sulfonate formaldehyde condensate, pull open in powder, alkylnaphthalene sulfonate, spaonin powder etc. one or more;
Dispersant can be one or more in sodium lignin sulfonate, calcium lignosulfonate, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, polycarboxylate, aliphatic amine polyoxyethylene ether, glycerine fatty acid fat acid ester polyoxyethylene ether;
Antifreezing agent can be one or more in ethylene glycol, propane diols, glycerine, urea;
Thickener can be one or more in xanthans, Magnesiumaluminumsilicate, CMC, polyvinyl alcohol;
Defoamer is one or more in silicone oil, C8-10 aliphatic alcohols compound, C10-20 saturated fat acid compounds;
Disintegrant can be one or more in bentonite, ammonium sulfate, succinic acid, sodium bicarbonate, aluminium chloride, succinic acid;
Filler can be one or more in white carbon, kaolin, diatomite, precipitated calcium carbonate, starch.
Concrete, the present invention also provides following concrete preferred embodiment by the proportioning of set each component:
Embodiment seven: take Diacloden 25g, chlopyrifos 5g, with dimethylbenzene 9g, methyl alcohol 5g, be dissolved into oil phase; Be mixed into aqueous phase by polyoxyethylene nonylphenol ether 6g, alkyl benzene sulfonate calcium salt 2g, ethylene glycol 4g, deionized water less than 100g, above aqueous phase added the oil phase in high shear, then shear 15min and namely make 30% Diacloden chlorpyrifos aqueous emulsion.
Embodiment eight: take Diacloden 15g, chlopyrifos 15g, with purified petroleum benzin 10g, cyclohexanol 10g dissolve, add calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene formaldehyde condensation products sulphate 6g, ethylene glycol 5g, deionized water supply 100g.Stir, shear, make 30% Diacloden chlorpyrifos micro emulsion.
Embodiment nine: take Diacloden 15g, chlopyrifos 10g, alkyl polyoxyethylene sulfate salt 3g, polyoxyethylene carboxylate 4g, dimethylbenzene 8g, turpentine oil adds to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and makes 25% Diacloden chlorpyrifos ec.
Embodiment ten: take Diacloden 5g, chlopyrifos 30g, sodium lignin sulfonate 8g, alkylphenol polyoxyethylene 3g, white carbon 6g, ammonium sulfate 5g, spaonin powder 4g, aluminium-magnesium silicate 0.8g, silicone oil 0.5g, kaolin mends to 100g, by above raw material co-grinding, make 35% Diacloden chlopyrifos water dispersible granules through granulation.
Embodiment 11: take Diacloden 30g, chlopyrifos 2g, sodium lignin sulfonate 10g, calcium dodecyl benzene sulfonate 7g, white carbon 3g, add to 100g with kaolin, by above raw material mixing ultramicro grinding, makes 32% Diacloden chlopyrifos wettable wetting powder.
Now enumerate the application example of the preventive effect utilizing Pesticidal combination of the present invention to different insect, please refer to:
1, the rice hoppers test of pesticide effectiveness is prevented and treated:
Take Diacloden 15g, chlopyrifos 10g, alkyl polyoxyethylene sulfate salt 3g, polyoxyethylene carboxylate 4g, dimethylbenzene 8g, turpentine oil adds to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and makes 25% Diacloden chlorpyrifos ec.。This proportioning uses by 2000 times of dilution sprayings, and after medicine, 7 days control efficiency are 95.8%; 21% Diacloden suspending agent and 40% chlorpyrifos aqueous emulsion are according to same method, and dilute 2000 times and 1500 times of uses respectively, after medicine, 7 days control efficiency are respectively 80.% and 79.6%, and preventive effect is better than single dose.
2, apple tree Control of Aphids is prevented and treated:
Take Diacloden 25g, chlopyrifos 5g, with dimethylbenzene 9g, methyl alcohol 5g, be dissolved into oil phase; Be mixed into aqueous phase by polyoxyethylene nonylphenol ether 6g, alkyl benzene sulfonate calcium salt 2g, ethylene glycol 4g, deionized water less than 100g, above aqueous phase added the oil phase in high shear, then shear 15min and namely make 30% Diacloden chlorpyrifos aqueous emulsion.By this proportioning by dilution 5000 times spraying, after medicine, 3 days control efficiency are 86.3%, after medicine, 10 days control efficiency are 94.6%, 21% Diacloden suspending agent and 40% chlorpyrifos aqueous emulsion press same method, dilute 3000 times and 2000 times respectively, after medicine, 3 days control efficiency are 67.4% and 61.4, and after medicine, 10 days control efficiency are 82.5% and 77.9%, and preventive effect is better than single dose.
3, the tea tree smaller green leaf hopper test of pesticide effectiveness is prevented and treated
Take Diacloden 15g, chlopyrifos 5g, alkyl polyoxyethylene sulfate salt 3g, polyoxyethylene carboxylate 3g, dimethylbenzene 9g, turpentine oil adds to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and makes 20% Diacloden chlorpyrifos ec.。By this proportioning by dilution 5000 times spraying, after medicine, 9 days control efficiency are that 89.7%, 21% Diacloden suspending agent and 40% chlorpyrifos aqueous emulsion press same method, and dilute 3000 times and 2000 times respectively, after medicine, 9 days control efficiency are 76.1% and 75.2%, and preventive effect is better than single dose.
4, the diaphorina citri test of pesticide effectiveness is prevented and treated
Take Diacloden 30g, chlopyrifos 2g, sodium lignin sulfonate 10g, calcium dodecyl benzene sulfonate 7g, white carbon 3g, add to 100g with kaolin, by above raw material mixing ultramicro grinding, make 32% Diacloden chlopyrifos wettable wetting powder.By this proportioning by dilution 4000 times spraying, after medicine, 7 days control efficiency are that 98.2%, 21% Diacloden suspending agent and 40% chlorpyrifos aqueous emulsion press same method, dilute 3000 times and 1500 times respectively, after medicine, 7 days control efficiency are respectively 88.3% and 80.9%, and preventive effect is better than single dose.
Pesticidal combination of the present invention all has good control efficiency to rice hoppers, paddy stem borer, rice leaf roller, apple tree aphid, melon trialeurodes vaporariorum, diaphorina citri, leaf miner, concrete, now enumerate this Pesticidal combination to the process of the test of the indoor virulence of diaphorina citri and result, please refer to following content:
Test adopts medicine embrane method, by Diacloden during test. and the mother liquor of each mixture preparation of chlopyrifos is diluted to 6 series concentration, is placed in beaker respectively for subsequent use.Get cylindrical transparent glass preserving jar (base diameter 6.8cm, bottleneck diameter 5.5cm, high 8.7cm), add the liquid that 50ml has been diluted to desired concn, cover tightly lid, shake up gently, be inverted 30s, make a bottle inwall all stick liquid, then liquid is poured out, then allow bottle naturally dry.The identical liquid of oranges and tangerines tender shoots is soaked 1min, after naturally drying, puts into the bottle dried; The moisturizing of tender shoots base portion is encased with the cotton of dipped identical liquid.Wood louse adult band plug teat glass gathers from kamuning tree.Each process repetition 3 times, each repetition 10 adults.With putting into each process bottle after co2 anesthesia (18-20s) during process, blank clear water, each bottleneck 40 order gauzes are built, in case adult flies out.Dead worm has been checked whether, borer population of living before record medicine after 20 minutes.To the vial after worm be connect be placed in the illumination box of temperature (25 ± 1) DEG C.After medicine, 24h estimates dead borer population, borer population alive, calculates lethality, and clear water contrast lethality is no more than 10% for efficiency test.
In the process of experimental result, first concentration conversion is become natural logrithm value, corrected mortality is converted into arcsine transformation, with arcsine transformation value for dependent variable, with dosage natural logrithm value for independent variable, carry out linear regression analysis by DPS Biological Statistic Analysis Software, draw the toxicity regression linear equation of each medicament.
Toxicity index and the co-toxicity coefficient (CTC) of medicament is calculated according to the abundant method of Sun Yun; Actual measurement toxicity index=standard agent EC50/ reagent agent EC50 × 100; The theoretical toxicity index of the single dose=content of single dose actual measurement toxicity index × single dose in mixture; The theoretical toxicity index sum of mixture theoretical toxicity index=each single dose; Theoretical toxicity index × 100 of toxicity index/mixture of co-toxicity coefficient=mixture actual measurement; Evaluation criterion: CTC is accurate: refer to for antagonism, 80 < CTC < 120 are summation action, CTC effect, and number is synergistic effect.
Table 1: the toxicity index of each medicament and chlopyrifos. the co-toxicity coefficient of Diacloden
| Reagent agent | Proportioning | Regression equation | EC 50（mg/kg） | Co-toxicity coefficient |
| Chlopyrifos | - | y=17.1838x+11.0341 | 7.22 | - |
| Diacloden | - | y=25.5000x+1.2668 | 5.56 | - |
| Diacloden: chlopyrifos | 1:60 | y=17.1125x+10.9413 | 6.95 | 121.4 |
| Diacloden: chlopyrifos | 1:40 | y=16.9645x+10.8853 | 6.88 | 130.6 |
| Diacloden: chlopyrifos | 1:30 | y=16.7965x+10.6324 | 6.12 | 180.5 |
| Diacloden: chlopyrifos | 1:20 | y=16.4736x+10.5526 | 6.00 | 184.3 |
| Diacloden: chlopyrifos | 1:10 | y=16.4429x+10.4596 | 5.87 | 197.5 |
| Diacloden: chlopyrifos | 1:1 | y=16.1311x+9.6843 | 5.80 | 200.2 |
| Diacloden: chlopyrifos | 10:1 | y=18.5521x+8.9512 | 4.39 | 210.4 |
| Diacloden: chlopyrifos | 20:1 | y=19.6088x+5.6873 | 4.87 | 220.21 |
| Diacloden: chlopyrifos | 30:1 | y=22.5456x+3.9783 | 5.15 | 230.16 |
| Diacloden: chlopyrifos | 40:1 | y=24.6031x+2.2433 | 5.38 | 165.7 |
| Diacloden: chlopyrifos | 60:1 | y=24.9622x+1.9845 | 5.42 | 134.8 |
Shown by above-mentioned experimental data: Diacloden and chlopyrifos in mass ratio 1:60 ~ 60:1 are composite, all have synergistic effect to diaphorina citri, when especially proportioning is between 1:30 ~ 30:1, synergy is more remarkable.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for a person skilled in the art, the present invention can have various modifications and variations.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (1)
1. Pesticidal combination, is characterized in that, according to weight parts, it consists of the following composition:
Diacloden 0.1-30 part, chlopyrifos 0.1-15 part, dispersant 0.1-10 part, emulsifier 0.1-10 part, antifreezing agent 0.1-4 part, thickener 0.1-4 part, defoamer 0.1-2 part and solvent 25-99.3 part;
Wherein, described emulsifier is one or more in calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, styrylphenol polyoxyethylene ether, thermally coupled distillation columns, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether, alkyl polyoxyethylene sulfate salt, phenethyl phenol polyethenoxy ether;
Described solvent is any one or more in dimethylbenzene, diesel oil, cyclohexanol, methyl alcohol, vegetable oil, turpentine oil, solvent naphtha, dimethyl formamide, ethanol, N-pyrrolidones, ethyl acetate, water;
Described dispersant is one or more in sodium lignin sulfonate, calcium lignosulfonate, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, polycarboxylate, aliphatic amine polyoxyethylene ether, glycerine fatty acid fat acid ester polyoxyethylene ether;
Described antifreezing agent is one or more in ethylene glycol, propane diols, glycerine, urea;
Described thickener is one or more in xanthans, Magnesiumaluminumsilicate, CMC, polyvinyl alcohol;
Described defoamer is one or more in silicone oil, C8-10 aliphatic alcohols compound, C10-20 saturated fat acid compounds.
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| CN103814944A (en) * | 2014-02-23 | 2014-05-28 | 红河蔗保科技有限责任公司 | Sugarcane pesticide containing chlopyrifos and thiamethoxam, and its production method |
| CN105330460A (en) * | 2015-10-21 | 2016-02-17 | 河南中天恒信生物化学科技有限公司 | Wheat field pesticide fertilizer granular preparation containing thiamethoxam and chlorpyrifos, and preparation method thereof |
| CN109042718A (en) * | 2016-07-05 | 2018-12-21 | 江苏新农化工有限公司 | Pesticidal combination and its preparation and application containing chlorpyrifos-methyl |
| CN106358863A (en) * | 2016-08-31 | 2017-02-01 | 山东瑞达有害生物防控有限公司 | Method for preventing and curing diaphorina citri by virtue of airplane |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1820604A (en) * | 2006-03-23 | 2006-08-23 | 浙江新安化工集团股份有限公司 | Pest killing composition |
| CN101156594A (en) * | 2007-11-19 | 2008-04-09 | 广西田园生化股份有限公司 | Compound agricultural chemical |
| WO2010100638A2 (en) * | 2009-03-04 | 2010-09-10 | Celsius Property B.V. Amsterdam (Nl) | Seed treatment and pesticidal composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1820604A (en) * | 2006-03-23 | 2006-08-23 | 浙江新安化工集团股份有限公司 | Pest killing composition |
| CN101156594A (en) * | 2007-11-19 | 2008-04-09 | 广西田园生化股份有限公司 | Compound agricultural chemical |
| WO2010100638A2 (en) * | 2009-03-04 | 2010-09-10 | Celsius Property B.V. Amsterdam (Nl) | Seed treatment and pesticidal composition |
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