CN105685045B - A kind of Pesticidal combination of fluorine-containing lice sulfanilamide (SN) - Google Patents
A kind of Pesticidal combination of fluorine-containing lice sulfanilamide (SN) Download PDFInfo
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- CN105685045B CN105685045B CN201610087971.3A CN201610087971A CN105685045B CN 105685045 B CN105685045 B CN 105685045B CN 201610087971 A CN201610087971 A CN 201610087971A CN 105685045 B CN105685045 B CN 105685045B
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- CN
- China
- Prior art keywords
- fluorine
- lice sulfanilamide
- grams
- acre
- metaflumizone
- Prior art date
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- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 title claims abstract description 224
- 229940124530 sulfonamide Drugs 0.000 title claims abstract description 224
- 241001674048 Phthiraptera Species 0.000 title claims abstract description 119
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title claims abstract description 116
- 229910052731 fluorine Inorganic materials 0.000 title claims abstract description 116
- 239000011737 fluorine Substances 0.000 title claims abstract description 116
- 230000000361 pesticidal effect Effects 0.000 title claims abstract description 15
- 239000005914 Metaflumizone Substances 0.000 claims abstract description 62
- MIFOMMKAVSCNKQ-HWIUFGAZSA-N Metaflumizone Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)N\N=C(C=1C=C(C=CC=1)C(F)(F)F)\CC1=CC=C(C#N)C=C1 MIFOMMKAVSCNKQ-HWIUFGAZSA-N 0.000 claims abstract description 62
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000005912 Lufenuron Substances 0.000 claims abstract description 61
- PWPJGUXAGUPAHP-UHFFFAOYSA-N lufenuron Chemical compound C1=C(Cl)C(OC(F)(F)C(C(F)(F)F)F)=CC(Cl)=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F PWPJGUXAGUPAHP-UHFFFAOYSA-N 0.000 claims abstract description 61
- 229960000521 lufenuron Drugs 0.000 claims abstract description 61
- 239000005926 Pyridalyl Substances 0.000 claims abstract description 51
- AEHJMNVBLRLZKK-UHFFFAOYSA-N pyridalyl Chemical group N1=CC(C(F)(F)F)=CC=C1OCCCOC1=C(Cl)C=C(OCC=C(Cl)Cl)C=C1Cl AEHJMNVBLRLZKK-UHFFFAOYSA-N 0.000 claims abstract description 49
- 239000000203 mixture Substances 0.000 claims abstract description 48
- 239000000470 constituent Substances 0.000 claims abstract description 28
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 24
- 230000000694 effects Effects 0.000 claims abstract description 21
- 239000000375 suspending agent Substances 0.000 claims description 56
- 239000003795 chemical substances by application Substances 0.000 claims description 25
- 241000500437 Plutella xylostella Species 0.000 claims description 15
- 239000003094 microcapsule Substances 0.000 claims description 15
- 241000255967 Helicoverpa zea Species 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 13
- 241001414989 Thysanoptera Species 0.000 claims description 12
- 241000008892 Cnaphalocrocis patnalis Species 0.000 claims description 11
- 241000255969 Pieris brassicae Species 0.000 claims description 11
- 241000258937 Hemiptera Species 0.000 claims description 10
- 241000985245 Spodoptera litura Species 0.000 claims description 10
- 241000218475 Agrotis segetum Species 0.000 claims description 9
- 241001124076 Aphididae Species 0.000 claims description 9
- 241000426497 Chilo suppressalis Species 0.000 claims description 9
- 241001498622 Cixius wagneri Species 0.000 claims description 9
- 239000000725 suspension Substances 0.000 claims description 9
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- 239000004530 micro-emulsion Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 239000004563 wettable powder Substances 0.000 claims description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 150000002825 nitriles Chemical class 0.000 claims description 3
- 238000007667 floating Methods 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 125000004494 ethyl ester group Chemical group 0.000 abstract description 60
- 230000002195 synergetic effect Effects 0.000 abstract description 30
- 239000000575 pesticide Substances 0.000 abstract description 17
- 150000001875 compounds Chemical class 0.000 abstract description 11
- 235000013339 cereals Nutrition 0.000 abstract description 4
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- 206010059866 Drug resistance Diseases 0.000 abstract description 2
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- 238000003912 environmental pollution Methods 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 48
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 26
- 238000013329 compounding Methods 0.000 description 26
- 239000004480 active ingredient Substances 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 230000003449 preventive effect Effects 0.000 description 19
- 238000012360 testing method Methods 0.000 description 19
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 16
- 230000010165 autogamy Effects 0.000 description 16
- 239000012071 phase Substances 0.000 description 15
- 230000002045 lasting effect Effects 0.000 description 14
- 238000002474 experimental method Methods 0.000 description 13
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 13
- 231100000820 toxicity test Toxicity 0.000 description 12
- 229940079593 drug Drugs 0.000 description 11
- 239000003995 emulsifying agent Substances 0.000 description 11
- 241000238631 Hexapoda Species 0.000 description 10
- 239000002518 antifoaming agent Substances 0.000 description 10
- 239000002270 dispersing agent Substances 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- 241000209094 Oryza Species 0.000 description 9
- 235000007164 Oryza sativa Nutrition 0.000 description 9
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 9
- 235000009566 rice Nutrition 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- 239000002562 thickening agent Substances 0.000 description 7
- 239000000080 wetting agent Substances 0.000 description 7
- 230000002528 anti-freeze Effects 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- -1 ethoxyl methyl Chemical group 0.000 description 6
- 238000013401 experimental design Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 235000006008 Brassica napus var napus Nutrition 0.000 description 5
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 5
- 241001182720 Cacopsylla pyrisuga Species 0.000 description 5
- 241001674939 Caulanthus Species 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000002574 poison Substances 0.000 description 5
- 231100000614 poison Toxicity 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 231100000419 toxicity Toxicity 0.000 description 5
- 230000001988 toxicity Effects 0.000 description 5
- 206010011732 Cyst Diseases 0.000 description 4
- 239000005927 Pyriproxyfen Substances 0.000 description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- 208000031513 cyst Diseases 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000002917 insecticide Substances 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 241000273311 Aphis spiraecola Species 0.000 description 3
- 241000207199 Citrus Species 0.000 description 3
- 241000255777 Lepidoptera Species 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 235000020971 citrus fruits Nutrition 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000003002 pH adjusting agent Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 210000002784 stomach Anatomy 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- 241000934067 Acarus Species 0.000 description 2
- 241000254127 Bemisia tabaci Species 0.000 description 2
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 2
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 2
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 2
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 2
- 241001525654 Phyllocnistis citrella Species 0.000 description 2
- 241000125167 Rhopalosiphum padi Species 0.000 description 2
- 240000003768 Solanum lycopersicum Species 0.000 description 2
- 244000061458 Solanum melongena Species 0.000 description 2
- 235000002597 Solanum melongena Nutrition 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 210000004681 ovum Anatomy 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 150000003233 pyrroles Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 description 1
- ZRNSSRODJSSVEJ-UHFFFAOYSA-N 2-methylpentacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC(C)C ZRNSSRODJSSVEJ-UHFFFAOYSA-N 0.000 description 1
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 241000238421 Arthropoda Species 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000005758 Cyprodinil Substances 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- 241000270322 Lepidosauria Species 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 241000256259 Noctuidae Species 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 239000005931 Spirotetramat Substances 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 241000255901 Tortricidae Species 0.000 description 1
- 241000018135 Trialeurodes Species 0.000 description 1
- ROMMVUMWISCVBE-UHFFFAOYSA-N [F].N#CC#N Chemical compound [F].N#CC#N ROMMVUMWISCVBE-UHFFFAOYSA-N 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
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- 238000004364 calculation method Methods 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 description 1
- 239000007957 coemulsifier Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- HAORKNGNJCEJBX-UHFFFAOYSA-N cyprodinil Chemical compound N=1C(C)=CC(C2CC2)=NC=1NC1=CC=CC=C1 HAORKNGNJCEJBX-UHFFFAOYSA-N 0.000 description 1
- DFBKLUNHFCTMDC-PICURKEMSA-N dieldrin Chemical compound C([C@H]1[C@H]2[C@@]3(Cl)C(Cl)=C([C@]([C@H]22)(Cl)C3(Cl)Cl)Cl)[C@H]2[C@@H]2[C@H]1O2 DFBKLUNHFCTMDC-PICURKEMSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
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- 230000000857 drug effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000013020 embryo development Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 210000000087 hemolymph Anatomy 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000004920 integrated pest control Methods 0.000 description 1
- 229930014550 juvenile hormone Natural products 0.000 description 1
- 239000002949 juvenile hormone Substances 0.000 description 1
- 150000003633 juvenile hormone derivatives Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N monofluoromethane Natural products FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- PEQJBOMPGWYIRO-UHFFFAOYSA-N n-ethyl-3,4-dimethoxyaniline Chemical class CCNC1=CC=C(OC)C(OC)=C1 PEQJBOMPGWYIRO-UHFFFAOYSA-N 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 230000001537 neural effect Effects 0.000 description 1
- 239000003987 organophosphate pesticide Substances 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 230000017448 oviposition Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 230000012865 response to insecticide Effects 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 210000004894 snout Anatomy 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- CLSVJBIHYWPGQY-GGYDESQDSA-N spirotetramat Chemical compound CCOC(=O)OC1=C(C=2C(=CC=C(C)C=2)C)C(=O)N[C@@]11CC[C@H](OC)CC1 CLSVJBIHYWPGQY-GGYDESQDSA-N 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/06—Sulfonic acid amides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Pesticidal combination of fluorine-containing lice sulfanilamide (SN), the Pesticidal combination containing active components A and active constituent B, active components A is selected from fluorine lice sulfanilamide (SN), and active constituent B is selected from any one following compound：Spiral shell worm ethyl ester, capillary, lufenuron, Nylar, metaflumizone, pyridalyl, and active components A, the weight ratio of active constituent B are 1 ︰, 70~70 ︰ 1.The present composition can prevent various pests, and have apparent synergistic effect, expand insecticidal spectrum, have greater activity to the various pests on vegetables, fruit tree, cereal crops, fibre crops；And reduces pesticide usage amount, reduce residual quantity of the pesticide on crop, alleviate environmental pollution；To safety of human and livestock, Environmental compatibility is good, and pest is not likely to produce drug resistance.
Description
The application is divisional application, and original application is that " one kind contains for the patent application of Shaanxi Welch Crop Protection Co., Ltd.
The Pesticidal combination of fluorine lice sulfanilamide (SN) ", the application Wei ︰ of original application
201210112747.7 original application day 2012.04.17.
Technical field
The invention belongs to technical field of pesticide, are related to a kind of Pesticidal combination of fluorine-containing lice sulfanilamide (SN).
Background technology
Spiral shell worm ethyl ester (spirotetramat) chemical name：4- (ethoxy carbonyl oxygroup) -8- methoxyl groups -3- (2,5- bis-
Tolyl) -1- azaspiros [4,5]-decyl- 3- alkene -2- ketone, molecular formula：C21H27NO5, spiral shell worm ethyl ester is a kind of novel tetronic acid class
Insecticide, insecticidal spectrum is wide, and the lasting period is long.It is to lead to dead larvae by the fatty biosynthesis of interference insect, reduces adult
Fertility.Due to its unique mechanism of action, the pest that resistance is generated to existing insecticide can be effectively prevented, while can
Important kind as nicotinic insecticide resistance management.
Capillary (chlorfenapyr) chemical name：4- bromos -2- (4- chlorphenyls) -1- (ethoxyl methyl) -5- (three
Methyl fluoride) pyrroles's -3- nitriles, molecular formula：C15H11BrClF3N2O, the capillary product are new pyrrole class desinsection, acaricide.It is right
Various pests have stomach toxicity and action of contace poison, and to crop safety, prevention diamondback moth is high with preventive effect, the lasting period is longer, dosage
Low advantage.
Lufenuron (lufenuron) chemical name：N- [[[bis- chloro- 4- of 2,5- (the third oxygen of 1,1,2,3,3,3- hexafluoros) phenyl]
Amino] carboxyl] -2,6- difluorobenzamides；Molecular formula：C17H8C12F8N2O3, lufenuron is latest generation substituted urea class desinsection
Agent.Medicament is by acting on insect larvae, preventingDecorticationProcess and kill off the insect pests, especially to fruit tree etc. food leaf caterpillar have it is outstanding
Preventive effect is rightThrips, rust mite,Trialeurodes vaporariorumThere is unique killing mechanism, is suitable for prevention and pyrethroid and organophosphorus pesticide are produced
Raw resistant insect.
Nylar (pyriproxyfen) chemical name：4- Phenoxyphenyls (RS) -2- (2- pyridyl groups oxygen) propyl ether, point
Minor：C20H19NO3, Nylar is a kind of chitin synthesis inhibitor of juvenile hormone type, has strong ovicidal action.Mosquito
Fly ether also has absorbability transfer activity, can influence the larva for being hidden in blade behind.The inhibiting effect of insect is shown
Insect is influenced to change in quality and breed.Toxicological test performance to prodenia litura, pyriproxyfen retain hemolymph middle and high concentration, accelerate
The secretion of insect prothoracotropic hormone；On the other hand, since pyriproxyfen can make insect lack the stimulus needed for oviposition, suppression
Embryonic development processed and the hatching of ovum, or the ovum of not viability is generated, to effectively control and reach the mesh of control of insect
's.
Metaflumizone (metaflumizone) chemical name：(E+Z)-[2- (4- cyano benzene) -1- [3- (trifluoromethyl)
Benzene] ethylidene]-N- [4- (trifluoromethyl) benzene]-hydrazine carbonyl oxamides, molecular formula：C24H16F6N4O2, metaflumizone is mainly stomach
Toxic action, band action of contace poison, hinders the sodium path of nervous system to cause neural paralysis, prevents lepidoptera and coleopteran pest, right
Mammal and non-target organism low-risk.
Pyridalyl (Pyridalyl) chemical name：2- [3- [bis- chloro- 4- of 2,6- [(bis- chloro- 2- acrylic of 3,3-) oxygen
Base] phenoxy group] propoxyl group] -5- (trifluoromethyl) pyrimidine, molecular formula：C32H14F3NO3.Pyridalyl has and existing insecticide
Entirely different structure, and have remarkable insecticidal activity to many lepidoptera pests on vegetables and cotton.Have simultaneously tactile
The effect with stomach toxicity is killed, there is original preventive effect to lepidoptera pest, certain activity, and pyridalyl are also showed that thrips
Influence very little to various arthropods, so it is expected to become an effective tool in integrated pest management.
However, in the real process of agricultural production, the problem of pest control most easily produces is the production of pest resistance to insecticide
It is raw.Different cultivars ingredient is compounded, and is to prevent the very common method of resistant insect.Heterogeneity is compounded, according to reality
Application effect, to judge that certain compounding is synergy, adduction, antagonism.In most cases, the compounding effect of pesticide is all
Additive effect really has the compounding of synergistic effect seldom, especially synergistic effect clearly, the very high compounding of co-toxicity coefficient just
It is less.Studied by inventor, find by fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, lufenuron, Nylar, metaflumizone,
Can generate good synergistic effect after pyridalyl compounding, and about fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, lufenuron,
The relevant report that Nylar, metaflumizone, pyridalyl compound not yet discloses.
Invention content
The problems such as resistance that may be brought occurs, drug effect declines is used for a long time in fluorine lice sulfanilamide (SN) single dose, proposed by the present invention to kill
Worm composition contains active components A and active constituent B and suitable surfactant and carrier.
A kind of Pesticidal combination of fluorine-containing lice sulfanilamide (SN), it is characterised in that：Containing active components A and active constituent B, activity at
It is 1 ︰, 70~70 ︰ 1 to divide the weight ratio of A and active constituent B, and the active components A is selected from fluorine lice sulfanilamide (SN), and active constituent B is selected from
One kind in spiral shell worm ethyl ester, capillary, lufenuron, Nylar, metaflumizone, pyridalyl, active components A and active constituent B
Weight ratio be preferably 1 ︰, 50~30 ︰ 1, the weight ratio of fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester is more preferably 10 ︰, 1~1 ︰ 20；Fluorine lice sulphur
The weight ratio of amine and capillary is more preferably 10 ︰, 1~1 ︰ 20；The weight ratio of fluorine lice sulfanilamide (SN) and lufenuron is more preferably 10 ︰, 1~1 ︰
10；The weight ratio of fluorine lice sulfanilamide (SN) and Nylar is more preferably 10 ︰, 1~1 ︰ 20；The weight ratio of fluorine lice sulfanilamide (SN) and metaflumizone is more excellent
It is selected as 10 ︰, 1~1 ︰ 30；The weight ratio of fluorine lice sulfanilamide (SN) and pyridalyl is more preferably 10 ︰, 1~1 ︰ 20.
The Pesticidal combination of the fluorine-containing lice sulfanilamide (SN) is used to prevent the purposes of crop pest, and the crops include vegetable
Dish, fruit tree, cereal crops, on fibre crops pest purposes.
The purposes, which is characterized in that the pest includes：Planthopper, aphid, wood louse, aleyrodid, mealybug, shell
Worm, thrips, cabbage caterpillar, prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf miner, blister mite, olethreutid,
Black cutworm, rice leaf roller, rice-stem borer.
Active components A and the weight ratio of active constituent B are 1 ︰, 70~70 ︰ 1.The weight hundred of active component in usual composition
Divide content for the 1%~90% of total weight, preferably 5%~85%.According to different preparation types, active component content model
It encloses different.In general, liquid preparation contains by weight 1%~70% active material, preferably 5%~50%；Gu
Body preparation contains by weight 5%~85% active material, preferably 10%~70%.
The present invention Pesticidal combination at least contain a kind of surfactant, in favor of application when active component in water
Dispersion.Surface-active contents are the 5%~40% of total formulation weight, and surplus is solid or liquid diluent.
The composition of the present invention can used before through dilution or directly by user.Its preparation can be by common
Prepared by the processing method well known to field technology personnel, i.e., after mixing active material with liquid flux or solid carrier, then add
Enter one or more of surfactant such as dispersant, stabilizer, wetting agent, emulsifier, binder, antifoaming agent etc..
The Pesticidal combination of the present invention, can be processed into any dosage form pesticide-acceptable on demand, wherein excellent relatively select
Dosage form is：Wettable powder, suspending agent, suspension emulsion, water dispersible granules, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension
Agent-suspending agent.
Composition includes following constituent content when wettable powder is made：Active components A 1%~70%, active constituent B
1%~70%, dispersant 1.5%~10%, wetting agent 1%~10%, filler surplus.
Composition includes following constituent content when water dispersible granules are made：Active components A 1%~70%, active constituent B
1%~70%, dispersant 1%~12%, wetting agent 1%~8%, disintegrant 1%~10%, binder 0%~8%, filler
Surplus.
Composition includes following constituent content when suspending agent is made：Active components A 1%~50%, active constituent B 1%
~50%, dispersant 1%~10%, wetting agent 1%~10%, antifoaming agent 0.1%~1%, thickener 0.05%~2%, anti-
Freeze agent 0%~8%, deionized water adds to 100%.
Composition includes following constituent content when suspension emulsion is made：Active components A 1%~50%, active constituent B 1%
~50%, solvent 0~15%, emulsifier 2%~12%, dispersant 2%~10%, antifoaming agent 0.1%~2%, thickener
0.05%~2%, antifreeze 0%~8%, stabilizer 0%~3%, water add to 100%.
Composition includes following constituent content when aqueous emulsion is made：Active components A 1%~50%, active constituent B 1%
~50%, solvent 1%~30%, emulsifier 1%~20%, co-emulsifier 1%~8%, antifreeze 0%~8%, thickener
0.05%~2%, antifoaming agent 0%~2%, deionized water supply surplus.
Composition includes following constituent content when microemulsion is made：Active components A 1%~50%, active constituent B 1%
~50%, solvent 1%~30%, emulsifier 3%~20%, antifreeze 0%~8%, thickener 0.05%~2%, antifoaming agent
0.01%~2%, stabilizer 0%~4%, deionized water supplies surplus.
Composition includes following constituent content when microcapsule suspending agent is made：Active components A 1%~50%, active constituent B
1%~50%, macromolecule cyst material 3%~10%, dispersant 2%~10%, organic solvent 0%~10%, emulsifier 2%
~7%, pH adjusting agent 0.1%~5%, deionized water adds to 100%.
Composition includes following constituent content when microcapsule suspension-suspendinagent agent is made：Active components A 1%~40%, activity
Ingredient B 1%~60%, macromolecule cyst material 2%~12%, surfactant 3%~15%, organic solvent 1%~5%,
Emulsifier 1%~6%, antifoaming agent 0.2%~5%, thickener 0.05%~1%, pH adjusting agent 1%~5%, water add to
100%.
The wettable powder the key technical indexes of the present invention：
The water dispersible granules the key technical indexes of the present invention：
The suspending agent the key technical indexes of the present invention：
The suspension emulsion the key technical indexes of the present invention：
The aqueous emulsion the key technical indexes of the present invention：
The microemulsion the key technical indexes of the present invention：
The microcapsule suspending agent the key technical indexes of the present invention：
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention：
The advantage of the invention is that：
(1) after fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, lufenuron, Nylar, metaflumizone, pyridalyl compound, tool
There are notable synergistic and lasting effect；(2) expand insecticidal spectrum, on vegetables, fruit tree, cereal crops, fibre crops planthopper,
Aphid, wood louse, aleyrodid, mealybug, scale insect, thrips, cabbage caterpillar, prodenia litura, diamondback moth, beet armyworm, bean-pod borer, cotton boll
Worm, leaf miner, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer etc. have greater activity；(3) subtract
The dosage for having lacked pesticide reduces residual quantity of the pesticide on crop；(4) to safety of human and livestock, Environmental compatibility is good, and pest is not
It is also easy to produce drug resistance.
Specific implementation mode
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The present invention is not limited thereto.
Application Example one
1~15 wettable powder of embodiment
Fluorine lice sulfanilamide (SN), active ingredient B, dispersant, wetting agent, filler are uniformly mixed in mixed cylinder, through air-flow crushing
Machine remixes uniformly after crushing, you can fluorine lice sulfanilamide (SN) active ingredient B wettable powder products is made, active ingredient B includes spiral shell
Worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are one such.
Specific formula is shown in Table 1.
1 embodiment of table, 1~15 each component and parts by weight
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, brand-new can be made
Agent.
2 fluorine lice sulfanilamide (SN) of table and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and its mixture
Prevent the rice hoppers test of pesticide effectiveness
| Treatment agent | Preparation dosage | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 1 | 8 grams/acre | 98.75 | 99.13 |
| Embodiment 2 | 5 grams/acre | 99.42 | 99.35 |
| Embodiment 5 | 12 grams/acre | 97.51 | 98.27 |
| Embodiment 6 | 4 grams/acre | 99.36 | 99.14 |
| Embodiment 9 | 6 grams/acre | 98.59 | 99.01 |
| Embodiment 11 | 4 grams/acre | 98.63 | 99.48 |
| Embodiment 13 | 10 grams/acre | 97.84 | 98.26 |
| Embodiment 15 | 5 grams/acre | 98.77 | 99.12 |
| 5% fluorine lice sulfanilamide (SN) suspending agent (autogamy) | 25 grams/acre | 65.45 | 68.76 |
| 240 grams per liter spiral shell worm ethyl ester suspending agents | 25 grams/acre | 64.31 | 69.23 |
| 10% capillary suspending agent | 30 grams/acre | 66.52 | 70.15 |
| 100 grams per liter Nylar missible oil | 45 grams/acre | 67.58 | 71.42 |
| 50 grams per liter lufenuron suspension agents | 50 grams/acre | 65.29 | 68.31 |
| 22% metaflumizone suspending agent | 75 grams/acre | 68.74 | 70.28 |
| 10% pyridalyl missible oil (autogamy) | 60 grams/acre | 64.38 | 69.53 |
As can be seen from Table 2, fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridine worm third
Comparison medicament is better than to rice hoppers control effect after ether compounding, the lasting period is long, to rice safety in experiment scope of medication.
3 fluorine lice sulfanilamide (SN) of table and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and its mixture
Prevent the citrus scale insect test of pesticide effectiveness
| Treatment agent | Extension rate | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 3 | 7500 times | 99.27 | 98.84 |
| Embodiment 4 | 8500 times | 99.06 | 98.59 |
| Embodiment 7 | 6000 times | 98.42 | 99.37 |
| Embodiment 8 | 5500 times | 98.76 | 99.02 |
| Embodiment 10 | 6500 times | 99.24 | 98.48 |
| Embodiment 12 | 7000 times | 99.85 | 99.09 |
| Embodiment 14 | 4500 times | 98.52 | 99.46 |
| 5% fluorine lice sulfanilamide (SN) suspending agent (autogamy) | 3000 times | 66.93 | 68.73 |
| 240 grams per liter spiral shell worm ethyl ester suspending agents | 4000 times | 64.29 | 65.39 |
| 10% capillary suspending agent | 1500 times | 67.84 | 69.76 |
| 100 grams per liter Nylar missible oil | 1500 times | 65.31 | 68.25 |
| 50 grams per liter lufenuron suspension agents | 2000 times | 63.76 | 69.41 |
| 22% metaflumizone suspending agent | 1000 times | 65.45 | 68.92 |
| 10% pyridalyl missible oil (autogamy) | 1200 times | 64.52 | 66.73 |
As can be seen from Table 3, fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridine worm third
Comparison medicament is better than to citrus scale insect control effect after ether compounding, the lasting period is long, to citrus safety in experiment scope of medication.
16~31 water dispersible granules of embodiment
Fluorine lice sulfanilamide (SN), active ingredient B, dispersant, wetting agent, disintegrant, filler etc. are needed through air-flow crushing together
The grain size wanted adds other auxiliary agents such as binder, obtains granulation materials.Item is quantified and is sent into fluidized bed granulating dryer
After granulation and drying, be made fluorine lice sulfanilamide (SN) active ingredient B water dispersible granules products, active ingredient B include spiral shell worm ethyl ester,
Capillary, Nylar, lufenuron, metaflumizone, pyridalyl are one such.
4 embodiment of table, 16~23 each component and parts by weight
5 embodiment of table, 24~31 each component and parts by weight
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, brand-new can be made
Agent.
6 fluorine lice sulfanilamide (SN) of table and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and its mixture
Prevent the wheat aphid test of pesticide effectiveness
| Treatment agent | Preparation dosage | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 16 | 7 grams/acre | 98.67 | 99.58 |
| Embodiment 17 | 5 grams/acre | 99.68 | 99.61 |
| Embodiment 18 | 6 grams/acre | 97.82 | 98.76 |
| Embodiment 19 | 8 grams/acre | 98.79 | 98.84 |
| Embodiment 20 | 10 grams/acre | 99.16 | 99.28 |
| Embodiment 21 | 5 grams/acre | 98.73 | 98.95 |
| Embodiment 22 | 10 grams/acre | 99.13 | 99.85 |
| Embodiment 23 | 5 grams/acre | 98.76 | 99.37 |
| 5% fluorine lice sulfanilamide (SN) suspending agent (autogamy) | 20 grams/acre | 68.25 | 66.46 |
| 240 grams per liter spiral shell worm ethyl ester suspending agents | 28 grams/acre | 67.51 | 65.92 |
| 10% capillary suspending agent | 25 grams/acre | 68.36 | 69.49 |
| 100 grams per liter Nylar missible oil | 48 grams/acre | 67.82 | 68.03 |
| 50 grams per liter lufenuron suspension agents | 55 grams/acre | 65.23 | 70.14 |
| 22% metaflumizone suspending agent | 80 grams/acre | 64.41 | 72.32 |
| 10% pyridalyl missible oil (autogamy) | 55 grams/acre | 65.75 | 69.85 |
As can be seen from Table 6, fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridine worm third
Comparison medicament is better than to wheat aphid control effect after ether compounding, the lasting period is long, to crop safety in experiment scope of medication.
7 fluorine lice sulfanilamide (SN) of table and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and its mixture
Prevent the tomato Bemisia tabaci test of pesticide effectiveness
As can be seen from Table 7, fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridine worm third
Comparison medicament is better than to tomato Bemisia tabaci control effect after ether compounding, the lasting period is long, to crop safety in experiment scope of medication.
25~36 suspending agent of embodiment
Fluorine lice sulfanilamide (SN), active ingredient B, dispersant, wetting agent, antifoaming agent, thickener, antifreeze are mixed by high speed shear
Close uniform, active compound be added, in the ball mill ball milling 2~3 hours, make diameter of particle all at 5 μm hereinafter, deionized water supplies more than
Fluorine lice sulfanilamide (SN) active ingredient B suspending agent products are made in amount, and active ingredient B includes spiral shell worm ethyl ester, capillary, Nylar, Acarus tritici
Urea, metaflumizone, pyridalyl are one such.
Specific formula is shown in Table 8, table 9, table 10, table 11.
8 embodiment of table, 32~35 each component and parts by weight
9 embodiment of table, 36~39 each component and parts by weight
10 embodiment of table, 40~43 each component and parts by weight
11 embodiment of table, 44~47 each component and parts by weight
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, novel formulation can be made.
12 fluorine lice sulfanilamide (SN) of table and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and its mixture
Prevent the pear sucker test of pesticide effectiveness
| Treatment agent | Extension rate | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 32 | 4500 times | 99.37 | 99.85 |
| Embodiment 33 | 5500 times | 98.56 | 98.62 |
| Embodiment 36 | 6000 times | 98.24 | 99.01 |
| Embodiment 37 | 5000 times | 98.79 | 99.13 |
| Embodiment 40 | 4500 times | 98.91 | 98.54 |
| Embodiment 42 | 5000 times | 97.62 | 97.48 |
| Embodiment 44 | 3500 times | 98.24 | 98.65 |
| Embodiment 46 | 4000 times | 99.37 | 98.89 |
| 5% fluorine lice sulfanilamide (SN) suspending agent (autogamy) | 3200 times | 68.51 | 66.27 |
| 240 grams per liter spiral shell worm ethyl ester suspending agents | 4500 times | 66.48 | 95.58 |
| 10% capillary suspending agent | 1200 times | 67.39 | 68.42 |
| 100 grams per liter Nylar missible oil | 1500 times | 67.82 | 69.14 |
| 50 grams per liter lufenuron suspension agents | 1600 times | 65.76 | 70.26 |
| 22% metaflumizone suspending agent | 1100 times | 64.83 | 68.97 |
| 10% pyridalyl missible oil (autogamy) | 1000 times | 6847 | 6613 |
As can be seen from Table 12, fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridine worm
Comparison medicament is better than to pear sucker control effect after propyl ether compounding, the lasting period is long, to crop safety in experiment scope of medication.
13 fluorine lice sulfanilamide (SN) of table and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and its mixture
Prevent the wild cabbage diamondback moth test of pesticide effectiveness
As can be seen from Table 13, fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridine worm
Comparison medicament is better than to wild cabbage diamondback moth control effect after propyl ether compounding, the lasting period is long, pacifies to crop in experiment scope of medication
Entirely.
48~53 suspension emulsion of embodiment
Active ingredient B, solvent, emulsifier, dispersant are added together, make to be dissolved into homogeneous oil phase；By fluorine lice sulfanilamide (SN),
Water, antifreeze, antifoaming agent etc. mix, at uniform water phase；Under high velocity agitation, oil phase is added in water phase or adds oil phase
Enter water phase, obtained fluorine lice sulfanilamide (SN) active ingredient B suspension emulsion products after well dispersed, active ingredient B includes spiral shell worm ethyl ester, worm mite
Nitrile, Nylar, lufenuron, metaflumizone, pyridalyl are one such.
Specific formula is shown in Table 14.
14 embodiment of table, 48~53 each component and parts by weight
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, brand-new can be made
Agent.
15 fluorine lice sulfanilamide (SN) of table and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and its mixture
Prevent the eggplant thrips test of pesticide effectiveness
| Treatment agent | Preparation dosage | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 48 | 4 grams/acre | 97.37 | 98.15 |
| Embodiment 49 | 18 grams/acre | 99.25 | 98.36 |
| Embodiment 50 | 12 grams/acre | 98.74 | 98.82 |
| Embodiment 51 | 5 grams/acre | 98.23 | 99.24 |
| Embodiment 52 | 10 grams/acre | 98.59 | 98.47 |
| Embodiment 53 | 6 grams/acre | 99.28 | 99.36 |
| 5% fluorine lice sulfanilamide (SN) suspending agent (autogamy) | 25 grams/acre | 68.57 | 66.84 |
| 240 grams per liter spiral shell worm ethyl ester suspending agents | 25 grams/acre | 68.13 | 66.47 |
| 10% capillary suspending agent | 30 grams/acre | 69.02 | 67.15 |
| 100 grams per liter Nylar missible oil | 45 grams/acre | 58.64 | 68.29 |
| 50 grams per liter lufenuron suspension agents | 50 grams/acre | 59.35 | 69.01 |
| 22% metaflumizone suspending agent | 75 grams/acre | 67.61 | 68.56 |
| 10% pyridalyl missible oil (autogamy) | 60 grams/acre | 65.29 | 69.48 |
As can be seen from Table 15, fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridine worm
Comparison medicament is better than to eggplant thrips control effect after propyl ether compounding, the lasting period is long, to crop safety in experiment scope of medication.
54~59 aqueous emulsion of embodiment
Fluorine lice sulfanilamide (SN), active ingredient B, solvent and emulsifier are added together, make to be dissolved into homogeneous oil phase；By water, freeze proof
Agent, antifoaming agent etc. mix, at uniform water phase；Under high velocity agitation, oil phase is added in water phase or the oil phase is added to the aqueous phase,
Obtained fluorine lice sulfanilamide (SN) spiral shell worm ethyl ester aqueous emulsion product after well dispersed, active ingredient B includes spiral shell worm ethyl ester, capillary, pyrrole third
Ether, lufenuron, metaflumizone, pyridalyl are one such.
Specific formula is shown in Table 16.
16 embodiment of table, 54~59 each component and parts by weight
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, brand-new can be made
Agent.
17 fluorine lice sulfanilamide (SN) of table and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and its mixture
Prevent the rice leaf roller test of pesticide effectiveness
| Treatment agent | Preparation dosage | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 54 | 10 grams/acre | 98.76 | 99.58 |
| Embodiment 55 | 9 grams/acre | 99.24 | 98.76 |
| Embodiment 56 | 8 grams/acre | 97.35 | 98.81 |
| Embodiment 57 | 4 grams/acre | 98.48 | 99.25 |
| Embodiment 58 | 12 grams/acre | 99.37 | 97.37 |
| Embodiment 59 | 11 grams/acre | 98.49 | 98.74 |
| 5% fluorine lice sulfanilamide (SN) suspending agent (autogamy) | 23 grams/acre | 59.48 | 67.52 |
| 240 grams per liter spiral shell worm ethyl ester suspending agents | 27 grams/acre | 60.07 | 67.86 |
| 10% capillary suspending agent | 31 grams/acre | 58.51 | 66.47 |
| 100 grams per liter Nylar missible oil | 48 grams/acre | 57.69 | 66.03 |
| 50 grams per liter lufenuron suspension agents | 52 grams/acre | 59.78 | 68.35 |
| 22% metaflumizone suspending agent | 78 grams/acre | 58.24 | 67.41 |
| 10% pyridalyl missible oil (autogamy) | 64 grams/acre | 64.25 | 68.68 |
As can be seen from Table 17, fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridine worm
Comparison medicament is better than to rice leaf roller control effect after propyl ether compounding, the lasting period is long, pacifies to crop in experiment scope of medication
Entirely.
60~65 microemulsion of embodiment
Fluorine lice sulfanilamide (SN), active ingredient B, solvent, emulsifier are sufficiently mixed into the oil phase of homogeneous transparent, under stiring slowly
Deionized water is added, forms WO emulsion, then agitated heating, is allowed to rapid phase inversion into oil-in-water type, is cooled to room temperature
Balance is made up to, through filtering the cyprodinil hexaconazole microemulsion product for being made stable, active ingredient B includes spiral shell worm second
Ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are one such.
Specific formula is shown in Table 18.
18 embodiment of table, 60~65 each component and parts by weight
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, brand-new can be made
Agent.
19 fluorine lice sulfanilamide (SN) of table and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and its mixture
Prevent the phyllocnistis citrella stainton test of pesticide effectiveness
As can be seen from Table 19, fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridine worm
Comparison medicament is better than to phyllocnistis citrella stainton control effect after propyl ether compounding, the lasting period is long, makees to target in experiment scope of medication
Object safety.
66~71 microcapsule suspending agent of example
Macromolecule cyst material addition PH conditioning agents are heated to certain temperature, thick liquid is obtained, is then diluted with water,
Stable prepolymer solution is formed, fluorine lice sulfanilamide (SN), active ingredient B are dissolved into organic solvent, are then added in prepolymer solution,
It is added emulsifier, surfactant, and fully shear agitation is dispersed into superfine microgranular, adds PH conditioning agents, and heat up,
Catalyzed polycondensation forms the firm microcapsules for being not easy to permeate, and micro-capsule suspension of the present invention is made, active ingredient B includes spiral shell
Worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are one such.
Specific formula is shown in Table 20.
20 embodiment of table, 66~71 each component and parts by weight
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, brand-new can be made
Agent.
21 fluorine lice sulfanilamide (SN) of table and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and its mixture
Prevent the cotton boll worm test of pesticide effectiveness
| Treatment agent | Preparation dosage | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 66 | 7 grams/acre | 99.85 | 98.79 |
| Embodiment 67 | 8 grams/acre | 98.92 | 98.24 |
| Embodiment 68 | 15 grams/acre | 99.07 | 99.36 |
| Embodiment 69 | 4 grams/acre | 97.46 | 98.65 |
| Embodiment 70 | 6 grams/acre | 98.61 | 98.43 |
| Embodiment 71 | 20 grams/acre | 97.98 | 99.02 |
| 5% fluorine lice sulfanilamide (SN) suspending agent (autogamy) | 28 grams/acre | 69.69 | 67.58 |
| 240 grams per liter spiral shell worm ethyl ester suspending agents | 24 grams/acre | 68.45 | 96.82 |
| 10% capillary suspending agent | 33 grams/acre | 68.76 | 67.17 |
| 100 grams per liter Nylar missible oil | 40 grams/acre | 67.58 | 66.24 |
| 50 grams per liter lufenuron suspension agents | 45 grams/acre | 58.52 | 68.73 |
| 22% metaflumizone suspending agent | 70 grams/acre | 59.24 | 69.05 |
| 10% pyridalyl missible oil (autogamy) | 65 grams/acre | 60.17 | 68.26 |
As can be seen from Table 21, fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridine worm
Comparison medicament is better than to cotton boll worm control effect after propyl ether compounding, the lasting period is long, in experiment scope of medication to crop safety.
72~77 microcapsule suspending agents of example-suspending agent
Using interfacial polymerization, active ingredient B, macromolecule cyst material, organic solvent in above-mentioned formula are mixed, made molten
Solution be added in a shear condition at homogeneous oil phase, by oil phase containing emulsifier, pH adjusting agent aqueous phase solution in, two kinds of materials
It reacts in oil-water interfaces, surrounds the droplet formation high score ascus wall containing chemical substance, it is outstanding that active ingredient B microcapsules are made
Floating agent.Surfactant, antifoaming agent, thickener, antifreeze are uniformly mixed by high speed shear, fluorine lice sulfanilamide (SN) active compound is added,
Ball milling 2~3 hours in the ball mill make diameter of particle all at 5 μm hereinafter, fluorine lice sulfanilamide (SN) suspending agent is made, then will dissolve
Stable fluorine lice sulfanilamide (SN) suspending agent is added in the aqueous phase solution of active ingredient B micro-capsule suspensions in water, and the present invention is made
The well dispersed microcapsule suspension-suspendinagent agent product of composition, active ingredient B include spiral shell worm ethyl ester, capillary, Nylar, Acarus tritici
Urea, metaflumizone, pyridalyl are one such.
Specific formula is shown in Table 22.
22 embodiment of table, 72~77 each component and parts by weight
23 fluorine lice sulfanilamide (SN) of table and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and its mixture
Prevent the Chinese cabbage cabbage caterpillar test of pesticide effectiveness
| Treatment agent | Preparation dosage | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 72 | 12 grams/acre | 98.64 | 98.71 |
| Embodiment 73 | 14 grams/acre | 99.59 | 98.82 |
| Embodiment 74 | 8 grams/acre | 98.13 | 99.46 |
| Embodiment 75 | 15 grams/acre | 97.95 | 99.27 |
| Embodiment 76 | 5 grams/acre | 98.41 | 98.35 |
| Embodiment 77 | 4 grams/acre | 97.26 | 97.53 |
| 5% fluorine lice sulfanilamide (SN) suspending agent (autogamy) | 25 grams/acre | 68.37 | 66.85 |
| 240 grams per liter spiral shell worm ethyl ester suspending agents | 25 grams/acre | 69.15 | 67.24 |
| 10% capillary suspending agent | 30 grams/acre | 68.74 | 67.02 |
| 100 grams per liter Nylar missible oil | 45 grams/acre | 87.86 | 66.37 |
| 50 grams per liter lufenuron suspension agents | 50 grams/acre | 67.18 | 67.45 |
| 22% metaflumizone suspending agent | 75 grams/acre | 68.29 | 68.36 |
| 10% pyridalyl missible oil (autogamy) | 60 grams/acre | 65.31 | 69.27 |
As can be seen from Table 23, fluorine lice sulfanilamide (SN) and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridine worm
Comparison medicament is better than to Chinese cabbage cabbage caterpillar control effect after propyl ether compounding, the lasting period is long, pacifies to crop in experiment scope of medication
Entirely.
The embodiment of the present invention is the method being combined using Toxicity Determination and field trial.First pass through indoor virulence survey
It is fixed, the co-toxicity coefficient (CTC) after two kinds of medicaments compound by a certain percentage is defined, CTC ＜ 80 are antagonism, 80≤CTC≤120
For summation action, CTC ＞ 120 are synergistic effect, on this basis, then carry out field trial.
Test method：The mother liquor of each mixed agent is diluted to five series concentrations respectively when experiment, is respectively placed in beaker
It is spare.Using the first leaching leaf method that is followed by worm, by not in contact with the blade of the same size of any medicament in the liquid configured
It takes out, naturally dry, is put into insect box after immersion 5s, then connect for trying larva, raised under the conditions of 25 DEG C, often handle 3
Secondary repetition, it is 50 often to repeat test worm number used, while setting blank control, checks dead borer population in 72h, calculates the death rate and correction
The death rate acquires virulence regression equation and calculates LC50Value.If compareing the death rate is more than 10%, it is considered as invalid experiment.It calculates public
Formula is as follows：
Pest corrected mortality is converted into probit value (y), concentration for the treatment of (μ g/ml) is converted into logarithm (x), with minimum
Square law obtains virulence regression equation, and thus calculates the value of each medicament.Total poison system is calculated according to the abundant equations of Sun Yun
Number CTC.Calculation formula is following (using fluorine lice sulfanilamide (SN) as standard agent, toxicity index 100)：
TI × P of the theoretical toxicity index (TTI) of M=fluorine lice sulfanilamide (SN)Fluorine lice sulfanilamide (SN)TI × P of+effective active composition BEffective active composition B
In formula：M is the mixture of different ratio
PEffective active composition BFor effective active composition B shared ratios in the composition
PFluorine lice sulfanilamide (SN)For fluorine lice sulfanilamide (SN) shared ratio in the composition
B is selected from any one following compound：Spiral shell worm ethyl ester, capillary, lufenuron, Nylar, metaflumizone, pyridine worm third
One of ether is planted.
Application Example two：For trying pest：Rice hoppers.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Having for fluorine lice sulfanilamide (SN), spiral shell worm ethyl ester active compound and the two different ratio mixture is determined by pilot study
Imitate lethasl concentration range.
Toxicity test result one
24 fluorine lice sulfanilamide (SN) of table is with spiral shell worm ethyl ester different ratio to the toxicity test of rice hoppers
As shown in Table 24, fluorine lice sulfanilamide (SN) prevents the proportioning of rice hoppers in 70 ︰ 1 to 1 with spiral shell worm ethyl ester compounding：When 70,
Co-toxicity coefficient is all higher than 120, illustrates the two 70：1 to 1：Mixture shows synergistic effect in 70 ranges, especially when fluorine lice
The proportioning of sulfanilamide (SN) and spiral shell worm ethyl ester is 10：1 to 1：When 20, synergistic effect becomes apparent protrusion, wherein when fluorine lice sulfanilamide (SN) and spiral shell worm
Co-toxicity coefficient is maximum when ethyl ester weight ratio is 1 ︰ 6, and synergistic effect is the most apparent, finds simultaneously, and fluorine lice sulfanilamide (SN) is matched with spiral shell worm ethyl ester
Than 10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、
1：10、1：11、1：12、1：13、1：14、1：15、1：16、1：17、1：18、1：19、1：Compounding is to planthopper, aphid, wood when 20
Lice, aleyrodid, mealybug, scale insect, thrips, cabbage caterpillar, prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf mining
Moth, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer also have good synergistic effect, altogether poison system
Number is all higher than 200.
Application Example three：For trying pest：Apple aphid.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：The effective of fluorine lice sulfanilamide (SN), capillary active compound and the two different ratio mixture is determined by pilot study
Lethasl concentration range.
Toxicity test result two
25 fluorine lice sulfanilamide (SN) of table is with capillary different ratio to the toxicity test of apple aphid
As shown in Table 25, fluorine lice sulfanilamide (SN) prevents the proportioning of apple aphid in 70 ︰ 1 to 1 with capillary compounding：It is malicious altogether when 70
Coefficient is all higher than 120, illustrates the two 70：Mixture shows synergistic effect in 1 to 1 ︰, 70 ranges, especially when fluorine lice sulfanilamide (SN)
It must be matched 10 with capillary：1 to 1：When 20, synergistic effect becomes apparent protrusion, is tested through applicant, when fluorine lice sulfanilamide (SN) and worm
Co-toxicity coefficient is maximum when mite nitrile weight ratio is 1 ︰ 6, and synergistic effect is the most apparent.It finds simultaneously, fluorine lice sulfanilamide (SN) is matched with capillary
10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：6、1：7、1：8、1：9、1：10、
1：11、1：12、1：13、1：14、1：16、1：17、1：18、1：19、1：Compounding is to planthopper, aphid, wood louse, aleyrodid, powder when 20
It is a red-spotted lizard, scale insect, thrips, cabbage caterpillar, prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf miner, blister mite, small
Also there is good synergistic effect, co-toxicity coefficient to be all higher than 200 for leaf roller, black cutworm, rice leaf roller, rice-stem borer.
Application Example four：For trying pest：Pear sucker.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：The effective of fluorine lice sulfanilamide (SN), Nylar active compound and the two different ratio mixture is determined by pilot study
Lethasl concentration range.
Toxicity test result three
26 fluorine lice sulfanilamide (SN) of table is with Nylar different ratio to the toxicity test of pear sucker
As shown in Table 26, fluorine lice sulfanilamide (SN) prevents the proportioning of pear sucker in 70 ︰ 1 to 1 with pyriproxyfen compound：When 70, poison is altogether
Number is all higher than 120, illustrates the two 70：Mixture shows synergistic effect in 1 to 1 ︰, 70 ranges, especially when fluorine lice sulfanilamide (SN) with
Nylar must be matched 10：1 to 1：When 20, synergistic effect becomes apparent protrusion, is tested through applicant, when fluorine lice sulfanilamide (SN) and pyrrole third
Co-toxicity coefficient is maximum when ether weight ratio is 1 ︰ 6, and synergistic effect is the most apparent.It finds simultaneously, fluorine lice sulfanilamide (SN) is matched with Nylar
10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：
10、1：11、1：12、1：13、1：14、1：15、1：16、1：17、1：18、1：19、1：When 20 compounding to planthopper, aphid, wood louse,
Aleyrodid, mealybug, scale insect, thrips, cabbage caterpillar, prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf miner, rust
Tick, olethreutid, black cutworm, rice leaf roller, rice-stem borer also have good synergistic effect, co-toxicity coefficient big
In 200.
Application Example five：For trying pest：Rice trialeurodes vaporariorum.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Determine fluorine lice sulfanilamide (SN) in the effective of lufenuron active compound and the two different ratio mixture by pilot study
Lethasl concentration range.
Toxicity test result four
27 fluorine lice sulfanilamide (SN) of table is with lufenuron different ratio to the toxicity test of rice trialeurodes vaporariorum
As shown in Table 27, fluorine lice sulfanilamide (SN) prevents the proportioning of rice trialeurodes vaporariorum in 70 ︰ 1 to 1 with lufenuron compounding：When 70, altogether
Malicious coefficient is all higher than 120, illustrates the two 70：Mixture shows synergistic effect in 1 to 1 ︰, 70 ranges, especially when fluorine lice sulphur
Amine must be matched with lufenuron 10：1 to 1：When 10, synergistic effect becomes apparent protrusion, is tested through applicant, when fluorine lice sulfanilamide (SN) with
Co-toxicity coefficient is maximum when lufenuron weight ratio is 1 ︰ 2, and synergistic effect is the most apparent.It finds simultaneously, fluorine lice sulfanilamide (SN) is matched with lufenuron
Than 10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、
1：Compounding is to planthopper, aphid, wood louse, aleyrodid, mealybug, scale insect, thrips, cabbage caterpillar, prodenia litura, diamondback moth, sweet tea when 10
Dish noctuid, bean-pod borer, bollworm, leaf miner, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer
With good synergistic effect, co-toxicity coefficient is all higher than 200.
Application Example five：For trying pest：Wild cabbage diamondback moth.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Having for fluorine lice sulfanilamide (SN) and metaflumizone active compound and the two different ratio mixture is determined by pilot study
Imitate lethasl concentration range.
Toxicity test result four
28 fluorine lice sulfanilamide (SN) of table is with metaflumizone different ratio to the toxicity test of wild cabbage diamondback moth
As shown in Table 28, fluorine lice sulfanilamide (SN) prevents the proportioning of wild cabbage diamondback moth in 70 ︰ 1 to 1 with metaflumizone compounding：When 70,
Co-toxicity coefficient is all higher than 120, illustrates the two 70：Mixture shows synergistic effect in 1 to 1 ︰, 70 ranges, especially when fluorine lice
Sulfanilamide (SN) must be matched with metaflumizone 10：1 to 1：When 30, synergistic effect becomes apparent protrusion, is tested through applicant, when fluorine lice sulphur
Co-toxicity coefficient is maximum when amine and metaflumizone weight ratio are 1 ︰ 10, and synergistic effect is the most apparent.It finds simultaneously, fluorine lice sulfanilamide (SN) and cyanogen
Fluorine worm hydrazone is matched 10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、
1：8、1：9、1：10、1：11、1：12、1：13、1：14、1：15、1：16、1：17、1：18、1：19、1：20、1:25、1:It is answered when 30
Match planthopper, aphid, wood louse, aleyrodid, mealybug, scale insect, thrips, cabbage caterpillar, prodenia litura, diamondback moth, beet armyworm, beans
Pod snout moth's larva, bollworm, leaf miner, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer also have good
Synergistic effect, co-toxicity coefficient are all higher than 200.
Application Example five：For trying pest：Cotton boll worm.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Having for fluorine lice sulfanilamide (SN) and pyridalyl active compound and the two different ratio mixture is determined by pilot study
Imitate lethasl concentration range.
Toxicity test result four
29 fluorine lice sulfanilamide (SN) of table is with pyridalyl different ratio to the toxicity test of cotton boll worm
As shown in Table 29, fluorine lice sulfanilamide (SN) prevents the proportioning of cotton boll worm in 70 ︰ 1 to 1 with pyridalyl compounding：When 70,
Co-toxicity coefficient is all higher than 120, illustrates the two 70：Mixture shows synergistic effect in 1 to 1 ︰, 70 ranges, especially when fluorine lice
Sulfanilamide (SN) must be matched with pyridalyl 10：1 to 1：When 20, synergistic effect becomes apparent protrusion, is tested through applicant, when fluorine lice sulphur
Co-toxicity coefficient is maximum when amine and pyridalyl weight ratio are 1 ︰ 6, and synergistic effect is the most apparent.It finds simultaneously, fluorine lice sulfanilamide (SN) and pyridine
Worm propyl ether is matched 10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、
1：8、1：9、1：10、1：11、1：12、1：13、1：14、1：15、1：16、1：17、1：18、1：19、1：When 20 compounding to planthopper,
Aphid, wood louse, aleyrodid, mealybug, scale insect, thrips, cabbage caterpillar, prodenia litura, diamondback moth, beet armyworm, bean-pod borer, cotton boll
Worm, leaf miner, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer also have good synergistic effect,
Co-toxicity coefficient is all higher than 200.
Claims (6)
1. a kind of Pesticidal combination of fluorine-containing lice sulfanilamide (SN), it is characterised in that：Contain active components A and active constituent B, active constituent
The weight ratio of A and active constituent B is 1 ︰, 70~70 ︰ 1, and the active components A is selected from fluorine lice sulfanilamide (SN), and active constituent B is selected from worm
One kind in mite nitrile, lufenuron, Nylar, metaflumizone, pyridalyl.
2. the Pesticidal combination of fluorine-containing lice sulfanilamide (SN) according to claim 1, it is characterised in that：Active components A with activity at
It is 1 ︰, 50~30 ︰ 1 to divide the weight ratio of B.
3. the Pesticidal combination of fluorine-containing lice sulfanilamide (SN) according to claim 2, feature exist
In：The weight ratio of fluorine lice sulfanilamide (SN) and capillary is 10 ︰, 1~1 ︰ 20；
The weight ratio of fluorine lice sulfanilamide (SN) and lufenuron is 10 ︰, 1~1 ︰ 10；
The weight ratio of fluorine lice sulfanilamide (SN) and Nylar is 10 ︰, 1~1 ︰ 20；
The weight ratio of fluorine lice sulfanilamide (SN) and metaflumizone is 10 ︰, 1~1 ︰ 30；
The weight ratio of fluorine lice sulfanilamide (SN) and pyridalyl is 10 ︰, 1~1 ︰ 20.
4. the Pesticidal combination of fluorine-containing lice sulfanilamide (SN) according to any one of claim 1 to 3, it is characterised in that：Composition
It is outstanding that wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-is made
Floating agent.
5. the Pesticidal combination of fluorine-containing lice sulfanilamide (SN) according to claim 4 is used to prevent the purposes of crop pest.
6. purposes according to claim 5, which is characterized in that the pest includes：Planthopper, aphid, wood louse, powder
Lice, mealybug, scale insect, thrips, cabbage caterpillar, prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf miner, rust wall
Lice, olethreutid, black cutworm, rice leaf roller, rice-stem borer.
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| CN104738038A (en) * | 2013-12-25 | 2015-07-01 | 南京华洲药业有限公司 | Composite insecticidal composition containing pyridalyl and chromafenozide and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4087525A (en) * | 1975-12-08 | 1978-05-02 | American Cyanamid Company | Pentadienone hydrazones as insecticides |
| US4921696A (en) * | 1982-03-25 | 1990-05-01 | The United States Of America As Represented By The Secretary Of Agriculture | Method for the control of insects |
| CN1858038A (en) * | 2006-06-09 | 2006-11-08 | 中国科学院上海有机化学研究所 | Oxo fluoroalkyl sulfamide compound and its preparing method and use |
-
2012
- 2012-04-17 CN CN201210112747.7A patent/CN103371157B/en not_active Expired - Fee Related
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4087525A (en) * | 1975-12-08 | 1978-05-02 | American Cyanamid Company | Pentadienone hydrazones as insecticides |
| US4921696A (en) * | 1982-03-25 | 1990-05-01 | The United States Of America As Represented By The Secretary Of Agriculture | Method for the control of insects |
| CN1858038A (en) * | 2006-06-09 | 2006-11-08 | 中国科学院上海有机化学研究所 | Oxo fluoroalkyl sulfamide compound and its preparing method and use |
Non-Patent Citations (2)
| Title |
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| "10%SIOC-I-002水乳剂配方研究";沈娟等;《上海化工》;20110430;第36卷(第04期);第6-9页 * |
| "氟虱磺胺(SIOC-I-002)对水稻褐飞虱的生物活性及田间防效";付群梅 等;《植物保护学报》;20120228;第39卷(第1期);第95-96页 * |
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