CN102369937A - Spirotetramat and fenvalerate containing pesticide composite - Google Patents
Spirotetramat and fenvalerate containing pesticide composite Download PDFInfo
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- CN102369937A CN102369937A CN2011103186418A CN201110318641A CN102369937A CN 102369937 A CN102369937 A CN 102369937A CN 2011103186418 A CN2011103186418 A CN 2011103186418A CN 201110318641 A CN201110318641 A CN 201110318641A CN 102369937 A CN102369937 A CN 102369937A
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- spiral shell
- ethyl ester
- shell worm
- sumicidin
- worm ethyl
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Abstract
The invention discloses a spirotetramat and fenvalerate containing pesticide composite, which is characterized in that in the pesticide composite, the pbw (parts-by-weight) ratio of spirotetramat to fenvalerate is (1:15)-(15:1). The pesticide composite disclosed by the invention has an obvious synergistic effect, thereby reducing the dosage of pesticides, reducing the cost for pesticide application, saving manpower and material resources, and reducing the environmental pollutions caused by the pesticides; and the pesticide composite is suitable to be used for preventing and controlling pests with piercing-sucking mouth parts.
Description
Technical field
The present invention relates to a kind of composition pesticide, specifically a kind of composition pesticide that contains spiral shell worm ethyl ester and sumicidin.
Background technology
Because the long-term single use of desinsection list agent causes the enhancing of pest resistance, control efficiency is affected, and how to guarantee that the continuity of existing agricultural chemicals is used, and reduces the pesticide producing use cost, is that the potential value of existing agricultural chemicals is a convenient way.Constantly can solve the resistance problem of insect through reasonably composite, but also can improve preventive effect agricultural chemicals.
Spiral shell worm ethyl ester, English spirotetramat by name is the tetronic acid compounds, the insecticidal/acaricidal agent spiral shell mite ester (spirodiclofen) of Bayer company and Spiromesifen (spiromesifen) belong to similar compound.Spiral shell worm ethyl ester has unique function Characteristics, is unique so far two-way interior insecticide of inhaling conductive performance that has.This compound can upwards move down in the whole plants body, arrives at blade face and bark, thereby control reaches the corticole insect of fruit as on romaine lettuce and the Chinese cabbage internal lobe.The interior absorption of this uniqueness can be protected newborn stem, leaf and root, prevents that ovum of insect and larva from causing harm.Its another characteristics are that the lasting period is long, and the effective control that reached for 8 weeks can be provided.Can effectively prevent and treat various suckings pest, like aphid, thrips, wood louse, mealybug, aleyrodid and scale insect etc.Applicable chief crop comprises cotton, soybean, oranges and tangerines, tropical fruit tree, nut, grape, lupulus, potato and vegetables etc.Research shows that it has good selectivity to important beneficial insect such as ladybug, syrphus fly and parasitic wasp.
Sumicidin, English by name fenvalerate, insecticidal spectrum is wide, to the natural enemy non-selectivity, to tag and stomach poison function is main, does not inhale and fumigation action in not having.Respond well to lepidopterous larvae.Insects such as Homoptera, orthoptera, Semiptera also there is effect preferably, but invalid to mite.Be applicable to crops such as cotton, fruit tree, vegetables, soybean, wheat.
Being mixed of different pesticide species is the common methods of the agriculture resistant insect of control.Through the formulation of pesticide screening, filter out rational prescription, can effectively improve actual control efficiency, reduce dosage, reduce cost, delay the generation of pest resistance to insecticide, prolong the service life of medicament, be the important means of the insect comprehensive regulation.The control sucking pest that is mixed of spiral shell worm ethyl ester and sumicidin does not still have report at present and uses.
Summary of the invention
It is long to the purpose of this invention is to provide a kind of good disinsection effect and lasting period, helps the composition pesticide that contains spiral shell worm ethyl ester and sumicidin of the insect comprehensive regulation.
For addressing the above problem, the technical scheme that the present invention adopted is: a kind of composition pesticide that contains spiral shell worm ethyl ester and sumicidin, the ratio of weight and number of spiral shell worm ethyl ester and sumicidin are 1:15～15:1.
Described composition pesticide can be selected suitable auxiliary agent for use according to well known to a person skilled in the art method, is mixed with the application forms that suitable agricultural such as suspending agent, missible oil, microemulsion, aqueous emulsion is used.
When being processed into suspending agent, the insecticides adjuvant of use is following: one or more among emulsifier such as Nongru-700 # (alkyl phenol formaldehyde resin polyoxyethylene ether), farming breast 2201, Tween-60 # (sorbitan monostearate polyoxyethylene groups ether), the agricultural newborn 600# (triphen ethyl phenol polyoxyethylene groups ether phosphate).In wetting agent such as alkylphenol-polyethenoxy base ether phosphate, alkylphenol-polyethenoxy base ether formaldehyde condensation products phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, the naphthalene sulfonate one or more.In dispersant such as polycarboxylate, sodium lignin sulfonate, the alkylnaphthalene sulfonate one or more.In thickener such as xanthans, polyvinyl alcohol, bentonite, the aluminium-magnesium silicate one or more.In antifreezing agent such as ethylene glycol, propane diols, glycerine, urea, the sodium chloride one or more.In stabilizing agent such as triphenyl phosphite, the epoxychloropropane one or more.Surplus is a deionized water.
When being processed into missible oil, use insecticides adjuvant following: one or more in the newborn 500# of emulsifier such as farming (calcium dodecyl benzene sulfonate), Span-60# (sorbitan monostearate), Nongru-700 # (alkyl phenol formaldehyde resin polyoxyethylene ether), agricultural newborn 2201#, Tween-60 # (sorbitan monostearate polyoxyethylene groups ether), TX-10 (octylphenol polyethylene vinethene), agricultural newborn 1601#, agricultural newborn 600#, the farming breast 400.In solvent such as xylol, solvent naphtha (S-150, S-180, S-200), toluene, methyl alcohol, dimethyl formamide, cyclohexanone, the diesel oil one or more.In stabilizing agent such as triphenyl phosphite, the epoxy chlorobenzene alkane one or more.
When being processed into microemulsion, the insecticides adjuvant of use is following: one or more among the newborn 500# of emulsifier such as farming (calcium dodecyl benzene sulfonate), Nongru-700 # (alkyl phenol formaldehyde resin polyoxyethylene ether), agricultural newborn 2201#, Arlacel-60 # (sorbitan monostearate), Tween-60 # (sorbitan monostearate polyoxyethylene groups ether), farming breast 1601 (triphen ethyl-phenol polyoxyethylene polyoxypropylene block polymers), the agricultural newborn 600#.In assistant for emulsifying agent such as methyl alcohol, acetone, cyclohexanone, the ethanol one or more.In solvent such as xylol, toluene, the solvent naphtha (S-150, S-180, S-200) one or more.Stabilizing agent is like, one or more in triphenyl phosphite, epoxychloropropane, the aceticanhydride.Surplus is a deionized water.
When being processed into aqueous emulsion, the insecticides adjuvant of use is following: one or more among the newborn 600# phosphate of emulsifier such as farming (triphen ethyl-phenol polyoxyethylene ether phosphate), Nongru-700 # (alkyl phenol formaldehyde resin polyoxyethylene ether), farming breast 2201, Arlacel-60 # (sorbitan monostearate), Tween-60 # (sorbitan monostearate polyoxyethylene groups ether), agricultural newborn 1601# (triphen ethyl-phenol polyoxyethylene polyoxypropylene block polymer), agricultural newborn 600#, the agricultural newborn 400#.Solvent such as xylol, toluene, solvent naphtha (S-120, S-180, S-200) one or more.In stabilizing agent such as triphenyl phosphite, the epoxychloropropane one or more.In antifreezing agent such as ethylene glycol, propane diols, glycerine, urea, the sodium chloride one or more.Thickener as, in xanthans, polyvinyl alcohol, bentonite, the aluminium-magnesium silicate one or more.In preservative such as formaldehyde, benzoic acid, the Sodium Benzoate one or more, water is deionized water.
Described composition pesticide is used to prevent and treat sucking pest, like aphid, thrips, wood louse, aleyrodid and scale insect etc.
Composition pesticide described in the invention can the finished product preparation form provide, and promptly each material mixes in the composition, and the composition of composition also can single agent form provide, and directly in bucket or jar, mixes before the use, is diluted to desired concn then.
Composition pesticide provided by the invention adopts the method for spraying to use usually, also can adopt agricultural to go up other operation techniques of using as required.
Compared with prior art, the present invention has following beneficial effect.
1, composition pesticide provided by the invention; In certain ratio range, show obvious synergistic effect; The control efficiency of composition is significantly improved than single agent, has reduced using dosage, dispenser recruitment and the cost of agricultural chemicals simultaneously, has also reduced influence and residue of pesticide to environment.
2, the active ingredient mechanism of action of composition pesticide provided by the invention has nothing in common with each other, and the application of composition can delay or overcome the generation of pest resistance to insecticide, prolongs the service life of medicament, helps the comprehensive regulation of insect.
3, Pesticidal combination provided by the invention is to crops safety.
Embodiment
In order to make the object of the invention, technical scheme and advantage more short and sweet, the present invention describes with following specific embodiment, but the present invention only limits to these examples absolutely not.The following stated is merely the present invention embodiment preferably, only is used to describe the present invention, can not be interpreted as the restriction to scope of the present invention.Should be pointed out that all any modifications of within spirit of the present invention and principle, being made, be equal to replacement and improvement etc., all should be included within protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with accompanying claims.
Below specify through different FORMULATION EXAMPLE and field practical application embodiment.In following examples, unless otherwise indicated, all percentages all are weight percentage.
FORMULATION EXAMPLE1: take by weighing 10% spiral shell worm ethyl ester, 2% sumicidin, 5% farming breast, 600,9% farming breast, 2201,3% lignosulfonates, 0.2% xanthans, 2% ethylene glycol, 0.5% silicone defoaming agent, add deionized water and mend to 100%.After the above-mentioned raw materials mixing, emulsification makes 12% spiral shell worm ethyl ester sumicidin suspending agent through high speed shear.
FORMULATION EXAMPLE2: take by weighing 15% spiral shell worm ethyl ester, 1% sumicidin, 5% Nongru-700 # (alkyl phenol formaldehyde resin polyoxyethylene ether), 2% Tween-60 # (sorbitan monostearate polyoxyethylene groups ether), 2% alkylphenol-polyethenoxy base ether formaldehyde condensation products phosphate, 3% propane diols, 0.2% xanthans, add deionized water and mend to 100%.After the above-mentioned raw materials mixing, emulsification makes 16% spiral shell worm ethyl ester sumicidin suspending agent through high speed shear.
FORMULATION EXAMPLE3: taking by weighing 10% spiral shell worm ethyl ester, 2% sumicidin, 7% agricultural newborn 500# (calcium dodecyl benzene sulfonate), 3%Span-60# (sorbitan monostearate), 5% agricultural newborn 2201#, 2% triphenyl phosphite, surplus is xylol.Above-mentioned raw materials is mixed back abundant dissolving mixing make 12% spiral shell worm ethyl ester fenvalerate missible oil.
FORMULATION EXAMPLE4: taking by weighing 15% spiral shell worm ethyl ester, 1% sumicidin, 4% Nongru-700 # (alkyl phenol formaldehyde resin polyoxyethylene ether), 6% agricultural newborn 2201#, 2% agricultural newborn 1601#, 1.5% triphenyl phosphite, surplus is xylol.Above-mentioned raw materials is mixed the abundant mixing in back make 16% spiral shell worm ethyl ester fenvalerate missible oil.
FORMULATION EXAMPLE5: take by weighing 10% spiral shell worm ethyl ester, 2% sumicidin, 6% agricultural newborn 500# (calcium dodecyl benzene sulfonate), 2% agricultural newborn 2201#, 3% agricultural newborn 600#, 1% methyl alcohol, 6% xylol, 1.2% epoxychloropropane, 0.4% aceticanhydride, deionized water and mend, above-mentioned raw materials is fully dissolved mixing make 12% spiral shell worm ethyl ester sumicidin microemulsion to 100%.
FORMULATION EXAMPLE6: take by weighing 15% spiral shell worm ethyl ester, 1% sumicidin, 3% agricultural newborn 2201#, 2% Arlacel-60 # (sorbitan monostearate), 6% farming breast, 1601 (triphen ethyl-phenol polyoxyethylene polyoxypropylene block polymers), 1% acetone, 1% solvent naphtha S-150,0.8% triphenyl phosphite, deionized water is mended to 100%.Above-mentioned raw materials is fully dissolved mixing make 16% spiral shell worm ethyl ester sumicidin microemulsion.
FORMULATION EXAMPLE7: take by weighing 10% spiral shell worm ethyl ester, 2% sumicidin, 6% agricultural newborn 600# phosphate (triphen ethyl-phenol polyoxyethylene ether phosphate), 2% Tween-60 # (sorbitan monostearate polyoxyethylene groups ether), 3% agricultural newborn 600#, 8% xylol, 1% triphenyl phosphite, 2% ethylene glycol, 1.5% xanthans, 0.8% polyvinyl alcohol, 0.2% benzoic acid, deionized water and mend to 100%.Above-mentioned raw materials is fully dissolved the mixing shearing make 12% spiral shell worm ethyl ester fenvalerate aqueous emulsion.
FORMULATION EXAMPLE8: take by weighing 15% spiral shell worm ethyl ester, 1% sumicidin, 2% Tween-60 # (sorbitan monostearate polyoxyethylene groups ether), 6% agricultural newborn 1601# (triphen ethyl-phenol polyoxyethylene polyoxypropylene block polymer), 4% agricultural newborn 600#, 6% xylol, 1% solvent naphtha S-180,1.2% epoxychloropropane, 2% propane diols, xanthans, 0.8% Sodium Benzoate, deionized water and mend to 100%.Above-mentioned raw materials is fully dissolved mixing make 16% spiral shell worm ethyl ester fenvalerate aqueous emulsion.
Field efficacy embodiment1: horse peace food market carry out eggplant trialeurodes vaporariorum field control effectiveness test in August, 2010 in the Huizhou City, Guangdong Province with above-mentioned FORMULATION EXAMPLE 1 (12% spiral shell worm ethyl ester sumicidin suspending agent).In the test, 12% spiral shell worm ethyl ester sumicidin suspending agent adopts 750,1000,2000 times of liquid even spraying, with 240 4000 times of liquid of grams per liter spiral shell worm ethyl ester suspending agent and 1000 times of liquid of 20% fenvalerate missible oil as the contrast medicament.Investigation insect population radix before the dispenser, 1d, 3d, 7d, 15d, 30d investigate residual insect population number respectively behind the medicine.Five point samplings are adopted in investigation, five leaf investigation records of each some picked at random.Control efficiency computational methods: control efficiency (%)=(1-CK
1* Pt
1/ CK
2* Pt
2) * 100.Wherein: CK
1Represent the preceding insect population number of check plot medicine, CK
2Represent insect population number behind the medicine of check plot, Pt
1Represent the preceding insect population number of treatment region medicine, Pt
2Represent insect population number behind the treatment region medicine.
Result of the test is seen table 1.Can find out from result of the test; Spiral shell worm ethyl ester of the present invention and sumicidin composition pesticide are outstanding to eggplant trialeurodes vaporariorum control efficiency; 3 days preventive effects are more than 86% behind the medicine, and composition still is that the persistence of drug effect all has significant improvement than single agent from quick-acting.Through to 7 days preventive effect analysis behind the medicine, it is remarkable to handle differences, and there are significant difference in the preventive effect and the composition of single agent.Simultaneously, medicament is to eggplant safety, to not influence of natural enemy in the process of the test.It is a kind of pesticide species that is worth of widely use.
Table 1,12% spiral shell worm ethyl ester sumicidin suspending agent control eggplant trialeurodes vaporariorum result of the test.
Field efficacy embodiment 2: Maoming City carries out cowpea thrips field control effectiveness test in Guangdong Province in June, 2010 with above-mentioned FORMULATION EXAMPLE 4 (16% spiral shell worm ethyl ester fenvalerate missible oil).In the test, 16% spiral shell worm ethyl ester fenvalerate missible oil adopts 1000,1500,2000 times of liquid even spraying, with 240 4000 times of liquid of grams per liter spiral shell worm ethyl ester suspending agent and 1000 times of liquid of 20% fenvalerate missible oil as the contrast medicament.Investigation insect population radix before the dispenser, 1d, 3d, 7d, 15d, 30d investigate residual insect population number respectively behind the medicine.Five point samplings are adopted in investigation, five leaf investigation records of each some picked at random.Control efficiency computational methods: control efficiency (%)=(1-CK
1* Pt
1/ CK
2* Pt
2) * 100.Wherein: CK
1Represent the preceding insect population number of check plot medicine, CK
2Represent insect population number behind the medicine of check plot, Pt
1Represent the preceding insect population number of treatment region medicine, Pt
2Represent insect population number behind the treatment region medicine.
Table 2,16% spiral shell worm ethyl ester fenvalerate missible oil control cowpea thrips result of the test.
Result of the test is seen table 2.Can find out that from result of the test spiral shell worm ethyl ester of the present invention and sumicidin composition pesticide are outstanding to cowpea thrips control efficiency, 3 days preventive effects are more than 87% behind the medicine, and composition still is that the persistence of drug effect all has significant improvement than single agent from quick-acting.Through to 7 days preventive effect analysis behind the medicine, it is remarkable to handle differences, and there are significant difference in the preventive effect and the composition of single agent.Simultaneously, medicament is to cowpea safety, to not influence of natural enemy in the process of the test.
Field efficacy embodiment 3: one oranges and tangerines garden carry out oranges and tangerines scale insect field control effectiveness test in October, 2010 in the Guangdong Huizhou city with above-mentioned FORMULATION EXAMPLE 5 (12% spiral shell worm ethyl ester sumicidin microemulsion).In the test, 12% spiral shell worm ethyl ester sumicidin microemulsion adopts 1500,2000,2500 times of liquid even spraying, with 240 4000 times of liquid of grams per liter spiral shell worm ethyl ester suspending agent and 2000 times of liquid of 20% fenvalerate missible oil as the contrast medicament.Investigation insect population radix before the dispenser, 1d, 3d, 7d, 15d, 30d investigate residual insect population number respectively behind the medicine.Five point samplings are adopted in investigation, five leaf investigation records of each some picked at random.Control efficiency computational methods: control efficiency (%)=(1-CK
1* Pt
1/ CK
2* Pt
2) * 100.Wherein: CK
1Represent the preceding insect population number of check plot medicine.CK
2Represent insect population number behind the medicine of check plot.Pt
1Represent the preceding insect population number of treatment region medicine, Pt
2Represent insect population number behind the treatment region medicine.
Table 3,12% spiral shell worm ethyl ester sumicidin microemulsion control oranges and tangerines scale insect result of the test.
Result of the test is seen table 3.Can find out from result of the test; Spiral shell worm ethyl ester of the present invention and sumicidin composition pesticide are outstanding to oranges and tangerines scale insect control efficiency; 7 days preventive effects are more than 86% behind the medicine, and composition still is that the persistence of drug effect all has significant improvement than single agent from quick-acting.Through to 7 days preventive effect analysis behind the medicine, it is remarkable to handle differences, and there are significant difference in the preventive effect and the composition of single agent.Simultaneously, medicament is to oranges and tangerines safety, to not influence of natural enemy in the process of the test.
Field efficacy embodiment 4: one food market save melon Bemisia tabaci field control effectiveness test in June, 2010 in the Nanning with the foregoing description preparation 8 (16% spiral shell worm ethyl ester fenvalerate aqueous emulsion).In the test, 16% spiral shell worm ethyl ester sumicidin water and milk adopts 1000,1500,2000 times of liquid even spraying, with 240 4000 times of liquid of grams per liter spiral shell worm ethyl ester suspending agent and 1000 times of liquid of 20% fenvalerate missible oil as contrast.Five point samplings are adopted in investigation, five leaf investigation records of each some picked at random.Control efficiency computational methods: control efficiency (%)=(1-CK
1* Pt
1/ CK
2* Pt
2) * 100.Wherein: CK
1Represent the preceding insect population number of check plot medicine, CK
2Represent insect population number behind the medicine of check plot, Pt
1Represent the preceding insect population number of treatment region medicine, Pt
2Represent insect population number behind the treatment region medicine.
Table 4,16% spiral shell worm ethyl ester fenvalerate aqueous emulsion control joint melon Bemisia tabaci result of the test.
Result of the test is seen table 4.Can find out from result of the test; Spiral shell worm ethyl ester of the present invention and sumicidin composition pesticide are outstanding to joint melon Bemisia tabaci control efficiency; 3 days preventive effects are more than 84% behind the medicine, and composition still is that the persistence of drug effect all has significant improvement than single agent from quick-acting.Through to 7 days preventive effect analysis behind the medicine, it is remarkable to handle differences, and there are significant difference in the preventive effect and the composition of single agent.Simultaneously, medicament is to joint melon safety, to not influence of natural enemy in the process of the test.
In sum; Composition pesticide of the present invention is very outstanding to control sucking pest effect; The duration of its desinsection quick-acting, drug effect and integrated control effect all obviously are better than single agent, and no poisoning produces in the use, also is safe to natural enemy; The safety requirements that meets pesticidal preparations is a kind of composition pesticide that is worth of widely use.
Claims (5)
1. composition pesticide that contains spiral shell worm ethyl ester and sumicidin, it is characterized in that: first active substance is a spiral shell worm ethyl ester, and second active substance is a sumicidin.
2. a kind of composition pesticide that contains spiral shell worm ethyl ester and sumicidin according to claim 1 is characterized in that: the ratio of weight and number of first active substance and second active substance is 1:15～15:1.
3. a kind of composition pesticide that contains spiral shell worm ethyl ester and sumicidin according to claim 1 and 2; It is characterized in that: described composition pesticide formulation is any one formulation that allows on the agricultural chemicals, and formulation has preferably: suspending agent, missible oil, microemulsion or aqueous emulsion.
4. a kind of composition pesticide that contains spiral shell worm ethyl ester and sumicidin according to claim 1 is characterized in that preventing and treating sucking pest.
5. a kind of composition pesticide that contains spiral shell worm ethyl ester and sumicidin according to claim 4 is characterized in that: described sucking pest is aphid, thrips, wood louse, aleyrodid or scale insect.
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| CN2011103186418A CN102369937A (en) | 2011-10-19 | 2011-10-19 | Spirotetramat and fenvalerate containing pesticide composite |
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|---|---|---|---|
| CN2011103186418A CN102369937A (en) | 2011-10-19 | 2011-10-19 | Spirotetramat and fenvalerate containing pesticide composite |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103250715A (en) * | 2012-02-21 | 2013-08-21 | 陕西美邦农药有限公司 | Insecticidal composition comprising spirotetramat and pyrethroid |
| CN103907601A (en) * | 2014-04-14 | 2014-07-09 | 武汉新联大生物有限公司 | Acaricide for treating sarcoptes suis |
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| CN1692099A (en) * | 2002-07-11 | 2005-11-02 | 拜尔农作物科学股份公司 | Cis-alkoxy-substituted spirocyclic 1-h-pyrrolidine-2,4-dione derivatives serving as pesticides |
| CN101489387A (en) * | 2006-07-11 | 2009-07-22 | 拜尔农作物科学股份公司 | Active ingredient combinations with insecticidal and acaricidal properties |
| CN101951761A (en) * | 2008-02-25 | 2011-01-19 | 拜尔农作物科学股份公司 | Oil-suspending agent |
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2011
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1692099A (en) * | 2002-07-11 | 2005-11-02 | 拜尔农作物科学股份公司 | Cis-alkoxy-substituted spirocyclic 1-h-pyrrolidine-2,4-dione derivatives serving as pesticides |
| CN101489387A (en) * | 2006-07-11 | 2009-07-22 | 拜尔农作物科学股份公司 | Active ingredient combinations with insecticidal and acaricidal properties |
| CN101951761A (en) * | 2008-02-25 | 2011-01-19 | 拜尔农作物科学股份公司 | Oil-suspending agent |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103250715A (en) * | 2012-02-21 | 2013-08-21 | 陕西美邦农药有限公司 | Insecticidal composition comprising spirotetramat and pyrethroid |
| CN103907601A (en) * | 2014-04-14 | 2014-07-09 | 武汉新联大生物有限公司 | Acaricide for treating sarcoptes suis |
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Application publication date: 20120314 |