CN102293218A - Insecticidal composition containing spirotetramat and bifenthrin - Google Patents
Insecticidal composition containing spirotetramat and bifenthrin Download PDFInfo
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- CN102293218A CN102293218A CN2010102161584A CN201010216158A CN102293218A CN 102293218 A CN102293218 A CN 102293218A CN 2010102161584 A CN2010102161584 A CN 2010102161584A CN 201010216158 A CN201010216158 A CN 201010216158A CN 102293218 A CN102293218 A CN 102293218A
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- biphenthrin
- ethyl ester
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Abstract
The invention discloses an insecticidal composition containing spirotetramat and bifenthrin, a preparation method thereof and an application thereof. The insecticidal composition has the characteristic of containing spirotetramat, bifenthrin and assistants, wherein the weight ratio of spirotetramat to bifenthrin is 1:50-70:1. The insecticidal composition can be used for controlling various pests of various crops. The insecticidal composition has the advantages of safety, environmental protection, low cost and good effect. Indoor virulence determinations and field drug effect tests prove that the complex formulation consisting of spirotetramat and bifenthrin has obvious synergistic effects on target pests. The insecticidal composition is provided by the invention because the mixed formulation of spirotetramat and bifenthrin has never been reported at home and abroad.
Description
Technical field
The invention belongs to the agriculture chemical compounding field, relate to a kind of Pesticidal combination and application thereof, especially a kind of is the Pesticidal combination and the application thereof of main active with spiral shell worm ethyl ester and Biphenthrin.
Technical background
In the real process of agricultural production, use chemical agent and be the most effectively means of control plant pest, but be the generation of pest resistance to insecticide by the problem that the chemical control insect is easy to generate most.And long-term use single chemical insecticide continuously high dose, cause a series of problems such as residual, environmental pollution of medicament easily.Reasonably chemical insecticide is composite or be mixed and have the expansion insecticidal spectrum, improve control efficiency, prolong the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, delay insect evil mite drug resistance and positive characteristics such as drug-fast generation and development, insecticidal/acaricidal agent is composite or to be mixed be one of the effective method the most that addresses the above problem.Exploitation new product insecticide price is constantly soaring, and by contrast, exploitation is efficient with research, low toxicity, low-residual composite be mixed have small investment, the lead time is short and be subjected to domestic and international attention, strengthens the development dynamics one after another.
Spiral shell worm ethyl ester (spirotetramat): 4-(ethoxy carbonyl oxygen base)-8-methoxyl group-3-(2, the 5-xylyl)-1-azaspiro [4,5]-last of the ten Heavenly stems-3-alkene-2-ketone
Former medicine outward appearance is a white powder, does not have special smell, and the preparation outward appearance is a tool fragranced white suspension.142 ℃ of molten points, solvability (20 ℃) water 33.4mg/L, organic solvent: ethanol 44.0mg/L, n-hexane 0.055mg/L, toluene 60mg/L, carrene＞600mg/L, acetone 100-120mg/L/ ethyl acetate 67mg/L, dimethyl sulfoxide (DMSO) 200-300mg/L.235 ℃ of decomposition temperatures. stability is better.Be a kind of novel tetronic acid insecticides, insecticidal spectrum is wide, and the lasting period is long.It is that fatty biosynthesis by interference insect causes larva death, reduces the fertility of adult.Because its unique mechanism of action can be prevented and treated the insect that existing insecticide is produced resistance effectively, can be used as the important kind of nicotinic insecticide resistance management simultaneously.
Biphenthrin (bifenthrin), (1R, S)-cis (Z) 2,2-dimethyl-3-(2-chloro-3,3,3-three fluoro-1-acrylic) cyclopropane-carboxylic acid-2-methyl-3-phenyl benzyl ester
Thick liquid is crystalline or waxy solid, and fusing point 51-66 ℃, proportion 1.21 (25 ℃), vapour pressure 0.024mPa (25 ℃), be dissolved in carrene, toluene, chloroform, acetone, ether, be slightly soluble in heptane and methyl alcohol, water-soluble hardly, in the time of 20 to 25 ℃, stablized 2 years.The pyrethroid Insecticidal and acaricidal agent.Have tag, stomach poison function, do not inhale in not having, fumigation action, insecticidal spectrum is wide, effect rapidly.Do not move in soil, safer to environment, the longevity of residure is longer.Be applicable to and prevent and treat insects such as lepidopterous larvae, aleyrodid, aphid, leaf miner, leafhopper, tetranychid, evil mite on the crops such as cotton, fruit tree, vegetables, tealeaves.Be used for worm, when mite is concurrent, province's medicine saves time.
Summary of the invention
The present invention's pleasantly surprised discovery in the Toxicity Determination experiment, the composite activity that can improve greatly of spiral shell worm ethyl ester and Biphenthrin to insect, the insect to list agent of spiral shell worm ethyl ester and Biphenthrin list agent generation resistance has higher activity equally.
The present invention realizes by following measures.
A kind of Pesticidal combination, it contains spiral shell worm ethyl ester and Biphenthrin, and wherein the weight ratio of spiral shell worm ethyl ester and Biphenthrin is 1: 50～70: 1.
Described Pesticidal combination, wherein the more excellent weight ratio of spiral shell worm ethyl ester and Biphenthrin is 1: 50～50: 1.
Described Pesticidal combination, wherein to accumulate the weight ratio of shared preparation be 2～71% to two kinds of active principles of spiral shell worm ethyl ester and Biphenthrin.
Described Pesticidal combination, spiral shell worm ethyl ester and Biphenthrin and auxiliary agent, carrier etc. are processed into any one formulation that allows on the agricultural chemicals.
Described Pesticidal combination is characterized in that the formulation that can be processed into is suspending agent, aqueous emulsion, microemulsion, wetting powder, soluble powder, water dispersible granules and microcapsule formulations etc.
Described Pesticidal combination is used to prevent and treat the sucking pest on the various crop, as lepidoptera pests such as sucking pests such as plant hopper, aphid, scale insect, thrips and rice leaf roller, cabbage caterpillars.
Insecticides with synergistic effect takes following measure to realize:
One of technical scheme of the present invention, described Pesticidal combination are suspending agent, and the percentage by weight of component is:
Spiral shell worm ethyl ester 1～70%
Biphenthrin 1～50%
Dispersant 5～20%
Antifreezing agent 0.5～3%
Thickener 0.1～2%
Defoamer 0.1～0.8%
Water surplus
The concrete production stage of this Pesticidal combination suspending agent is earlier other auxiliary agents to be mixed, mix through high speed shear, add spiral shell worm ethyl ester and Biphenthrin, abrading-ball is 2～3 hours in ball crusher, make a diameter all below 5mm, make the suspending agent preparation that contains the Pesticidal combination of spiral shell worm ethyl ester and Biphenthrin of the present invention.
Two of technical scheme of the present invention, described Pesticidal combination are aqueous emulsion, and the percentage by weight of component is:
Spiral shell worm ethyl ester 1～70%
Biphenthrin 1～50%
Emulsifier 3～30%
Solvent 5～15%
Stabilizing agent 2～15%
Antifreezing agent 1～5%
Defoamer 0.1～8%
Thickener 0.2～2%
Water surplus
The concrete production stage of this Pesticidal combination aqueous emulsion is: at first former medicine spiral shell worm ethyl ester is added with Biphenthrin, solvent and emulsifier, cosolvent and be in the same place, make and be dissolved into uniform oil phase; With part water, antifreeze, other insecticides adjuvant such as antimicrobial mixes into uniform water; When the reactor high speed stirs, oil phase is added water, slowly add water until reaching the phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear half an hour approximately, form the aqueous emulsion of oil-in-water type, promptly make the aqueous emulsion of the Pesticidal combination that contains spiral shell worm ethyl ester and Biphenthrin.
Three of technical scheme of the present invention, described Pesticidal combination are microemulsion, and the percentage by weight of component is:
Spiral shell worm ethyl ester 1～70%
Biphenthrin 1～50%
Solvent 1～30%
Emulsifier 3～30%
Stabilizing agent 2～15%
Synergist 2～10%
Water 10～78%
The concrete procedure of processing of this Pesticidal combination microemulsion is: spiral shell worm ethyl ester and the former medicine of Biphenthrin are added in the solvent, add auxiliary agents such as emulsifier, stabilizing agent and synergist while stirring, at last it is added in the entry and stir, form transparent and homogeneous liquid, promptly get the microemulsion of the present composition.
Four of technical scheme of the present invention, described Pesticidal combination are wetting powder, and the percentage by weight of component is:
Spiral shell worm ethyl ester 1～70%
Biphenthrin 1～50%
Dispersant 3～20%
Wetting agent 3～10%
Filler 10～70%
The concrete procedure of processing of this Pesticidal combination wetting powder is: press above-mentioned prescription with spiral shell worm ethyl ester and Biphenthrin and dispersant, wetting agent and filler mixing, in stirred tank, evenly stir, behind airslide disintegrating mill, mixing, promptly can be made into the wetting powder of the present composition.
Five of technical scheme of the present invention, described Pesticidal combination are soluble powder, and the percentage by weight of component is:
Spiral shell worm ethyl ester 1～70%
Biphenthrin 1～50%
Dispersant 3～20%
Stabilizing agent 3～10%
Adhesive agent 1～5%
Filler 10～70%
The concrete procedure of processing of this Herbicidal combinations soluble powder is: press above-mentioned prescription with spiral shell worm ethyl ester and Biphenthrin and dispersant, stabilizing agent, adhesive agent and filler mixing, in stirred tank, evenly stir, behind airslide disintegrating mill, mixing, promptly can be made into the soluble powder of the present composition.
Six of technical scheme of the present invention, described Pesticidal combination are water dispersible granules, and the percentage by weight of component is:
Spiral shell worm ethyl ester 1～70%
Biphenthrin 1～50%
Dispersant 3～20%
Wetting agent 3～10%
Disintegrant 2～5%
Filler 10～70%
The concrete procedure of processing of this Pesticidal combination water dispersible granules is: by above-mentioned prescription spiral shell worm ethyl ester, Biphenthrin and dispersant, wetting agent, disintegrant and filler are mixed, pulverize with micro jet, through mediating, add then and carry out granulation, drying, screening in the fluidized bed prilling dryer after sample analysis makes the water dispersible granules that contains the Pesticidal combination of spiral shell worm ethyl ester and Biphenthrin of the present invention.
Seven of technical scheme of the present invention, described Pesticidal combination are microcapsule formulations, and the percentage by weight of component is:
Spiral shell worm ethyl ester 1～70%
Biphenthrin 1～50%
Urea 5～20%
Formaldehyde 5～20%
Emulsifying dispersant 5～20%
Antifreezing agent 1～5%
Thickener 0.1～2%
Defoamer 0.1～0.8%
Water surplus
This Pesticidal combination microcapsule formulations procedure of processing is: add urea and formaldehyde (amount of substance ratio be about 1: 1.5～2.0) in the there-necked flask of agitating device is housed, about pH value to 8～9 with the sodium hydroxide solution regulator solution, be warming up to 70～80 ℃ then, reaction obtains stable urea resin prepolymer.The former medicine of getting a certain amount of spiral shell worm ethyl ester and Biphenthrin is dissolved in the cyclohexane, and adds emulsifying dispersant in solution, follows vigorous stirring, and being made into the aqueous solution that contains emulsifying dispersant is the O/W type stable emulsion of water.Above-mentioned urea resin prepolymer is added in the emulsion, regulate the pH value, polymerization reaction take place under the acid catalysis condition is wrapped oil phase substance, forms microcapsule granule.Slowly heat up, solidify, temperature is controlled at 40～50 ℃, hardening time 1h.Select to add an amount of auxiliary agent, the microcapsule suspending agent that gets final product stablely.
Described emulsifier is selected from any one or more mixtures formed with arbitrary proportion in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styryl phenol APEO, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, the polyoxyethylene aliphatic alcohol ether.
Described dispersant is selected from one or more in polycarboxylate, sodium lignin sulfonate, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic acid polyethenoxy ether, polyoxyethylene carboxylate, the fatty acid glyceride APEO.
Described solvent is any one or more mixed solvents formed with arbitrary proportion in dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), the water equal solvent.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, calcium dodecyl benzene sulfonate, Nekal BX, wetting and penetrating agent F, alkylnaphthalene sulfonate, alkylphenol ethoxylate, polyoxyethylene triphenylethylene phosphenylic acid salt, spaonin powder, silkworm excrement, the soapberry powder.
Described synergist is meant to have the medicament of enhancing penetration, wetting extended capability, knock down insect speed, improve the resistance of rainwater washing against power of agricultural chemicals, thereby improve a class safety, environmental protection of agricultural insecticide effect, the New-type adjuvant of nontoxic, noresidue, optional in organic silicon pesticide synergist ZC-650 or organic silicon pesticide bleeding agent spreading agent Agrowet810c, agricultural organic silicon pesticide synergist Silwet408, azone any.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, the sodium bicarbonate.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.
Described antimicrobial is selected from: one or both in Sodium Benzoate, sodium salicylate, the sodium sorbate.
Described stabilizing agent is selected from: a kind of in sodium citrate, resorcinol, the oxirane.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), the triethylene glycol.
Described defoamer is selected from: silicone oil, silicone compound, C
10-20Saturated fat acid compounds, C
8-10In aliphatic alcohols compound and the polyoxyethylene glycerol ether one or more.
Described emulsifying dispersant comprises: wetting agent, dispersant, stabilizing agent, thickener, defoamer and antifreezing agent etc.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
The invention has the beneficial effects as follows:
1, the used spiral shell worm ethyl ester of the present invention is the insecticide of new generation that the tetronic acid class has two-way conduction, differs greatly with the carbamate insecticide Biphenthrin mechanism of action, and does not have cross resistance.
2, composite two kinds of insecticide double action mechanism can delay the generation of pest resistance to insecticide.
3, reduced the agricultural chemicals usage amount, strengthened friendly environment.
Embodiment: the different proportioning co-toxicities of spiral shell worm ethyl ester with Biphenthrin
1.1 reagent agent
The former medicine of 95% spiral shell worm ethyl ester, the former medicine of 98% Biphenthrin, Jiangsu Changlong Chemical Co provides.
1.2 indoor examination worm source
Gathering the citrus psylla adult from the kamuning of the urban district greenbelt that seldom sprays medicine, is that 0.45mm nets indoor kamuning and bred for 7 generations in the aperture.
1.3 single agent assay method
Adopt the unified in the world drop method of doing the rice fulgorid toxicity test.Accurately take by weighing reagent agent, with a small amount of 25% acetone (because the wood louse adult is very responsive to acetone, can make the lethality of wood louse adult surpass 30% when making blank with analytically pure acetone soln, so with pure water with acetone diluted to 25%) dissolve former medicine, be made into into 5 series concentration of equal difference more respectively with the 0.1% Tween 80 aqueous solution, make blank with 25% acetone soln, repeat 3 times, repeat 10 adults at every turn.Use CO during processing
2After the anesthesia, rapidly with 0.036 micro-drop instrument with medicine liquid droplet on the pronotary of wood louse adult, every worm is dripped 0.036ul, blank drips 0.036ul 25% acetone soln, the illumination box of putting into the culture dish of the tender tip of kamuning after the processing and inserting temperature (25～1) ℃, 24h observes dead borer population, borer population alive behind the medicine, calculates lethality and corrected mortality, carries out data with the DPS Biological Statistic Analysis Software and handles.
1.4 the joint toxicity measuring method of different proportionings,
According to total active ingredient is 24%, and both mass ratioes are that m (Biphenthrin): m (spiral shell worm ethyl ester) was respectively 1: 2,2: 1, and 3: 2,4: 1, be Biphenthrin at 5: 3: spiral shell worm ethyl ester is 8%: 16%, 16%: 8%, 14.4%: 9.6%, 19.2%: 4.8%, 15%: 9%.Adopt above-mentioned 1.3 methods to carry out toxicity test, calculate LC
50, and press the abundant method of Sun Yun and calculate co-toxicity coefficient (CTC).Co-toxicity coefficient CTC, computing formula is as follows: (with spiral shell worm ethyl ester is the standard medicament, and its toxicity index is 100):
The LC of the toxicity index of Biphenthrin (TI)=spiral shell worm ethyl ester
50The LC of/Biphenthrin
50* 100
The LC of the actual toxicity index (ATI) of M=spiral shell worm ethyl ester
50The LC of/M
50* 100
TI * P the Biphenthrin of the TI of the theoretical toxicity index (TTI) of M=spiral shell worm ethyl ester * P spiral shell worm ethyl ester+Biphenthrin
TTI * 100 of the ATI/M of the co-toxicity coefficient of M (CTC)=M
In the formula:
M is a Biphenthrin and the mixture of the different proportionings of spiral shell worm ethyl ester
The P Biphenthrin is Biphenthrin shared ratio in mixture
P spiral shell worm ethyl ester is spiral shell worm ethyl ester shared ratio in mixture
2.1 toxicity test result
Spiral shell worm ethyl ester, Biphenthrin are to the indoor measurement result of citrus psylla
As can be seen from the table, in being mixed of different proportion, its co-toxicity coefficient is all greater than 120 except 5: 3 o'clock, and all show certain synergistic effect, wherein Biphenthrin: spiral shell worm ethyl ester is that 2: 1 synergistic effect is the most obvious, and co-toxicity coefficient is 147.52.Result of the test shows, Biphenthrin, two kinds of medicaments of spiral shell worm ethyl ester all have higher activity to the oranges and tangerines wood louse under indoor conditions, the result of the test of different proportion proportioning shows, in active ingredient ratio Biphenthrin: spiral shell worm ethyl ester is 1: 2,2: 1,3: 2,4: 1,, all show stronger synergistic effect at 5: 3 o'clock.Suggestion is carried out further field control effectiveness test to the mixture preparation of 2: 1 left and right sides scopes of suitable proportion, to estimate its field practical application effect.
3 field trials control paddy rice rice leaf roller, the oranges and tangerines wood louse
3.1 field experiment control paddy rice rice leaf roller
3.1.1 test method
Tested on August 20th, 2009 to September 10 and carry out in Xiangyin, Hunan institute of agricultural sciences experimental field.Tested on August 20th, 2009 and carry out routine to water spray by each processing design concentration.Spraying equipment is a WF-16 type knapsack hand sprayer, and shower nozzle is single fan nozzle, and operating pressure is 0.2-0.4Mpa, and spray amount is 0.36-0.48L/min, carries out the routine spraying, makes every effort to evenly thoughtful during the spray medicine.The field rice leaf roller is 1～2 instar larvae peak period during dispenser.Every 667m
2To the water yield is 50kg.
Duration of test weather is good, and daily mean temperature is 19.8～29.1 ℃.Dispenser did not have rain the same day.
3.1.2 investigation method
Adopt 5 point samplings, 5 points are selected in every sub-district, every sub-district 20m
2, 5 clumps every, investigate 25 clumps of paddy rice altogether.Before dispenser and after the dispenser the 3rd, 7d investigates whole blades of 25 clumps respectively, wins all the old and new worms bags, the residual borer population alive of stripping bag record then calculates go down rate and proofread and correct preventive effect of insect population; 20d investigated the leaf roll number when present age, harm was finalized the design behind medicine, calculated leaf roll rate and preventive effect.Notice that the viewing test chemicals treatment has or not poisoning to paddy rice.
3.1.3 drug effect computational methods.
3.1.4 poisoning investigation method
It is good that the sub-district paddy growth is respectively handled in the duration of test observation, all finds no the poisoning phenomenon and take place.
3.1.5 field control effectiveness test result of the test
Table 2 is handled chemical control paddy rice rice leaf roller field control effectiveness test result
As can be seen from Table 2, the Mixed Pharmacy of different proportion carries out field experiment by different consumptions, and its control efficiency to the paddy rice rice leaf roller all is better than contrasting medicament behind the medicine, 16% Biphenthrin+8% spiral shell worm ethyl ester control paddy rice rice leaf roller is effective, and the lasting period reaches more than the 20d.7 days insecticidal effect is respectively 88.42%, 90.53% and 94.25% behind medicine, and insecticidal effect increases progressively along with the increase of consumption.20d behind the medicine, this processing leaf roll preventive effect all reaches more than 80%, shows that this patent has very strong desinsection and Bao Ye effect, and simultaneously it is to people, animal, pest natural enemy safety.According to experimental observation, each medication is handled does not all have poisoning to paddy rice, finds that it also has favorable effect to insects such as rice fulgorids simultaneously yet.Suggestion the insect ovum hatching peak phase to the phase dispenser of 1--2 instar larvae.Note the suitable use continuously of 1 season crop 2 times, avoid insect to develop immunity to drugs.It is to agricultural product and Environmental security, and use is worth promoting.
3.2 field experiment control oranges and tangerines wood louse
3.2.1 test method
Tested July 10 to July 20 in 2009 and test in the oranges and tangerines garden of Liuzhou Liubei District wood louse harm.Spraying equipment is a WF-16 type knapsack hand sprayer, and shower nozzle is single fan nozzle, every sub-district 20m
2Tree crown and the interior thorax of mandarin tree all to be sprayed onto, the spraying liquid amount with blade have drip on a small quantity till.Take out a phase dispenser at the tender tip that wood louse is taken place.
Duration of test weather is good, and daily mean temperature is 21.6～31.4 ℃.Dispenser did not have rain the same day.
3.2.2 investigation method
3 repetitions (sub-district) are established in every processing, every sub-district 20m
2, middle 2m
2As enumeration district.Before the medicine, behind the medicine 1,3,7d investigates 2m in the middle of each sub-district
2One-tenth borer population or nymph number, calculate go down rate and preventive effect.Notice that the viewing test chemicals treatment has or not poisoning to mandarin tree.
3.2.3 drug effect computational methods.
3.2.4 poisoning investigation method
Duration of test is observed and respectively to be handled the sub-district mandarin tree and grow fine, and all finds no the poisoning phenomenon and takes place.
3.2.5 field control effectiveness test result of the test
Table 3 is handled chemical control oranges and tangerines wood louse field control effectiveness test result
As can be seen from Table 3, the Mixed Pharmacy of different proportion carries out field experiment by different consumptions, and its control efficiency to the oranges and tangerines wood louse is better than contrasting medicament behind the medicine, 16% Biphenthrin+8% spiral shell worm ethyl ester control oranges and tangerines wood louse instant effect, and effective, the lasting period is long.7 days insecticidal effect is respectively 86.96%, 90.11% and 91.42% behind medicine, and insecticidal effect increases progressively along with the increase of consumption, and it is to pest natural enemy safety simultaneously.According to experimental observation, the mandarin tree that each medication is handled grows fine, and also finds that it also has fine preventive effect to scale insect etc. simultaneously.The tender tip that suggestion takes place wood louse is taken out the phase of sending out and is just begun control.By observing, it can effectively control the harm of wood louse, indirectly also to the carrying out of yellow twig excellent prevention, be worth of widely use in the oranges and tangerines main producing region.
Claims (5)
1. Pesticidal combination, it is characterized in that: contain two kinds of active components of spiral shell worm ethyl ester and Biphenthrin, wherein the weight ratio of spiral shell worm ethyl ester and Biphenthrin is 1: 50～70: 1;
2. Pesticidal combination according to claim 1 is characterized in that: the more excellent weight ratio of spiral shell worm ethyl ester and Biphenthrin is 1: 50～50: 1;
3. Pesticidal combination according to claim 1 is characterized in that: the percentage by weight that spiral shell worm ethyl ester and Biphenthrin are accumulated shared preparation is 2～71%;
4. Pesticidal combination according to claim 1 is characterized in that: spiral shell worm ethyl ester and Biphenthrin and auxiliary agent and cosolvent are re-dubbed any one formulation that allows on the agricultural chemicals;
5. Pesticidal combination according to claim 4 is characterized in that: the formulation that can be processed into is suspending agent, aqueous emulsion, microemulsion, wetting powder, soluble powder, water dispersible granules and microcapsule formulations etc.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106417331A (en) * | 2016-09-21 | 2017-02-22 | 江西省农业科学院植物保护研究所 | Compound pesticide composition containing spirotetramat and application thereof |
| CN108294045A (en) * | 2018-03-15 | 2018-07-20 | 重庆中邦药业（集团）有限公司 | One vegetative insecticide composition, preparation and its application |
| WO2021048714A1 (en) * | 2019-09-10 | 2021-03-18 | Upl Limited | A stable liquid composition |
| WO2022234595A1 (en) * | 2021-05-06 | 2022-11-10 | Willowood Chemicals Limited | Insecticidal compositions comprising of diamide and tetramic acid compound |
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| US20100137233A1 (en) * | 2008-11-14 | 2010-06-03 | Bayer Cropscience Ag | Active substance combinations with insecticides and acaricide properties |
| CN101755816A (en) * | 2009-10-29 | 2010-06-30 | 深圳诺普信农化股份有限公司 | Insecticidal composition |
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| CN101489387A (en) * | 2006-07-11 | 2009-07-22 | 拜尔农作物科学股份公司 | Active ingredient combinations with insecticidal and acaricidal properties |
| US20100137233A1 (en) * | 2008-11-14 | 2010-06-03 | Bayer Cropscience Ag | Active substance combinations with insecticides and acaricide properties |
| CN101755816A (en) * | 2009-10-29 | 2010-06-30 | 深圳诺普信农化股份有限公司 | Insecticidal composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106417331A (en) * | 2016-09-21 | 2017-02-22 | 江西省农业科学院植物保护研究所 | Compound pesticide composition containing spirotetramat and application thereof |
| CN108294045A (en) * | 2018-03-15 | 2018-07-20 | 重庆中邦药业（集团）有限公司 | One vegetative insecticide composition, preparation and its application |
| WO2021048714A1 (en) * | 2019-09-10 | 2021-03-18 | Upl Limited | A stable liquid composition |
| WO2022234595A1 (en) * | 2021-05-06 | 2022-11-10 | Willowood Chemicals Limited | Insecticidal compositions comprising of diamide and tetramic acid compound |
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Application publication date: 20111228 |