KR101972419B1 - Pesticides Promoting or Delaying Photodegradation - Google Patents

Pesticides Promoting or Delaying Photodegradation Download PDF

Info

Publication number
KR101972419B1
KR101972419B1 KR1020170167612A KR20170167612A KR101972419B1 KR 101972419 B1 KR101972419 B1 KR 101972419B1 KR 1020170167612 A KR1020170167612 A KR 1020170167612A KR 20170167612 A KR20170167612 A KR 20170167612A KR 101972419 B1 KR101972419 B1 KR 101972419B1
Authority
KR
South Korea
Prior art keywords
aluminum oxide
gold
pesticide
photolysis
mixtures
Prior art date
Application number
KR1020170167612A
Other languages
Korean (ko)
Inventor
이중혁
김학기
Original Assignee
이중혁
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 이중혁 filed Critical 이중혁
Priority to KR1020170167612A priority Critical patent/KR101972419B1/en
Application granted granted Critical
Publication of KR101972419B1 publication Critical patent/KR101972419B1/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06—Aerosols
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • Y10S514/919—

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a method of preparing a pesticide photolysis accelerator or retarder which accelerates or retards photolysis of a pesticide, a pesticide photolysis accelerator or retarder prepared thereby, and a natural pesticide comprising the same. Therefore, the method of preparing a photolysis promoting pyrethrum insecticide comprises steps of: thinly forming gold or aluminum oxide; cutting the thinly formed gold or aluminum oxide into small pieces such that the thinly formed gold or aluminum oxide is cut in a triangular shape; selectively mixing the triangular shaped gold or aluminum oxide chips with compressed gas or water to obtain mixtures; and containing the mixtures in each of spray containers to be sprayed. Further, the present invention provides a pesticide photolysis accelerator or retarder which is prepared by mixing 8 to 10 vol% of the triangular shaped gold or aluminum oxide chips with a thickness of 0.1 to 0.3 μm with 90 to 92 vol% of the compressed gas or water to obtain the mixtures, and containing the mixtures in each of the spray containers to be sprayed, and a pyrethrum insecticide which comprises the pesticide photolysis accelerator or retarder, wherein pyrethrum insecticide is prepared by mixing 4 to 8 vol% of the triangular shaped gold or aluminum oxide chips with a thickness of 0.1 to 0.3 μm, 2 to 3 vol% of the pyrethrum insecticide, and 90 to 93 vol% of the compressed gas or water to obtain the mixtures, and containing the mixtures in each of the spray containers to be sprayed. The present invention has an effect of rapidly promoting killing of insects by promoting photolysis of the natural pesticide such as a pyrethrum flower and an effect of killing insects for a long time by delaying photolysis of the pesticide.

Description

제충제 광분해 촉진제와 지연제 제조방법 및 이를 이용하여 제조된 제충제 광분해 촉진제 또는 지연제 및 광분해가 촉진되는 제충국제 제조방법{Pesticides Promoting or Delaying Photodegradation}[0001] The present invention relates to a photocatalytic photocatalyst, a photocatalytic photocatalytic photocatalyst, a photocatalytic photocatalytic photocatalyst, a photocatalytic photocatalytic photocatalyst,

본 발명은 제충제가 광분해되는 것을 촉진되게 하거나 지연되게 하는 제충제 광분해 촉진제와 지연제 제조방법 및 이를 이용하여 제조된 제충제 광분해 촉진제 또는 지연제 및 광분해가 촉진되는 제충국제 제조방법에 관한 것이다.The present invention relates to an accelerator for accelerating or retarding photodecomposition of a insect repellent, a method for producing a retarder, a desiccant photopolymerization accelerator or retarder prepared using the same, and a method for producing a repellent agent promoting photolysis.

종래에는 농업해충과 위생해충 구제용 살충제로 화학농약을 많이 이용하였다. 그에 따라 동물과 인체에 화학 살충제 성분이 다량 축적되면서 인체나 가축에 유해하게 되었으며 결국 환경파괴로 이어져 생태계도 점점 이상 현상을 일으키게 되었다.Conventionally, chemical pesticides have been widely used as insecticides for agricultural pests and sanitary insect remedies. As a result, large amounts of chemical insecticides accumulate in animals and humans, making them harmful to humans and livestock, and eventually leading to environmental destruction, resulting in more and more ecosystems.

즉, 종래의 화학농약은 농약성분의 85-90%가 대기, 토양, 수계에 살포되어 지속적으로 환경을 파괴시키고, 병해충에 대한 내성 및 저항성이 커지고, 인체나 가축에 해를 끼치는 문제가 있다.That is, conventional chemical pesticides have a problem in that 85-90% of the pesticide ingredient is sprayed on the atmosphere, soil, and water system to continuously destroy the environment, increase resistance and resistance to pests, and harm human bodies and livestock.

따라서, 근자에는 이러한 문제를 해결하기 위한 방안으로 환경 친화적이고 인체나 가축에 대한 독성이 약한 천연 식물을 해충 방제로 이용하려는 연구가 활발하게 이루어지고 있으며, 그 하나로서 선행기술문헌의 특허문헌에 기재된 제충국이 있다.In recent years, studies have been actively conducted to utilize natural plants, which are eco-friendly and less toxic to humans and livestock, as a pest control agent, in order to solve such problems, and as one of them, There is a buggy station.

제충국(Insect flower, Pyrethrum flower)은 쌍떡잎식물 초롱꽃목 국화과의 여러해살이풀로서, 그 식물체, 특히 꽃 부분에 피레트린(Pyrethrin)이라는 담적황색의 유상(油狀) 물질을 함유하고 있다.Insect flower (Pyrethrum flower) is a perennial herbaceous plant of the perennial herbaceous plant, and contains a pale yellow-yellow oily substance called pyrethrin in the plant, especially in the flower part.

피레트린은 냉혈동물, 특히 곤충의 신경계를 마비시켜 강한 살충력을 나타내지만, 사람과 같은 온혈동물에는 독성이 없는 안전한 천연 유래의 살충성분이다.Pyretrin is a safe, naturally occurring insecticide that is toxic to warm-blooded animals such as humans, although it exhibits strong insecticidal power by paralyzing cold-blooded animals, particularly insects.

구체적으로는, 피레트린은 곤충에 대한 강한 살충 작용을 지니는바, 유제(油劑) 외에 코일(Coil)형 모기향 등으로서 모기, 파리의 구제에 사용되고 있으며, 바퀴벌레, 벼룩, 개미 및 이와 유사한 기어다니는 곤충에 대해서도 적용가능한 것으로 알려져 있다.Specifically, pyretrin has a strong insecticidal action against insects. In addition to oil agents, it is used as a coil type mortar and the like for relieving mosquitoes and flies, and is widely used in the fields of cockroaches, fleas, It is also known to be applicable to insects.

반면에, 피레트린이 살충제로서 사람에게 유해한 독성을 나타낸다는 보고는 아직까지 없다.On the other hand, there is no report yet that pyrethrin shows harmful toxicity to humans as an insecticide.

그러므로 제충국(피레트린)의 안전하면서도 강한 살충력을 이용하여 제충제로서 사용되고 있으나, 선행기술문헌의 특허문헌에 기재된 선행기술들은 제충제의 광분해 촉진이나 지연시키지 못하고 단순히 살충 역할만 하기 때문에 보다 신속하게 제충시킬 수 없거나 또는 지연시킬 수 없으므로 효율적인 사용이 도모되지 못하는 문제점이 있다.Therefore, although the prior art described in the patent documents of the prior art documents does not promote or retard photodegradation of the insecticide and simply acts as a insecticide, Or can not be delayed, so that there is a problem that efficient use can not be achieved.

KR 10-0831577 B1 2008.05.22KR 10-0831577 B1 2008.05.22 KR 10-2014-0084596 A 2014.07.07KR 10-2014-0084596 A 2014.07.07

본 발명은 제충제가 광분해되는 것을 촉진되게 하거나 지연되게 하는 제충제 광분해 촉진제와 지연제 제조방법 및 이를 이용하여 제조된 제충제 광분해 촉진제 또는 지연제 및 광분해가 촉진되는 제충국제 제조방법을 제공하려는데 그 목적이 있다.Disclosure of Invention Technical Problem [8] The present invention provides a method for preparing accelerators and retarders for accelerating or delaying photodegradation of a insect repellent, a method for preparing a desiccant photolysing accelerator or a retarder, .

본 발명은, 금 또는 산화알루미늄을 얇게 성형한 다음 잘게 절단되도록 하되 삼각형 형태로 절단되도록 하여 금칩 또는 산화알루미늄칩이 이루어지게 한 후에 압축가스 또는 물과 선택적으로 각각 혼합되게 하여 분무될 수 있도록 각각의 스프레이 용기에 수용되도록 제조되는 것을 그 특징으로 한다.In the present invention, gold or aluminum oxide is formed into a thin shape and then finely cut, but is cut into a triangle shape to form a gold chip or an aluminum oxide chip, and then mixed with a compressed gas or water, Characterized in that it is manufactured to be accommodated in a spray container.

상기 성형된 금 또는 산화알루미늄이 0.1~0.3㎛로 잘게 절단되고, 압축가스 또는 물 90~92부피%, 금칩 또는 산화알루미늄칩 8~10부피%가 혼합되도록 이루어지는 것을 다른 특징으로 한다.The formed gold or aluminum oxide is finely cut to 0.1 to 0.3 탆 and mixed with 90 to 92% by volume of compressed gas or water, 8 to 10% by volume of a gold chip or aluminum oxide chip.

또한, 본 발명은 삼각형태의 0.1~0.3㎛의 각각의 금칩 또는 산화알루미늄칩 8~10부피%, 압축가스 또는 물 90~92부피%가 각각 혼합되어 각각의 스프레이 용기에 수용되고 분무될 수 있도록 이루어지는 제충제 광분해 촉진제 또는 지연제를 또 다른 특징으로 한다.In addition, the present invention provides a method for mixing and spraying each spray vessel with a mixture of 8 to 10% by volume of each of gold chips or aluminum oxide chips of 0.1 to 0.3 탆 in triangular form, 90 to 92% by volume of compressed gas or water, The present invention also provides a photocatalyst for photocatalytic polymerization,

그리고 본 발명은, 금을 시트형태로 성형한 다음 절단되도록 하되 삼각형 형태로 절단되도록 하여 금칩이 이루어지게 하고, 상기 삼각형태의 0.1~0.3㎛로 절단된 금칩 4~8부피%, 제충국제 2~3부피%, 압축가스 또는 물 90~93부피%가 각각 혼합되어 빛이 투과되지 못하는 검정색의 스프레이 용기에 수용되고 분무될 수 있도록 제조되게 이루어지는 것을 또 다른 특징으로 한다.According to the present invention, gold is formed into a sheet and then cut into a triangle to form a gold chip. The gold chip is cut to a thickness of 0.1 to 0.3 탆 in a triangular shape by 4 to 8% by volume, 3 volume%, compressed gas, or 90 to 93 volume% of water, respectively, so as to be accommodated and sprayed in a black spray container which does not transmit light.

본 발명은 제충국과 같은 천연 제충제가 광분해되는 것을 촉진되게 하므로 신속한 살충이 도모되게 하는 효과 및 제충제가 광분해되는 것을 지연되게 하므로 장시간 동안 살충되게 하는 효과가 있다.The present invention promotes the photodecomposition of natural insecticides such as insect repellents, so that rapid insecticide is promoted and insecticides are delayed for a long period of time because the insect repellent is delayed.

그러므로 필요에 따라 신속한 살충 또는 지연 살충이 되도록 선택적으로 살충시킬 수 있게 되는 효과를 제공하게 된다.Therefore, it is possible to selectively insect the insects so that they are rapidly insecticidal or delayed insecticides according to need.

그리고 광분해가 촉진되는 제충국제와 같은 천연 제충제를 제공하게 되므로 필요에 따라 선택적이고 효율적인 사용이 도모되게 하는 효과를 제공하게 되는 것이다.And a natural insecticide such as a pest control agent which promotes photodegradation. Thus, it is possible to provide selective and efficient use as needed.

본 발명을 상세하게 설명하면 더욱 명확하게 이해될 것이다.The present invention will be more clearly understood from the following description.

본 발명은 금 및 산화알루미늄이 사용되는 것으로서, 상기한 금 및 산화알루미늄을 가령 금박지나 은박지와 같이 매우 얇은 두께을 갖는 시트형태가 되도록 성형을 한다.In the present invention, gold and aluminum oxide are used, and the gold and the aluminum oxide are shaped into a sheet having a very thin thickness, such as a gold foil or a tin foil.

그리고 매우 얇은 두께로 성형된 금 및 산화알루미늄을 잘게 절단되도록 하는 것으로서, 이와 같이 잘게 절단하는 기술은 이미 알려진 것이므로 상세한 설명은 생략하는 것으로 한다.The gold and aluminum oxide formed into a very thin thickness are finely cut, and the technique of finely cutting the aluminum and aluminum oxide is already known, so a detailed description will be omitted.

따라서, 잘게 절단되는 금 및 산화알루미늄은 삼각형으로 절단되게 하는 것이 바람직하나, 경우에 따라서는 사각이나 원형 형태가 되도록 할 수도 있다.Therefore, it is preferable to cut the finely cut gold and aluminum oxide into a triangle, but in some cases, it may be a square or a circular shape.

상기와 같이 삼각형으로 절단되는 금 및 산화알루미늄은 0.1~0.3㎛로 잘게 절단되도록 하는 것이 바람직한 것으로서, 이와 같이 금 및 산화알루미늄을 잘게 절단된 것을 본 발명의 이해를 돕기 위해서 금칩 및 산화알루미늄칩이라고 명칭하고 설명하는 것으로 한다.The gold and aluminum oxide cut in the triangle as described above are preferably finely cut to 0.1 to 0.3 탆. In order to facilitate the understanding of the present invention, .

따라서, 금칩 또는 산화알루미늄칩은 각각 가령 에어로졸이라고 불리우고 있는 압축가스와 함께 각각 스프레이 용기에 담겨져서 제충제 광분해 촉진제 또는 지연제가 제조되는 것이다.Thus, the gold chips or aluminum oxide chips are respectively packed in a spray vessel together with a compressed gas, which is referred to as an aerosol, to produce an accelerator for accelerating decomposition of an accelerator or a retarder.

그러나 경우에 따라서는 물과 함께 혼합되어 스프레이 용기에 담겨져서 제충제 광분해 촉진제 또는 지연제가 제조될 수도 있다.However, in some cases, they may be mixed with water and placed in a spray container to prepare a disposable photocatalytic accelerator or retarder.

상기 스프레이 용기는, 용기를 한 손으로 잡은 상태에서 손가락으로 스프레이 당김레버를 당기게 되면 스프레이노즐을 통해서 용기 본체내에 있는 내용물이 외부로 분무되는 스프레이 용기를 일컫는 것으로서, 이미 알려진 것이므로 상세한 도면과 설명은 생략하는 것으로 한다.The spray container refers to a spray container in which the contents in the container body are sprayed to the outside through a spray nozzle when the spray pull lever is pulled by a finger while holding the container with one hand, and detailed drawings and explanations are omitted .

따라서, 스프레이 용기를 이용하여 분무되게 하면 에어로졸과 같은 압축가스와 함께 칩들이 분무되거나 또는 물과 함께 칩들이 분무되는 것으로서, 금칩이 압축가스 또는 물과 함께 각각의 스프레이 용기에 각각 담겨지는 것은 제충제 광분해 촉진제가 되는 것이고, 산화알루미늄칩이 압축가스 또는 물과 함께 각각의 스프레이 용기에 각각 담겨지는 것은 제충제 광분해 지연제가 되는 것이다.Accordingly, when sprayed using a spray container, chips are sprayed together with a compressed gas such as an aerosol, or chips are sprayed with water, and the gold chips are contained in each spray container together with compressed gas or water, And the aluminum oxide chips are contained in the respective spray containers together with the compressed gas or the water, respectively, is a depigmentation photodecomposition retarder.

상기 압축가스 또는 물과 금칩 또느 산화알루미늄칩은 압축가스 또는 물 90~92부피%, 금칩 또는 산화알루미늄칩 8~10부피%가 되도록 혼합되게 하는 것이 바람직하고, 금칩 또는 산화알루미늄칩은 매우 미세한 칩이기 때문에 압축가스 또는 물과 혼합되었을 때 스프레이 용기 내에서 밑으로 가라앉지 않게 됨으로써 분사시에 금칩 또는 산화알루미늄칩이 고르게 분사되는 상태가 된다.It is preferable that the compressed gas or water and the gold chip or the aluminum oxide chip are mixed so as to be 90 to 92 vol% of compressed gas or water, 8 to 10 vol% of the gold chip or the aluminum oxide chip, So that it does not sink downward in the spray container when mixed with compressed gas or water, so that the gold chip or the aluminum oxide chip is uniformly sprayed at the time of spraying.

따라서, 본 발명은 금 또는 산화알루미늄을 얇게 성형한 다음 잘게 절단되도록 하되 삼각형 형태로 절단되도록 하여 금칩 또는 산화알루미늄칩이 이루어지게 한 후에 압축가스 또는 물과 선택적으로 각각 혼합되게 하여 분무될 수 있도록 각각의 스프레이 용기에 수용되도록 제조되는 것에 특징이 있다.Accordingly, the present invention is characterized in that gold or aluminum oxide is formed into a thin shape and then finely cut, but is cut into a triangular shape to form a gold chip or an aluminum oxide chip, and then mixed with a compressed gas or water, Of the spray container of the present invention.

그리고 본 발명은 삼각형태의 0.1~0.3㎛의 각각의 금칩 또는 산화알루미늄칩 8~10부피%, 압축가스 또는 물 90~92부피%가 각각 혼합되어 각각의 스프레이 용기에 수용되고 분무될 수 있도록 이루어지는 제충제 광분해 촉진제 또는 지연제를 제공하게 된다.The present invention is characterized in that each of the triangular-shaped gold chips or aluminum oxide chips of 8 to 10% by volume, compressed gas or 90 to 92% by volume of water is mixed and sprayed in each spray container, Thereby providing an additive photolysis accelerator or retarding agent.

따라서, 스프레이 용기에 담긴 금칩이 제충제가 분사된 식물에 분사되면 수많은 금칩이 식물에게 달라 붙게 되어 빛이 사방으로 반사됨에 따라 광분해가 촉진되고, 산화알루미늄칩이 분사되는 경우에는 자외선, 가시광선, 적외선등이 반사되는 것을 흡수하므로 광분해가 지연되는 상태가 된다. 상기 광분해 작용은 이미 알려진 것이므로 상세한 설명은 생략하는 것으로 한다.Therefore, when the gold chip contained in the spray container is sprayed onto the sprayed plant, a lot of gold chips stick to the plant, and the light is reflected in all directions, thereby promoting photodegradation. When the aluminum oxide chip is sprayed, ultraviolet rays, visible rays, Absorbs the reflection of light, and thus the state of photodegradation is retarded. Since the photolytic action is already known, a detailed description thereof will be omitted.

한편, 이미 알려져 있는 살충제로 가공된 제충국제(제충국추출물)와 함께 금칩 또는 산화알루미늄칩이 검정색의 스프레이 용기에 담겨져서 분사되면 천연 제충제가 되고, 이러한 천연 제충제가 식물에 분사되면 살충제가 금칩에 의해서 광분해 촉진되거나 또는 산화알루미늄침에 의해서 광분해가 지연되는 것이다.On the other hand, when a gold chip or an aluminum oxide chip is injected into a black spray container together with a known insecticide-treated insecticide-treated insecticide (insect repellent extract), it is a natural insecticide. When such a natural insecticide is sprayed on a plant, Photodegradation is accelerated or photodegradation is delayed by aluminum oxide needles.

그러므로 본 발명의 제조방법에 의해 제조된 삼각형태의 0.1~0.3㎛의 각각의 금칩 또는 산화알루미늄칩 4~8부피%, 제충국제 2~3부피%, 압축가스 또는 물 90~93부피%가 각각 혼합되어 각각의 스프레이 용기에 수용되고 분무될 수 있도록 제조되게 이루어지는 제충국제를 제공하게 된다.Therefore, each of the triangular gold chips or aluminum oxide chips of from 0.1 to 0.3 탆 in volume, from 4 to 8% by volume, from the second to third volume of the pest control station, from 90 to 93% by volume of compressed gas or water, And mixed to be contained in each spray container and to be sprayed.

따라서, 가령 실내에서 개미와 같은 위생해충을 살충시킬 경우에는 제충국제가 장시간 살충약효를 발휘할 필요성이 있으며, 이 경우에는 산화알루미늄칩에 함유된 제충국제를 개미가 다니는 길목에 분사하게 됨으로써 제충국제의 광분해가 지연되게 함으로써 효율적인 제충이 도모되는 것이다.Therefore, when insecticidal insects such as ants are inseminated in a room, it is necessary that the antimicrobial agent exhibits long-term insecticidal action. In this case, the antimicrobial agent contained in the aluminum oxide chip is sprayed on the way of the ants, So that efficient debugging can be achieved.

그리고 순수한 제충국제의 유효성분인 피레쓰린은 산소나 햇빛에 빠르게 분해되므로 이른 아침나 저녁에 살포해야 바람직하지만 살충제에 약한 식물의 경우에는 금칩이 함유된 제충국제가 살포되게 함으로써 제충국제의 광분해가 촉진되게 함에 따라 효율적인 제충 효과를 기대할 수 있게 되는 것이다.Pyrathrine, which is an effective ingredient of a pure insecticide, is quickly decomposed into oxygen or sunlight, so it is desirable to spray it early in the morning or evening. In the case of plants that are weak against insecticides, the insecticide containing gold chips is sprayed, It is possible to expect an effective debugging effect.

본 발명의 구체적인 설명은 실시예적으로 설명한 것이므로 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자라면 본 발명의 본질적인 특성을 벗어나지 않는 범위에서 다양한 수정 및 변형이 가능할 것이다.It will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.

따라서 본 발명에 개시된 실시예는 본 발명의 기술사상을 한정하기 위한 것이 아니라 설명하기 위한 것으로서, 본 발명과 동등한 범위 내에 있는 모든 기술사상은 본 발명의 권리범위에 포함되는 것으로 해석되어야 하는 것이 자명한 것이다.It is therefore to be understood that the invention is not to be limited to the disclosed embodiments but is to be accorded the widest scope consistent with the spirit and scope of the present invention as defined by the appended claims. will be.

Claims (4)

삭제delete 삭제delete 삭제delete 금을 시트형태로 성형한 다음 절단되도록 하되 삼각형 형태로 절단되도록 하여 금칩이 이루어지게 하고, 상기 삼각형태의 0.1~0.3㎛로 절단된 금칩 4~8부피%, 제충국제 2~3부피%, 압축가스 또는 물 90~93부피%가 각각 혼합되어 빛이 투과되지 못하는 검정색의 스프레이 용기에 수용되고 분무될 수 있도록 이루어지는 것을 특징으로 하는 광분해가 촉진되는 제충국제 제조방법.The gold is cut into a sheet form and then cut into a triangular shape to form a gold chip. The gold chip is cut to 0.1 to 0.3 탆 in a triangular shape, 4 to 8% by volume of a gold chip cut into the triangle form, 2 to 3% And 90 to 93% by volume of a gas or water are mixed with each other to be received and sprayed in a black spray container which does not allow light to pass therethrough.
KR1020170167612A 2017-12-07 2017-12-07 Pesticides Promoting or Delaying Photodegradation KR101972419B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020170167612A KR101972419B1 (en) 2017-12-07 2017-12-07 Pesticides Promoting or Delaying Photodegradation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020170167612A KR101972419B1 (en) 2017-12-07 2017-12-07 Pesticides Promoting or Delaying Photodegradation

Publications (1)

Publication Number Publication Date
KR101972419B1 true KR101972419B1 (en) 2019-04-25

Family

ID=66281870

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020170167612A KR101972419B1 (en) 2017-12-07 2017-12-07 Pesticides Promoting or Delaying Photodegradation

Country Status (1)

Country Link
KR (1) KR101972419B1 (en)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08143401A (en) * 1994-11-24 1996-06-04 Kuraray Chem Corp Coating for controlling termite
KR20040083215A (en) * 2003-03-21 2004-10-01 한국화학연구원 Functional capsules with photo-degradable activity and enhanced antibacterial and sterilizing activity, and process for preparing them
KR100590466B1 (en) * 2002-06-25 2006-06-19 후지쯔 가부시끼가이샤 Pesticide composition and pesticide residue decomposing agent
JP2006321721A (en) * 2005-05-17 2006-11-30 Shinto Paint Co Ltd Blooming and fruit-bearing promoter
KR100831577B1 (en) 2008-03-26 2008-05-22 주식회사 그린환경 Extraction mathode of natural insecticide in phrethrum flower
JP2008214755A (en) * 2001-02-27 2008-09-18 Fuairudo Kk High-function water containing ultra-fine gold particle
JP2009275021A (en) * 2008-05-19 2009-11-26 Sumika Life Tech Co Ltd Insecticidal composition comprising pyrethrum extract
KR20140084596A (en) 2012-12-27 2014-07-07 ㈜엠알이노베이션 Pesticides using the Insect flower powder or sludge
JP2014195797A (en) * 2013-03-07 2014-10-16 学校法人神奈川大学 Preparation method of visible light-responsive photocatalyst and visible light-responsive photocatalyst intermediate, usage of visible light-responsive photocatalyst, and visible light-responsive photocatalyst
US20170225958A1 (en) * 2014-08-01 2017-08-10 Smart Inovation, Lda Functional particles, production process and uses

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08143401A (en) * 1994-11-24 1996-06-04 Kuraray Chem Corp Coating for controlling termite
JP2008214755A (en) * 2001-02-27 2008-09-18 Fuairudo Kk High-function water containing ultra-fine gold particle
KR100590466B1 (en) * 2002-06-25 2006-06-19 후지쯔 가부시끼가이샤 Pesticide composition and pesticide residue decomposing agent
KR20040083215A (en) * 2003-03-21 2004-10-01 한국화학연구원 Functional capsules with photo-degradable activity and enhanced antibacterial and sterilizing activity, and process for preparing them
JP2006321721A (en) * 2005-05-17 2006-11-30 Shinto Paint Co Ltd Blooming and fruit-bearing promoter
KR100831577B1 (en) 2008-03-26 2008-05-22 주식회사 그린환경 Extraction mathode of natural insecticide in phrethrum flower
JP2009275021A (en) * 2008-05-19 2009-11-26 Sumika Life Tech Co Ltd Insecticidal composition comprising pyrethrum extract
KR20140084596A (en) 2012-12-27 2014-07-07 ㈜엠알이노베이션 Pesticides using the Insect flower powder or sludge
JP2014195797A (en) * 2013-03-07 2014-10-16 学校法人神奈川大学 Preparation method of visible light-responsive photocatalyst and visible light-responsive photocatalyst intermediate, usage of visible light-responsive photocatalyst, and visible light-responsive photocatalyst
US20170225958A1 (en) * 2014-08-01 2017-08-10 Smart Inovation, Lda Functional particles, production process and uses

Similar Documents

Publication Publication Date Title
CN101731260B (en) L-terpineol synergist-containing beta-cypermethrin pesticide composition
US8397427B2 (en) Wasp, hornet, and yellowjacket spray repellant and nest pesticide
RU2010116175A (en) FLYING COMPONENTS OF PLANTS
Fernando et al. Ethnobotanicals for Storage Insect Pest Management: Effect of Powdered Leaves of Olaxzeylanica in Suppressing Infestations of Rice Weevil Sitophilusoryzae (L.)(Coleoptera: Curculionidae
JP2020011944A (en) Controlled release type composition
KR101972419B1 (en) Pesticides Promoting or Delaying Photodegradation
EP2489261B1 (en) Trapping device for fruit-feeding insects
CN105746571A (en) Scale insect and reptile attractive toxicant and application
US11896008B2 (en) Use of nootkatone to treat mosquito infestations
CN105532760A (en) Green insecticide for forests
CN105028536B (en) It is a kind of for the compound plant insecticide of mosquito larvae control and its preparation and application
CN101707995A (en) Safe rodenticide bait for non-target animals
JP4836763B2 (en) Thrips control agent
JPH10327732A (en) Pest-controlling tape
JP7433404B2 (en) Spray products for controlling flies and methods for preventing the occurrence of flies
JP2002322004A (en) Expellent for wasp and method for exterminating wasp
JPH1029902A (en) Pest-controlling agent for plant
CN103039503A (en) Synergia composition of phoxim and cypermethrin
KR20120072894A (en) Sex pheromone composition for attraction synanthedon bicingulata and manufacturing thereof
US10827759B2 (en) Rat repellent system and method
US20170099843A1 (en) Animal repellent composition
WO2021158192A1 (en) A mass trapping formulation for controlling mediterranean fruit fly
Nandwana et al. Evaluation of Mosquito Repellent Activity of Marigold Petals Extract
TR2021007241A2 (en) PESTICIDE AND PRODUCTION METHOD
JP5136814B2 (en) Insect repellent

Legal Events

Date Code Title Description
E701 Decision to grant or registration of patent right
GRNT Written decision to grant