CN101724964A - High-temperature resistant flame-retarding textile - Google Patents
High-temperature resistant flame-retarding textile Download PDFInfo
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- CN101724964A CN101724964A CN200910309943A CN200910309943A CN101724964A CN 101724964 A CN101724964 A CN 101724964A CN 200910309943 A CN200910309943 A CN 200910309943A CN 200910309943 A CN200910309943 A CN 200910309943A CN 101724964 A CN101724964 A CN 101724964A
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Abstract
The invention aims to provide high-temperature resistant flame-retarding textile. The high-temperature resistant flame-retarding textile is weaved by high-temperature resistant flame-retarding yarns, and the high-temperature resistant flame-retarding yarns are blended with preoxidized fibers, high tenacity flame-retarding fibers and common flame-retarding fibers; and conducting fibers can also be used to weave the high-temperature resistant flame-retarding textile when the high-temperature resistant flame-retarding textile is prepared. The high-temperature resistant flame-retarding textile overcomes the drawback that the preoxidized fiber is difficultly spun, low in tenacity and only has single color of blackness; and the high-temperature resistant flame-retarding textile also has the advantages of high high-temperature resistance, high tenacity, good wearing comfortability, rich color, proper price and safety and reliability for the human body and is reasonable high-temperature resistant flame-retarding textile.
Description
Technical field
The present invention relates to a kind of high-temperature resistant flame-retarding textile, described high-temperature resistant flame-retarding textile is formed by the heat-resistant fireproof yarn weaving, and described heat-resistant fireproof yarn is formed by pre-oxidized fibers and the blending of high-tenacity fire resistance fibre.
Background technology
Along with China's economic development, fire report in all kinds of places is frequent, and people's awareness of the importance of fire prevention progressively improves, and national relevant laws and regulations and standard are put into effect in succession, and the fire protection flame retarding fabric is required and also increase year by year of demand.
At present, fire resistance fibre generally divides common fire-retardant and heat-resistance and flame-retardant fiber.Common fire resistance fibre has: anti-flaming viscose, Vinyon N, melacel, flame-resistant terylene, dimension polyvinyl chloride fibre, retardant cotton, wool etc.; High-temperature fibre has: meta-aramid, p-aramid fiber, polysulfones base acid amides, polyamide-imide fiber, pre-oxidized fibers, polybenzimidazoles, the two oxazoles of polyparaphenylene's benzene, basalt fibre, ceramic fibre etc.In the high-temperature fibre, fibers such as meta-aramid, p-aramid fiber, polysulfones base acid amides, polyamidoimide have higher tension brute force, can be described as the high-tenacity fire resistance fibre again.Can heatproof in high-temperature fibre surpass and have only pre-oxidized fibers, polybenzimidazoles, the two oxazoles of polyparaphenylene's benzene and inorfils such as basalt fibre, ceramic fibre more than 500 ℃.Common fire resistance fibre resistance to elevated temperatures is poor, is used for general flame-resistant garment but spinnability, taking are good, cheap.Require higher fire-entry suit, proximity suit then to need to use resistant to elevated temperatures fire resistance fibre as meta-aramid, p-aramid fiber, polysulfones base acid amides, polyamidoimide etc.Yet, welding, smelting etc. have the clothes that use under the motlten metal splash environment that fire proofing is had higher requirement, needing can the anti-in short-term high temperature more than 500 ℃, what can reach this requirement has only the two oxazoles of pre-oxidized fibers, polybenzimidazoles, polyparaphenylene's benzene, also has inorfils such as basalt fibre, ceramic fibre.Inorfil such as basalt fibre, ceramic fibre spinning property extreme difference, easily brittle failure, difficulty is weaved, and is difficult on the clothes to use.The resistance to elevated temperatures of pre-oxidized fibers can reach 500 ℃～900 ℃, and is heat insulation good, limited oxygen index 45～60, not fusion of high temperature, softening, do not shrink, do not have to melt and advantage such as drip, and moderate, be desirable high temperature resistant textile material.Yet pre-oxidized fibers also has the defective of self, poor, the brittle failure easily of pre-oxidized fibers spinnability, and powerful low, color is that black can't dye, clothes accommodation is little.
At these defectives of pre-oxidized fibers, domestic part scholar, producer have carried out some improvement, but effect is all undesirable:
Chinese patent application " manufacture method of a kind of slow burning fabric or yarn " (number of patent application 96112582.9, patent publication No. CN1177659A) disclose in make yarn or fabric with polyacrylonitrile fibre after, carry out pre-oxidation again and obtain the manufacture method of pre-oxidation fabric, though solved difficult spinning of pre-oxidized fibers and woven problem, but its color is a black can't be changed, and the fabric strength deficiency does not still solve.
Chinese patent application " weaving techniques of pre-oxidized polyacrylonitrile fiber " (number of patent application 88101770.1, patent publication No. CN1036235A) is made into fabric after publication number discloses pre-oxidized fibers and water-soluble fibre blending in, and then the molten soluble fiber that anhydrates, obtain the pre-oxidized fibers fabric at last, utilize the water-soluble fibre of good spinnability to solve the problem of the difficult spinning of pre-oxidized fibers, but its color is a black can't be changed, and the fabric strength deficiency does not still solve.
Chinese patent application " the fine denier binary cladded yarn and the manufacture method thereof that are used for the fire safety clothes " (number of patent application 90100717.X, patent publication No. CN1044963) discloses in pre-oxidized fibers as heart yarn, the method that low-temperature resistant fiber coats for the skin yarn, though can change the black problem of pre-oxidized fibers by dying the skin yarn, but the skin yarn can not be high temperature resistant, directly influenced the resistance to elevated temperatures of fabric.
So, need a kind of heat-resisting quantity good in people's work and the life, powerful high, performance comfortable and easy to wear is good, the high-temperature resistant flame-retarding textile that color is abundant, moderate.
Summary of the invention
The object of the present invention is to provide a kind of high-temperature resistant flame-retarding textile, described high-temperature resistant flame-retarding textile is formed by the heat-resistant fireproof yarn weaving, and described heat-resistant fireproof yarn is formed by pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre blending; Can also inweave conductive fiber when weaving forms.High-temperature resistant flame-retarding textile of the present invention has solved the shortcoming that pre-oxidized fibers is difficult for spinning, powerful low, single black; And heat-resisting quantity is good, and powerful high, performance comfortable and easy to wear is good, and color is abundant, moderate, is desirable high-temperature resistant flame-retarding textile.
Purpose of the present invention is achieved through the following technical solutions:
Described high-temperature resistant flame-retarding textile is formed by the heat-resistant fireproof yarn weaving, described heat-resistant fireproof yarn is formed by pre-oxidized fibers and the blending of high-tenacity fire resistance fibre, and the weight ratio of described pre-oxidized fibers and high-tenacity fire resistance fibre is 40～80: 20～60; Square metre quality of described high-temperature resistant flame-retarding textile is 150～600g/m
2Described high-tenacity fire resistance fibre is a kind of in the two oxazole fibers of meta-aramid fibers, para-aramid fiber, polysulfones base nylon, polyamide-imide fiber, polyparaphenylene's benzene or at least two kinds.
Purpose of the present invention can also be achieved through the following technical solutions:
Described high-temperature resistant flame-retarding textile is formed by the heat-resistant fireproof yarn weaving, described heat-resistant fireproof yarn is formed by pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre blending, and described pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre weight ratio are 40～80: 5～60: 5～40; Square metre quality of described high-temperature resistant flame-retarding textile is 150～600g/m
2
Described high-tenacity fire resistance fibre is a kind of or at least two kinds in para-aramid fiber, meta-aramid fibers, the polysulfones base nylon;
Described common fire resistance fibre is a kind of in polyacrylic and polyester fiber, Fire resistant viscose fiber, melacel, flame retardant polyester fiber, dimension polyvinyl chloride fibre fiber, retardant cotton fiber, the wool fibre or at least two kinds.
Purpose of the present invention can also be achieved through the following technical solutions:
A kind of high-temperature resistant flame-retarding textile, it is characterized in that: described high-temperature resistant flame-retarding textile is formed by the heat-resistant fireproof yarn weaving, described heat-resistant fireproof yarn is formed by pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre, conductive fiber blending, and described pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre, conductive fiber weight ratio are 40～80: 5～60: 5～40: 1～5; Square metre quality of described high-temperature resistant flame-retarding textile is 150～600g/m
2
Described high-tenacity fire resistance fibre is a kind of in para-aramid fiber, meta-aramid fibers, the polysulfones base nylon or at least two kinds;
Described common fire resistance fibre is a kind of in polyacrylic and polyester fiber, Fire resistant viscose fiber, melacel, flame retardant polyester fiber, dimension polyvinyl chloride fibre fiber, retardant cotton fiber, the wool fibre or at least two kinds;
Described conductive fiber is a kind of in metallic conduction fiber, electrically conductive organic fibre, the carbon fiber.
Purpose of the present invention can also be achieved through the following technical solutions:
Described high-temperature resistant flame-retarding textile becomes the heat-resistant fireproof yarn by pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre blending, inweaves conductive fiber when weaving and forms; Described pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre, conductive fiber weight ratio are 40～80: 5～60: 5～40: 1～5; Square metre quality of described high-temperature resistant flame-retarding textile is 150～600g/m
2
Described high-tenacity fire resistance fibre is a kind of in para-aramid fiber, meta-aramid fibers, the polysulfones base nylon or at least two kinds;
Described common fire resistance fibre is a kind of in polyacrylic and polyester fiber, Fire resistant viscose fiber, melacel, flame retardant polyester fiber, dimension polyvinyl chloride fibre fiber, retardant cotton fiber, the wool fibre or at least two kinds;
Described conductive fiber is a kind of in metallic conduction fiber, electrically conductive organic fibre, the carbon fiber.
Purpose of the present invention can also be achieved through the following technical solutions:
Described high-temperature resistant flame-retarding textile becomes the heat-resistant fireproof yarn by pre-oxidized fibers, the blending of high-tenacity fire resistance fibre, inweaves conductive fiber when weaving and forms; Described pre-oxidized fibers, high-tenacity fire resistance fibre, conductive fiber weight ratio are 40～80: 15～60: 1～5; Square metre quality of described high-temperature resistant flame-retarding textile is 150～600g/m
2
Described high-tenacity fire resistance fibre is a kind of in para-aramid fiber, meta-aramid fibers, the polysulfones base nylon or at least two kinds;
Described conductive fiber is a kind of in metallic conduction fiber, electrically conductive organic fibre, the carbon fiber.
The present invention compared with prior art has following excellent effect:
1. the invention provides poor, the easily brittle failure of better solution pre-oxidized fibers spinnability, powerful low, color is the method that black can't dyeing speck;
2. production process of the present invention has reduced the textile dyeing link, produces to consume energy less, pollute and lack, and the back arrangement does not need to add fire retardant and other RESIN FINISH, does not have formaldehyde and other noxious materials to produce the production process energy-conserving and environment-protective;
3. the limited oxygen index height of the pre-oxidized fibers that adopts of the present invention, the fabrics flame resistance excellent performance, especially high temperature resistant heat insulation performance, can anti-high temperature more than 500 ℃, the metal melt of the metal drop of welding, smelting splash, contact in short-term with high-temperature resistant flame-retarding textile of the present invention, can not cause damage fabric;
4. the present invention compares with flame-retardant after-finishing, and fabric has permanent anti-flammability, and washing back fire resistance can not descend, and fabric strength is better.
5. can not produce molten drop after the present invention's burning, no toxic gas and heavy smog, safe and reliable to human body, security performance is good.
The specific embodiment
Embodiment 1:
High-temperature resistant flame-retarding textile described in the present embodiment is the fire smothering blanket fabric.
The fabric of present embodiment is formed by the heat-resistant fireproof yarn weaving, and described heat-resistant fireproof yarn is formed by pre-oxidized fibers and the blending of high-tenacity fire resistance fibre; Described high-tenacity fire resistance fibre is a para-aramid fiber; The color of described para-aramid fiber is yellow; The weight ratio of described pre-oxidized fibers and described para-aramid fiber can be 40～80: select in 20～60 the scope, preferred weight ratio is 80: 20; The fineness of described heat-resistant fireproof yarn is 58.3tex, and square metre quality of described fire smothering blanket fabric is 600g/m
2
After testing, the fire resistance index of the fabric of present embodiment reaches the requirement of the BS EN of European Union 1869～1997 " fire smothering blanket " standard.
The making step of the described fabric of present embodiment is as follows:
With described pre-oxidized fibers and described para-aramid fiber through shredding, combing, drafting, rove, spun yarn, winder, warping, sizing, weave, the processing of back arrangement, obtain described fire smothering blanket fabric;
This preparation method is a conventional method, need defer to following principle in preparation process:
A. in described shredding, combing step, should be starting point, adopt corresponding technological parameter with " many loose few low speed of beating, comb more ";
Because the fibre frictoin factor of described pre-oxidized fibers is big, easily produces static, influences fiber and becomes net, slivering, causes the heat-resistant fireproof yarn in later stage to produce a large amount of filoplumes; So humidity indoor in this step is 60%-85%, a little more than conventional spinning; Indoor temperature is 25 ℃-35 ℃;
B. in described drafting, in order to guarantee the mixed uniformity, adopt the twice drafting, slubbing, two roads all adopt 8 and close, and adopt less back area draft;
C. in described spinning heat-resistant fireproof rove step, adopt FA498 type Speed frames, design less total draft multiple, suitable spinning tension, help improving bar evenness;
D. in described spinning heat-resistant fireproof yarn step, adopt the JFA502 type closely to spin fine spining machine, adopt big back area draft to space and little back zone drafting multiple; Design that big back area draft spaces and little back zone drafting multiple;
Technical scheme in the present embodiment has solved the defective that pre-oxidized fibers exists in the existing technology of field of textiles:
1. select the para-aramid fiber and the pre-oxidized fibers blending of high-tenacity for use, can improve the brute force of fabric greatly, solved the problem of pre-oxidized fibers spinnability difference;
2. selecting intrinsic colour for use is yellow para-aramid fiber and pre-oxidized fibers blending, obtains having color fire smothering blanket fabric, solves the single black problem of pre-oxidized fibers.
Embodiment 2:
High-temperature resistant flame-retarding textile described in the present embodiment is sofa, mattress fire retardant cushion layer fabric.
The fabric of present embodiment is formed by the heat-resistant fireproof yarn weaving, and described heat-resistant fireproof yarn is formed by pre-oxidized fibers and the blending of high-tenacity fire resistance fibre; Described high-tenacity fire resistance fibre is a polysulfones base nylon; The weight ratio of described pre-oxidized fibers and described polysulfones base nylon can be 40～80: select in 20～60 the scope, preferred weight ratio is 50: 50; The fineness of described heat-resistant fireproof yarn is 41.6tex, and square metre quality of described sofa, mattress fire retardant cushion layer fabric is 350g/m
2
After testing, the fabric of present embodiment meets the requirement of standard GB 20286 " public place fire-retardant product and assembly combustibility require and sign ".
The manufacture method and the equipment of the fabric of present embodiment are substantially the same manner as Example 1, and difference is: with the processing of dyeing earlier before described drafting, combing step of described polysulfones base nylon.
Raw material and equipment related in the present embodiment all can be bought acquisition in market.
Embodiment 3:
High-temperature resistant flame-retarding textile described in the present embodiment is the fire retardant cushion layer fabric that is used for train, aircraft back cushion, cushion.
The fabric of present embodiment is formed by the heat-resistant fireproof yarn weaving, and described heat-resistant fireproof yarn is formed by pre-oxidized fibers and the blending of high-tenacity fire resistance fibre; Described high-tenacity fire resistance fibre is meta-aramid fibers and para-aramid fiber; The color of described p-aramid fiber is yellow; The color of described meta-aramid is yellow; The weight ratio of described pre-oxidized fibers, meta-aramid fibers, para-aramid fiber can be 40～80: select in 20～60: 20～60 the scope, preferred weight ratio is 40: 30: 30; The fineness of described heat-resistant fireproof yarn is 45tex, and the described square metre quality that is used for the fire retardant cushion layer fabric of train, aircraft back cushion, cushion is 400g/m
2
After testing, the fabric of present embodiment meets the requirement of standard GB 20286 " public place fire-retardant product and assembly combustibility require and sign ".
The manufacture method and the equipment of the fabric of present embodiment are substantially the same manner as Example 2, and raw material and equipment related in the present embodiment all can be bought acquisition in market.
Embodiment 4:
High-temperature resistant flame-retarding textile described in the present embodiment is the welding protection suit fabric.
The fabric of present embodiment is formed by the heat-resistant fireproof yarn weaving, and described heat-resistant fireproof yarn is formed by pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre blending; Described high-tenacity fire resistance fibre is a para-aramid fiber, and described common fire resistance fibre is a Fire resistant viscose fiber; The weight ratio of described pre-oxidized fibers, para-aramid fiber, Fire resistant viscose fiber can be 40～80: 5～60: select in 5～40, preferred weight ratio is 55: 10: 35; The color of described para-aramid fiber is yellow, and the color of described Fire resistant viscose fiber is a Chinese red; The fineness of described heat-resistant fireproof yarn is 22.4tex, and square metre quality of described welding protection suit fabric is 156g/m
2The color of described welding protection suit fabric is brown;
After testing, the fabric of present embodiment meets the requirement of standard GB 8965.2～2009 " the fire-retardant protection part 2 welding of protective clothes clothes "; Described welding protection suit fabric after flame time is 1 second, and the time of glowing is 1 second, and char length is 30mm, reaches the standard of welding clothes fully.
The manufacture method and the equipment of the fabric of present embodiment are substantially the same manner as Example 1, and difference is:
With the processing of before described drafting, rove step, dyeing earlier of described Fire resistant viscose fiber, obtain the Fire resistant viscose fiber that color is a Chinese red;
Raw material and equipment related in the present embodiment all can be bought acquisition in market.
Technical scheme in the present embodiment has solved the defective that pre-oxidized fibers exists in the existing technology of field of textiles:
1. select for use good spinnability, Fire resistant viscose fiber and pre-oxidized fibers that comfortableness is good to carry out blending, solved poor, the problem of brittle failure easily of pre-oxidized fibers spinnability;
2. earlier stainable Fire resistant viscose fiber is dyeed, to catch the Fire resistant viscose fiber of color again and carry out blending with this para-aramid fiber, pre-oxidized fibers as yellow, change the color of pre-oxidized fibers heat-resistant fireproof yarn by color and blending rate, solve the single black problem of pre-oxidized fibers.
Embodiment 5:
High-temperature resistant flame-retarding textile described in the present embodiment is the flame-retardant clothing fabric.
The fabric of present embodiment is formed by the heat-resistant fireproof yarn weaving, and described heat-resistant fireproof yarn is formed by pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre blending; Described high-tenacity fire resistance fibre is a para-aramid fiber, and described common fire resistance fibre is a polyacrylic and polyester fiber; The color of described para-aramid fiber is yellow, and the color of described polyacrylic and polyester fiber is blue; The weight ratio of described pre-oxidized fibers, para-aramid fiber, polyacrylic and polyester fiber can be 40～80: 5～60: select in 5～40, preferred weight ratio is 60: 10: 30; The fineness of described heat-resistant fireproof yarn is 36tex, and square metre quality of described flame-retardant clothing fabric is 210g/m
2The color of described flame-retardant clothing fabric is a green black colour.
After testing, the fabrics flame resistance performance indications of present embodiment are as follows: press the method check among the GB 8965.1～2009 " the fire-retardant protection part 1 of protective clothes flame-retardant clothing ", the afterflame burning time of described flame-retardant clothing fabric is 0 second, the time of glowing is 1 second, char length is 25mm, reaches the standard of flame-retardant clothing fully.
The manufacture method and the equipment of the fabric of present embodiment are substantially the same manner as Example 4, and raw material and equipment related in the present embodiment all can be bought acquisition in market.
Embodiment 6:
High-temperature resistant flame-retarding textile described in the present embodiment is back cushion, cushion fire retardant cushion layer fabric or the fire blanket fabric of automobile, cinema.
The fabric of present embodiment is formed by the heat-resistant fireproof yarn weaving, and described heat-resistant fireproof yarn is formed by pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre blending; Described high-tenacity fire resistance fibre is a para-aramid fiber, and described common fire resistance fibre is a flame retardant polyester fiber; The color of described para-aramid fiber is yellow, and the color of described flame retardant polyester fiber is yellow; The weight ratio of described pre-oxidized fibers, para-aramid fiber, flame retardant polyester fiber can be 40～80: 5～60: select in 5～40, preferred weight ratio is 60: 5: 35; The fineness of described heat-resistant fireproof yarn is 48.5tex, and square metre quality of the back cushion of described automobile, cinema, cushion fire retardant cushion layer fabric or fire blanket fabric is 480g/m
2
After testing, the performance of the fabric of present embodiment meets the requirement of standard GB 20286 " public place fire-retardant product and assembly combustibility require and sign ".
The manufacture method and the equipment of the fabric of present embodiment are substantially the same manner as Example 4, and raw material and equipment related in the present embodiment all can be bought acquisition in market.
Embodiment 7:
High-temperature resistant flame-retarding textile described in the present embodiment is the fire-entry suit fabric.
The fabric of present embodiment is formed by the heat-resistant fireproof yarn weaving, and described heat-resistant fireproof yarn is formed by pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre, conductive fiber blending; Described high-tenacity fire resistance fibre is a para-aramid fiber, and described common fire resistance fibre is the dimension polyvinyl chloride fibre fiber, and described conductive fiber is the metallic conduction fiber, and the color of described para-aramid fiber is yellow, and the color of described dimension polyvinyl chloride fibre fiber is brown; The weight ratio of described pre-oxidized fibers, para-aramid fiber, dimension polyvinyl chloride fibre fiber, metallic conduction fiber can be 40～80: 5～60: 5～40: select in 1～5, preferred weight ratio is 63: 5: 30: 2; The fineness of described heat-resistant fireproof yarn is 36.4tex, and square metre quality of described fire-entry suit fabric is 248.3g/m
2The color of described fire-entry suit fabric is a brown-green.
After testing, the fire resistance index of the fabric of present embodiment is as follows: detect by GB GA 634～2006 " fireman's protective clothing for proximity fire fighting ", after flame time is 0 second, and the time of glowing is 0 second, and char length is 20mm, reaches the standard of fireman's proximity suit fully.
The manufacture method and the equipment of the fabric of present embodiment are substantially the same manner as Example 4, and raw material and equipment related in the present embodiment all can be bought acquisition in market.
Embodiment 8:
High-temperature resistant flame-retarding textile described in the present embodiment is the welding protection suit fabric.
The fabric of present embodiment becomes the heat-resistant fireproof yarn by pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre blending, inweaves conductive fiber when weaving and forms; Described high-tenacity fire resistance fibre is a para-aramid fiber, and described common fire resistance fibre is a wool fibre, and described conductive fiber is an electrically conductive organic fibre, and the color of described para-aramid fiber is yellow, and the color of described wool fibre is yellow; The weight ratio of described pre-oxidized fibers, para-aramid fiber, wool fibre, electrically conductive organic fibre can be 40～80: 5～60: 5～40: select in 1～5, preferred weight ratio is 60: 7: 30: 3; The fineness of described heat-resistant fireproof yarn is 36.4tex, and square metre quality of described welding clothes fabric is 255g/m
2The color of described welding protection suit fabric is blackish green.
After testing, the fabric of present embodiment meets the requirement of standard GB 8965.2～2009 " the fire-retardant protection part 2 welding of protective clothes clothes "; Described welding protection suit fabric after flame time is 0 second, and the time of glowing is 1 second, and char length is 35mm, reaches the standard of welding clothes fully.
The manufacture method and the equipment of the fabric of present embodiment are substantially the same manner as Example 4, and difference is: inweave described electrically conductive organic fibre in the step described weaving; Raw material and equipment related in the present embodiment all can be bought acquisition in market.
Embodiment 9:
High-temperature resistant flame-retarding textile described in the present embodiment is the welding protection suit fabric.
The fabric of present embodiment becomes the heat-resistant fireproof yarn by described high-temperature resistant flame-retarding textile by pre-oxidized fibers, the blending of high-tenacity fire resistance fibre, inweaves conductive fiber when weaving and forms; Described high-tenacity fire resistance fibre is a para-aramid fiber, and described conductive fiber is an electrically conductive organic fibre, and the color of described para-aramid fiber is yellow; The weight ratio of described pre-oxidized fibers, para-aramid fiber, electrically conductive organic fibre can be 40～80: 15～60: select in 1～5, preferred weight ratio is 55: 42: 3; The fineness of described heat-resistant fireproof yarn is 35tex, and square metre quality of described welding clothes fabric is 230g/m
2The color of described welding protection suit fabric is blackish green.
After testing, the fabric of present embodiment meets the requirement of standard GB 8965.2～2009 " the fire-retardant protection part 2 welding of protective clothes clothes "; Described welding protection suit fabric after flame time is 0 second, and the time of glowing is 1 second, and char length is 30mm, reaches the standard of welding clothes fully.
The manufacture method and the equipment of the fabric of present embodiment are substantially the same manner as Example 1, and difference is: inweave described electrically conductive organic fibre in the step described weaving; Raw material and equipment related in the present embodiment all can be bought acquisition in market.
Claims (15)
1. high-temperature resistant flame-retarding textile, it is characterized in that: described high-temperature resistant flame-retarding textile is formed by the heat-resistant fireproof yarn weaving, described heat-resistant fireproof yarn is formed by pre-oxidized fibers and the blending of high-tenacity fire resistance fibre, and the weight ratio of described pre-oxidized fibers and high-tenacity fire resistance fibre is 40～80: 20～60; Square metre quality of described high-temperature resistant flame-retarding textile is 150～600g/m2.
2. high-temperature resistant flame-retarding textile according to claim 1 is characterized in that: described high-tenacity fire resistance fibre is a kind of in the two oxazole fibers of meta-aramid fibers, para-aramid fiber, polysulfones base nylon, polyamide-imide fiber, polyparaphenylene's benzene or at least two kinds.
3. high-temperature resistant flame-retarding textile according to claim 2 is characterized in that: described high-tenacity fire resistance fibre is a para-aramid fiber; The color of described para-aramid fiber is yellow; The weight ratio of described pre-oxidized fibers and described para-aramid fiber is 80: 20; The fineness of described heat-resistant fireproof yarn is 58.3tex, and square metre quality of described high-temperature resistant flame-retarding textile is 600g/m2.
4. high-temperature resistant flame-retarding textile according to claim 2 is characterized in that: described high-tenacity fire resistance fibre is a polysulfones base nylon; The weight ratio of described pre-oxidized fibers and described polysulfones base nylon is 50: 50; The fineness of described heat-resistant fireproof yarn is 41.6tex, and square metre quality of described high-temperature resistant flame-retarding textile is 350g/m2.
5. high-temperature resistant flame-retarding textile according to claim 2 is characterized in that: described high-tenacity fire resistance fibre is meta-aramid fibers and para-aramid fiber; The weight ratio of described pre-oxidized fibers, meta-aramid fibers, para-aramid fiber is 40: 30: 30; The fineness of described heat-resistant fireproof yarn is 45tex, and square metre quality of described high-temperature resistant flame-retarding textile is 400g/m2.
6. high-temperature resistant flame-retarding textile, it is characterized in that: described high-temperature resistant flame-retarding textile is formed by the heat-resistant fireproof yarn weaving, described heat-resistant fireproof yarn is formed by pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre blending, and described pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre weight ratio are 40～80: 5～60: 5～40; Square metre quality of described high-temperature resistant flame-retarding textile is 150～600g/m2;
Described high-tenacity fire resistance fibre is a kind of or at least two kinds in para-aramid fiber, meta-aramid fibers, the polysulfones base nylon;
Described common fire resistance fibre is a kind of in polyacrylic and polyester fiber, Fire resistant viscose fiber, melacel, flame retardant polyester fiber, dimension polyvinyl chloride fibre fiber, retardant cotton fiber, the wool fibre or at least two kinds.
7. high-temperature resistant flame-retarding textile according to claim 6 is characterized in that: described high-tenacity fire resistance fibre is a para-aramid fiber, and described common fire resistance fibre is a Fire resistant viscose fiber; The weight ratio of described pre-oxidized fibers, para-aramid fiber, Fire resistant viscose fiber is 55: 10: 35; The color of described para-aramid fiber is yellow, and the color of described Fire resistant viscose fiber is a Chinese red; The fineness of described heat-resistant fireproof yarn is 22.4tex, and square metre quality of described high-temperature resistant flame-retarding textile is 156g/m2.
8. high-temperature resistant flame-retarding textile according to claim 6 is characterized in that: described high-tenacity fire resistance fibre is a para-aramid fiber, and described common fire resistance fibre is a polyacrylic and polyester fiber; The color of described para-aramid fiber is yellow, and the color of described polyacrylic and polyester fiber is blue; The weight ratio of described pre-oxidized fibers, para-aramid fiber, polyacrylic and polyester fiber is 60: 10: 30; The fineness of described heat-resistant fireproof yarn is 36tex, and square metre quality of described high-temperature resistant flame-retarding textile is 210g/m2.
9. high-temperature resistant flame-retarding textile according to claim 6 is characterized in that: described high-tenacity fire resistance fibre is a para-aramid fiber, and described common fire resistance fibre is a flame retardant polyester fiber; The color of described para-aramid fiber is yellow, and the color of described flame retardant polyester fiber is yellow; The weight ratio of described pre-oxidized fibers, para-aramid fiber, flame retardant polyester fiber is 60: 5: 35; The fineness of described heat-resistant fireproof yarn is 48.5tex, and square metre quality of described high-temperature resistant flame-retarding textile is 480g/m2.
10. high-temperature resistant flame-retarding textile, it is characterized in that: described high-temperature resistant flame-retarding textile is formed by the heat-resistant fireproof yarn weaving, described heat-resistant fireproof yarn is formed by pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre, conductive fiber blending, and described pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre, conductive fiber weight ratio are 40～80: 5～60: 5～40: 1～5; Square metre quality of described high-temperature resistant flame-retarding textile is 150～600g/m2;
Described high-tenacity fire resistance fibre is a kind of in para-aramid fiber, meta-aramid fibers, the polysulfones base nylon or at least two kinds;
Described common fire resistance fibre is a kind of in polyacrylic and polyester fiber, Fire resistant viscose fiber, melacel, flame retardant polyester fiber, dimension polyvinyl chloride fibre fiber, retardant cotton fiber, the wool fibre or at least two kinds;
Described conductive fiber is a kind of in metallic conduction fiber, electrically conductive organic fibre, the carbon fiber.
11. high-temperature resistant flame-retarding textile according to claim 10 is characterized in that: described high-tenacity fire resistance fibre is a para-aramid fiber, and described common fire resistance fibre is the dimension polyvinyl chloride fibre fiber, and described conductive fiber is the metallic conduction fiber; The color of described para-aramid fiber is yellow, and the color of described dimension polyvinyl chloride fibre fiber is brown; The weight ratio of described pre-oxidized fibers, para-aramid fiber, dimension polyvinyl chloride fibre fiber, metallic conduction fiber is 63: 5: 30: 2; The fineness of described heat-resistant fireproof yarn is 36.4tex, and square metre quality of described high-temperature resistant flame-retarding textile is 248.3g/m2.
12. a high-temperature resistant flame-retarding textile is characterized in that: described high-temperature resistant flame-retarding textile becomes the heat-resistant fireproof yarn by pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre blending, inweaves conductive fiber when weaving and forms; Described pre-oxidized fibers, high-tenacity fire resistance fibre, common fire resistance fibre, conductive fiber weight ratio are 40～80: 5～60: 5～40: 1～5; Square metre quality of described high-temperature resistant flame-retarding textile is 150～600g/m2;
Described high-tenacity fire resistance fibre is a kind of in para-aramid fiber, meta-aramid fibers, the polysulfones base nylon or at least two kinds;
Described common fire resistance fibre is a kind of in polyacrylic and polyester fiber, Fire resistant viscose fiber, melacel, flame retardant polyester fiber, dimension polyvinyl chloride fibre fiber, retardant cotton fiber, the wool fibre or at least two kinds;
Described conductive fiber is a kind of in metallic conduction fiber, electrically conductive organic fibre, the carbon fiber.
13. high-temperature resistant flame-retarding textile according to claim 12, it is characterized in that: described high-tenacity fire resistance fibre is a para-aramid fiber, described common fire resistance fibre is a wool fibre, described conductive fiber is an electrically conductive organic fibre, the color of described para-aramid fiber is yellow, and the color of described wool fibre is yellow; The weight ratio of the weight ratio of described pre-oxidized fibers, para-aramid fiber, wool fibre, electrically conductive organic fibre is 60: 7: 30: 3; The fineness of described heat-resistant fireproof yarn is 36.4tex, and square metre quality of described high-temperature resistant flame-retarding textile is 255g/m2.
14. a high-temperature resistant flame-retarding textile is characterized in that: described high-temperature resistant flame-retarding textile becomes the heat-resistant fireproof yarn by pre-oxidized fibers, the blending of high-tenacity fire resistance fibre, inweaves conductive fiber when weaving and forms; Described pre-oxidized fibers, high-tenacity fire resistance fibre, conductive fiber weight ratio are 40～80: 15～60: 1～5; Square metre quality of described high-temperature resistant flame-retarding textile is 150～600g/m2;
Described high-tenacity fire resistance fibre is a kind of in para-aramid fiber, meta-aramid fibers, the polysulfones base nylon or at least two kinds;
Described conductive fiber is a kind of in metallic conduction fiber, electrically conductive organic fibre, the carbon fiber.
15. high temperature resistant fabric according to claim 14 is characterized in that: described high-tenacity fire resistance fibre is a para-aramid fiber, and described conductive fiber is an electrically conductive organic fibre, and the color of described para-aramid fiber is yellow; The weight ratio of described pre-oxidized fibers, para-aramid fiber, electrically conductive organic fibre is 55: 42: 3; The fineness of described heat-resistant fireproof yarn is 35tex, and square metre quality of described high temperature resistant fabric is 230g/m2.
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Application publication date: 20100609 |