CN109487398A - A kind of Antistatic Fabric and its preparation process - Google Patents
A kind of Antistatic Fabric and its preparation process Download PDFInfo
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- CN109487398A CN109487398A CN201710813078.9A CN201710813078A CN109487398A CN 109487398 A CN109487398 A CN 109487398A CN 201710813078 A CN201710813078 A CN 201710813078A CN 109487398 A CN109487398 A CN 109487398A
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/533—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2246—Esters of unsaturated carboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/10—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
Abstract
The invention discloses a kind of Antistatic Fabric and its preparation process, the Antistatic Fabric includes following raw materials: flame-retardant acrylic fibre fiber.A kind of Antistatic Fabric of the present invention, preparation method is simple, and fabric specific resistance is lower, and antistatic property is good, and wash resistant, rub resistance are good, can be used for high-grade fabric and the industrial circle with antistatic requirement.
Description
Technical field
The present invention relates to technical field of textile fabric more particularly to a kind of Antistatic Fabric and its preparation processes.
Background technique
With the continuous improvement of people's living standards, more and more people start to pursue the quality of life, and wear especially
Valued by people, common saying has the saying of title " people is by clothes horse by saddle ", can embody people to the importance of dressing.
In dry autumn, in daily life, we often run into this phenomenon: the sleep undressed at night when
It waits, crack the sound is often heard in dark, and with blue light, when meeting is shaken hands, finger can be felt to refer to upon contacting other side
Shouting pain as prong thorn；When getting up morning to comb one's hair, hair can be often " floaing " unreasonable more random, sliding door handle, when turning on the tap
Will " electric shock ", the sound of sending ", " often.And these are exactly the electrostatic occurred in human body.Above-mentioned electrostatic is in daily life
It will appear some harm and influence in work.In autumn, the skin young man that compares is drier by the elderly, due to and the elderly's painstaking effort
The factors such as aging, the anti-interference ability decrease of guard system, therefore the elderly is easier to be influenced by electrostatic.However cardiovascular system
Natively there is a elderly of various lesions, electrostatic but will aggravate disease or induce the arrhythmia cordis such as ventricular premature beat.Excessively high is quiet
Electricity can also make one lather, headache, uncomfortable in chest, expiratory dyspnea, cough.
In the prior art, common textile fabric is usually and is made of chemical fibre fabric, which is easy to volatilize,
Only have some basic functions, such as the functions such as basic waterproof, moisture-penetrable ventilated, fire prevention, high temperature resistant, acid and alkali-resistance；But only have
There are these basic functions not to be able to satisfy the neck such as materials requirement, such as aerospace, operation of precision tool of certain special dimensions
Domain requires that electrostatic should be reduced, and prevents the disorder for causing instrument and meter and device data, oil depot and gas station attendant should be reduced
Electrostatic prevents fire caused by electrostatic and explosion, and hospital and home for destitute medical staff should reduce electrostatic, in favor of instrument detection,
Safety and stability under the particular surroundings such as operation.
Therefore, it studies a kind of Antistatic Fabric haveing excellent performance and its preparation process has become those skilled in the art urgently
The technical problem of solution.
Summary of the invention
Of the existing technology in order to solve the problems, such as, the present invention provides a kind of Antistatic Fabric and its preparation processes.
Technical solution is as follows:
A kind of Antistatic Fabric, including following raw materials: flame-retardant acrylic fibre fiber.
A kind of Antistatic Fabric is prepared by following raw materials: nylon fiber, flame-retardant acrylic fibre fiber, conductive fiber.
A kind of Antistatic Fabric is prepared by the raw material of following mass percents: 0.5-15% nylon fiber, 75-
90% flame-retardant acrylic fibre fiber, 3-15% conductive fiber.
Preferably, the conductive fiber is electrically conductive filament fiber.
Preferably, the nylon fiber is nylon short fibre.
Preferably, the flame-retardant acrylic fibre fiber the preparation method comprises the following steps: by 4-9 parts by weight octadecyldiethanol amine, 3-7 weight
Measure part glycerin triglycidyl ether, 0.5-1.5 parts by weight laruyl alcohol oleate, 2-4 weight account polyethylene alcohol, 1.5-2.5 weight
Measure part octadecylamine polyoxyethylene ether, 2-5 parts by weight triethanolamine, 7-13 parts by weight of flame retardant, 5-15 parts by weight of polypropylene
Acid esters lotion is added in 75-95 parts by weight water and is uniformly mixed, and obtains fire-retardant treatment liquid；Acrylic fiber is impregnated in fire-retardant treatment liquid
In, temperature is 80-100 DEG C, dip time 50-100min, and the mass ratio of the acrylic fiber and fire-retardant treatment liquid is 1:10-
30；Take out acrylic fiber, temperature be 95-105 DEG C dry 1-5 hours to get.
It is further preferred that the flame-retardant acrylic fibre fiber the preparation method comprises the following steps: by polyvinyl alcohol, water, dimethyl ethenyl
Chlorosilane, ethyl thioglycolate are 1:(1-3 in mass ratio): (0.4-0.8): (0.01-0.015) mixing is 85- in temperature
It is stirred to react at 95 DEG C 3-7 hours, obtains modified polyvinylalcohol；By 4-9 parts by weight octadecyldiethanol amine, 3-7 parts by weight
Glycerin triglycidyl ether, 0.5-1.5 parts by weight laruyl alcohol oleate, the part by weight modified polyvinyl alcohol of 2-4,1.5-2.5 weight
Measure part octadecylamine polyoxyethylene ether, 2-5 parts by weight triethanolamine, 7-13 parts by weight of flame retardant, 5-15 parts by weight of polypropylene
Acid esters lotion is added in 75-95 parts by weight water and is uniformly mixed, and obtains fire-retardant treatment liquid；Acrylic fiber is impregnated in fire-retardant treatment liquid
In, temperature is 80-100 DEG C, dip time 50-100min, and the mass ratio of the acrylic fiber and fire-retardant treatment liquid is 1:10-
30；Take out acrylic fiber, temperature be 95-105 DEG C dry 1-5 hours to get.
The fire retardant is siliceous phosphonate fire retardant and/or phosphorus-nitrogen containing flame retardant.In one embodiment of the present invention,
The fire retardant is made of the siliceous phosphonate fire retardant of 75-85wt% and 15-25wt% phosphorus-nitrogen containing flame retardant.
The phosphorus-nitrogen containing flame retardant is the water-soluble phosphorus nitrogenated flame retardant of amido-containing acid ester structure.
The present invention also provides a kind of preparation processes of Antistatic Fabric, comprising the following steps:
By nylon fiber and flame-retardant acrylic fibre fiber blend at scribbled, then through to and/or broadwise on use mixed yarn
Line and conductive fiber carry out warping, and weaving obtains fabric.
Technical effect:
A kind of Antistatic Fabric of the present invention, preparation method is simple, and fabric specific resistance is lower, and antistatic property is good, wash resistant,
Rub resistance is good, can be used for high-grade fabric and the industrial circle with antistatic requirement.
Specific embodiment
Elongation at break measurement: it is in length when being straightened without extending that measurement flame-retardant acrylic fibre fiber sample, which is applied first loading,
For L0, then in a manner of described in ASTM D2256-2002 tested flame-retardant acrylic fibre fiber sample is stretched, and measures its stretching
It is L1 to length when fracture, then the elongation at break of the flame-retardant acrylic fibre fiber is (L1-L0)/L0 × 100%.
Limiting oxygen index determination: it is carried out referring to FZT 50017-2011 " polyester fiber flammability test method oxygen index method ".
Determination of resistivity: flame-retardant acrylic fibre fiber sample both ends are fixed on EST121 type digital resistance micro current instrument
Its resistance value (R) is measured in (Beijing Zhong Yiyouxin Science and Technology Ltd.), calculates fabric resistor rate, resistivity using following equation
(Ω cm)=π D2R/4L, wherein D is fibre diameter (cm), and L is fibre length (cm), and R is resistance value (Ω).
Polyvinyl alcohol is the model 088-50 that Inner Mongol Shuan Xin environment-friendly materials limited liability company provides in embodiment
(2488) polyvinyl alcohol.
Dimethyl vinyl chlorosilane in embodiment, No. CAS: 1719-58-0.
Ethyl thioglycolate in embodiment, No. CAS: 623-51-8.
Octadecyldiethanol amine in embodiment, No. CAS: 10213-78-2.
Glycerin triglycidyl ether in embodiment, is provided by Hubei Yuancheng Saichuang Technology Co., Ltd., and No. CAS:
25038-04-4。
Laruyl alcohol oleate in embodiment, No. CAS: 36078-10-1.
Octadecylamine polyoxyethylene ether is the model AC- that Jiangsu Hai'an Petrochemical Plant provides in embodiment
1810 octadecylamine polyoxyethylene ether.
Triethanolamine in embodiment, No. CAS: 102-71-6.
Siliceous phosphonate fire retardant is referring to application number in embodiment: embodiment 1 in 200310117742.4 Chinese patent
Shown method preparation.
The water-soluble phosphorus nitrogenated flame retardant of amido-containing acid ester structure is referring to application number in embodiment:
201310689455.4 Chinese patent in the preparation of method shown in embodiment 3.
Polyacrylate dispersion is referring to application number in embodiment: 1 institute of embodiment in 201310579303.9 Chinese patent
Show prepared by method.
Acrylic fiber is provided by Suzhou Long Bang macromolecular fibre Co., Ltd in embodiment, and specification is 2.2D × 64mm.
Nylon short fibre in embodiment: Britain's Shakespear's nylon short fibre of 2.4dtex 63mm.
Electrically conductive filament fiber is the silver-plated conductive fibre that the extraordinary weaving Science and Technology Ltd. of Dongguan City life cyclopentadienyl provides in embodiment
Tie up silk, specification 70D.
Embodiment 1
Using Britain's Shakespear's nylon short fibre of the 2.4dtex 63mm of 1wt%, with 99wt% flame-retardant acrylic fibre fiber
It is carried out by common process blended, forms the staple yarn of 30s/2, then through to equal using above-mentioned staple yarn and electrically conductive filament
Neat and well spaced warp makes electrically conductive filament ratio reach the 15% of fabric total weight, passes through common process weaving.The surface of finished fabric
Specific resistance < 106.After 10 washings, fabric surface specific resistance < 106.Through the continuous rub resistance test of 72h, surface specific resistance
< 106。
Embodiment 2
Using Britain's Shakespear's nylon short fibre of the 2.4dtex 63mm of 10wt%, with 90wt% flame-retardant acrylic fibre fiber
It is carried out by common process blended, forms the staple yarn of 30s/2, then equal using above-mentioned staple yarn and electrically conductive filament in broadwise
Neat and well spaced warp makes electrically conductive filament ratio reach the 3% of fabric total weight, passes through common process weaving.The surface of finished fabric
Specific resistance < 106.After 10 washings, fabric surface specific resistance < 106.Through the continuous rub resistance test of 72h, surface specific resistance
< 106。
Embodiment 3
Using Britain's Shakespear's nylon short fibre of the 2.4dtex 63mm of 15wt%, with 85wt% flame-retardant acrylic fibre fiber
It is carried out by common process blended, forms the staple yarn of 30s/2, then long using above-mentioned staple yarn and conduction in warp, broadwise
The uniform warping of silk, makes electrically conductive filament ratio reach the 5% of fabric total weight, passes through common process weaving.Finished fabric
Surface specific resistance < 106.After 10 washings, fabric surface specific resistance < 106.Through the continuous rub resistance test of 72h, surface ratio
Resistance < 106。
Comparative example 1
Yarn weaving is carried out after fabric molding by common process using the 100% flame-retardant acrylic fibre fiber of 30s/2 to use
Antistatic finish makes fabric obtain antistatic property, the surface specific resistance < 10 of finished fabric6.After 10 washings, fabric table
Area specific resistance > 1012.Through the continuous rub resistance test of 72h, surface specific resistance > 1010。
Embodiment 4
A kind of Antistatic Fabric is prepared by the raw material of following mass percents: 14.25% nylon short fibre,
80.75% flame-retardant acrylic fibre fiber, 5% electrically conductive filament fiber.
The flame-retardant acrylic fibre fiber the preparation method comprises the following steps: by polyvinyl alcohol, water, dimethyl vinyl chlorosilane, sulfydryl second
Acetoacetic ester is 1:2:0.6:0.012 mixing in mass ratio, and with revolving speed being 150 revs/min at being 90 DEG C in temperature, to be stirred to react 5 small
When, obtain modified polyvinylalcohol；By 7.5 parts by weight octadecyldiethanol amines, 3.5 parts by weight glycerin triglycidyl ethers, 1
Parts by weight laruyl alcohol oleate, 3 part by weight modified polyvinyl alcohol, 2 parts by weight octadecylamine polyoxyethylene ether, 3 parts by weight three
Ethanol amine, the siliceous phosphonate fire retardant of 10 parts by weight, 10 parts by weight of polypropylene acid esters lotions are added in 85 parts by weight water with revolving speed
It is uniformly mixed for 150 revs/min of stirring 20min, obtains fire-retardant treatment liquid；Acrylic fiber is impregnated in fire-retardant treatment liquid, temperature
It is 90 DEG C, dip time 80min, the mass ratio of the acrylic fiber and fire-retardant treatment liquid is 1:20；Acrylic fiber is taken out,
Temperature be 100 DEG C dry 3 hours to get.
A kind of preparation process of Antistatic Fabric, comprising the following steps:
Nylon short fibre and flame-retardant acrylic fibre fiber is blended at scribbled by common process, form the short fibre of 30s/2
Tie up yarn, then through using scribbled and electrically conductive filament fiber to carry out warping to in broadwise, by common process weaving,
Obtain fabric.
Embodiment 5
A kind of Antistatic Fabric is prepared by the raw material of following mass percents: 14.25% nylon short fibre,
80.75% flame-retardant acrylic fibre fiber, 5% electrically conductive filament fiber.
The flame-retardant acrylic fibre fiber the preparation method comprises the following steps: by 7.5 parts by weight octadecyldiethanol amines, 3.5 parts by weight third
Triol triglycidyl ether, 1 parts by weight laruyl alcohol oleate, 3 weight account polyethylene alcohol, 2 parts by weight octadecylamine polyoxy second
85 weights are added in alkene ether, 3 parts by weight triethanolamines, the siliceous phosphonate fire retardant of 10 parts by weight, 10 parts by weight of polypropylene acid esters lotions
It measures in part water and is uniformly mixed with revolving speed for 150 revs/min of stirring 20min, obtain fire-retardant treatment liquid；Acrylic fiber is impregnated in resistance
It fires in treatment fluid, temperature is 90 DEG C, dip time 80min, and the mass ratio of the acrylic fiber and fire-retardant treatment liquid is 1:20；
Take out acrylic fiber, temperature be 100 DEG C dry 3 hours to get.
A kind of preparation process of Antistatic Fabric, comprising the following steps:
Nylon short fibre and flame-retardant acrylic fibre fiber is blended at scribbled by common process, form the short fibre of 30s/2
Tie up yarn, then through using scribbled and electrically conductive filament fiber to carry out warping to in broadwise, by common process weaving,
Obtain fabric.
Embodiment 6
A kind of Antistatic Fabric is prepared by the raw material of following mass percents: 14.25% nylon short fibre,
80.75% flame-retardant acrylic fibre fiber, 5% electrically conductive filament fiber.
The flame-retardant acrylic fibre fiber the preparation method comprises the following steps: by polyvinyl alcohol, water, dimethyl vinyl chlorosilane, sulfydryl second
Acetoacetic ester is 1:2:0.6:0.012 mixing in mass ratio, and with revolving speed being 150 revs/min at being 90 DEG C in temperature, to be stirred to react 5 small
When, obtain modified polyvinylalcohol；By 7.5 parts by weight octadecyldiethanol amines, 3.5 parts by weight glycerin triglycidyl ethers, 1
Parts by weight laruyl alcohol oleate, 3 part by weight modified polyvinyl alcohol, 2 parts by weight octadecylamine polyoxyethylene ether, 3 parts by weight three
Ethanol amine, the water-soluble phosphorus nitrogenated flame retardant of 10 parts by weight amido-containing acid ester structures, 10 parts by weight of polypropylene acid esters lotions add
Enter in 85 parts by weight water and be uniformly mixed with revolving speed for 150 revs/min of stirring 20min, obtains fire-retardant treatment liquid；Acrylic fiber is impregnated
In fire-retardant treatment liquid, temperature is 90 DEG C, dip time 80min, and the mass ratio of the acrylic fiber and fire-retardant treatment liquid is
1:20；Take out acrylic fiber, temperature be 100 DEG C dry 3 hours to get.
A kind of preparation process of Antistatic Fabric, comprising the following steps:
Nylon short fibre and flame-retardant acrylic fibre fiber is blended at scribbled by common process, form the short fibre of 30s/2
Tie up yarn, then through using scribbled and electrically conductive filament fiber to carry out warping to in broadwise, by common process weaving,
Obtain fabric.
Embodiment 7
A kind of Antistatic Fabric is prepared by the raw material of following mass percents: 14.25% nylon short fibre,
80.75% flame-retardant acrylic fibre fiber, 5% electrically conductive filament fiber.
The flame-retardant acrylic fibre fiber the preparation method comprises the following steps: by polyvinyl alcohol, water, dimethyl vinyl chlorosilane, sulfydryl second
Acetoacetic ester is 1:2:0.6:0.012 mixing in mass ratio, and with revolving speed being 150 revs/min at being 90 DEG C in temperature, to be stirred to react 5 small
When, obtain modified polyvinylalcohol；By 7.5 parts by weight octadecyldiethanol amines, 3.5 parts by weight glycerin triglycidyl ethers, 1
Parts by weight laruyl alcohol oleate, 3 part by weight modified polyvinyl alcohol, 2 parts by weight octadecylamine polyoxyethylene ether, 3 parts by weight three
Ethanol amine, the siliceous phosphonate fire retardant of 8 parts by weight, 2 parts by weight amido-containing acid ester structures water-soluble phosphorus nitrogenated flame retardant,
It is that 150 revs/min of stirring 20min are uniformly mixed that 10 parts by weight of polypropylene acid esters lotions, which are added in 85 parts by weight water with revolving speed, is obtained
Fire-retardant treatment liquid；Acrylic fiber is impregnated in fire-retardant treatment liquid, temperature is 90 DEG C, dip time 80min, and the acrylic fibers are fine
The mass ratio of dimension and fire-retardant treatment liquid is 1:20；Take out acrylic fiber, temperature be 100 DEG C dry 3 hours to get.It will be fire-retardant
Acrylic fiber is tested for the property, test result are as follows: oxygen index (OI) 36.1%, elongation at break 32.55%, resistivity are
3.3×105Ω·cm。
A kind of preparation process of Antistatic Fabric, comprising the following steps:
Nylon short fibre and flame-retardant acrylic fibre fiber is blended at scribbled by common process, form the short fibre of 30s/2
Tie up yarn, then through using scribbled and electrically conductive filament fiber to carry out warping to in broadwise, by common process weaving,
Obtain fabric.
Test case 1
Flame-retardant acrylic fibre fiber prepared by embodiment 4-6 is tested for the property.Specific test result is shown in Table 1.
Table 1: test result table
The preparation process of Antistatic Fabric of the present invention, by carrying out flame-retardant and anti-static processing to acrylic fiber, with acrylic fibers fibre
Dimension is compared, and antistatic, fire-retardant, elongation at break is improved significantly.
Claims (10)
1. a kind of Antistatic Fabric, which is characterized in that including following raw materials: flame-retardant acrylic fibre fiber.
2. Antistatic Fabric as described in claim 1, which is characterized in that be prepared by following raw materials: nylon fiber, fire-retardant nitrile
Synthetic fibre fiber, conductive fiber.
3. Antistatic Fabric as described in claim 1, which is characterized in that a kind of Antistatic Fabric, by following mass percents
Raw material is prepared: 0.5-15% nylon fiber, 75-90% flame-retardant acrylic fibre fiber, 3-15% conductive fiber.
4. Antistatic Fabric as claimed in claim 3, which is characterized in that the conductive fiber is electrically conductive filament fiber.
5. Antistatic Fabric as claimed in claim 3, which is characterized in that the nylon fiber is nylon short fibre.
6. Antistatic Fabric as described in claim 1, which is characterized in that the flame-retardant acrylic fibre fiber the preparation method comprises the following steps: by 4-9
Parts by weight octadecyldiethanol amine, 3-7 parts by weight glycerin triglycidyl ether, 0.5-1.5 parts by weight laruyl alcohol oleate,
2-4 weight account polyethylene alcohol, 1.5-2.5 parts by weight octadecylamine polyoxyethylene ether, 2-5 parts by weight triethanolamine, 7-13 weight
Amount part fire retardant, 5-15 parts by weight of polypropylene acid esters lotion are added in 75-95 parts by weight water and are uniformly mixed, and obtain flame retardant treatment
Liquid；Acrylic fiber is impregnated in fire-retardant treatment liquid, temperature is 80-100 DEG C, dip time 50-100min, and the acrylic fibers are fine
The mass ratio of dimension and fire-retardant treatment liquid is 1:10-30；Acrylic fiber is taken out, is 95-105 DEG C 1-5 hours dry in temperature, i.e.,
?.
7. Antistatic Fabric as described in claim 1, which is characterized in that the flame-retardant acrylic fibre fiber the preparation method comprises the following steps: will gather
Vinyl alcohol, water, dimethyl vinyl chlorosilane, ethyl thioglycolate are 1:(1-3 in mass ratio): (0.4-0.8): (0.01-
0.015) it mixes, is stirred to react 3-7 hours at being 85-95 DEG C in temperature, obtains modified polyvinylalcohol；By 4-9 parts by weight 18
Alkyldiethanolamine, 3-7 parts by weight glycerin triglycidyl ether, 0.5-1.5 parts by weight laruyl alcohol oleate, 2-4 parts by weight
Modified polyvinylalcohol, 1.5-2.5 parts by weight octadecylamine polyoxyethylene ether, 2-5 parts by weight triethanolamine, the resistance of 7-13 parts by weight
Combustion agent, 5-15 parts by weight of polypropylene acid esters lotion are added in 75-95 parts by weight water and are uniformly mixed, and obtain fire-retardant treatment liquid；By nitrile
For synthetic fibre fiber impregnation in fire-retardant treatment liquid, temperature is 80-100 DEG C, dip time 50-100min, the acrylic fiber and resistance
The mass ratio for firing treatment fluid is 1:10-30；Take out acrylic fiber, temperature be 95-105 DEG C dry 1-5 hours to get.
8. Antistatic Fabric as claimed in claims 6 or 7, which is characterized in that the fire retardant be siliceous phosphonate fire retardant and/
Or phosphorus-nitrogen containing flame retardant.
9. Antistatic Fabric as claimed in claim 8, which is characterized in that the phosphorus-nitrogen containing flame retardant is amido-containing acid ester structure
Water-soluble phosphorus nitrogenated flame retardant.
10. the preparation process of Antistatic Fabric as described in any one of claim 1-9, comprising the following steps:
By nylon fiber and flame-retardant acrylic fibre fiber blend at scribbled, then through to and/or broadwise on using scribbled with
Conductive fiber carries out warping, and weaving obtains fabric.
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Cited By (1)
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