CN106032602A - Permanent flame retardant deflagration and electric arc prevention fabric and manufacturing method thereof - Google Patents
Permanent flame retardant deflagration and electric arc prevention fabric and manufacturing method thereof Download PDFInfo
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- CN106032602A CN106032602A CN201510114060.0A CN201510114060A CN106032602A CN 106032602 A CN106032602 A CN 106032602A CN 201510114060 A CN201510114060 A CN 201510114060A CN 106032602 A CN106032602 A CN 106032602A
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Abstract
The invention provides a permanent flame retardant deflagration and electric arc prevention fabric and a manufacturing method thereof, and belongs to the technical fields of armored fabrics and processing technology thereof. The raw materials and weight percentage comprise: 20-85% of inherent fire-retardant fibers, 5-30% of high temperature resistance dimensional stability fibers, 8-40% of natural fibers or regenerated cellulose fibers, and lower than 10% of nylon fibers, and 1-3% of antistatic fibers. The steps comprise: selecting the above raw materials according to weight percentage, mixing the raw materials and making the raw materials into scutching blending strips, guiding the scutching blending strips to a spinning device to spin, to obtain 24-38 S one-ply yarns, twisting the 24-38 S one-ply yarns through a two-for-one twisting machine, to obtain 24-38 S double-strand yarns; sending the double-strand yarns to a weaving machine to weave, to obtain finished products whose gram weight is 180-290 g/m<2>. The fabric has electric arc prevention property, and the fabric keeps ideal flame retardant property and deflagration prevention property permanently. The fabric has good environmental protection property, permeability and comfort in wearing. The fabric is simple in process, and reduces equipment and manpower investment.
Description
Technical field
The invention belongs to armored fabric and processing technique field thereof, be specifically related to the anti-deflagration Anti-arc fabric of a kind of permanent fire retardant, and also relate to its preparation method.
Background technology
Understood it by the word face paraphrase of the anti-deflagration Anti-arc fabric of aforesaid permanent fire retardant and belong to features fabric category, so-called " permanent fire retardant " refers to that the fire resistance i.e. flame-retarding characteristic of fabric is depended on the fiber itself constituted used by fabric rather than particularly given by a series of artificial treatment measures during fabric carries out Final finishing in the fabric course of processing, and industry is also accustomed to the fiber with this function is referred to as " inherent fire-retardant fiber " in view of this.Due to aforesaid " anti-deflagration " can by China license notification number CN102124152B(for the anti-deflagration improved and the crystal form meta-aramid copolymer of electric arc) the reading of patent specification the 0004th to 0007 section and be fully understood, thus the applicant repeats no more.
It is always a big killer of the personal safety threatening the maintenance of power industry staff particularly power circuit, workmen due to flash burn (electric arc burn), due to the arc protection clothes that material is excellent, there is permanent arc protection characteristic again, will not fail because of the prolongation of the time of wearing and/or the increase of washing times, and can significantly alleviate when being exposed to scintillation, attack suddenly by electric arc and meeting high temperature threat or even be prevented effectively from and human body be injured, because having formed the important protective articles in power system.
Heat-resistance and flame-retardant fiber such as aramid fiber 1313, Fanglun l414, open Mil's fiber (Kermel), Lenzin fiber (Lenzing), BASF fiber (Basfil), virtue vitriol synthetic fibre fiber and flame-retardant acrylic fibre fiber etc. be the very good material preparing Anti-arc fabric, but the price is rather stiff due to this fiber, thus prior art mostly avoids this fiber in the way of " parting reluctantly with what one treasures ", replace and generally make fabric embody arc protection performance by means of corresponding function additive during Final finishing.At present, fabric post-treatment make fabric possess the measure of arc protection function such as: pad the method for baking, coating, organic solvent method, etc., the Anti-arc fabric obtained by this method can make its function fade because of the prolongation of the time of wearing and the increase of washing times during routine use, and lose environmental protection owing to function additive i.e. post-finishing agent commonly uses Halogen or phosphonium flame retardant, thus constrain quality and the using effect of Anti-arc fabric to a certain extent.
nullThe technical information using heat-resistance and flame-retardant fiber to make Anti-arc fabric can be seen in disclosed Chinese patent literature，As such as document A) .CN102449214A " for the anti-deflagration improved and the crystal form meta-aramid blend of excellent arc resistance " recommended，The yarn system of knitting being made up of permanent fire retardant fiber forms，This patent application scheme uses 50-60 weight % and has the meta-aramid fiber of at least 20% degree of crystallinity、The modified acrylic fibre of 31-39 weight % and the Para-aromatic Aramide Fibre blending of 5-15 weight % obtain arc protection fabric，When the clothes being made up of this fabric provides thermal protection to make wearer be exposed to deflagration 4s according to ASTM F 1930, experience is less than the prediction health burn of 65%，Keep 2 class electric arc grades according to ASTM F 1959 and NFPA 70E simultaneously.Although this patent application scheme has arc protection performance, but owing to being chemical fibre in fibre composition, without natural fiber, therefore, the snugness of fit of fabric is poor.It addition, power industry requires that arc protection clothes harness has high temperature resistant deflagration to rupture performance, and this patent application scheme is not directed to.
And for example document B) .CN102859055A provide " there is the crystalline m-aramid blend for anti-deflagration and electric arc of the comfortableness of improvement ", this patent application scheme uses 50-80 weight % and has the meta aromatic polyimide fibre of degree of crystallinity of at least 20%, the fire retardant man-made silk fiber of 10-30 weight %, the modified acrylic fibre of 10-20% weight %, the Para-aromatic Aramide Fibre of 0-5 weight %, and the antistatic fiber composition of 0-3% weight %.The fabric be made up of this raw material provides thermal protection, enables a wearer to be exposed to according to ASTM F 1930 and will stand the prediction health burn less than 65% under the deflagration of 4S, is equal to 2 class electric arc grades simultaneously.Although this patent application scheme has arc protection performance, but power industry requires that the arc protection clothing of staff's dress should also have the deflagration preventing electric arc moment generation high temperature from causing and rupture performance, and this patent application scheme is not directed to.
In sum, how to make fabric permanent fire resistance, preferable high temperature resistant anti-deflagration prevention of arc energy and the performance comfortable and easy to wear after making clothing be held concurrently and it, be that industry is pursued and expects the problem broken through all the time.To this end, the applicant has made positive and useful exploration, finally define technical scheme described below.
Summary of the invention
The top priority of the present invention is to provide and a kind of contributes to embodying preferable inherent flame retardant characteristic, is conducive to embodying the anti-deflagration Anti-arc fabric of the permanent fire retardant that excellent anti-deflagration prevention of arc and having is easy to embody good comfortable ventilating.
Another task of the present invention is to provide the preparation method of the anti-deflagration Anti-arc fabric of a kind of permanent fire retardant, the method need not use Final finishing and uses Simplified flowsheet and meet industrial amplification production and require and can fully ensure permanent fire retardant and improve the described technique effect of comfortable anti-deflagration Anti-arc fabric and embodied comprehensively.
For having embodied the top priority of the present invention, present invention provide the technical scheme that the anti-deflagration Anti-arc fabric of a kind of permanent fire retardant, its raw material and weight % thereof is: inherent fire-retardant fiber 20-85%, high temperature resistant dimensional stability fiber 5-30%, natural fiber or regenerated celulose fibre 8-40%, nylon fiber are less than 10% and antistatic fibre 1-3%.
In a specific embodiment of the present invention, described inherent fire-retardant fiber be poly-isophtalamide diamidogen fiber, FRC with in inflaming retarding modified nitrilon fiber one or more and by any weight % than the composite fibre that mixes mutually.
In another specific embodiment of the present invention, described high temperature resistant dimensional stability fiber is to maintain the Fanglun 1414 less than 3% of percent thermal shrinkage during 5min and/or polyimide fiber at 260 DEG C.
In another specific embodiment of the present invention, described natural fiber is Plant fiber and/or animal fiber；Described regenerated celulose fibre be viscose rayon, bamboo fibre, Modal fibre, chitin fiber, Lyocell fibers with in tencel any one or above and by any weight % than the composite fibre mixed mutually.
In another specific embodiment of the present invention, described Plant fiber is cotton fiber, and described animal fiber is wool fiber.
Also having in a specific embodiment in the present invention, described antistatic fibre is antistatic long filament, and described antistatic long filament is to be added with the nylon yarn of conductive materials, dacron thread or acrylics filament in coating mode or with complex method in spinning process.
In more and in a specific embodiment of the present invention, described conductive materials is white carbon black, Copper diiodide or stannum oxide.
For having embodied another task of the present invention, present invention provide the technical scheme that the preparation method of the anti-deflagration Anti-arc fabric of a kind of permanent fire retardant, comprise the following steps:
A) material choice, by weight % choose inherent fire-retardant fiber 20-84%, high temperature resistant dimensional stability fiber 5-30%, natural fiber or regenerated celulose fibre 8-40%, nylon fiber is less than 10% and antistatic fibre 1-3%, obtain raw material；
B) spinning, first by by step A) raw material that obtains mix and makes scutching cotton blending bar, then scutching cotton blending bar is caused spinning apparatus spin, obtain the one-ply yarn of 24-38S, then by the one-ply yarn of 24-38S through two-for-one twister double twisting, obtain the double strand yarn of 24-38S；
C) weaving, by by step B) double strand yarn that obtains delivers to loom weaving, obtains the anti-deflagration Anti-arc fabric of the permanent fire retardant that grammes per square metre is 180-290g/.
In again and then in a specific embodiment of the present invention, step B) described in spinning be ring spinning or open-end spinning, the twist of described double twisting is that 50-80 twists with the fingers/10；Step C) described in loom be rapier loom.
The present invention provide technical scheme have the technical effect that owing to employing resistant to elevated temperatures inherent fire-retardant fiber, the high heat being thus able to prevent electric arc moment from producing causes human body to cause the probability of burn, i.e. prevention of arc, meet wearer to be exposed to according to ASTM F1930 under the deflagration of 4S and stand the prediction bodily injury requirement less than 65%, and the preferable flame-retarding characteristic of fabric permanent retention, will not fail because of the passage of time or the increase of washing times；Owing to employing high temperature resistant dimensional stability fiber, it is thus possible to the probability preventing electric arc moment generation high heat from causing fabric to produce 1 inch of slight crack is E when 50%btEnergy threshold weighs requirement, the most anti-deflagrability；Owing to adding natural fiber or regenerated celulose fibre, thus comfortableness when can embody the good feature of environmental protection, breathability and wear；The preparation method provided is due to without carrying out Final finishing to fabric, thus not only simplify technique and be satisfied industrial amplification production requirement, and can substantially reduce equipment and human input and the aforementioned techniques effect of fabric can be made comprehensively to be embodied.
Detailed description of the invention
Embodiment 1:
A) material choice, the content of % by weight (i.e. weight % ratio, as follows) choose and maintain Fanglun 1414 10%, the cotton fiber 10% less than 3% of percent thermal shrinkage during 5min at poly-isophtalamide diamidogen fiber 28%, FRC 10%, inflaming retarding modified nitrilon fiber 41%, 260 DEG C and in spinning process, be coated with the nylon yarn 1% of white carbon black in coating mode, obtain raw material；
B) spinning, first will be by step A) raw material (the i.e. fibrous raw material that obtains, as follows) composite fibre that is obtained by mixing makes scutching cotton blending bar, scutching cotton blending bar is caused the spinning of RING SPINNING spinning machine again, obtain the one-ply yarn of 37S, it is then 78 sth. made by twisting/10 by the one-ply yarn of 37S through two-for-one twister double twisting, the twist, obtains the double strand yarn of 37S；
C) weaving, by by step B) double strand yarn of 37S that obtains delivers to rapier loom weaving, obtains the anti-deflagration Anti-arc fabric of the permanent fire retardant that grammes per square metre is 180g/.
Embodiment 2:
A) material choice, the content of % by weight is chosen and is maintained the Fanglun 1414 20% less than 3% of percent thermal shrinkage during 5min, polyimide fiber 10%, wool fiber 34%, nylon fiber 3% at poly-isophtalamide diamidogen fiber 30%, 260 DEG C and be added with the acrylics filament i.e. antistatic acrylic fiber long filament 3% of Copper diiodide in spinning process, obtains raw material；
B) spinning, first by by step A) composite fibre that is obtained by mixing of the raw material that obtains makes scutching cotton blending bar, then scutching cotton blending bar caused open-end spinning frame open-end spinning, obtain the one-ply yarn of 24S, it is then 50 sth. made by twisting/10 by the one-ply yarn of 24S through two-for-one twister double twisting, the twist, obtains the double strand yarn of 24S；
C) weaving, by by step B) double strand yarn of 24S that obtains delivers to rapier loom weaving, obtains the anti-deflagration Anti-arc fabric of the permanent fire retardant that grammes per square metre is 220g/.
Embodiment 3:
A) material choice, the content of % by weight is chosen poly-isophtalamide diamidogen fiber 40%, inflaming retarding modified nitrilon fiber 45%, polyimide fiber 5%, viscose rayon 1%, Modal fibre 1%, Lyocell fibers 2%, tencel 1%, nylon fiber 2.5% and is added with the dacron thread i.e. Antistatic PET Filaments 2.5% of stannum oxide in spinning process, obtains raw material；
B) spinning, first by by step A) composite fibre that is obtained by mixing of the raw material that obtains makes scutching cotton blending bar, then scutching cotton blending bar causes the spinning of RING SPINNING spinning machine, obtain the one-ply yarn of 30S, it is then 70 sth. made by twisting/10 by the one-ply yarn of 30S through two-for-one twister double twisting, the twist, obtains the double strand yarn of 30S；
C) weaving, by by step B) double strand yarn of 30S that obtains delivers to rapier loom weaving, obtains the anti-deflagration Anti-arc fabric of the permanent fire retardant that grammes per square metre is 290g/.
Embodiment 4:
A) material choice, the content of % by weight is chosen poly-isophtalamide diamidogen fiber 20%, is maintained the Fanglun 1414 30% less than 3% of percent thermal shrinkage during 5min, cotton fiber 40%, nylon fiber 8% and be coated with the acrylics filament i.e. antistatic acrylic fiber long filament 2% of white carbon black in spinning process in coating mode at 260 DEG C, obtains raw material；
B) spinning, first by by step A) composite fibre that is obtained by mixing of the raw material that obtains makes scutching cotton blending bar, then scutching cotton blending bar causes the spinning of RING SPINNING spinning machine, obtain the one-ply yarn of 35S, it is then 60 sth. made by twisting/10 by the one-ply yarn of 35S through two-for-one twister double twisting, the twist, obtains the double strand yarn of 35S；
C) weaving, by by step B) double strand yarn of 35S that obtains delivers to rapier loom weaving, obtains the anti-deflagration Anti-arc fabric of the permanent fire retardant that grammes per square metre is 260g/.
The anti-deflagration Anti-arc fabric of the permanent fire retardant obtained by above-described embodiment 1 to 4 being tested according to ASTM F 959 and NFPA 70E standard, arc protection performance all can reach ATPV value requirement, and tests according to DL/T3200, all can meet ATPV value and EbtRequirement.
Claims (9)
1. the anti-deflagration Anti-arc fabric of a permanent fire retardant, it is characterised in that its raw material and weight % thereof is: inherent fire-retardant fiber 20-85%, high temperature resistant dimensional stability fiber 5-30%, natural fiber or regenerated celulose fibre 8-40%, nylon fiber are less than 10% and antistatic fibre 1-3%.
The anti-deflagration Anti-arc fabric of permanent fire retardant the most according to claim 1, it is characterised in that described inherent fire-retardant fiber be poly-isophtalamide diamidogen fiber, FRC with in inflaming retarding modified nitrilon fiber one or more and by any weight % than the composite fibre that mixes mutually.
The anti-deflagration Anti-arc fabric of permanent fire retardant the most according to claim 1, it is characterised in that described high temperature resistant dimensional stability fiber is to maintain the Fanglun 1414 less than 3% of percent thermal shrinkage during 5min and/or polyimide fiber at 260 DEG C.
The anti-deflagration Anti-arc fabric of permanent fire retardant the most according to claim 1, it is characterised in that described natural fiber is Plant fiber and/or animal fiber；Described regenerated celulose fibre be viscose rayon, bamboo fibre, Modal fibre, chitin fiber, Lyocell fibers with in tencel any one or above and by any weight % than the composite fibre mixed mutually.
The anti-deflagration Anti-arc fabric of permanent fire retardant the most according to claim 4, it is characterised in that described Plant fiber is cotton fiber, described animal fiber is wool fiber.
The anti-deflagration Anti-arc fabric of permanent fire retardant the most according to claim 1, it is characterized in that described antistatic fibre is antistatic long filament, described antistatic long filament is to be added with the nylon yarn of conductive materials, dacron thread or acrylics filament in coating mode or with complex method in spinning process.
The anti-deflagration Anti-arc fabric of permanent fire retardant the most according to claim 6, it is characterised in that described conductive materials is white carbon black, Copper diiodide or stannum oxide.
8. the preparation method of the anti-deflagration Anti-arc fabric of a permanent fire retardant as claimed in claim 1, it is characterised in that comprise the following steps:
A) material choice, by weight % choose inherent fire-retardant fiber 20-84%, high temperature resistant dimensional stability fiber 5-30%, natural fiber or regenerated celulose fibre 8-40%, nylon fiber is less than 10% and antistatic fibre 1-3%, obtain raw material；
B) spinning, first by by step A) raw material that obtains mix and makes scutching cotton blending bar, then scutching cotton blending bar is caused spinning apparatus spin, obtain the one-ply yarn of 24-38S, then by the one-ply yarn of 24-38S through two-for-one twister double twisting, obtain the double strand yarn of 24-38S；
C) weaving, by by step B) double strand yarn that obtains delivers to loom weaving, obtains the anti-deflagration Anti-arc fabric of the permanent fire retardant that grammes per square metre is 180-290g/.
The preparation method of the anti-deflagration Anti-arc fabric of permanent fire retardant the most according to claim 8, it is characterised in that step B) described in spinning be ring spinning or open-end spinning, the twist of described double twisting be 50-80 twist with the fingers/10；Step C) described in loom be rapier loom.
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| CN201510114060.0A CN106032602A (en) | 2015-03-17 | 2015-03-17 | Permanent flame retardant deflagration and electric arc prevention fabric and manufacturing method thereof |
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| CN201510114060.0A CN106032602A (en) | 2015-03-17 | 2015-03-17 | Permanent flame retardant deflagration and electric arc prevention fabric and manufacturing method thereof |
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| CN106939466A (en) * | 2017-05-11 | 2017-07-11 | 江苏科德宝建筑节能科技有限公司 | It is a kind of that there is permanent fire retardant multifunctional fabric of improvement comfortableness and preparation method thereof |
| CN107447327A (en) * | 2017-09-06 | 2017-12-08 | 四川航天系统工程研究所 | Space flight special type antibacterial and mouldproof fiber cloth based on chitin fiber and preparation method thereof |
| CN108117750A (en) * | 2017-12-27 | 2018-06-05 | 南通谐好安全科技有限公司 | Arc protection flame-retardant mixture and preparation method thereof |
| CN109222285A (en) * | 2018-06-29 | 2019-01-18 | 南通嘉得利安全用品有限公司 | Arc protection butyronitrile gloves and its production method |
| CN109322016A (en) * | 2018-11-12 | 2019-02-12 | 山东华晨彩装科技有限公司 | A kind of air-flow spinning process for washing 21 count yarns blended with beautiful jade Sai Er |
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| CN109487398A (en) * | 2017-09-11 | 2019-03-19 | 苏州存异新材料科技有限公司 | A kind of Antistatic Fabric and its preparation process |
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| CN110352268A (en) * | 2017-02-27 | 2019-10-18 | 阿文德有限公司 | Wearable lightweight protective garment |
| CN110359148A (en) * | 2019-07-26 | 2019-10-22 | 康帝雅高档面料（苏州）有限公司 | Multicomponent scribbled, fabric, fabric manufacturing technique and the fusion proof metal splash protection clothes of permanent fire retardant |
| CN111172647A (en) * | 2020-03-04 | 2020-05-19 | 青岛永聚坤元纺织科技有限公司 | Fabric and preparation method thereof |
| CN113322564A (en) * | 2021-06-23 | 2021-08-31 | 山东省产品质量检验研究院 | Anti-electric arc fabric and preparation method and application thereof |
| CN115449952A (en) * | 2022-09-29 | 2022-12-09 | 董健 | Antibacterial breathable moisture absorption type textile fabric |
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| CN109322016A (en) * | 2018-11-12 | 2019-02-12 | 山东华晨彩装科技有限公司 | A kind of air-flow spinning process for washing 21 count yarns blended with beautiful jade Sai Er |
| CN109440262A (en) * | 2018-12-27 | 2019-03-08 | 陕西元丰纺织技术研究有限公司 | The general alert war instruction of one kind takes fabric and preparation method thereof |
| CN109576868A (en) * | 2018-12-27 | 2019-04-05 | 陕西元丰纺织技术研究有限公司 | A kind of Anti-arc fabric and preparation method thereof |
| CN109797474A (en) * | 2019-01-28 | 2019-05-24 | 陕西元丰纺织技术研究有限公司 | A kind of molten metal splatter guard fabric and its manufacturing method |
| CN110359148A (en) * | 2019-07-26 | 2019-10-22 | 康帝雅高档面料（苏州）有限公司 | Multicomponent scribbled, fabric, fabric manufacturing technique and the fusion proof metal splash protection clothes of permanent fire retardant |
| CN111172647A (en) * | 2020-03-04 | 2020-05-19 | 青岛永聚坤元纺织科技有限公司 | Fabric and preparation method thereof |
| CN113322564A (en) * | 2021-06-23 | 2021-08-31 | 山东省产品质量检验研究院 | Anti-electric arc fabric and preparation method and application thereof |
| CN115449952A (en) * | 2022-09-29 | 2022-12-09 | 董健 | Antibacterial breathable moisture absorption type textile fabric |
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Application publication date: 20161019 |