CN101717189A - 高耐化学性硼硅玻璃及用途 - Google Patents

高耐化学性硼硅玻璃及用途 Download PDF

Info

Publication number
CN101717189A
CN101717189A CN200910017775A CN200910017775A CN101717189A CN 101717189 A CN101717189 A CN 101717189A CN 200910017775 A CN200910017775 A CN 200910017775A CN 200910017775 A CN200910017775 A CN 200910017775A CN 101717189 A CN101717189 A CN 101717189A
Authority
CN
China
Prior art keywords
borosilicate glass
chemical resistance
high chemical
degc
cao
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN200910017775A
Other languages
English (en)
Other versions
CN101717189B (zh
Inventor
郑树祥
史生宏
孙翔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Linuo New Material Co., Ltd.
Original Assignee
LINUO SOLAR GROUP CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LINUO SOLAR GROUP CO Ltd filed Critical LINUO SOLAR GROUP CO Ltd
Priority to CN2009100177759A priority Critical patent/CN101717189B/zh
Publication of CN101717189A publication Critical patent/CN101717189A/zh
Application granted granted Critical
Publication of CN101717189B publication Critical patent/CN101717189B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Glass Compositions (AREA)

Abstract

本发明公开了一种高耐化学性硼硅玻璃，组成按重量％基于氧化物计为：SiO2、71～75，AL2O3、3～6，B2O3、8～10，Na2O、4～10，K2O、0～2.5其中Na2O+K2O、7～10，CaO、0～1.2，MgO、0～1，其中CaO+MgO、0～1.2，BaO、1～3和CeO2、0～0.3。本发明的有益效果：1.组成成分中不使用As2O3、Sb2O3和BaSO4等有害成分，能作为药物包装材料；2.实验测得用上述成分的物质采用现有的生产设备生产得到的高耐化学性硼硅玻璃的热膨胀系数为5.0×10-6～6.0×10-6K-1，转换温度Tg为520～572℃，软化点为765～782℃，工作温度为920-1200℃，密度2.32～2.5g/cm3符合药物包装要求，且降低了生产成本。

Description

高耐化学性硼硅玻璃及用途
技术领域
本发明涉及一种高耐化学性硼硅玻璃及用途。
背景技术
我国采用膨胀系数为7.0×10-6k-1低硼硅玻璃制作药物初级包装材料，该玻璃为我国自主研发的药用包装材料，医用玻璃的性质要求主要有化学稳定性，热稳定性和机械强度等方面，各国对医用玻璃的耐水性和耐碱性都制定了相关标准，我国药用玻璃的耐水性的国家标准为GB12416.1-90、GB12416.2-90和耐碱性国家标准GB4771-84，分别是医药用玻璃容器内表面以及玻璃材质耐水性和耐碱性的试验方法、分级标准。材料基本满足标准要求，但在二次加工后就超出标准要求。在开发之初，我国的药业生产对包装材料的要求不高，该材料能够满足需求，同时大大降低了生产难度和生产成本，符合当时的实际情况。
随着我国药业快速发展，对药品包装材料质量要求越来越高，相应开发之初的硼硅玻璃无法满足药用包装要求，国际上普遍采用的生产设备及方法要求工艺条件严格且投资较大。
发明内容
本发明要解决的技术问题提供了一种高耐化学性硼硅玻璃，既能满足药业包装的要求，又可以采用现有的生产设备，生产成本相对较低。
为了解决上述技术问题，本发明是通过以下措施来实现的：
一种高耐化学性硼硅玻璃，其特征在于：其组成按重量％基于氧化物计为：
SiO2     71～75
AL2O3    3～6
B2O3     8～10
Na2O     4～10
K2O      0～2.5
其中Na2O+K2O    7～10
CaO             0～1.2
MgO             0～1
其中CaO+MgO     0～1.2
BaO             1～3和
CeO2            0～0.3。
进一步地，它还包括有(按重量％基于氧化物)：Fe2O3  0～0.2。
本发明实施中，其组成按重量％基于氧化物计为：
SiO2    72.5
AL2O3   5
B2O3    8.5
Na2O    7
K2O     2.5
CaO     1
BaO     3
CeO2    0.3
Fe2O3   0.06。
本发明另一实施中，其组成按重量％基于氧化物计为：
SiO2     72
AL2O3    5.5
B2O3     9
Na2O     7
K2O      2.5
CaO      1
BaO      2.5
CeO2     0.3
Fe2O3    0.06。
为了澄清均化混合物，高耐化学性硼硅玻璃还包括有(按重量％基于氧化物)：NaCl 0～1。
为了降低熔化物的粘度、提高精炼速度，高耐化学性硼硅玻璃还包括有(按重量％基于氧化物)：CaF2 0～0.25。
本发明实施中，高耐化学性硼硅玻璃的热膨胀系数为5.0×10-6～6.0×10-6K-1，转换温度Tg为520～572℃，软化点为765～782℃，工作温度为920-1200℃，密度2.32～2.5g/cm3。
本发明所述高耐化学性硼硅玻璃作为药物初级包装材料的用途。
本发明各个组分设计原则：
SiO2作为玻璃结构的主要成分含量过高会造成工作点过度增加，并使膨胀系数降低过多，含量过低将破坏其耐酸性；以B2O3代替一部分SiO2可以降低工作温度和熔解温度，同时提高水解稳定性，低了不能充分降低熔化点，会使玻璃更加容易结晶，高了会对耐酸性产生破坏性；Al2O3与B2O3一样，将碱金属离子更加牢固的结合到玻璃结构中，对抗玻璃结晶有积极作用，含量低了结晶的可能性增加，尤其是高B2O3的条件下会增加碱金属蒸发，含量高了会增加熔化点和工作点；
K2O最高2.5％，碱金属总量控制在10％以下，该成分的控制对产品的水解稳定性和膨胀系数影响明显；
其它的二价金属氧化物的含量控制：CaO用来调节玻璃可用来加工的温度范围，以满足生产和加工的需要，同时降低了工作点，并且被牢固的结合到玻璃结构中，MgO也起到同样的作用，但含量要很低，CaO+MgO控制总量不大于1.2％，BaO可能来增加玻璃的透光性；
此外最高0.3％氧化铈可以起到澄清均化的作用，同时改善玻璃的抗辐射性；最高0.5％的F-1可以有效的降低熔化温度，加速均化；
除了已经提到的氧化铈组分和氟化物组分(如氟化钙)外，还可以采用氯化钠起到澄清作用，用量为0.5％。
本发明的有益效果：
1.组成成分中不使用As2O3、Sb2O3和BaSO4等有害成分，能作为药物包装材料；
2.实验测得用上述成分的物质采用现有的生产设备生产得到的高耐化学性硼硅玻璃的热膨胀系数为5.0×10-6～6.0×10-6K-1，转换温度Tg为520～572℃，软化点为765～782℃，工作温度为920-1200℃，密度2.32～2.5g/cm3符合药物包装要求，且降低了生产成本。
具体实施方式
按下列方式制备高耐化学性硼硅玻璃：
1.按重量％基于氧化物计算原料重量，称出原料并混合均匀，在1560℃使之熔化，然后倒入钢模中；如下面表1列出了各组成(按重量％基于氧化物计)，热膨胀系数α20/300[10-6K-1]，转换温度Tg(℃)，软化点E(℃)，工作温度V(℃)，密度ρ(g/cm3)
2.根据以下方式测定耐化学性：
耐酸实验方法：GB/T15728---1995每克玻璃消耗0.5ml 0.02mol/l的HCl溶液
耐碱实验方法：GB/T6580---1997消耗135mg/dm3
耐水实验方法：GB12416.2-90消耗0.85mg/dm3
表1各组成(按重量％基于氧化物计)及性能
  A1   A2   A3   A4   A5
  SiO2   75   74   72.5   72   71
  AL2O3   3   4   5   5.5   6
  B2O3   10   8   8.5   9   9.82
  Na2O   4   7.5   7   7   10
  K2O   3   2.5   2.5   2.5   0
  CaO   1   0   1   1   0.8
  MgO   0.2   1   0   0   0.4
  BaO   2.05   1.7   3   2.5   1
  CeO2   0.3   0.15   0.3   0.3   0
  A1   A2   A3   A4   A5
  Fe2O3   0.06   0.06   0.06   0.06   0.06
  NaCl   1   1   0   0   0.5
  CaF2   0.25   0   0   0   0.18
  α20/300   5.05   5.35   5.7   5.82   5.96
  Tg(℃)   560   520   572   545   568
  E(℃)   782   775   768   765   763
  V(℃)   1170   1150   1140   1130   1120
  ρ(g/cm3)   2.32   2.34   2.43   2.44   2.5
表1本发明满足耐水1级，耐1级，耐碱至少为2级，完全满足国际对药用包装材料的要求。即使在二次加工后依然满足要求。比较适用于作为国内药用包装材料的替代材料。

Claims (8)

1.一种高耐化学性硼硅玻璃，其特征在于：其组成按重量％基于氧化物计为：
SiO2           71～75
AL2O3          3～6
B2O3           8～10
Na2O           4～10
K2O            0～2.5
其中Na2O+K2O   7～10
CaO            0～1.2
MgO            0～1
其中CaO+MgO    0～1.2
BaO            1～3和
CeO2           0～0.3
2.根据权利要求1所述高耐化学性硼硅玻璃，其特征在于：它还包括有(按重量％基于氧化物)：Fe2O3 0～0.06。
3.根据权利要求2所述高耐化学性硼硅玻璃，其特征在于：其组成按重量％基于氧化物计为：
SiO2    72.5
AL2O3   5
B2O3    8.5
Na2O    7
K2O     2.5
CaO     1
BaO     3
CeO2    0.3
Fe2O3   0.06。
4.根据权利要求2所述高耐化学性硼硅玻璃，其特征在于：其组成按重量％基于氧化物计为：
SiO2        72
AL2O3      5.5
B2O3       9
Na2O       7
K2O        2.5
CaO        1
BaO        2.5
CeO2       0.3
Fe2O3      0.06。
5.根据权利要求1、2、3或4所述高耐化学性硼硅玻璃，其特征在于：它还包括有(按重量％基于氧化物)：NaCl 0～1。
6.根据权利要求1、2、3或4所述高耐化学性硼硅玻璃，其特征在于：它还包括有(按重量％基于氧化物)：CaF2 0～0.25。
7.根据权利要求1、2、3或4所述高耐化学性硼硅玻璃，其特征在于：其热膨胀系数为5.0×10-6～6.0×10-6K-1，转换温度Tg为520～572℃，软化点为765～782℃，工作温度为920-1200℃，密度2.32～2.5g/cm3。
8.一种权利要求1、2、3或4所述高耐化学性硼硅玻璃作为药物初级包装材料的用途。
CN2009100177759A 2009-08-28 2009-08-28 高耐化学性硼硅玻璃及用途 Expired - Fee Related CN101717189B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2009100177759A CN101717189B (zh) 2009-08-28 2009-08-28 高耐化学性硼硅玻璃及用途

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2009100177759A CN101717189B (zh) 2009-08-28 2009-08-28 高耐化学性硼硅玻璃及用途

Publications (2)

Publication Number Publication Date
CN101717189A true CN101717189A (zh) 2010-06-02
CN101717189B CN101717189B (zh) 2011-06-08

Family

ID=42431837

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2009100177759A Expired - Fee Related CN101717189B (zh) 2009-08-28 2009-08-28 高耐化学性硼硅玻璃及用途

Country Status (1)

Country Link
CN (1) CN101717189B (zh)

Cited By (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8551898B2 (en) 2011-10-25 2013-10-08 Corning Incorporated Glass compositions with improved chemical and mechanical durability
CN103708725A (zh) * 2013-12-30 2014-04-09 山东省药用玻璃股份有限公司 硼硅玻璃管制注射剂瓶及其制备方法
CN103819087A (zh) * 2014-01-21 2014-05-28 江苏奥蓝工程玻璃有限公司 一种硼硅酸盐玻璃及其制备方法
CN104556686A (zh) * 2015-01-19 2015-04-29 濮阳市新和实业发展有限公司 一种铁锰着色低硼硅药用玻璃管及其制备方法
US9034442B2 (en) 2012-11-30 2015-05-19 Corning Incorporated Strengthened borosilicate glass containers with improved damage tolerance
US9145329B2 (en) 2011-10-25 2015-09-29 Corning Incorporated Alkaline earth alumino-silicate glass compositions with improved chemical and mechanical durability
US9186295B2 (en) 2011-10-25 2015-11-17 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9428302B2 (en) 2012-06-28 2016-08-30 Corning Incorporated Delamination resistant glass containers with heat-tolerant coatings
US9517966B2 (en) 2011-10-25 2016-12-13 Corning Incorporated Glass compositions with improved chemical and mechanical durability
US9603775B2 (en) 2013-04-24 2017-03-28 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9668936B2 (en) 2012-02-28 2017-06-06 Corning Incorporated Glass articles with low-friction coatings
CN106800369A (zh) * 2015-11-26 2017-06-06 肖特股份有限公司 热钢化玻璃元件及其用途
US9700486B2 (en) 2013-04-24 2017-07-11 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9700485B2 (en) 2013-04-24 2017-07-11 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9707153B2 (en) 2013-04-24 2017-07-18 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9707154B2 (en) 2013-04-24 2017-07-18 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9707155B2 (en) 2013-04-24 2017-07-18 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9713572B2 (en) 2013-04-24 2017-07-25 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9717648B2 (en) 2013-04-24 2017-08-01 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9717649B2 (en) 2013-04-24 2017-08-01 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
TWI600626B (zh) * 2012-06-07 2017-10-01 康寧公司 抗脫層的玻璃容器
US9839579B2 (en) 2013-04-24 2017-12-12 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9849066B2 (en) 2013-04-24 2017-12-26 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US10065884B2 (en) 2014-11-26 2018-09-04 Corning Incorporated Methods for producing strengthened and durable glass containers
US10117806B2 (en) 2012-11-30 2018-11-06 Corning Incorporated Strengthened glass containers resistant to delamination and damage
US10350139B2 (en) 2011-10-25 2019-07-16 Corning Incorporated Pharmaceutical glass packaging assuring pharmaceutical sterility
US10737973B2 (en) 2012-02-28 2020-08-11 Corning Incorporated Pharmaceutical glass coating for achieving particle reduction
US10899659B2 (en) 2014-09-05 2021-01-26 Corning Incorporated Glass articles and methods for improving the reliability of glass articles
CN113831013A (zh) * 2021-08-31 2021-12-24 甘肃旭康材料科技有限公司 中性硼硅玻璃组合物、中性硼硅玻璃及其制备方法与应用
US11208348B2 (en) 2015-09-30 2021-12-28 Corning Incorporated Halogenated polyimide siloxane chemical compositions and glass articles with halogenated polyimide siloxane low-friction coatings
CN113860729A (zh) * 2021-10-25 2021-12-31 北京工业大学 一种中硼硅药用玻璃
US11497681B2 (en) 2012-02-28 2022-11-15 Corning Incorporated Glass articles with low-friction coatings
US11772846B2 (en) 2015-10-30 2023-10-03 Corning Incorporated Glass articles with mixed polymer and metal oxide coatings

Cited By (94)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9718721B2 (en) 2011-10-25 2017-08-01 Corning Incorporated Alkaline earth alumino-silicate glass compositions with improved chemical and mechanical durability
JP7432570B2 (ja) 2011-10-25 2024-02-16 コーニング インコーポレイテッド 改良された化学的および機械的耐久性を有するガラス組成物
US11707408B2 (en) 2011-10-25 2023-07-25 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US8753994B2 (en) 2011-10-25 2014-06-17 Corning Incorporated Glass compositions with improved chemical and mechanical durability
US8980777B2 (en) 2011-10-25 2015-03-17 Corning Incorporated Glass compositions with improved chemical and mechanical durability
US11707410B2 (en) 2011-10-25 2023-07-25 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US11707409B2 (en) 2011-10-25 2023-07-25 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9145329B2 (en) 2011-10-25 2015-09-29 Corning Incorporated Alkaline earth alumino-silicate glass compositions with improved chemical and mechanical durability
US9186295B2 (en) 2011-10-25 2015-11-17 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US11325855B2 (en) 2011-10-25 2022-05-10 Corning Incorporated Glass compositions with improved chemical and mechanical durability
US9198829B2 (en) 2011-10-25 2015-12-01 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9241869B2 (en) 2011-10-25 2016-01-26 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
JP2022009932A (ja) * 2011-10-25 2022-01-14 コーニング インコーポレイテッド 改良された化学的および機械的耐久性を有するガラス組成物
US9340447B2 (en) 2011-10-25 2016-05-17 Corning Incorporated Glass compositions with improved chemical and mechanical durability
US11168017B2 (en) 2011-10-25 2021-11-09 Corning Incorporated Alkaline earth alumino-silicate glass compositions with improved chemical and mechanical durability
US8551898B2 (en) 2011-10-25 2013-10-08 Corning Incorporated Glass compositions with improved chemical and mechanical durability
US10597322B2 (en) 2011-10-25 2020-03-24 Corning Incorporated Glass compositions with improved chemical and mechanical durability
US9474688B2 (en) 2011-10-25 2016-10-25 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9474689B2 (en) 2011-10-25 2016-10-25 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9517966B2 (en) 2011-10-25 2016-12-13 Corning Incorporated Glass compositions with improved chemical and mechanical durability
US10577274B2 (en) 2011-10-25 2020-03-03 Corning Incorporated Alkaline earth alumino-silicate glass compositions with improved chemical and mechanical durability
US9617183B2 (en) 2011-10-25 2017-04-11 Corning Incorporated Glass compositions with improved chemical and mechanical durability
US9624125B2 (en) 2011-10-25 2017-04-18 Corning Incorporated Glass compositions with improved chemical and mechanical durability
US10441505B2 (en) 2011-10-25 2019-10-15 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US10413482B2 (en) 2011-10-25 2019-09-17 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US10413483B2 (en) 2011-10-25 2019-09-17 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US10413481B2 (en) 2011-10-25 2019-09-17 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US10350139B2 (en) 2011-10-25 2019-07-16 Corning Incorporated Pharmaceutical glass packaging assuring pharmaceutical sterility
US10196298B2 (en) 2011-10-25 2019-02-05 Corning Incorporated Glass compositions with improved chemical and mechanical durability
US11071689B2 (en) 2012-02-28 2021-07-27 Corning Incorporated Glass articles with low-friction coatings
US9918898B2 (en) 2012-02-28 2018-03-20 Corning Incorporated Glass articles with low-friction coatings
US11939259B2 (en) 2012-02-28 2024-03-26 Corning Incorporated Pharmaceutical glass coating for achieving particle reduction
US11872189B2 (en) 2012-02-28 2024-01-16 Corning Incorporated Glass articles with low-friction coatings
US11786441B2 (en) 2012-02-28 2023-10-17 Corning Incorporated Glass articles with low-friction coatings
US9744099B2 (en) 2012-02-28 2017-08-29 Corning Incorporated Glass articles with low-friction coatings
US9763852B2 (en) 2012-02-28 2017-09-19 Corning Incorporated Glass articles with low-friction coatings
US10737973B2 (en) 2012-02-28 2020-08-11 Corning Incorporated Pharmaceutical glass coating for achieving particle reduction
US9775775B2 (en) 2012-02-28 2017-10-03 Corning Incorporated Glass articles with low-friction coatings
US11737951B2 (en) 2012-02-28 2023-08-29 Corning Incorporated Glass articles with low-friction coatings
US11007117B2 (en) 2012-02-28 2021-05-18 Corning Incorporated Glass articles with low-friction coatings
US9668936B2 (en) 2012-02-28 2017-06-06 Corning Incorporated Glass articles with low-friction coatings
US11020317B2 (en) 2012-02-28 2021-06-01 Corning Incorporated Glass articles with low-friction coatings
US11497681B2 (en) 2012-02-28 2022-11-15 Corning Incorporated Glass articles with low-friction coatings
US10034816B2 (en) 2012-02-28 2018-07-31 Corning Incorporated Glass articles with low-friction coatings
US11124328B2 (en) 2012-06-07 2021-09-21 Corning Incorporated Delamination resistant glass containers
US9988174B2 (en) 2012-06-07 2018-06-05 Corning Incorporated Delamination resistant glass containers
US10273048B2 (en) 2012-06-07 2019-04-30 Corning Incorporated Delamination resistant glass containers with heat-tolerant coatings
TWI600626B (zh) * 2012-06-07 2017-10-01 康寧公司 抗脫層的玻璃容器
US11608290B2 (en) 2012-06-28 2023-03-21 Corning Incorporated Delamination resistant glass containers with heat-tolerant coatings
US10787292B2 (en) 2012-06-28 2020-09-29 Corning Incorporated Delamination resistant glass containers with heat-tolerant coatings
US10273049B2 (en) 2012-06-28 2019-04-30 Corning Incorporated Delamination resistant glass containers with heat-tolerant coatings
US9428302B2 (en) 2012-06-28 2016-08-30 Corning Incorporated Delamination resistant glass containers with heat-tolerant coatings
US10786431B2 (en) 2012-11-30 2020-09-29 Corning Incorporated Glass containers with delamination resistance and improved damage tolerance
US10023495B2 (en) 2012-11-30 2018-07-17 Corning Incorporated Glass containers with improved strength and improved damage tolerance
US9034442B2 (en) 2012-11-30 2015-05-19 Corning Incorporated Strengthened borosilicate glass containers with improved damage tolerance
US11963927B2 (en) 2012-11-30 2024-04-23 Corning Incorporated Glass containers with delamination resistance and improved damage tolerance
US9272946B2 (en) 2012-11-30 2016-03-01 Corning Incorporated Glass containers with delamination resistance and improved strength
US10507164B2 (en) 2012-11-30 2019-12-17 Corning Incorporated Glass containers with improved strength and improved damage tolerance
US9346707B2 (en) 2012-11-30 2016-05-24 Corning Incorporated Methods for forming delamination resistant glass containers
US10307333B2 (en) 2012-11-30 2019-06-04 Corning Incorporated Glass containers with delamination resistance and improved damage tolerance
US10307334B2 (en) 2012-11-30 2019-06-04 Corning Incorporated Glass containers with delamination resistance and improved damage tolerance
TWI629980B (zh) * 2012-11-30 2018-07-21 康寧公司 形成抗分層玻璃容器的方法
US11951072B2 (en) 2012-11-30 2024-04-09 Corning Incorporated Glass containers with improved strength and improved damage tolerance
US10813835B2 (en) 2012-11-30 2020-10-27 Corning Incorporated Glass containers with improved strength and improved damage tolerance
US10117806B2 (en) 2012-11-30 2018-11-06 Corning Incorporated Strengthened glass containers resistant to delamination and damage
US9717648B2 (en) 2013-04-24 2017-08-01 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9839579B2 (en) 2013-04-24 2017-12-12 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9700485B2 (en) 2013-04-24 2017-07-11 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9707153B2 (en) 2013-04-24 2017-07-18 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9707154B2 (en) 2013-04-24 2017-07-18 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9603775B2 (en) 2013-04-24 2017-03-28 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9707155B2 (en) 2013-04-24 2017-07-18 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9700486B2 (en) 2013-04-24 2017-07-11 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9717649B2 (en) 2013-04-24 2017-08-01 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9713572B2 (en) 2013-04-24 2017-07-25 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
US9849066B2 (en) 2013-04-24 2017-12-26 Corning Incorporated Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients
CN103708725B (zh) * 2013-12-30 2015-11-25 山东省药用玻璃股份有限公司 硼硅玻璃管制注射剂瓶及其制备方法
CN103708725A (zh) * 2013-12-30 2014-04-09 山东省药用玻璃股份有限公司 硼硅玻璃管制注射剂瓶及其制备方法
CN103819087A (zh) * 2014-01-21 2014-05-28 江苏奥蓝工程玻璃有限公司 一种硼硅酸盐玻璃及其制备方法
CN103819087B (zh) * 2014-01-21 2016-08-17 江苏奥蓝工程玻璃有限公司 一种硼硅酸盐玻璃及其制备方法
US11807570B2 (en) 2014-09-05 2023-11-07 Corning Incorporated Glass articles and methods for improving the reliability of glass articles
US10899659B2 (en) 2014-09-05 2021-01-26 Corning Incorporated Glass articles and methods for improving the reliability of glass articles
US10065884B2 (en) 2014-11-26 2018-09-04 Corning Incorporated Methods for producing strengthened and durable glass containers
CN104556686A (zh) * 2015-01-19 2015-04-29 濮阳市新和实业发展有限公司 一种铁锰着色低硼硅药用玻璃管及其制备方法
US11208348B2 (en) 2015-09-30 2021-12-28 Corning Incorporated Halogenated polyimide siloxane chemical compositions and glass articles with halogenated polyimide siloxane low-friction coatings
US11772846B2 (en) 2015-10-30 2023-10-03 Corning Incorporated Glass articles with mixed polymer and metal oxide coatings
US12103734B2 (en) 2015-10-30 2024-10-01 Corning Incorporated Glass articles with mixed polymer and metal oxide coatings
US12110151B2 (en) 2015-10-30 2024-10-08 Corning Incorporated Glass articles with mixed polymer and metal oxide coatings
CN106800369B (zh) * 2015-11-26 2022-02-11 肖特股份有限公司 热钢化玻璃元件及其用途
USRE49895E1 (en) 2015-11-26 2024-04-02 Schott Ag Thermally tempered glass element and use thereof
US11021390B2 (en) 2015-11-26 2021-06-01 Schott Ag Thermally tempered glass element and use thereof
CN106800369A (zh) * 2015-11-26 2017-06-06 肖特股份有限公司 热钢化玻璃元件及其用途
CN113831013A (zh) * 2021-08-31 2021-12-24 甘肃旭康材料科技有限公司 中性硼硅玻璃组合物、中性硼硅玻璃及其制备方法与应用
CN113860729A (zh) * 2021-10-25 2021-12-31 北京工业大学 一种中硼硅药用玻璃

Also Published As

Publication number Publication date
CN101717189B (zh) 2011-06-08

Similar Documents

Publication Publication Date Title
CN101717189B (zh) 高耐化学性硼硅玻璃及用途
JP7432570B2 (ja) 改良された化学的および機械的耐久性を有するガラス組成物
CN104261676B (zh) 一种中性硼硅玻璃及其应用
CN112811813B (zh) 一种硼硅玻璃组合物、硼硅玻璃及其制备方法和应用
CN113998886A (zh) 药物容器用玻璃
US11319242B2 (en) Borosilicate glass with high chemical resistance and application thereof
JP2014037343A (ja) 医薬品容器用ガラス及びこれを用いたガラス管
JP6709501B2 (ja) 医薬品容器用ガラス及び医薬品容器用ガラス管
JP6627779B2 (ja) 医薬品容器用ガラス及び医薬容器用ガラス管
CN106396371A (zh) 具有优化的碱金属比的低硼无锆中性玻璃
CN113213755B (zh) 一种中性硼硅玻璃组合物、中性硼硅玻璃制品及其制备方法和应用
CN114195382B (zh) 硼硅酸盐玻璃组合物、硼硅酸盐玻璃制备方法和药用玻璃
CN107344813B (zh) 包括耐化学性玻璃的医药包装
CN104118988A (zh) 一种超白玻璃配方
CN112551891B (zh) 玻璃组合物、玻璃管及其制备方法和应用
WO2020153294A1 (ja) 医薬品容器用ガラス、これを用いた医薬品容器用ガラス管及び医薬品容器
CN113227008B (zh) 医药品容器用玻璃、使用其的医药品容器用玻璃管及医药品容器
WO2014069177A1 (ja) 医薬用ガラス及び医薬用ガラス管
CN101462824B (zh) 一种药用管制瓶的半中性硼硅玻璃
CN110510873B (zh) 硼硅酸盐玻璃及其制备方法
CN114212999A (zh) 一种含磷含锆的硼硅酸盐玻璃
WO2015129495A1 (ja) 珪酸塩ガラスの製造方法、珪酸塩ガラス及び珪酸塩ガラス用シリカ原料
WO2021220801A1 (ja) 医薬品容器用ガラス、医薬品容器用ガラス管及び医薬品容器
JPH04280833A (ja) ホウケイ酸ガラス
CN116119924A (zh) 玻璃组合物、玻璃及其制备方法和应用

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: SHANDONG LINUO NEW MATERIAL CO., LTD.

Free format text: FORMER OWNER: WUHAN LINUO SOLAR ENERGY GROUP CO., LTD.

Effective date: 20121204

C41 Transfer of patent application or patent right or utility model
COR Change of bibliographic data

Free format text: CORRECT: ADDRESS; FROM: 250100 JINAN, SHANDONG PROVINCE TO: 251600 JINAN, SHANDONG PROVINCE

TR01 Transfer of patent right

Effective date of registration: 20121204

Address after: 251600 No. 10, Petrochemical Road, Shanghe County, Shandong, Ji'nan

Patentee after: Shandong Linuo New Material Co., Ltd.

Address before: 250100, No. ten East 8169, Licheng District, Shandong, Ji'nan

Patentee before: Linuo Solar Group Co., Ltd.

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20110608

Termination date: 20130828