CN101634183B - Polished tiles imitating border texture effect of natural stone and preparation method thereof - Google Patents
Polished tiles imitating border texture effect of natural stone and preparation method thereof Download PDFInfo
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- CN101634183B CN101634183B CN200910039854XA CN200910039854A CN101634183B CN 101634183 B CN101634183 B CN 101634183B CN 200910039854X A CN200910039854X A CN 200910039854XA CN 200910039854 A CN200910039854 A CN 200910039854A CN 101634183 B CN101634183 B CN 101634183B
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Abstract
The invention relates to polished tiles imitating border texture effect of natural stone and a preparation method thereof. The invention is characterized by comprising two kinds of soluble salts which can occur chemical reaction to generate precipitate and has strong dyeing power, wherein, one kind of the soluble salt directly added into powder is called as material A, the other kind of the soluble salt capable of chemically reacting with the material A is called material B. The method comprises the following steps: preparing the material B into fancy glaze; mixing the material A with ceramicslurry; carrying out spraying and power making on the mixture of the material A and the ceramic slurry, or processing the power by using the water solution of the mixture of the material A and the ceramic slurry, and then carrying out micro-powder random fabric distribution on other materials; carrying out large-area screen printing on the material B after drying in a drying kiln, and finally carrying out leaching and water seepage, so that fine anti-high temperature dyeing materials are generated on the border of the material A, while penetration is synchronized with reaction. The texture ofthe product prepared by the invention is greatly fine, smooth and natural, and is exactly similar to the texture effect of the natural stone border.
Description
Technical field
The present invention relates to a kind of building and ornament materials and preparation method thereof, particularly polished bricks of a kind of imitating border texture effect of natural stone and preparation method thereof.
Background technology
Polished brick in porcelain character because of its intensity height, compact structure, glossiness is good, wear-resisting, antifouling property is good, physicochemical property is superior, the pursuing of the changeable customer of firmly getting of pattern.Comparatively dullness, comparatively flat fuzzy, the fine and smooth sense of texture show not good enough the colored polished bricks color that oozes of prior art making.By the too late all the time lithotome of the whole decorative effect of the micro-powdered polishing brick lines of plant equipment cloth.The present invention rolls into one the advantage of the pattern permeating tile on the existing market, micro-powder brick and stone material, and pattern is full of variety, and more can embody the stone material border texture effect, has greatly improved product specification.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, provide that a kind of good decorating effect, abrasion resistance height, antifouling property are good, pattern is full of variety, more can embody the polished bricks and preparation method thereof of the imitating border texture effect of natural stone of the fine and smooth lines of stone material.
The present invention adopts following technical scheme to realize above-mentioned purpose:
Polished bricks of a kind of imitating border texture effect of natural stone and preparation method thereof, described critical materials comprises that two kinds chemical reaction can take place generate precipitation, solubility salt with strong colorability, a kind of is the be referred to as A material that directly adds in the powder, and another kind is can carry out chemical reaction with the A material to be called the B material.The B material is made fancy glaze, the A material mixes with ceramic size, spraying is made powder or is directly handled powder with its aqueous solution, carry out the micro mist random distributing with other material again, after the drying kiln drying is dry, with large tracts of land serigraphy B material, drench at last and help infiltration, produce the limit infiltration like this on A material border, the limit reaction forms very thin high temperature resistant painted thing.
Described A material can be a potassium chromate, potassium bichromate, sodium chromate, sodium dichromate, sodium phosphate, water soluble salts such as sodium pyrophosphate.The B material can be a frerrous chloride, iron chloride, and ferrous nitrate, ferric nitrate, nickel chloride, copper chloride etc. have the acid water soluble salt of strong colorability.Between A material and the B material chemical reaction can take place and generate infusible precipitate, this precipitation can be high temperature resistant, and strong coloring force.
Described B material also can directly be handled powder with its aqueous solution, carries out micro mist cloth with the powder that contains the A material again.Before entering dry kiln, drench an amount of water and expect to react between the interface to promote A material and B.Penetration-assisting agent adopts natrium citricum, ammonium citrate etc.
Described B material can also replace helping infiltration with its aqueous solution without serigraphy, directly sprays.
This border texture generating principle is: under the effect that helps infiltration, water soluble salt produces the limit infiltration simultaneously to the infiltration of base substrate diffusion inside on the border, the specific physical chemical phenomenon of limit reaction.This just makes and has generated the reaction precipitation thing of one deck along A material bed of cloth in polished bricks inside.After process kiln high temperature burns till and polishes, form the texture with boundary effect of the exquisiteness that only in lithotome, just can see.
The present invention adopts the beneficial effect that can reach after the technique scheme to be:
1. novelty.The present invention can react, and have the solubility salt of strong colorability to introduce in the micro mist material and carry out cloth, and it is insoluble, high temperature resistant to utilize chemical reaction to generate on the material border, the precipitation of strong coloring force.It is very high to be particularly suitable for certain salt amount of ask for something, and the smaller situation of this salt solubility.This technology rolls into one the advantage of pattern permeating tile, micro-powder brick and stone material, good decorating effect.Because the randomness of micro mist cloth, the line image of formation is full of variety, and has fully showed the stone material border texture effect.Do not find identical product at ceramic field.
2. good decorating effect.After the paving, whole structure is natural and tripping, and pattern is true to nature naturally, more can embody the stone material border texture effect.
3. good product performance.Antifouling property is good, and the rupture strength height is "dead", abrasion resistance height, advantage such as soil resistance is good.
The specific embodiment
Ceramic body is formed (by weight percentage) content: all mountains sand 20%, and middle temperature sand 22%, southern peak hypothermia grait 20%, Jiangxi weathering potassium sand 16% is washed pure mud 9%, brilliant ball clay 13%.The A material adopts sodium phosphate, and each powder carries out the micro mist random distributing by forming as following table:
| The powder title | Toner is formed | Each powder proportion |
| Powder A | 99.2% base-material+0.8% sodium phosphate | 30％ |
| Powder material B | 99.5% base-material+0.5% is beautiful yellow | 40％ |
| Powder C | 99% base-material+1% zirconium silicate | 30％ |
B material adopts iron chloride, and 40% iron chloride and penetration-assisting agent natrium citricum 10% are dissolved in water, adds 0.1% high sticking sodium carboxymethylcellulose, and the make flow velocity fancy glaze of 35 seconds (200ml volt cup) adopts 80 order full impregnated screen printings.Pouring helps infiltration 150 grams (800*800mm).Under the effect that helps infiltration, water soluble salt sodium phosphate and iron chloride produce the limit infiltration simultaneously to the infiltration of base substrate diffusion inside on the border, the specific physical chemical phenomenon of limit reaction.This has just generated one deck and has formed very thin one deck reaction precipitation thing ferric phosphate along adding sodium phosphate micro mist material bed of cloth in polished bricks inside.And ferric phosphate itself is exactly a kind of ceramic pigment, after burning till and polish through 1200 ℃ of high temperature of kiln like this, forms the texture with boundary effect of the exquisiteness that only just can see in lithotome.
Claims (1)
1. the preparation method of an imitating border texture effect of natural stone polished bricks, it is characterized in that: it comprises that two kinds the solubility salt with strong colorability that chemical reaction generates precipitation can take place, a kind of is that the A that is referred to as that directly adds in the powder expects, described A material is potassium chromate, potassium bichromate, sodium chromate, sodium dichromate, sodium phosphate or sodium pyrophosphate, another kind is to expect that with A the B that is called that carries out chemical reaction expects, described B material is frerrous chloride, iron chloride, ferrous nitrate, ferric nitrate, nickel chloride or copper chloride; The B material is made the Hua You, the A material is made powder or is directly handled powder with its aqueous solution with the ceramic size mixed atomizing, carry out the micro mist random distributing with other material again, after the drying kiln drying is dry, expect with large tracts of land serigraphy B, drench at last and help infiltration, perhaps the aqueous solution of the dry back of drying kiln drying direct spray B material replaces helping infiltration, and the permeate side reaction of generation limit forms very thin high temperature resistant painted thing on A material border like this.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910039854XA CN101634183B (en) | 2009-05-31 | 2009-05-31 | Polished tiles imitating border texture effect of natural stone and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910039854XA CN101634183B (en) | 2009-05-31 | 2009-05-31 | Polished tiles imitating border texture effect of natural stone and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101634183A CN101634183A (en) | 2010-01-27 |
| CN101634183B true CN101634183B (en) | 2011-06-15 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN200910039854XA Active CN101634183B (en) | 2009-05-31 | 2009-05-31 | Polished tiles imitating border texture effect of natural stone and preparation method thereof |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104325823A (en) * | 2014-10-10 | 2015-02-04 | 德清诺贝尔陶瓷有限公司 | Glazed porcelain polished tile and production method thereof |
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Owner name: GUANGDONG MONALISA NEW MATERIALS GROUP CO., LTD. Free format text: FORMER NAME: GUANGDONG MONA LISA CERAMIC CO., LTD. |
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| CP01 | Change in the name or title of a patent holder |
Address after: 528211, Foshan Nanhai Xiqiao Taiping Industrial Zone Guangdong Guangdong Monalisa Ceramic Co., Ltd. Patentee after: Guangdong Monalisa New Material Group Co., Ltd. Address before: 528211, Foshan Nanhai Xiqiao Taiping Industrial Zone Guangdong Guangdong Monalisa Ceramic Co., Ltd. Patentee before: Guangdong Mona Lisa Ceramic Co., Ltd. |
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Address after: 528211 Taiping Industrial Zone, Xiqiao Town, Nanhai District, Guangdong, Foshan, China Patentee after: MONALISA GROUP CO., LTD. Address before: 528211, Foshan Nanhai Xiqiao Taiping Industrial Zone Guangdong Guangdong Monalisa Ceramic Co., Ltd. Patentee before: Guangdong Monalisa New Material Group Co., Ltd. |