CN101633587A - Saline-alkali land improving and fertilizing agent and preparation method thereof - Google Patents

Saline-alkali land improving and fertilizing agent and preparation method thereof Download PDF

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CN101633587A
CN101633587A CN200810072918A CN200810072918A CN101633587A CN 101633587 A CN101633587 A CN 101633587A CN 200810072918 A CN200810072918 A CN 200810072918A CN 200810072918 A CN200810072918 A CN 200810072918A CN 101633587 A CN101633587 A CN 101633587A
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saline
fertilizer
alkali land
land improving
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CN101633587B (en
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石师宁
于建兵
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Abstract

The invention discloses a saline-alkali land improving and fertilizing agent and a preparation method thereof. The saline-alkali land improving and fertilizing agent are mainly prepared from 20 to 40 portions of fly ash, 10 to 20 portions of humic acid and 5 to 10 portions of organic substance through processes of crushing, matching and mixing, granulating, drying, cooling, sieving, magnetizing and the like. Compared with the prior art, a product of the invention has the advantages of short period for improving the saline-alkali land, high efficiency and low cost; if 50 kilograms of product is applied to each acre as base fertilizer, the seedling emergence rate of planted crops can reach 98 percent, for example, 406 kilograms of wheat is harvested in each acre and is equal to the planting harvest of the normal soil, and after the harvest, the salt content of the soil is 0.55 percent and the desalination rate reaches 47 percent through soil measurement, so that the soil granule structure is improved; and the product can reduce the salt and restrain the alkali, is soil improvement agent, also can be used as fertilizer, reduces the planting cost, has the same using method as a common fertilizer when the product is used as the fertilizer, has remarkable fertilizer efficiency in saline-alkali and poor soil, and can increase the yield by 10 to 30 percent relative to different crops compared with the used common fertilizer. Therefore, the saline-alkali land improving and fertilizing agent not only can improve the soil granule structure, but also can accelerate the improvement of soil desalination; meanwhile, the saline-alkali land improving and fertilizing agent is fertilizer, greatly reduces the planting cost of peasants, and improves the planting income of the peasants.

Description

Saline-alkali land improving and fertilizing agent and preparation method thereof
Technical field:
The present invention relates to a kind of saline-alkali land improving and fertilizing agent and preparation method thereof.
Background technology:
Alkaline land improving is a global problem always, and a lot of countries all are devoted to the improvement and the utilization in saltings.At present, the method for alkaline land improving and improvement is a lot, as the improvement of the biological processes of pioneer crops such as rice cultivation, clover, and the water desalinization of soil by flooding or leaching physically improved, and with the chemical modifying of gypsum and sulphur etc.But these modification methods exist the improvement cycle long, have high input, the shortcoming that water consumption is big.There is the saltings more than 14.87 hundred million mu in China and is subjected to the middle-and-low-yielding fields of saline and alkaline harm, wherein much reasonably developments and utilizations.The today that is subjected to the invasion and attack of urbanization occupation of land, desertification, desertification, salinization in the arable land and reduces day by day, the improvement in saltings and improvement seem more and more important.It is just not obvious that existing alkaline land modifying agent is higher than the effect of 0.6% saltings to salinity, and its crop seedling rate is lower than 40%, and surviving rate and output are low especially.Chinese patent CN 1631857A discloses a kind of saline-alkali land improving and fertilizing agent and preparation method thereof, comprise microbial composite bacteria liquid and siccative, described microbial composite bacteria liquid is made up of Trichodermareesei, plant lactobacillus, yeast saccharomyces cerevisiae and actinoplanes missouriensis, shortcoming is that the raw material sources face is narrow, for scale operation certain difficulty is arranged, and preparation method's complexity, long to the saline-alkali land improving and fertilizing cycle, usage quantity is bigger, need use 2-3 time every year, use continuously 3 years, just executes and must turn over the plough soil, application process is comparatively complicated, and fertilizer efficiency is limited.
Summary of the invention:
It is short to the purpose of this invention is to provide a kind of improvement getting fat saltings relative cycle, and usage quantity is few, and application process is simple, and cost is lower, and the higher a kind of saline-alkali land improving and fertilizing agent of fertilizer efficiency and preparation method thereof.
Fertilizer synergist of the present invention is mainly processed by the raw material of the component of following weight: flyash: 20~40 parts, and humic acids: 10~20 parts, organic matter: 5~10 parts.
Above-mentioned humic acids is: a kind of in xanthohumic acid, the potassium humate.
Above-mentioned organic matter is at least a in the fulvo acid potassium, Sodium salts humic acids, humic acids amine of purification by liquid extraction from weathered coal.
Above-mentioned saline-alkali land improving and fertilizing agent contains: in nitrogen, phosphorus, potash fertilizer and the powdered iron ore any at least two kinds, wherein nitrogenous fertilizer: 8~30 parts, phosphate fertilizer: 10~30 parts, potash fertilizer: 1~5 part of 5~10 part, powdered iron ore.
Above-mentioned nitrogenous fertilizer can be a kind of in urea, ammonium nitrate, sulfuric acid amine and the phosphamide, phosphate fertilizer can be compound phosphoric acid one amine, phosphoric acid diamines, and potassium primary phosphate in a kind of, potash fertilizer can be a kind of in vitriolate of tartar, the Repone K.
Above-mentioned saline-alkali land improving and fertilizing agent is to process by the following method:
Pulverizing → proportioning mixes → granulation → oven dry → cooling → screening → magnetization → metering packing;
Pulverize: with the particle of various materials pulverizing for≤180 microns;
Proportioning is mixed: by described composition by weight proportioning, pH value is preferably between 5.5~7.5, mixes the back and adds 5~8 parts of stirrings of binding agent, and then add 5~10 parts in water, stirs, and described binding agent can be a kind of in organic diatomite or the inorganic bentonite;
Granulation: granulating and forming in tablets press, particle diameter are 1.5~5 millimeters;
Oven dry: in dryer, oven dry in 5~10 minutes under 110~200 ℃ the temperature;
Cooling: be cooled to below 40 ℃; Preference is 15~40 ℃;
Screening: with sifted component selections 1.5~5 mm granules;
Magnetization: the particle that sieves out is passed through magnetizer, under 1500~4000 Gausses' magneticstrength, magnetized 2~8 seconds, carry out weighing and pack getting final product.
Compare with existing other saline-alkali land improving and fertilizing agents, the present invention is short to the alkaline land improving cycle, the efficient height, cost is low, improvement fertilizer synergist of the present invention is used 50 kilograms for every mu and is made base fertilizer, plantation farm crop seedling rate can reach 98%, as: mu is received 406 kilograms of wheats, equate with the plantation results of normal soil, and after the results, through soil surveying, its saliferous 0.55%, ratio of desalinization reaches 47%, having improved soil aggregate, can press salt to press down alkali, is soil improvement agent, can be used as fertilizer again, lowered planting cost, as fertilizer sources uses identical with the common fertilizer using method, and fertilizer efficiency is remarkable in saline and alkaline and lean soil, with respect to different crops, than using common chemical fertilizer can increase production 10-30%.So the present invention not only can improve soil aggregate, can also accelerate the improvement of soil desalination, be again fertilizer simultaneously, reduce peasant's planting cost greatly, improved the income of peasant planting.
Embodiment:
Embodiment 1:
Get 20 parts in flyash by weight, 10 parts of xanthohumic acids, 8 parts in the fulvo acid potassium of purification by liquid extraction from weathered coal, 8 parts in urea, 10 parts of MAPs, 4 parts of powdered iron ore are crushed into particle diameter≤105 micron respectively; Mix, mix the back and add 5 parts of stirrings of the organic diatomite of binding agent, add water again and stir for 5 parts, granulating and forming in tablets press, particle diameter are 2 millimeters; In dryer, under 120 ℃ the temperature, dried 6 minutes, in cooler, be cooled to 40 ℃, select the particle of 2~4mm with sifted, the particle that filters out is passed through magnetizer, and magnetization is 8 seconds under magneticstrength 1500 Gausses' environment, enters metering packing program weighing and bagging.
Embodiment 2:
Get 25 parts in flyash, 15 parts of potassium humates by weight, from weathered coal 10 parts of 15 parts of 7 parts in fulvo acid potassium, ammonium nitrates, phosphoric acid diamines, 5 parts of the powdered iron ore of purification by liquid extraction, be crushed into particle diameter≤110 micron respectively; Mix; transfer pH value 6; mix the back and add 6 parts of stirrings of binding agent inorganic bentonite, and then add 6 parts of stirrings of water, the granulation particle diameter is 1.5 millimeters in tablets press; the oven dry of 110 ℃ temperature is 7 minutes in dryer; in cooler, be cooled to 35 ℃, select 1.5~3.5 millimeters particle, pass through magnetizer again with sifted; magnetization is 7 seconds under magneticstrength 1800 Gausses' environment, enters metering packing program weighing and bagging.
Embodiment 3:
Get 30 parts in flyash, 20 parts of xanthohumic acids by weight, 8 parts of 20 parts of 10 parts in fulvo acid sodium, sulfuric acid amine, potassium primary phosphates, 3 parts of the powdered iron ore of purification by liquid extraction from weathered coal, be crushed into particle diameter≤120 micron respectively, mix, transfer pH value 6.5, mix the organic diatomite of back adding binding agent and stir for 8 parts, add water again and stir for 10 parts, granulation in tablets press, particle diameter is 3 millimeters, dries 10 minutes under 200 ℃ the temperature in dryer, is cooled to 25 ℃; Select 3~4 millimeters particle with sifted, magnetized 5 seconds under magneticstrength 2000 Gausses' environment by magnetizer again, enter metering packing program weighing and bagging.
Embodiment 4:
Get 35 parts in flyash by weight; 12 parts of potassium humates; 6 parts of the fulvo acid amine of purification by liquid extraction from weathered coal; 30 parts of phosphamides; 10 parts of vitriolate of tartar; 1 part of powdered iron ore; be crushed into particle diameter≤150 micron respectively; mix; transfer pH value 7; mix the back and add 7 parts of stirrings of the organic diatomite of binding agent; and then add 8 parts of stirrings of water; the granulation particle diameter is 4 millimeters in tablets press; in dryer, dried 7 minutes under 180 ℃ the temperature; be cooled to 30 ℃; select 4~5 millimeters particle with sifted, magnetized 6 seconds under magneticstrength 3000 Gausses' environment by magnetizer again, enter metering packing program weighing and bagging.
Embodiment 5:
Get 40 parts in flyash by weight; 18 parts of potassium humates; 5 parts of the fulvo acid amine of purification by liquid extraction from weathered coal; 20 parts of phosphamides; 7 parts of vitriolate of tartar; 2 parts of powdered iron ore; be crushed into particle diameter≤170 micron respectively; mix; transfer pH value 7.5; mix the back and add 6 parts of stirrings of the organic diatomite of binding agent; and then add 7 parts of stirrings of water; the granulation particle diameter is 4 millimeters in tablets press; in dryer, dried 9 minutes under 150 ℃ the temperature; be cooled to 20 ℃; select 1.5~5 millimeters particle with sifted, magnetized 2 seconds under magneticstrength 4000 Gausses' environment by magnetizer again, enter metering packing program weighing and bagging.
Embodiment 6:
Get 37 parts in flyash by weight; 19 parts of xanthohumic acids; 8 parts in the fulvo acid potassium of purification by liquid extraction from weathered coal; 10 parts in urea; 6 parts in Repone K; 2 parts of powdered iron ore; be crushed into particle diameter≤175 micron respectively; mix the back and add 7 parts of stirrings of binding agent inorganic bentonite; and then add 9 parts of stirrings of water; the granulation particle diameter is 5 millimeters in tablets press; in dryer, dried 7 minutes under 190 ℃ the temperature; be cooled to 22 ℃; select 2~5 millimeters particle with sifted; magnetized 3 seconds under magneticstrength 3500 Gausses' environment by magnetizer again, enter metering packing program weighing and bagging.
Embodiment 7:
Get 23 parts in flyash, 13 parts of xanthohumic acids by weight, 9 parts of 15 parts of 6 parts in fulvo acid potassium, ammonium nitrates, vitriolate of tartar, 3 parts of the powdered iron ore of purification by liquid extraction from weathered coal, be crushed into particle diameter≤160 micron respectively, mix the back and add 7 parts of stirrings of binding agent inorganic bentonite, and then add 8 parts of stirrings of water, the granulation particle diameter is 4.5 millimeters in tablets press, in dryer, dried 6 minutes under 170 ℃ the temperature, be cooled to 18 ℃; Select 1.5~4.5 millimeters particle with sifted, magnetized 7 seconds under magneticstrength 2500 Gausses' environment by magnetizer again, enter metering packing program weighing and bagging.
Embodiment 8:
Get 33 parts in flyash by weight; 17 parts of potassium humates; 9 parts in the fulvo acid sodium of purification by liquid extraction from weathered coal; 21 parts of sulfuric acid amine; 18 parts of potassium primary phosphates; 4 parts of powdered iron ore; be crushed into particle diameter≤130 micron respectively; mix; transfer pH value 6.5; mix the back and add 5 parts of stirrings of binding agent inorganic bentonite; and then add 6 parts of stirrings of water; the granulation particle diameter is 2 millimeters in tablets press; in dryer, dried 6 minutes under 150 ℃ the temperature; be cooled to 26 ℃; select 2 millimeters particle with sifted, magnetized 4 seconds under magneticstrength 2800 Gausses' environment by magnetizer again, enter metering packing program weighing and bagging.
Embodiment 9:
Get 28 parts in flyash by weight; 12 parts of potassium humates; 5 parts in the fulvo acid sodium of purification by liquid extraction from weathered coal; 27 parts of sulfuric acid amine; 26 parts of potassium primary phosphates; 5 parts of powdered iron ore; be crushed into particle diameter≤120 micron respectively; mix; transfer pH value 5.5; mix the back and add 8 parts of stirrings of binding agent inorganic bentonite; and then add 8 parts of stirrings of water; the granulation particle diameter is 3 millimeters in tablets press; in dryer, dried 8 minutes under 120 ℃ the temperature; be cooled to 36 ℃; select 3.5~5 millimeters particle with sifted, magnetized 3 seconds under magneticstrength 3800 Gausses' environment by magnetizer again, enter metering packing program weighing and bagging.
Embodiment 10:
Get 38 parts in flyash by weight; 19 parts of xanthohumic acids; 9 parts in the fulvo acid potassium of purification by liquid extraction from weathered coal; 12 parts of ammonium nitrates; 16 parts of MAPs; 1 part of powdered iron ore; be crushed into particle diameter≤140 micron respectively; mix; transfer pH value 6.5; mix the back and add 6 parts of stirrings of binding agent inorganic bentonite; and then add 7 parts of stirrings of water; the granulation particle diameter is 2 millimeters in tablets press; in dryer, dried 6 minutes under 170 ℃ the temperature; be cooled to 32 ℃; the particle of selecting 4 millimeters with sifted passes through magnetizer again, and magnetization is 5 seconds under magneticstrength 3200 Gausses' environment, enters metering packing program weighing and bagging.
Embodiment 11:
Get 25 parts in flyash by weight; 12 parts of xanthohumic acids; 7 parts of the fulvo acid amine of purification by liquid extraction from weathered coal; 18 parts of phosphamides; 25 parts of phosphoric acid diamines; 5 parts of powdered iron ore; be crushed into particle diameter≤160 micron respectively; mix; transfer pH value 7.5; mix the back and add 7 parts of stirrings of the organic diatomite of binding agent; and then add 10 parts of stirrings of water; the granulation particle diameter is 5 millimeters in tablets press; in dryer, dried 5 minutes under 190 ℃ the temperature; be cooled to 37 ℃; select 1.5~5 millimeters particle with sifted, magnetized 6 seconds under magneticstrength 3600 Gausses' environment by magnetizer again, enter metering packing program weighing and bagging.
Embodiment 12:
Get 30 parts in flyash by weight; 11 parts of xanthohumic acids; 6 parts of the fulvo acid amine of purification by liquid extraction from weathered coal; 10 parts of sulfuric acid amine; 30 parts of MAPs; 2 parts of powdered iron ore; be crushed into particle diameter≤110 micron respectively; mix the back and add 5 parts of stirrings of the organic diatomite of binding agent; and then add 6 parts of stirrings of water; the granulation particle diameter is 4 millimeters in tablets press; in dryer, dried 5 minutes under 190 ℃ the temperature; be cooled to 37 ℃; select 2~5 millimeters particle with sifted; magnetized 8 seconds under magneticstrength 2600 Gausses' environment by magnetizer again, enter metering packing program weighing and bagging.
Embodiment 13:
Get 38 parts in flyash by weight; 15 parts of potassium humates; 6 parts in the fulvo acid potassium of purification by liquid extraction from weathered coal; 28 parts in urea; 20 parts of potassium primary phosphates; 4 parts of powdered iron ore; be crushed into particle diameter≤140 micron respectively; mix; transfer pH value 6; mix the back and add 6 parts of stirrings of the organic diatomite of binding agent; and then add 8 parts of stirrings of water; the granulation particle diameter is 2 millimeters in tablets press; in dryer, dried 9 minutes under 120 ℃ the temperature; be cooled to 30 ℃; select 2.5~5 millimeters particle with sifted, magnetized 7 seconds under magneticstrength 2000 Gausses' environment by magnetizer again, enter metering packing program weighing and bagging.
Embodiment 14:
Get 21 parts in flyash by weight; 16 parts of potassium humates; 9 parts in the fulvo acid sodium of purification by liquid extraction from weathered coal; 12 parts in urea; 5 parts of vitriolate of tartar; 1 part of powdered iron ore; be crushed into particle diameter≤160 micron respectively; mix the back and add 8 parts of stirrings of binding agent inorganic bentonite; and then add 9 parts of stirrings of water; the granulation particle diameter is 5 millimeters in tablets press; in dryer, dried 7 minutes under 170 ℃ the temperature; be cooled to 36 ℃; select 1.5~5 millimeters particle with sifted; magnetized 8 seconds under magneticstrength 1500 Gausses' environment by magnetizer again, enter metering packing program weighing and bagging.
Embodiment 15:
Get 32 parts in flyash by weight; 14 parts of xanthohumic acids; 9 parts in the fulvo acid sodium of purification by liquid extraction from weathered coal; 20 parts in urea; 6 parts in Repone K; 3 parts of powdered iron ore; be crushed into particle diameter≤130 micron respectively; mix the back and add 6 parts of stirrings of the organic diatomite of binding agent; and then add 9 parts of stirrings of water; the granulation particle diameter is 3 millimeters in tablets press; in dryer, dried 6 minutes under 140 ℃ the temperature; be cooled to 27 ℃; select 3~5 millimeters particle with sifted; magnetized 6 seconds under magneticstrength 1800 Gausses' environment by magnetizer again, enter metering packing program weighing and bagging.

Claims (7)

1, a kind of saline-alkali land improving and fertilizing agent is characterized in that containing at least following components by weight percent: 20~40 parts in flyash, 10~20 parts of humic acidss, organic 5~10 parts.
2, saline-alkali land improving and fertilizing agent according to claim 1 is characterized in that described humic acids is: at least a in xanthohumic acid or the potassium humate.
3, saline-alkali land improving and fertilizing agent according to claim 1 and 2 is characterized in that described organic matter is at least a in the fulvo acid potassium, Sodium salts humic acids, humic acids amine of purification by liquid extraction from weathered coal.
4, saline-alkali land improving and fertilizing agent according to claim 1 and 2 is characterized in that containing at least two kinds of following components by weight percent: 8~30 parts in nitrogenous fertilizer, 10~30 parts in phosphate fertilizer, 5~10 parts in potash fertilizer, 1~5 part of powdered iron ore.
5, saline-alkali land improving and fertilizing agent according to claim 3, it is characterized in that containing at least two kinds of following components by weight percent: 8~30 parts in nitrogenous fertilizer, 10~30 parts in phosphate fertilizer, 5~10 parts in potash fertilizer, 1~5 part of powdered iron ore.
6, saline-alkali land improving and fertilizing agent according to claim 5, it is characterized in that described nitrogenous fertilizer is a kind of in urea, ammonium nitrate, sulfuric acid amine and the phosphamide, described phosphate fertilizer be compound phosphoric acid one amine, phosphoric acid diamines, and potassium primary phosphate in a kind of, described potash fertilizer is a kind of in vitriolate of tartar, the Repone K.
7,, it is characterized in that comprising following process according to the preparation method of each described saline-alkali land improving and fertilizing agent of claim 1~6:
Pulverize: with the particle of various materials pulverizing for≤180 microns;
Proportioning is mixed: by described composition by weight proportioning, mix the back and add 5~8 parts of stirrings of binding agent, and then add water: 5~10 parts, stir, and described binding agent is a kind of in organic diatomite or the inorganic bentonite;
Granulation: granulating and forming in tablets press, particle diameter are 1.5~5 millimeters;
Oven dry: in dryer, oven dry in 5~10 minutes under 110~200 ℃ the temperature;
Cooling: be cooled to below 4 ℃;
Screening: with sifted component selections 1.5~5 mm granules;
Magnetization: the particle that sieves out is passed through magnetizer, under 1500~4000 Gausses' magneticstrength, magnetized 2~8 seconds.
CN200810072918A 2008-07-21 2008-07-21 Saline-alkali land improving and fertilizing agent and preparation method thereof Expired - Fee Related CN101633587B (en)

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CN102304363A (en) * 2011-05-06 2012-01-04 内蒙古禾创农业科技发展有限公司 Composition employing power plant waste and peat and weathered coal resources to improve saline-alkali soil
CN103333696A (en) * 2013-07-10 2013-10-02 丹阳市淸云农业发展有限公司 Modifier used for alkaline soil
CN104140821A (en) * 2013-05-08 2014-11-12 深圳海川新材料科技有限公司 Soil structure conditioner and preparation method thereof
CN104845634A (en) * 2015-04-02 2015-08-19 梁志华 Soil activator
CN105112062A (en) * 2015-08-27 2015-12-02 江苏沃野生物科技发展有限公司 Production process of organic saline soil improver
CN105272718A (en) * 2015-09-21 2016-01-27 潍坊友容实业有限公司 Saline land dedicated improvement sprinkle fertilizer
CN103787774B (en) * 2014-01-24 2016-03-09 安徽省化工设计院 A kind of soil conditioner and preparation method thereof
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CN107417432A (en) * 2017-09-21 2017-12-01 界首市众建家庭农场 A kind of high-activity humic acid fertilizer synergist
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CN112125730A (en) * 2020-09-01 2020-12-25 内蒙古晟宇泰合农林生物科技有限公司 Preparation and application of soil conditioner for treating desertification by changing kitchen waste into soil
CN113121288A (en) * 2019-12-31 2021-07-16 北京紫光英力化工技术有限公司 Fertilizer containing bio-based sulfonate and application thereof in sand stabilization and soil improvement
CN113354484A (en) * 2021-07-21 2021-09-07 王晴 Environment-friendly agricultural fertilizer and preparation method thereof
CN114350375A (en) * 2022-01-19 2022-04-15 山西省岩矿测试应用研究所(山西省贵金属及珠宝玉石检测中心) Fly ash selenium-rich soil conditioner and preparation method and application thereof

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CN104140821A (en) * 2013-05-08 2014-11-12 深圳海川新材料科技有限公司 Soil structure conditioner and preparation method thereof
CN103333696A (en) * 2013-07-10 2013-10-02 丹阳市淸云农业发展有限公司 Modifier used for alkaline soil
CN103787774B (en) * 2014-01-24 2016-03-09 安徽省化工设计院 A kind of soil conditioner and preparation method thereof
CN105566001A (en) * 2014-10-10 2016-05-11 河南艾农肥业有限公司 Preparation method of composite microbe soil nutrition remediation agent
CN104845634A (en) * 2015-04-02 2015-08-19 梁志华 Soil activator
CN105112062A (en) * 2015-08-27 2015-12-02 江苏沃野生物科技发展有限公司 Production process of organic saline soil improver
CN105272718A (en) * 2015-09-21 2016-01-27 潍坊友容实业有限公司 Saline land dedicated improvement sprinkle fertilizer
CN106083473A (en) * 2016-06-17 2016-11-09 中化化肥有限公司临沂农业研发中心 A kind of light simplification fertilizer special for cotton being applicable to salt-soda soil and preparation method thereof
CN107417432A (en) * 2017-09-21 2017-12-01 界首市众建家庭农场 A kind of high-activity humic acid fertilizer synergist
CN107417432B (en) * 2017-09-21 2018-08-24 界首市众建家庭农场 A kind of high-activity humic acid fertilizer synergist
CN108018848A (en) * 2017-12-18 2018-05-11 俞瑞山 Sodium humate or humic acid potassium are used for control of desert with suppressing the method for earth's surface dust
CN110157441A (en) * 2018-03-05 2019-08-23 苏州睿烁环境科技有限公司 A kind of soil conditioner and preparation method thereof for salt-soda soil
CN108633673A (en) * 2018-05-03 2018-10-12 山东胜伟旅游发展有限公司 A method of utilizing saline and alkaline real estate soybean extract oil
CN113121288A (en) * 2019-12-31 2021-07-16 北京紫光英力化工技术有限公司 Fertilizer containing bio-based sulfonate and application thereof in sand stabilization and soil improvement
CN112125730A (en) * 2020-09-01 2020-12-25 内蒙古晟宇泰合农林生物科技有限公司 Preparation and application of soil conditioner for treating desertification by changing kitchen waste into soil
CN113354484A (en) * 2021-07-21 2021-09-07 王晴 Environment-friendly agricultural fertilizer and preparation method thereof
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