CN101623238B - Long-acting deodorization composition for animals and preparation method thereof - Google Patents
Long-acting deodorization composition for animals and preparation method thereof Download PDFInfo
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- CN101623238B CN101623238B CN 200810029487 CN200810029487A CN101623238B CN 101623238 B CN101623238 B CN 101623238B CN 200810029487 CN200810029487 CN 200810029487 CN 200810029487 A CN200810029487 A CN 200810029487A CN 101623238 B CN101623238 B CN 101623238B
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Abstract
The invention relates to a long-acting deodorization composition for animals, and belongs to animal care products. The composition comprises the following components in percentage by weight: 1 to 20 percent of chlorine dioxide, 1 to 20 percent of hypochlorite, 1 to 20 percent of pH regulator, 0.1 to 5 percent of super absorbent polymer, 1 to 15 percent of humectant, and the balance of deionized water. The invention also relates to a preparation method of the deodorization composition, which comprises the following steps: dissolving hypochlorite into proper amount of deionized water to obtain hypochlorite deionized water solution; dissolving hyperchlorous anhydride gas into proper amount of water to obtain chlorine dioxide water solution; adding the pH regulator into the hypochlorite water solution; mixing the mixed solution of the pH regulator and hypochlorite water solution and the chlorine dioxide water solution; and adding proper amount of super absorbent polymer and the humectant into the mixed solution to obtain the long-acting deodorization composition. Through mutual action of a buffer system formed by the hypochlorite, the pH regulator and the super absorbent polymer in the materials and chlorine dioxide, the composition slowly and stably releases certain concentration of chlorine dioxide so as to achieve the effect of removing animal odor in long acting.
Description
[invention field]
The present invention relates to a kind of long-acting deodorization composition for animals and preparation method, belong to the manufacturing of animal care articles for use.
[background of invention]
Animal, particularly doggie, kitten abnormal flavour with it is a puzzlement pet fan difficult problem for many years, its main source is animal self secretions, plays to roll and climbs the filthy composition that causes and decompose under the microbial actions such as antibacterial and produce.The animal deodorising product has the function of eliminating the animal abnormal flavour.At present animal deodorization mainly is the mode that adopts the washings such as bath gel, fancy soap, and these method troubles can not be removed stink for a long time.The present invention is directed to the deficiency of existing product, proposed a kind of long-acting deodorization composition for animals.
[summary of the invention]
The object of the invention provides a kind of long-acting deodorization composition for animals and preparation method.
The implementation of the object of the invention is: a kind of long-acting deodorization composition for animals is characterized in that comprising by weight percentage following component:
Can also include the surfactant that accounts for composition weight than being 1～20% in this compositions is 0.01～2% essence and flavoring agent with accounting for the composition weight ratio.
Chlorine dioxide (ClO wherein
2) molecular weight is 67.46, the chemical compound that exists with monomer free base form fully at occurring in nature.ClO
211 ℃ of boiling points, one 59 ℃ of freezing pointes are yellow green or orange colour gas at normal temperatures.
Hypochlorite is one or more the compositions in lithium hypochlorite, sodium hypochlorite, postassium hypochlorite, magnesium hypochlorite, calcium hypochlorite, the hypochlorous acid ammonium.
Super absorbent resin is one or more the compositions in polyacrylate, polyacrylamide, polyvinyl alcohol, acetate ethylene copolymer, polyurethane, poly(ethylene oxide), the starch graft copolymer.
PH adjusting agent is one or more the compositions in hydrochloric acid, citric acid, phosphoric acid, carbonic acid, acetic acid, fruit acid, formic acid, lactic acid, tartaric acid, ferric chloride, aluminum chloride, the sodium bisulfate.
Wetting agent is Polyethylene Glycol below 10000 of propylene glycol, glycerol, Sorbitol, butanediol, hexanediol, ethyoxyl glucose, 1,2 one hexanediol, hexanetriol, dipropylene glycol, hyaluronic acid, hyaluronate sodium, erithritol, trehalose, xylitol, maltose, glucose, fructose, molecular weight, one or more the moisture-keeping composition in the cyclodextrin.
Surfactant refers to have the auxiliary agent that hydrophilic and oleophilic plays decontamination, conditioning, solubilising, stabilization function, can be one or more mixture in fatty acid salt, quaternary ammonium salt, the multiple yin, yang of polyethylene glycols, the non-ionic surface active agent.
Essence and flavoring agent has been the material of aromatic odor, can be one or more mixture in all kinds of essence, the spice.
The preparation method that a kind of long-acting deodorization composition for animals reaches is characterized in that may further comprise the steps:
A, be that 1～20% hypochlorite is dissolved into and obtains the hypochlorite deionized water solution in an amount of deionized water with percentage by weight;
B, be that 1～20% chlorine dioxide is dissolved in the water and obtains aqueous solution of chlorine dioxide with percentage by weight;
C, be that 1～20% pH adjusting agent joins in the aqueous hypochlorite solution of step a preparation with percentage by weight;
The solution of d, the aqueous solution of chlorine dioxide of getting step b preparation and step c preparation is mixed to get the concentrated solution of chlorine dioxide;
E, the solution adding percentage by weight for preparing to steps d are that 0.1～5% super absorbent resin, 1～15% wetting agent obtain long-acting deodorization composition for animals.
Wherein, can also add percentage by weight among the step e and be 1～20% surfactant, 0.01～2% essence and flavoring agent.
The present invention is take chlorine dioxide as main component, the present composition can slowly discharge chlorine dioxide, utilize chlorine dioxide that cell wall is had stronger absorption and penetration capacity, can pass cell wall is the SH radical reaction of cysteine with the key element that consists of microprotein, make the enzymatic inactivation take the SH base as active site, and with the cell membrane of its oxidability destroy microorganisms, kill animals microorganism with it, decompose the thalline remains, kill the spore of spore, thereby reach the purpose of removing stink, chlorine dioxide can decomposing hydrogen sulfide simultaneously, the stink substances such as ammonia reach the effect of deodorization.
The present invention compared with prior art has the following advantages: the present invention is easy to use, need not clean animal and just can reach the effect of eliminating the animal abnormal flavour.Chlorine dioxide in the animal deodorant liquid solution is safe and reliable, has the several functions such as sterilization, sterilization, anticorrosion, deodorization, does not have carcinogenic, teratogenecity fully.The long-acting chlorine dioxide hydrogel that super absorbent resin is made has further been strengthened the buffer system effect, makes the release of chlorine dioxide more slowly reach the effect of long-acting deodorization.
[specific embodiment]
The below provides a plurality of experiment illustrations of a plurality of preparation long-acting deodorization compositions, comes the present invention is described further, and these embodiment only are illustrative, but not limit the scope of the invention.
Embodiment 1:
The 10g sodium hypochlorite is dissolved into obtains the sodium hypochlorite deionized water solution in the 90g deionized water; Obtain aqueous solution of chlorine dioxide with in the dissolving of the chlorine dioxide of 10g and the 90g water; The 10g citric acid is joined in the aqueous sodium hypochlorite solution of above-mentioned preparation, obtain the buffering delivery systme in the chemical equation (2); The aqueous solution of chlorine dioxide of getting the citric acid of step preparation and sodium hypochlorite mixed solution and above-mentioned preparation is mixed to get the concentrated solution of chlorine dioxide; After adding 2g polyacrylate, 10g propylene glycol, 10g sodium n-alkylbenzenesulfonate LAS (surfactant a kind of) and 0.5g essence and flavoring agent to the concentrated solution of chlorine dioxide, add again deionized water and obtain long-acting deodorization composition for animals to 1000g.
According to the chemical equation analysis:
Utilize citric acid faintly acid feature, allow citric acid in water, slowly ionize and discharge H
+, with lithium hypochlorite LiClO
2Reaction generates HClO
2, allow chemical reaction (1) move the release chlorine dioxide to the left side.
Embodiment 2:
The 200g sodium hypochlorite is dissolved into obtains the sodium hypochlorite deionized water solution in the 50g deionized water; Obtain aqueous solution of chlorine dioxide with in the dissolving of the chlorine dioxide of 200g and the 50g water; The 20g citric acid is joined in the aqueous sodium hypochlorite solution of above-mentioned preparation, obtain the buffering delivery systme in the chemical equation (2); The aqueous solution of chlorine dioxide of getting the citric acid of step preparation and sodium hypochlorite mixed solution and above-mentioned preparation is mixed to get the concentrated solution of chlorine dioxide; Add the compositions, 49g sodium alkyl sulfonate SAS (surfactant a kind of) and 1g essence and flavoring agent of compositions, 50g glycerol and Sorbitol and the butanediol of 30g polyacrylamide and polyvinyl alcohol to the concentrated solution of chlorine dioxide after, add again deionized water and obtain long-acting deodorization composition for animals to 1000g.
Embodiment 3:
The 10g sodium hypochlorite is dissolved into obtains the sodium hypochlorite deionized water solution in the 90g deionized water; Obtain aqueous solution of chlorine dioxide with in the dissolving of the chlorine dioxide of 10g and the 90g water; The 200g citric acid is joined in the aqueous sodium hypochlorite solution of above-mentioned preparation, obtain the buffering delivery systme in the chemical equation (2); The aqueous solution of chlorine dioxide of getting the citric acid of step preparation and sodium hypochlorite mixed solution and above-mentioned preparation is mixed to get the concentrated solution of chlorine dioxide; Add 50g acetate ethylene copolymer and urethane composition, 150g hexanetriol and 1 to the concentrated solution of chlorine dioxide, behind the compositions of 2 one hexanediol, 200g sodium alkyl sulfonate SAS (surfactant a kind of) and the 20g essence and flavoring agent, add again deionized water and obtain long-acting deodorization composition for animals to 1000g.
Embodiment 4:
The 200g sodium hypochlorite is dissolved into obtains the sodium hypochlorite deionized water solution in the 200g deionized water; Obtain aqueous solution of chlorine dioxide with in the dissolving of the chlorine dioxide of 200g and the 200g water; The 10g citric acid is joined in the aqueous sodium hypochlorite solution of above-mentioned preparation, obtain the buffering delivery systme in the chemical equation (2); The aqueous solution of chlorine dioxide of getting the citric acid of step preparation and sodium hypochlorite mixed solution and above-mentioned preparation is mixed to get the concentrated solution of chlorine dioxide; After adding 1g polyurethane, 10g dipropylene glycol, 10g sodium n-alkylbenzenesulfonate LAS (surfactant a kind of) and 0.1g essence and flavoring agent to the concentrated solution of chlorine dioxide, add again deionized water and obtain long-acting deodorization composition for animals to 1000g.
Embodiment 5:
The 120g sodium hypochlorite is dissolved into obtains the sodium hypochlorite deionized water solution in the 150g deionized water; Obtain aqueous solution of chlorine dioxide with in the dissolving of the chlorine dioxide of 140g and the 150g water; The 100g citric acid is joined in the aqueous sodium hypochlorite solution of above-mentioned preparation, obtain the buffering delivery systme in the chemical equation (2); The aqueous solution of chlorine dioxide of getting the citric acid of step preparation and sodium hypochlorite mixed solution and above-mentioned preparation is mixed to get the concentrated solution of chlorine dioxide; After adding 30g poly(ethylene oxide), 40g hyaluronate sodium, 15g sodium n-alkylbenzenesulfonate LAS (surfactant a kind of) and 5g essence and flavoring agent to the concentrated solution of chlorine dioxide, add again deionized water and obtain long-acting deodorization composition for animals to 1000g.
Embodiment 6:
In advance 50 gram lithium hypochlorites are dissolved into the lithium hypochlorite water solution A that obtains 50000ppm in the 950ml deionized water; The chlorine dioxide of 25 grams is obtained B solution by dissolving in the bottom bubbling adding 1000ml water; In advance 10 gram lithium hypochlorites are dissolved into the lithium hypochlorite aqueous solution C that obtains 10000ppm in the 990ml deionized water; 5 gram citric acids are joined in the C solution dissolving obtain solution D.With 100mlA and 700mlB, and the 200mlD mixed at room temperature is even, adds appropriate amount of starch graft copolymer, erithritol, sodium n-alkylbenzenesulfonate LAS (surfactant a kind of) and essence and flavoring agent again and obtains long-acting deodorization composition for animals.
Embodiment 7:
50 gram sodium hypochlorite are dissolved into and obtain 5% aqueous sodium hypochlorite solution in the 950ml deionized water; To obtain 2% aqueous solution of chlorine dioxide in the 25 chlorine dioxide dissolvings that restrain and the 1225ml water; 25 gram citric acids are joined in the aqueous sodium hypochlorite solution of above-mentioned preparation, obtain the buffering delivery systme in the chemical equation (2); Get citric acid that step prepares 300ml and the aqueous solution of chlorine dioxide 700ml of sodium hypochlorite mixed solution and above-mentioned preparation and be mixed to get the concentrated solution that chlorine dioxide content is 25000ppm; Add again an amount of deionized water, polyacrylamide, glucose, sodium n-alkylbenzenesulfonate LAS (surfactant a kind of) and essence and flavoring agent and obtain long-acting deodorization composition for animals.
Embodiment 8:
50 gram lithium hypochlorites are dissolved into and obtain 5% lithium hypochlorite aqueous solution in the 950ml deionized water; To obtain 2% aqueous solution of chlorine dioxide in the 25 chlorine dioxide dissolvings that restrain and the 1225ml water; 25 gram tartaric acid are joined in the lithium hypochlorite aqueous solution, obtain the buffering delivery systme in the chemical equation (2); Get tartaric acid that step prepares 300ml and the 700ml aqueous solution of chlorine dioxide of lithium hypochlorite mixed liquor and above-mentioned preparation and be mixed to get the concentrated solution that chlorine dioxide content is 25000ppm; Add again an amount of deionized water, acetate ethylene copolymer, xylitol, sodium alkyl sulfonate SAS and essence and flavoring agent and obtain long-acting deodorization composition for animals.
Embodiment 9:
Aqueous solution of chlorine dioxide and aqueous hypochlorite solution can certainly be mixed first, pH adjusting agent and super absorbent resin are being mixed to get long-acting deodorization composition for animals with above-mentioned mixed liquor.
First 50 gram lithium hypochlorites are dissolved into and obtain 5% lithium hypochlorite aqueous solution in the 950ml deionized water; To obtain 2% ClO 2 solution in the 25 chlorine dioxide dissolvings that restrain and the 1225ml water; 300ml lithium hypochlorite aqueous solution is mixed with the 700ml ClO 2 solution, then add an amount of deionized water dilution and obtain the liquid part; The polyurethane hybrid package of 7.5 gram citric acids and 3-5 gram is obtained solid portion; Mix during use and get final product.
The long-acting animal deodorizing gel that said method is made is packed into and is opened in the container of big or small uncovered lid with scalable, is placed on the animal activities such as lodge, basket, toilet waste collector local, can keep one month to three months free from extraneous odour.
Claims (6)
1. long-acting deodorization composition for animals is characterized in that comprising by weight percentage following component:
Described compositions prepares a in accordance with the following steps, be that 1～20% hypochlorite is dissolved into and obtains the hypochlorite deionized water solution in an amount of deionized water with percentage by weight; B, be that 1～20% chlorine dioxide is dissolved in and obtains aqueous solution of chlorine dioxide in the suitable quantity of water with percentage by weight; C, be that 1～20% pH adjusting agent joins in the aqueous hypochlorite solution of step a preparation with percentage by weight; The solution of d, the aqueous solution of chlorine dioxide of getting step b preparation and step c preparation is mixed to get the concentrated solution of chlorine dioxide; E, the solution adding percentage by weight for preparing to steps d are that 0.1～5% super absorbent resin, 1～15% wetting agent obtain long-acting deodorization composition for animals;
Described pH adjusting agent is one or more the compositions in hydrochloric acid, citric acid, phosphoric acid, carbonic acid, acetic acid, fruit acid, formic acid, lactic acid, tartaric acid, ferric chloride, aluminum chloride, the sodium bisulfate.
2. a kind of long-acting deodorization composition for animals according to claim 1 is characterized in that it is 1～20% surfactant, 0.01～2% essence and flavoring agent that said composition also includes weight ratio.
3. a kind of long-acting deodorization composition for animals according to claim 1 is characterized in that described hypochlorite is one or more the compositions in lithium hypochlorite, sodium hypochlorite, postassium hypochlorite, magnesium hypochlorite, calcium hypochlorite, the hypochlorous acid ammonium.
4. a kind of long-acting deodorization composition for animals according to claim 1 is characterized in that described super absorbent resin is one or more the compositions in polyacrylate, polyacrylamide, polyvinyl alcohol, acetate ethylene copolymer, polyurethane, poly(ethylene oxide), the starch graft copolymer.
5. a kind of long-acting deodorization composition for animals according to claim 1, it is characterized in that described wetting agent is Polyethylene Glycol below 10000 of propylene glycol, glycerol, Sorbitol, butanediol, hexanediol, ethyoxyl glucose, 1,2 one hexanediol, hexanetriol, dipropylene glycol, hyaluronic acid, hyaluronate sodium, erithritol, trehalose, xylitol, maltose, glucose, fructose, molecular weight, one or more the moisture-keeping composition in the cyclodextrin.
6. a kind of long-acting deodorization composition for animals according to claim 2 is characterized in that described surfactant is one or more mixture in fatty acid salt, quaternary ammonium salt, the multiple yin, yang of polyethylene glycols, the non-ionic surface active agent.
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| US10858453B2 (en) | 2015-04-01 | 2020-12-08 | International Dioxcide, Inc. | Stabilized composition for combined odor control and enhanced dewatering |
| CN107952347A (en) * | 2017-10-16 | 2018-04-24 | 浙江天多好环保科技有限公司 | A kind of long-acting air purifying composition and preparation method |
| CN111528220B (en) * | 2020-04-21 | 2022-02-08 | 聊城大学 | Hydrogel for slowly releasing chlorine dioxide and preparation method thereof |
| CN111567518B (en) * | 2020-05-27 | 2022-03-15 | 山东省科学院能源研究所 | Gel-like sodium hypochlorite disinfectant and preparation method and application thereof |
| CN111493091B (en) * | 2020-05-27 | 2022-03-11 | 山东省科学院能源研究所 | Disinfectant, and preparation method and application thereof |
| CN111972432A (en) * | 2020-09-17 | 2020-11-24 | 武汉市格勒特新材料有限公司 | Sodium hyaluronate/hypochlorous acid mixed disinfectant and preparation method thereof |
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| JPH0232193A (en) * | 1988-07-21 | 1990-02-01 | Takasugi Seiyaku Kk | Gel-like instant cold-storing and freshness-preserving agent |
| US6197215B1 (en) * | 1999-02-25 | 2001-03-06 | Vulcan Chemicals | Composition for generating chlorine dioxide |
| EP1034799A1 (en) * | 1999-03-05 | 2000-09-13 | The Procter & Gamble Company | Articles having an odour control system comprising a water soluble oxidising agent and an emulsifier |
| CA2429908C (en) * | 2001-01-16 | 2011-05-17 | Joseph M. Kelley | An electrolytic process for the generation of stable solutions of chlorine dioxide |
| JP2004210596A (en) * | 2002-12-31 | 2004-07-29 | Yoshihiko Okubo | Preparation method for solid agent for forming aqueous chlorine dioxide solution |
| US20080274206A1 (en) * | 2004-10-07 | 2008-11-06 | Ngen Pharmaceuticals N.V. | Stabilised Oxygen Releasing Composition |
| JP4373366B2 (en) * | 2005-05-17 | 2009-11-25 | 株式会社アマテラ | Generation method of chlorine dioxide gas |
| JP2007001807A (en) * | 2005-06-23 | 2007-01-11 | Amatera:Kk | Method for generating chlorine dioxide gas |
| JP2008036559A (en) * | 2006-08-08 | 2008-02-21 | Toray Ind Inc | Method of oxidization processing fluororesin-based polymer separation membrane |
| CN100534305C (en) * | 2007-06-14 | 2009-09-02 | 河北科技大学 | Aromatic chlorine dioxide air-antiseptic table and its production |
| US8361944B2 (en) * | 2008-12-09 | 2013-01-29 | The Clorox Company | Solid-layered bleach compositions and methods of use |
-
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- 2008-07-11 CN CN 200810029487 patent/CN101623238B/en active Active
Non-Patent Citations (1)
| Title |
|---|
| 董银卯.化妆品配方工艺手册.《化妆品配方工艺手册》.化学工业出版社,2005,778-779页,表13-5. * |
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Effective date of registration: 20170615 Address after: 463400 north side of Industrial Road, Pingyu County, Henan, Zhumadian Patentee after: Pingyu Iceking Biological Engineering Co., Ltd. Address before: 450000 Henan province Zhengzhou City Xinyuan Road No. 18 Building No. 17 Hospital No. 15 Patentee before: Huang Bingran |