CN100534305C - Aromatic chlorine dioxide air-antiseptic table and its production - Google Patents
Aromatic chlorine dioxide air-antiseptic table and its production Download PDFInfo
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- CN100534305C CN100534305C CNB2007100621473A CN200710062147A CN100534305C CN 100534305 C CN100534305 C CN 100534305C CN B2007100621473 A CNB2007100621473 A CN B2007100621473A CN 200710062147 A CN200710062147 A CN 200710062147A CN 100534305 C CN100534305 C CN 100534305C
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Abstract
The invention is concerned with the spicery chlorine dioxide air sterilization tablet and the preparation method. The project is: the A tablet and the B tablet composes the two-spot tablet, as the following weight: the A tablet including the chlorine dioxide matrix is 1 - 8, the cladding agents is 1 - 10, the adhesive is 1 - 5, the lubrication release agent is 1 - 8, the acidoid is 60 - 95; the B tablet including foaming agent is 60 - 95, the adhesive is 1 - 5, the lubrication release agent is 1 - 10, the solid un-reductibility spice powder is 0.5 - 5. The invention is low price of the tablet, easy using, and simple operation.
Description
Technical field
Type of the present invention relates to a kind of air sterillization tablet and preparation method, belongs to the gas depoisoning technical field.
Background technology
Along with economic development and growth in the living standard, the finishing in office and family place is more and more general, brings hidden danger but fit up improper people's the health of also giving.In recent years, the healthy incident of air pollution harm resident that causes because of interior decoration happens occasionally.In addition, along with popularizing of air-conditioning, the interior length time is in air-tight state, and the comfortableness environment is suitable for growing of various bacteriums, virus more and propagates, and has aggravated the pollution of room air, has also increased chance ill and that communicable disease is broken out.
Chlorine dioxide is a kind of disinfection sanitizer of internationally recognized efficient, nontoxic, quick, wide spectrum, it has 100% sterilization effect to bacterium, fungi, virus, gemma, the chlorine dioxide that in designated space, only need contain enough concentration, can kill therebetween various microorganisms by its powerful oxidation, and harmful substances such as the formaldehyde in the room air, benzene, toluene there is very desirable degradation, it can be reduced to safety standard fully.Chlorine dioxide has good deodorizing effect, the atomic oxygen that it produces can become nitrogen with the ammoniacal liquor dehydration, odorous gas such as hydrogen sulphide, sulphur dioxide and mercaptan are oxidized to sulfuric acid or sulfonic acid and remove, thereby become a kind of air pollution clarificant of new generation of superior performance.
Chlorine dioxide is as the existing report of air sanitizer, generally be to make active aqueous solution of chlorine dioxide earlier to utilize the ultrasonic atomizatio technology again or directly the chlorine dioxide stripping in the solution is gone out and enter air and reach disinfective action, as relevant " chlorine dioxide space disinfection device " (CN200420029695.8), " the chlorine dioxide gasification device that is used for the central air-conditioning gas sterilizing system " (CN200320111238.9), " sterilization detoxifcation air cleaner " report of patent such as (CN03131632.8), these equipment all need utilize mechanical external force, take up room, and must shut down by timing start-up, also to regularly change the pharmacy product, operate very loaded down with trivial details.Other has a kind of chlorine dioxide slow-release agent, can slowly discharge chlorine dioxide constantly, because chlorine dioxide is heavier than air, self decomposes easily, is difficult to be diffused into each corner of the interior space under the effect that does not have external force.Air after their sterilizations does not have pleasant smell, is difficult for being accepted by people.
Summary of the invention
Technical problem to be solved by this invention is to overcome the defective of prior art and a kind of aromatic chlorinedioxide air-antiseptic table and preparation method are provided, adopt the chlorine dioxide air disinfectant tablet of this method manufacturing to have efficiently, sterilizing, deodorizing, can eliminate the effect of indoor decoration pollution.
The technical scheme that addresses the above problem is:
A kind of aromatic chlorinedioxide air-antiseptic table, it is made up of two kinds of tablets of A, B, and the A sheet is a chlorine dioxide generation sheet, and the B sheet is a chlorine dioxide stripping sheet, and each tablet is made by the raw material of following weight portion:
The A tablet:
Chlorine dioxide matrix 1～8, covering 1～10, binder 1～5, lubricant releasing agent 1～8, acidic materials 60～95;
The B tablet:
Blowing agent 60～95, binder 1～5, lubricant releasing agent 1～10, solid irreducibility spices powder 0.5～5;
Described chlorine dioxide matrix is sodium chlorite, potassium chlorite, barium chlorite or its mixture; Described covering is anhydrous calcium chloride, anhydrous magnesium chloride, anhydrous sodium sulfate, anhydrous magnesium sulfate or its mixture; Described binder is microcrystalline cellulose, polyvinylpyrrolidone, pregelatinized starch or hydroxypropyl cellulose; Described lubricant releasing agent is sodium chloride or dolomol; Described acidic materials are citric acid, tartaric acid, oxalic acid, boric acid, niter cake or its mixture; Described blowing agent is sodium carbonate, sodium bicarbonate, magnesium carbonate, magnesium bicarbonate or its mixture; Described solid irreducibility spices powder is muskone, fragrant wingceltis Moschus, rose powder, benzoin resin or its mixture.
Above-mentioned aromatic chlorinedioxide air-antiseptic table, described A, B two tablets are made by the raw material of following weight portion:
The A tablet:
Chlorine dioxide matrix 3～6, covering 3～6, binder 2～3, lubricant releasing agent 2～5, acidic materials 75～85;
The B tablet:
Blowing agent 65～75, binder 2～3, lubricant releasing agent 2～8, solid irreducibility spices powder 1～3.
Above-mentioned aromatic chlorinedioxide air-antiseptic table, described A, B two tablets are made by the raw material of following weight portion:
The A tablet:
Sodium chlorite 5, anhydrous magnesium chloride 4, polyvinylpyrrolidone 3, sodium chloride 3, niter cake 85;
The B tablet:
Sodium bicarbonate 69, polyvinylpyrrolidone 3, sodium chloride 6, fragrant wingceltis Moschus 2.
A kind of preparation method of aromatic chlorinedioxide air-antiseptic table, it carries out according to following steps:
Preparation A sheet:
A, 60 purpose chlorine dioxide matrix, 1～8 weight portion and 120 purpose coverings, 1～10 weight portion are mixed;
B, add 80 order binders, 1～5 weight portion, 80 order lubricant releasing agents, 1～8 weight portion, 60 order acidic materials, 60～95 weight portions in said mixture, mix, above-mentioned moisture content of material is not more than 0.5%;
C, above-mentioned pulvis is pressed into tablet, packing, humidity is controlled less than 35%R.H., pressure 3.2T/cm
2
Preparation B sheet:
A, 80 purpose blowing agents, 60～95 weight portions, 80 purpose binders, 1～5 weight portion, 80 purpose lubricant releasing agents, 1～10 weight portion and 80 purpose solid irreducibility spices powder, 0.5～5 weight portion are mixed, above-mentioned moisture content of material is not more than 0.5%;
B, above-mentioned pulvis is pressed into tablet, packing, humidity is controlled less than 35%R.H., pressure 3.8T/cm
2
A kind of aromatic chlorinedioxide air-antiseptic table, it also can adopt the unary form tablet form, and tablet is made by the raw material of following weight portion:
Chlorine dioxide matrix 0.5～4, covering 0.5～5, binder 1～5, lubricant releasing agent 1～8, acidic materials 30～55, blowing agent 20～45, solid irreducibility spices powder 0.5～2.5, chlorinated product 0.5～3;
Described chlorine dioxide matrix is sodium chlorite, potassium chlorite, barium chlorite or its mixture; Described covering is anhydrous calcium chloride, anhydrous magnesium chloride, anhydrous sodium sulfate, anhydrous magnesium sulfate or its mixture; Described binder is microcrystalline cellulose, polyvinylpyrrolidone, pregelatinized starch or hydroxypropyl cellulose; Described lubricant releasing agent is sodium chloride or dolomol; Described acidic materials are citric acid, tartaric acid, oxalic acid, boric acid, niter cake or its mixture; Described blowing agent is sodium carbonate, sodium bicarbonate, magnesium carbonate, magnesium bicarbonate or its mixture; Described solid irreducibility spices powder is muskone, fragrant wingceltis Moschus, rose powder, benzoin resin or its mixture; Described chlorinated product is DCCNa, DCCA, TCCA (Trichloroisocyanuric acid), calcium hypochlorite, lithium hypochlorite etc.
Above-mentioned aromatic chlorinedioxide air-antiseptic table, described tablet is made by the raw material of following weight portion:
Chlorine dioxide matrix 1～3, covering 1～3, binder 2～3, lubricant releasing agent 2～5, acidic materials 35～50, blowing agent 30～45, solid irreducibility spices powder 0.5～1.5, chlorinated product 2～3.
Above-mentioned aromatic chlorinedioxide air-antiseptic table, described tablet is made by the raw material of following weight portion:
Sodium chlorite 2.5, anhydrous magnesium chloride 2.5, polyvinylpyrrolidone 3, sodium chloride 3, niter cake 47, sodium bicarbonate 38, fragrant wingceltis Moschus 1, DCCNa 3.
A kind of preparation method of aromatic chlorinedioxide air-antiseptic table, it carries out according to following steps:
A, 60 purpose chlorine dioxide matrix, 0.5～4 weight portion and 120 purpose coverings, 0.5～5 weight portion are mixed;
B, add 80 purpose binders, 1～5 weight portion, 80 purpose lubricant releasing agents, 1～8 weight portion, 60 purpose acidic materials, 30～55 weight portions, 60 purpose blowing agents, 20～45 weight portions, 80 purpose solid irreducibility spices powder, 0.5～2.5 weight portion, 80 purpose chlorinated products, 0.5～3 weight portion mix in said mixture, above-mentioned moisture content of material is not more than 0.5%;
C, above-mentioned pulvis is pressed into tablet, packing, humidity is controlled less than 35%R.H., pressure 3.5T/cm
2
The present invention compared with prior art has following remarkable advantage: 1, cheap, easy to use, safe and effective; 2, simple to operate, do not take up room, save power; 3, make the chlorine dioxide diffusion evenly, can reach each corner in space, whole space is carried out disinfection; 4, sterilization back air odor fragrance.
Embodiment
Theoretical foundation of the present invention is such:
Chlorine dioxide matrix (chlorite) reacts in acidic aqueous solution (pH＜1) and produces active chlorine dioxide, and its reaction equation is:
5ClO
2 -+4H
+→4ClO
2+Cl
-+2H
2O
If have chlorinated product in the solution, chlorine dioxide matrix (chlorite) in acidic aqueous solution directly with the chlorinated product active chlorine dioxide of generation that reacts, its reaction equation is:
2ClO
2 -+H
++HClO→2ClO
2+Cl
-+H
2O
The active aqueous solution of chlorine dioxide of the water-soluble formation of the chlorine dioxide that generates in the solution, in solution, add a large amount of blowing agent (carbonate or bicarbonate) and solid irreducibility powder perfume again, blowing agent and acid reaction generate a large amount of carbon dioxides, and its reaction equation is:
CO
3 2-+ 2H
+→ H
2O+CO
2↑ or HCO
3 -+ H
+→ H
2O+CO
2↑
A large amount of carbon dioxides that generate come out the fragrance stripping of active chlorine dioxide in the solution and spices, are diffused in the room air, reach sterilizing and purifying to air, the purpose of fresh air.
Specific implementation method is:
Earlier a certain amount of chlorine dioxide matrix (chlorite) is coated with covering, add then after binder, lubricant releasing agent and a large amount of acidic materials (solid acid or acid salt) mix, under certain pressure, be pressed into tablet, claim the A tablet.
After again certain amount of foaming agent (carbonate or bicarbonate), solid irreducibility powder perfume, binder and lubricant releasing agent being mixed, be pressed into tablet under the certain pressure, claim the B tablet.
During use, in plastic containers, add entry, the water yield is 5～10 times of tablet quality, earlier the A tablet is put into water, the A tablet will dissolve rapidly, it is soluble in water that reaction generates chlorine dioxide, excessive acidic materials also can water-soluble formation strongly acidic solution, treat the A tablet dissolved, after having reacted, the B tablet is put into water, blowing agent will with solution reaction, constantly discharge carbonic acid gas till blowing agent has reacted, because the preparation pressure of B tablet is bigger, dissolving, reaction time is longer, the whole strippings of active chlorine dioxide in the solution can be gone out and enter in the room air, the smell of spices also enters room air in stripping, reach the sterilizing and purifying air, the purpose of fresh air.
The present invention can be made into the monobasic tablet form.Earlier a certain amount of chlorine dioxide matrix (chlorite) is coated with covering, add then after chlorinated product, binder, lubricant releasing agent, solid irreducibility powder perfume, blowing agent and a large amount of acidic materials (solid acid or acid salt) mix, under certain pressure, be pressed into tablet.Using method is with two yuan of tablets.Two yuan of tablets and monobasic tablet relatively, two yuan of tablet active principle content are higher, conversion ratio is higher by 10% than monobasic tablet; But the monobasic tablet uses more simple and convenient.
Several embodiment below are provided, and wherein, embodiment 1～5 is two tablet forms, and embodiment 6～10 is a tablet form:
Embodiment 1:
Preparation A sheet: 60 purpose chlorine dioxide matrix 1kg and 120 purpose covering 1kg are mixed; Add 80 order binder 1kg, 80 order lubricant releasing agent 1kg, 60 order acidic materials 60kg in said mixture, mix, above-mentioned material is dried material, and moisture is not more than 0.5%; Above-mentioned pulvis is pressed into tablet, packing, humidity is controlled less than 35%R.H., pressure 3.2T/cm
2
Preparation B sheet: 80 purpose blowing agent 60kg, 80 purpose binder 1kg, 80 purpose lubricant releasing agent 1kg and 80 purpose solid irreducibility spices powder 0.5kg mix, and above-mentioned material is dried material, and moisture is not more than 0.5%; Above-mentioned pulvis is pressed into tablet, packing, humidity is controlled less than 35%R.H., pressure 3.8T/cm
2
Embodiment 2:
Sheet A tablet needed raw material takes place in preparation: chlorine dioxide matrix 8kg, covering 10kg, binder 5kg, lubricant releasing agent 8kg, acidic materials 95kg;
Preparation stripping sheet B tablet needed raw material: blowing agent 95kg, binder 5kg, lubricant releasing agent 10kg, solid irreducibility spices powder 5kg,
Embodiment 3:
Sheet A tablet needed raw material takes place in preparation: chlorine dioxide matrix 3kg, covering 3kg, binder 2kg, lubricant releasing agent 2kg, acidic materials 75kg.
Preparation stripping sheet B tablet needed raw material: blowing agent 65kg, binder 2kg, lubricant releasing agent 2kg, solid irreducibility spices powder 1kg.
Embodiment 4:
Sheet A tablet needed raw material takes place in preparation: chlorine dioxide matrix 6kg, covering 6kg, binder 3kg, lubricant releasing agent 5kg, acidic materials 85kg.
Preparation stripping sheet B tablet needed raw material: blowing agent 75kg, binder 3kg, lubricant releasing agent 8kg, solid irreducibility spices powder 3kg.
Embodiment 5:
Sheet A tablet needed raw material takes place in preparation: chlorine dioxide matrix 5kg, covering 4kg, binder 3kg, lubricant releasing agent 3kg, acidic materials 85kg.
Preparation stripping sheet B tablet needed raw material: blowing agent 69kg, binder 3kg, lubricant releasing agent 6kg, solid irreducibility spices powder 2kg.
The preparation process of embodiment 2～5 and technology controlling and process are with embodiment 1.
Embodiment 6:
60 purpose chlorine dioxide matrix 2.5kg and 120 purpose covering 2.5kg are mixed; In said mixture, add 80 purpose binder 3kg, 80 purpose lubricant releasing agent 3kg, 60 purpose acidic materials 47kg, 60 purpose blowing agent 38kg, 80 purpose solid irreducibility spices powder 1kg, 80 purpose chlorinated product 3kg, mix, above-mentioned moisture content of material is not more than 0.5%; Above-mentioned pulvis is pressed into tablet, and promptly the monobasic aromatic chlorinedioxide air-antiseptic table is packed, and humidity is controlled less than 35%R.H., pressure 3.5T/cm
2
Embodiment 7:
Preparation monobasic aromatic chlorinedioxide air-antiseptic table needed raw material: chlorine dioxide matrix 0.5kg, covering 0.5kg, binder 1kg, lubricant releasing agent 1kg, acidic materials 30kg, blowing agent 20kg, solid irreducibility spices powder 0.5kg, chlorinated product 0.5kg.
Embodiment 8:
Preparation monobasic aromatic chlorinedioxide air-antiseptic table needed raw material: chlorine dioxide matrix 4kg, covering 5kg, binder 5kg, lubricant releasing agent 8kg, acidic materials 55kg, blowing agent 45kg, solid irreducibility spices powder 2.5kg, chlorinated product 3kg.
Embodiment 9:
Preparation monobasic aromatic chlorinedioxide air-antiseptic table needed raw material: chlorine dioxide matrix 4kg, covering 4.5kg, binder 3.5kg, lubricant releasing agent 3kg, acidic materials 40kg, blowing agent 35kg, solid irreducibility spices powder 1.5kg, chlorinated product 2kg.
Embodiment 10:
Preparation monobasic aromatic chlorinedioxide air-antiseptic table needed raw material: chlorine dioxide matrix 3kg, covering 3.5kg, binder 2.5kg, lubricant releasing agent 3kg, acidic materials 35kg, blowing agent 30kg, solid irreducibility spices powder 2.5kg, chlorinated product 3kg.
The preparation process of embodiment 7～10 and technology controlling and process are with embodiment 6.
The tablet weight for preparing among each embodiment is 1.2～1.5 gram/sheets, and the consumption during sterilization is can killing effect different and adjust, and two pairings of A, B are used.
Claims (4)
1. an aromatic chlorinedioxide air-antiseptic table is characterized in that, it is made up of two kinds of tablets of A, B, and the A sheet is a chlorine dioxide generation sheet, and the B sheet is a chlorine dioxide stripping sheet, and each tablet is made by the raw material of following weight portion:
The A tablet:
Chlorine dioxide matrix 1～8, covering 1～10, binder 1～5, lubricant releasing agent 1～8, acidic materials 60～95;
The B tablet:
Blowing agent 60～95, binder 1～5, lubricant releasing agent 1～10, solid irreducibility spices powder 0.5～5;
Described chlorine dioxide matrix is sodium chlorite, potassium chlorite, barium chlorite or its mixture; Described covering is anhydrous calcium chloride, anhydrous magnesium chloride, anhydrous sodium sulfate, anhydrous magnesium sulfate or its mixture; Described binder is microcrystalline cellulose, polyvinylpyrrolidone, pregelatinized starch or hydroxypropyl cellulose; Described lubricant releasing agent is sodium chloride or dolomol; Described acidic materials are citric acid, tartaric acid, oxalic acid, boric acid, niter cake or its mixture; Described blowing agent is sodium carbonate, sodium bicarbonate, magnesium carbonate, magnesium bicarbonate or its mixture; Described solid irreducibility spices powder is muskone, fragrant wingceltis Moschus, rose powder, benzoin resin or its mixture.
2. aromatic chlorinedioxide air-antiseptic table according to claim 1 is characterized in that, described A, B two tablets are made by the raw material of following weight portion:
The A tablet:
Chlorine dioxide matrix 3～6, covering 3～6, binder 2～3, lubricant releasing agent 2～5, acidic materials 75～85;
The B tablet:
Blowing agent 65～75, binder 2～3, lubricant releasing agent 2～8, solid irreducibility spices powder 1～3.
3. aromatic chlorinedioxide air-antiseptic table according to claim 1 is characterized in that, described A, B two tablets are made by the raw material of following weight portion:
The A tablet:
Sodium chlorite 5, anhydrous magnesium chloride 4, polyvinylpyrrolidone 3, sodium chloride 3, niter cake 85;
The B tablet:
Sodium bicarbonate 69, polyvinylpyrrolidone 3, sodium chloride 6, fragrant wingceltis Moschus 2.
4. one kind as claim 1,2 or 3 described aromatic chlorinedioxide air-antiseptic table preparation methods, it is characterized in that it carries out according to following steps:
Preparation A sheet:
A, 60 purpose chlorine dioxide matrix and 120 purpose coverings are mixed by prescription;
B, add 80 order binders, 80 order lubricant releasing agents, 60 order acidic materials in said mixture, mix, above-mentioned moisture content of material is not more than 0.5%;
C, above-mentioned pulvis is pressed into tablet, packing, humidity is controlled less than 35%R.H., pressure 3.2T/cm
2
Preparation B sheet:
A, 80 purpose blowing agents, 80 purpose binders, 80 purpose lubricant releasing agents and 80 purpose solid irreducibility spices powder are even, above-mentioned moisture content of material is not more than 0.5%;
B, above-mentioned pulvis is pressed into tablet, packing, humidity is controlled less than 35%R.H., pressure 3.8T/cm
2
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100621473A CN100534305C (en) | 2007-06-14 | 2007-06-14 | Aromatic chlorine dioxide air-antiseptic table and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100621473A CN100534305C (en) | 2007-06-14 | 2007-06-14 | Aromatic chlorine dioxide air-antiseptic table and its production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101073319A CN101073319A (en) | 2007-11-21 |
| CN100534305C true CN100534305C (en) | 2009-09-02 |
Family
ID=38974724
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100621473A Expired - Fee Related CN100534305C (en) | 2007-06-14 | 2007-06-14 | Aromatic chlorine dioxide air-antiseptic table and its production |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100534305C (en) |
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| CN102379309B (en) * | 2011-07-27 | 2013-05-22 | 中北大学 | Binary-packaged reactive chlorine dioxide tablet and preparation method thereof |
| CN102687728A (en) * | 2012-06-07 | 2012-09-26 | 安徽省黄淮兽药有限公司 | Chlorine dioxide tablet disinfectant and preparation method of chlorine dioxide tablet disinfectant |
| CN103858930A (en) * | 2012-12-16 | 2014-06-18 | 王宝燕 | Medical air disinfection tablet |
| TWI605759B (en) * | 2013-03-29 | 2017-11-21 | 大阪曹達股份有限公司 | Tablet for preparing chlorine dioxide solution |
| US20140308371A1 (en) * | 2013-04-10 | 2014-10-16 | Axiall Ohio, Inc. | Acid Tablet Composition |
| CN104026147A (en) * | 2013-08-29 | 2014-09-10 | 四川省龙天源环保设备制造有限公司 | Soil amendment having disinfection and sterilization effect and application method thereof |
| CN105165891A (en) * | 2015-09-22 | 2015-12-23 | 上海普吉生物科技有限公司 | Chlorine dioxide tablet disinfector and preparing method thereof |
| US10400198B2 (en) | 2016-08-25 | 2019-09-03 | Eagle Us 2 Llc | Method of sanitizing a surface |
| CN106719796A (en) * | 2016-11-19 | 2017-05-31 | 湖南云康共享生物环保有限公司 | A kind of air disinfection sanitizer |
| CN108157365A (en) * | 2017-12-07 | 2018-06-15 | 成都顺发消洗科技有限公司 | A kind of air purifying and sterilizing piece |
| CN108786410A (en) * | 2018-06-12 | 2018-11-13 | 御林军生物科技（深圳）有限公司 | A kind of preparation method and applications of slow released ClO 2 |
| CN108719321A (en) * | 2018-08-06 | 2018-11-02 | 山东华实药业有限公司 | A kind of stability disinfection tablet and its manufacture craft |
-
2007
- 2007-06-14 CN CNB2007100621473A patent/CN100534305C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN101073319A (en) | 2007-11-21 |
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