CN101617681A - Pesticide composition containing ethiprole - Google Patents
Pesticide composition containing ethiprole Download PDFInfo
- Publication number
- CN101617681A CN101617681A CN200910164500A CN200910164500A CN101617681A CN 101617681 A CN101617681 A CN 101617681A CN 200910164500 A CN200910164500 A CN 200910164500A CN 200910164500 A CN200910164500 A CN 200910164500A CN 101617681 A CN101617681 A CN 101617681A
- Authority
- CN
- China
- Prior art keywords
- mobucin
- active component
- worm nitrile
- ethiprole
- medicine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 33
- 239000000575 pesticide Substances 0.000 title claims abstract description 11
- FNELVJVBIYMIMC-UHFFFAOYSA-N Ethiprole Chemical compound N1=C(C#N)C(S(=O)CC)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl FNELVJVBIYMIMC-UHFFFAOYSA-N 0.000 title abstract description 6
- 239000000375 suspending agent Substances 0.000 claims abstract description 13
- 241001414720 Cicadellidae Species 0.000 claims abstract description 6
- 239000004480 active ingredient Substances 0.000 claims abstract description 6
- 238000009472 formulation Methods 0.000 claims abstract description 5
- 150000002825 nitriles Chemical class 0.000 claims description 39
- 239000000843 powder Substances 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 8
- 241001498622 Cixius wagneri Species 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- 241001466042 Fulgoromorpha Species 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 25
- 239000000306 component Substances 0.000 description 20
- 241000209094 Oryza Species 0.000 description 18
- 235000007164 Oryza sativa Nutrition 0.000 description 18
- 235000009566 rice Nutrition 0.000 description 18
- 239000002270 dispersing agent Substances 0.000 description 15
- 230000000694 effects Effects 0.000 description 10
- 239000002131 composite material Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 230000001988 toxicity Effects 0.000 description 8
- 231100000419 toxicity Toxicity 0.000 description 8
- 239000000080 wetting agent Substances 0.000 description 8
- 239000003153 chemical reaction reagent Substances 0.000 description 7
- 239000000945 filler Substances 0.000 description 7
- 230000003449 preventive effect Effects 0.000 description 7
- 241001556089 Nilaparvata lugens Species 0.000 description 6
- 238000010790 dilution Methods 0.000 description 6
- 239000012895 dilution Substances 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 241000607479 Yersinia pestis Species 0.000 description 5
- 239000013530 defoamer Substances 0.000 description 5
- 230000000361 pesticidal effect Effects 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 3
- 241000176086 Sogatella furcifera Species 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000007884 disintegrant Substances 0.000 description 3
- PKJZYOFPPJHDRW-UHFFFAOYSA-N formaldehyde;sulfuric acid Chemical compound O=C.OS(O)(=O)=O PKJZYOFPPJHDRW-UHFFFAOYSA-N 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 2
- 239000005885 Buprofezin Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 description 2
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 2
- 210000003169 central nervous system Anatomy 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- XUZHLZDRCCUWEV-UHFFFAOYSA-N formaldehyde;methyl naphthalene-1-sulfonate Chemical compound O=C.C1=CC=C2C(S(=O)(=O)OC)=CC=CC2=C1 XUZHLZDRCCUWEV-UHFFFAOYSA-N 0.000 description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 239000005875 Acetamiprid Substances 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 108010062745 Chloride Channels Proteins 0.000 description 1
- 102000011045 Chloride Channels Human genes 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241000086608 Empoasca vitis Species 0.000 description 1
- 244000299507 Gossypium hirsutum Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 244000141359 Malus pumila Species 0.000 description 1
- -1 Negel Chemical compound 0.000 description 1
- 241000819999 Nymphes Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 235000021329 brown rice Nutrition 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 239000000073 carbamate insecticide Substances 0.000 description 1
- JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 description 1
- 230000001055 chewing effect Effects 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 1
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- QBSJMKIUCUGGNG-UHFFFAOYSA-N isoprocarb Chemical compound CNC(=O)OC1=CC=CC=C1C(C)C QBSJMKIUCUGGNG-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000012946 outsourcing Methods 0.000 description 1
- KFSLWBXXFJQRDL-UHFFFAOYSA-N peroxyacetic acid Substances CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a pesticide composition containing ethiprole, which is characterized by taking the ethiprole and mobucin as active ingredients, wherein the weight ratio of the ethiprole to the mobucin is 1:2 to 1:5, a preferable weight ratio of the ethiprole to the mobucin is 1:4 to 1:10, and the active ingredients account for 5-80 percent of a formulation. The pesticide composition can be one or multiple of a wettable pulvis, a suspending agent or an aqueous dispersible granula and can be used for controlling plant hoppers and leafhoppers.
Description
Technical field
The present invention relates to a kind of Pesticidal combination that contains second worm nitrile, its preparation can be used for preventing and treating pest, wherein particularly plant hopper and leafhopper.
Background technology
Second worm nitrile (Ethiprole) is a kind of novel pyrazoles broad spectrum pesticide, mainly disturbs chloride channel by γ-An Jidingsuan (GABA), thereby destroys central nervous system (CNS) normal activity, and insect is caused death.There is not the problem that produces interactivity in the insecticide main with pyrethroid, organic phosphates, carbamates etc., and the multiple chewing type and the sucking pest of various crop all had control efficiency.It is the desirable kind of pest resistance treatment, can be mixed, be used alternatingly with other chemical pesticide.Lasting period is about 14d though this medicine quick-acting is relatively poor.
Mobucin (Isoprocarb) belongs to carbamate insecticide, and its quick-acting is good, but the lasting period is short, and is low to the person poultry toxicity, easily degrades non-residual toxicity at natural world.
Rice hoppers is one of paddy rice three major pests, the main harm paddy rice, and can propagate the paddy rice virus disease, often cause crushing disaster.The Mobucin of conventional pesticide composition such as carbamates and meta-tolyl-N-methylcarbamate (MTMC), carbosulfan etc., control produces little effect separately, the composite kind that existing market is sold has the composite of composite, the pyrrole aphid ketone of composite, the Buprofezin of Imidacloprid and Buprofezin and Mobucin and Acetamiprid, exist consumption big, waste is serious, shortcomings such as control efficiency is undesirable again, special antagonism brown planthopper preventive effect is relatively poor.
Summary of the invention
The purpose of this invention is to provide a kind of Pesticidal combination that contains second worm nitrile.This Pesticidal combination contains two kinds of active components: first active component is a second worm nitrile, and second active component is a Mobucin.Two kinds of mixing active ingredients proportionings are 1: 2 to 1: 15, and preferred proportion is 1: 4 to 1: 10.
The present composition can be processed into formulations such as suspending agent, wetting powder and water dispersible granules, and the active ingredient total content is 5% to 80% in the preparation, and all the other are to allow in the agricultural chemicals to use and the acceptable auxiliary element.
The auxiliary agent that uses in the composition of the present invention comprises that solvent, dispersant, wetting agent, bleeding agent, stabilizing agent, antifreezing agent, thickener, defoamer, adhesive etc. and other are of value to the known substance that active ingredient is stablized and drug effect is brought into play in preparation, all be the various compositions of using or allow use in the pesticidal preparations always, be not particularly limited, concrete composition and consumption are definite by test according to formulation, for example:
Described dispersant, wetting agent, bleeding agent can be sodium lignin sulfonate, calcium lignosulfonate, condensation compound of methyl naphthalene sulfonic acid and formaldehyde sulphate, Negel, naphthalene sulfonic acid-formaldehyde condensation product, draw back powder, lauryl sodium sulfate, glycerine etc.
Described stabilizing agent can be isopropyl alcohol monoethanolamine, epoxychloropropane etc.
Described thickener can be xanthans, aluminium-magnesium silicate, PAA, gum Arabic.
Described defoamer can be a silicone.
Described adhesive can be starch, xanthans, sodium alginate, separately or use with.
Operable filler comprises white carbon, precipitated calcium carbonate, potter's clay, kaolin, diatomite etc. in the composition of the present invention.
Second worm nitrile and Mobucin carry out the composite obvious synergistic effect that has, have long characteristics of quick-acting and lasting period, obviously improved control efficiency, reduced the agricultural chemicals usage amount, simultaneously because the effect characteristics are different with the mechanism of action, having delayed drug-fast generation greatly, is the important medicament of preventing and treating the resistance brown planthopper.
The present composition can be used for crop control plant hopper, leafhopper, aphid, thrips, mirid pentatomids etc. such as paddy rice, wheat, cotton, apple, citrus, and particularly suitable target crop is a paddy rice, and the insect that is particularly suitable for preventing and treating is plant hopper and leafhopper.
Facts have proved, first active component and second active component is composite has significant synergies, suspension of pesticide resistance generation is saved dosage simultaneously to a certain extent, reduces the Rice Production cost, increases peasant income.
Embodiment
Below in conjunction with example content of the present invention is described further.
The biologicall test example:
Go up the generation resistance rice planthopper in order to prevent and treat agricultural, the inventor has carried out mutual composite synergy research with second worm nitrile and Mobucin.It is tested object that rice fulgorid (brown planthopper Nilaparvata lugens) is adopted in test, and concrete grammar is:
The former medicine that test medicine second worm nitrile adopts Bayer crop science company to produce, the former medicine that Mobucin adopts Shandong Huayang Science ﹠. Technology Co., Ltd. to produce.After test method was mixed with mother liquor with reference to " the agricultural industry criteria NY/T1154.11-2008 of the People's Republic of China (PRC) " with former medicinal organic solvent acetone, the soil temperature with 0.1%-80 aqueous solution was by 9 series mass concentration of method configuration of geometric ratio.The examination worm is the rice fulgorid nymph of indoor feeding, physiological status unanimity.Choose the healthy and strong consistent paddy rice seedling in tillering stage of laboratory cultures, grubbed out, clean, be cut into the long band of 10cm root rice stem, the place dries in the air anhydrous to the surface in the cool place, the rice stem is flooded 30s in the medicament that configures, taking-up is dried, and encases root with absorbent cotton and preserves moisture, the outsourcing preservative film, place test tube, every test tube 3 strains.4 repetitions of every processing, and establish the processing that does not contain medicament and do blank.To try worm with pest sucking device and move in the test tube, 15 in every test tube, the mouth of pipe covers with gauze.Examination worm after the processing places temperature (25 ± 1) ℃, relative moisture 60%～80%, and periodicity of illumination is to raise under L: D=(16: 8) the h condition and observe.Carry out statistical analysis with the DPS data processing software, calculate the LC of each medicament
50, estimate the activity of reagent agent to the examination worm with this.
The co-toxicity coefficient of mixture (CTC value) calculates by following formula:
In the formula:
AT1---mixture actual measurement toxicity index;
The LC of S---standard insecticide
50, unit is every liter (mg/l) of milligram;
The LC of M---mixture
50, unit is every liter (mg/l) of milligram;
TTI＝TIA×PA+TIB×PB
In the formula:
The theoretical toxicity index of TTI---mixture;
TIA----A medicament toxicity index;
The percentage composition of PA-----A medicament in mixture, unit are percentage;
TIB----B medicament toxicity index;
The percentage composition of PB-----B medicament in mixture, unit are percentage.
In the formula:
The CTC----co-toxicity coefficient;
AT1---mixture actual measurement toxicity index;
The theoretical toxicity index of TTI---mixture.
Composite dose co-toxicity coefficient (CTC) 〉=120 shows as synergistic effect; CTC≤80 show as antagonism; 80＜CTC＜120 show as summation action.
Measurement result sees the following form 1.
The composite toxicity test result of table 1 second worm nitrile and Mobucin to the paddy rice brown planthopper
| Handle | ??LC 50??(mg/L) | ??AT1 | ??TTI | Co-toxicity coefficient CTC |
| Second worm nitrile | ??15.21 | ??100.00 | ||
| Mobucin | ??85.16 | ??17.86 | ||
| Second worm nitrile: Mobucin=1: 2 | ??19.7 | ??77.21 | ??45.23 | ??170.66 |
| Second worm nitrile: Mobucin=1: 4 | ??20.23 | ??75.19 | ??34.29 | ??219.27 |
| Second worm nitrile: Mobucin=1: 6 | ??21.3 | ??71.4 | ??29.59 | ??241.29 |
| Second worm nitrile: Mobucin=1: 8 | ??22.21 | ??68.48 | ??26.99 | ??253.76 |
| Second worm nitrile: Mobucin=1: 10 | ??24.32 | ??62.54 | ??25.33 | ??246.93 |
| Second worm nitrile: Mobucin=1: 12 | ??32.56 | ??46.71 | ??24.18 | ??193.2 |
| Second worm nitrile: Mobucin=1: 14 | ??36.68 | ??41.47 | ??23.34 | ??177.69 |
| Second worm nitrile: Mobucin=1: 15 | ??40.25 | ??37.79 | ??22.69 | ??166.5 |
As seen from Table 1, second worm nitrile and Mobucin proportioning are 1: 2～1: 15 o'clock, and the co-toxicity coefficient of mixture is more than 160, and especially at 1: 4,1: 6,1: 8,1: 10 o'clock, synergistic effect was quite remarkable, and co-toxicity coefficient is all more than 200.
Example of formulations:
The present invention describes with the following example, but does not limit the present invention.
1, the preparation of suspending agent
By the prescription requirement, be medium with water, active component, dispersant, thickener and defoamer etc. are added in the sand milling still, carry out porphyrize, make suspending agent.
Embodiment 1:9% second worm nitrile Mobucin suspending agent
Second worm nitrile (active component) 3%
Mobucin (active component) 6%
Sodium lignin sulfonate (dispersant) 10%
Draw back powder (dispersant) 2%
Xanthans (thickener) 1%
Silicone (defoamer) 0.5%
Water is supplemented to 100%
This prescription is by 30 milliliters of/mu dilution spraying control paddy rice brown planthoppers, and 48 hours field control effects are 91.5% behind the medicine.This prescription serves as that the contrast reagent spray uses with 10% second worm nitrile suspending agent (40 milliliters/mu) and 20% Mobucin missible oil (80 milliliters/mu), and 48 hours preventive effect is respectively 74.1% and 60.2% behind the medicine.
Embodiment 2:20% second worm nitrile Mobucin suspending agent
Second worm nitrile (active component) 4%
Mobucin (active component) 16%
Naphthalene sulfonic acid-formaldehyde condensation product (dispersant) 10%
Draw back powder (dispersant) 2%
PAA (thickener) 5%
Silicone (defoamer) 0.1%
Water is supplemented to 100%
This prescription is by 25 milliliters of/mu dilution spraying control rice black-tailed leafhoppers, and 72 hours field control effects are 92.4% behind the medicine.This invention serves as that the contrast reagent spray uses with 10% second worm nitrile suspending agent (40 milliliters/mu) and 20% Mobucin missible oil (80 milliliters/mu), and according to using with quadrat method, 48 hours preventive effect is respectively 80.2% and 54.1% behind the medicine.
2, the preparation of wetting powder
Active component, wetting agent, dispersant and filler etc. are fully mixed in the ratio of prescription, after ultrafine crusher is pulverized, promptly get wetting powder.Can convert the suspension that water is diluted to any desired concn.
Embodiment 3:24% second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) wetting powder
Second worm nitrile (active component) 4%
Mobucin (active component) 20%
Dodecyl sodium sulfate (wetting agent) 5%
Condensation compound of methyl naphthalene sulfonic acid and formaldehyde sulphate (dispersant) 10%
White carbon (filler) is supplemented to 100%
This prescription is by 25 gram/mus dilution spraying control paddy rice small brown rice planthopper, and 48 hours field control effects are 95.4% behind the medicine.This prescription serves as that the contrast reagent spray uses with 10% second worm nitrile suspending agent (40 milliliters/mu) and 20% Mobucin missible oil (100 milliliters/mu), and according to using with quadrat method, 48 hours preventive effect is respectively 76.3% and 59.6% behind the medicine.
Embodiment 4:54% second worm nitrile Mobucin wetting powder
Second worm nitrile (active component) 6%
Mobucin (active component) 48%
Dodecyl sodium sulfate (wetting agent) 5%
Condensation compound of methyl naphthalene sulfonic acid and formaldehyde sulphate (dispersant) 10%
Kaolin (filler) is supplemented to 100%
This prescription is by 20 gram/mus dilution spraying control paddy rice white-backed planthopper, and 48 hours field control effects are 95.7% behind the medicine.This invention serves as that the contrast reagent spray uses with 10% second worm nitrile suspending agent (40 milliliters/mu) and 20% Mobucin missible oil (100 milliliters/mu), and according to using with quadrat method, 48 hours preventive effect is respectively 82.3% and 63.3% behind the medicine.
3, the preparation of water dispersible granules
Former medicine active component, dispersant, wetting agent, binding agent, disintegrant, filler are mixed in proportion,, add the water of 15-20% then, make the water dispersible granules product through kneading, granulation, drying, screening through comminution by gas stream.
Embodiment 5:66% second worm nitrile Mobucin water dispersible granules
Second worm nitrile (active component) 6%
Mobucin (active component) 60%
Sodium lignin sulfonate (dispersant) 5%
Methyl naphthalene sulfonate formaldehyde condensate (dispersant) 5%
Lauryl sodium sulfate (wetting agent) 2%
Sodium cellulose glycolate (binding agent) 2%
Aluminium-magnesium silicate (disintegrant) 2%
White carbon (filler) is supplemented to 100%
This prescription is by 20 gram/mus dilution spraying control paddy rice brown planthopper, and 48 hours field control effects are 96.2% behind the medicine.This prescription serves as that the contrast reagent spray uses with 10% second worm nitrile suspending agent (40 milliliters/mu) and 20% Mobucin missible oil (100 milliliters/mu), and 48 hours preventive effect is respectively 75.3% and 54.6% behind the medicine.
Embodiment 6:65% second worm nitrile Mobucin water dispersible granules
Second worm nitrile (active component) 5%
Mobucin (active component) 60%
Sodium lignin sulfonate (dispersant) 2%
Methyl naphthalene sulfonate formaldehyde condensate (dispersant) 2%
Lauryl sodium sulfate (wetting agent) 2%
Sodium alginate (binding agent) 2%
Ammonium sulfate (disintegrant) 3%
Potter's clay (filler) is supplemented to 100%
This prescription is by 20 gram/mus dilution spraying control paddy rice smaller green leaf hopper, and 48 hours field control effects are 95.4% behind the medicine.This prescription is that the object reagent spray uses with 10% second worm nitrile suspending agent (40 milliliters/mu) and 20% Mobucin missible oil (100 milliliters/mu), and 48 hours preventive effect is respectively 81.3% and 52.6% behind the medicine.
Claims (5)
1, a kind of composition pesticide that contains second worm nitrile is characterized in that comprising:
A) first active component is a second worm nitrile;
B) second active component is a Mobucin;
The weight ratio of first active component and second active component is 1: 2～1: 15.
2, a kind of composition pesticide according to claim 1 is characterized in that: first active component and the preferred weight ratio of second active component are 1: 4～1: 10.
3, composition pesticide according to claim 1 and 2, the formulation that it is characterized in that described composition can be one or more in wetting powder, suspending agent or the water-dispersible granules.
4, composition pesticide according to claim 1 and 2 is characterized in that: the quality percentage composition of active ingredient in preparation is between 5%～80%.
5, claim 1 or the 2 described compositions purposes in control plant hopper and leafhopper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910164500A CN101617681A (en) | 2009-08-01 | 2009-08-01 | Pesticide composition containing ethiprole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910164500A CN101617681A (en) | 2009-08-01 | 2009-08-01 | Pesticide composition containing ethiprole |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101617681A true CN101617681A (en) | 2010-01-06 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910164500A Pending CN101617681A (en) | 2009-08-01 | 2009-08-01 | Pesticide composition containing ethiprole |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103229775A (en) * | 2013-05-28 | 2013-08-07 | 上海赫腾精细化工有限公司 | Pesticide mainly used for crops |
| CN103651379A (en) * | 2012-09-04 | 2014-03-26 | 南京华洲药业有限公司 | Synergistic pesticidal composition containing ethiprole and pyridalyl and application thereof |
| CN103651457A (en) * | 2012-09-04 | 2014-03-26 | 南京华洲药业有限公司 | Compound pesticidal composition containing ethiprole and mobucin and application thereof |
-
2009
- 2009-08-01 CN CN200910164500A patent/CN101617681A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651379A (en) * | 2012-09-04 | 2014-03-26 | 南京华洲药业有限公司 | Synergistic pesticidal composition containing ethiprole and pyridalyl and application thereof |
| CN103651457A (en) * | 2012-09-04 | 2014-03-26 | 南京华洲药业有限公司 | Compound pesticidal composition containing ethiprole and mobucin and application thereof |
| CN103229775A (en) * | 2013-05-28 | 2013-08-07 | 上海赫腾精细化工有限公司 | Pesticide mainly used for crops |
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