CN101608078A - A kind of decorative paper water-based gravure printing ink composition - Google Patents
A kind of decorative paper water-based gravure printing ink composition Download PDFInfo
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- CN101608078A CN101608078A CN 200910069857 CN200910069857A CN101608078A CN 101608078 A CN101608078 A CN 101608078A CN 200910069857 CN200910069857 CN 200910069857 CN 200910069857 A CN200910069857 A CN 200910069857A CN 101608078 A CN101608078 A CN 101608078A
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Abstract
The invention provides a kind of decorative paper gravure printing ink composition, component that said composition comprises and parts by weight thereof are: at least a pigment dyestuff of A and/or mineral dye 10-50 part, at least a acrylic resin of B or its solution 10-40 part, at least a wetting agent 0.5-1 of C part, D hydrotrophy material 0-10 part, E additive 0-5 part, F water is mended to 100 parts.The preparation method of said composition is: the parts by weight by said components mix making beating with each component, being ground to particle diameter through ball mill under cooling conditions is 0.5-2um, regulate final pigment concentration with softening water then, separate grinding medium and aqueous color paste obtain ink.
Description
Technical field
The present invention relates to decorative paper intaglio printing dye technology Application Areas, particularly a kind of decorative paper water-based gravure printing ink composition.
Background technology
Global forest reserves scarcity has promoted the mass production of wood-base fibre and particle panel material, and the surface decoration problem has become to solve the task of top priority that wood-based plate replaces solid wood to use.Therefore, the decorative paper production technology has had and has developed rapidly, the sign and the trend of development also occurred in China.This paper is specious, and texture is true to nature, and gloss is soft, and sense of touch is warm, and wear-resisting, resistant, flexible and high resilience is fit to various moulding is for bigger space has been opened up in furniture design, wood-based plate utilization.Because it has finish surface, thereby has simplified the furniture production technique, has improved production efficiency, reduced produce and use in the nuisance volatilization, be a large amount of finishing material that use of upholstery and decorative craft of building, be the ideal substitute of natural veneer.
Along with the raising of living standards of the people, the increase of living space must cause the increase of upholstery material requirement.It is powerful that the development of demand is decorated in present domestic PLASTIC LAMINATED, floor, furniture and indoor and outdoor etc.Especially develop rapidly a large amount of outlets over past ten years.Be used to make the printing ink of starting material-veneer decorative paper use of decorative sheets such as PLASTIC LAMINATED, floor, furniture, require printing ink that good preservation stability is arranged; The printing characteristics of decorative paper are to adopt the mode of intaglio printing painted on decorative paper, and ink should have excellent printability, good sticking power, dried fastness and sharpness; Decorative paper after the printing should have good dipping (unfading in melamine resin) to fit property; Satisfy overlaying condition, have high thermostability (200 ℃) and good anti-ultraviolet, light permanency (7-8 level).But traditional wash has high waterproof, film-forming properties is good, has changed decorative paper high-hydroscopicity and ventilation property, so be not suitable for the printing color of decorative paper.
Domestic, early stage, adopt the printing of textile coating printing paste, be equipped with tackiness agent to increase fastness.Fastness improves, and prints out diatom, pressing plate haftplatte, heat-resisting, sun-proof (weathering resistance) deficiency; In recent years, progress along with synthetic water-base resin, very much progress is arranged in the decorative paper printing, and the requirement of still can not satisfy sharpness, sticking power that decorative paper is printed on printing suitability, printing, soaking on the performances such as melamine-formaldehyde resin adhesive perviousness, pressing plate thermotolerance, uvioresistant and sun-proof differs greatly with the German Hartmann ink of external highest level, the gravure printing ink of Spain's sky fragrant plant ink like product level.
1. the FAQs of printability aspect: dark earlier back is shallow in (1) printing process, and behind the 500-1000m, color shoals; (2) go out in the printing process that cutter line, printing lifts, printing are done the fastness deficiency, the colour reproduction circulation ratio is bad;
2. soak the FAQs of melamine glue: impregnation, the color drift miscible of fading with glue; Impregnation speed car 10-40m.;
3. pressing plate thermotolerance effect: 200 ℃ of variable colors in following 3 minutes, colour-darkening;
4. weathering resistance effect: 4-6 level;
5. sheet material is processed crisp limit.
For a long time, print the main dependence on import ink of high-grade decorative paper and exported product, reduced the competitive power of products export on the mountain, world market.Along with social progress, market requires more and more higher to decorative paper printing class and printing quality, and print product requires decorative pattern meticulous, have ornamental accordingly, the painted aesthetic consciousness that meets people, and durable in use, environmental protection is reliable; Development and exploitation decorative paper dedicated high performance aqueous intaglio printing China ink help improving the quality of China's decorative sheet product, change the situation that China produces the used gravure printing ink dependence on import of high-grade decorative paper.
Summary of the invention
The purpose of this invention is to provide a kind of decorative paper gravure printing ink composition, said composition at printing suitability, sticking power, soak and obviously be better than having now the decorative paper water-based gravure printing China ink on the performances such as melamine-formaldehyde resin adhesive perviousness, pressing plate thermotolerance, uvioresistant and sun-proof, can satisfy the decorating printing requirement.
Particularly, the invention provides a kind of decorative paper gravure printing ink composition, component and parts by weight thereof that said composition comprises are as follows:
At least a pigment dyestuff of A and/or mineral dye 10-50 part
At least a acrylic resin of B or acrylic resin soln 10-40 part
At least a wetting agent 0.5-1 of C part
D hydrotrophy material 0-10 part
E additive 0-5 part
F water is mended to 100 parts
In the above-mentioned composition, pigment dyestuff is a CI. Pigment Yellow 73 18, CI. Pigment Yellow 73 24, CI. Pigment Yellow 73 55, CI. Pigment Yellow 73 62, CI. Pigment Yellow 73 75, CI. pigment yellow 81, CI. pigment yellow 83, CI. Pigment Yellow 73 95, CI. Pigment Yellow 73 97, CI. Pigment Yellow 73 110, CI. pigment Yellow 12 0, CI. pigment yellow 13 8, CI. pigment yellow 13 9, CI. pigment yellow 147, CI. Pigment Yellow 73 150, CI. pigment yellow 154, CI. pigment yellow 17 5, CI. Pigment Yellow 73 180, CI. Pigment Yellow 73 181CI. Pigment Yellow 73 194, CI. pigment orange 34, CI. pigment orange 36, CI. pigment orange, CI. pigment Red 89, CI. pigment red 122, CI. Pigment red 144, CI. pigment red 149, CI. Pigment red 166, CI. Pigment red 168, CI. Pigment red CI. Pigment red 170, CI. Pigment red 171, CI. Pigment red 175, CI. Pigment red 176, CI. Pigment red 177, CI. Pigment red 178, CI. Pigment red 179, CI. Pigment red 185, CI. Pigment red 187, CI. Pigment red 194, CI. Pigment red 202, CI. Pigment red 206, CI. Pigment Red 207, CI. Pigment red 208, CI. Pigment red 254, CI. Pigment red 255, CI. Pigment red 272, CI. pigment violet 19, CI. the blue 15:0 of pigment, CI. the blue 15:1 of pigment, CI. the blue 15:2 of pigment, CI. blue 15:3 of pigment or the blue 15:4 of CI. pigment etc.Mineral dye is the oxide compound of titanium dioxide, iron or carbon black etc.
Wherein at least a acrylic resin of B component or its solution, particularly, wherein acrylic resin can be thermoplastic acrylic resin or thermosetting acrylic resin, preferably, acrylic resin soln is the ammonia soln of acrylic resin.The example of acrylic resin, for example, acrylic resin is water soluble acrylic acid solid resin village minister J678 (market is on sale), Korea S Han Hua water soluble acrylic acid solid resin S20 (market is on sale) etc., and these products join in the composition of the present invention can both solve technical problem of the present invention.Preferred this acrylic resin soln is the ammonia soln of the 20-40 weight % of acrylic resin.
Component C wetting agent is preferably sulfo-succinic acid half ester sodium salt, the tetramethyl alkynediols of fatty alcohol-polyoxyethylene ether, fatty acid alkoxylates.
Component D hydrotrophy material is selected from ethylene glycol, propylene glycol, glycerine, glycol ether, triglycol, polyoxyethylene glycol, ethanol, Virahol, ethylene glycol ethyl ether, one or more in butyl glycol ether, propylene glycol monomethyl ether, the propylene glycol butyl ether;
Component E additive be selected from antisettling agent, sanitas/sterilant, antioxidant, air release agent/or defoamer, filler etc. in one or more.
Antisettling agent, sanitas, antioxidant, air release agent and/or defoamer etc., auxiliary agent commonly used in the dispersible pigment color paste preparation, for example, sanitas is the promise moral
C15 coating sterilant sanitas, sterilant mould inhibitor DC-2011 etc., antioxidant such as Ug-150 antioxidant, defoamer are Dormant oils class, lower alcohols etc., as FEB-100 defoamer etc.
Component F water is preferably distilled water, softening water, also available tap water.
The preparation of above-mentioned ink composition can use conventional blending means to carry out, and just above-mentioned raw materials is mixed, and grinds and has just obtained ink composition.
The preparation of above-mentioned ink composition also can prepare by the following method:
By the parts by weight of said components each component is mixed making beating, being ground to particle diameter through ball mill under cooling conditions is 0.5-2um, regulates final pigment concentration with softening water then, separate grinding medium and aqueous color paste obtain ink.
Particularly; the production method of ink composition be with powder pigment or pigment filter cake in softening water with acrylic resin or its solution and other additive furnishing pasty states; or other suitable device homogenizing; use ball mill or other suitable dispersing apparatus dispersion grinding subsequently; wherein grind quartz silica bead or the Zirconium oxide bead that uses size d=1mm; under cooling, carry out; until reaching required colour intensity; regulate final pigment concentration with softening water, separate grinding medium and aqueous color paste and get ink.
The ink composition that method for preparing obtains is under 25 ℃ temperature condition, and viscosity T4# is 20-30s, and PH is 8-9, and said composition can be mixed the acquisition required color arbitrarily with pigment.
Above-mentioned decorative paper gravure printing ink composition of the present invention has following beneficial effect:
Ink composition of the present invention can print 10 tons of about 100000m and not have colour-change; Do not have in the printing and print out bad phenomenon such as cutter line, lifts; The attachment fastness of composition meets the requirements, the colour reproduction favorable reproducibility.Have good effect aspect the melamine glue soaking, as impregnation do not fade, no color drift; Impregnation speed is applicable to that 10-60m impregnation speed is good.And the pressing plate thermotolerance reaches 200 ℃ of following 3 minutes nondiscolorations, colors and increases gorgeous.Weathering resistance reaches 7 grades.The not crisp limit of sheet material processing.
Embodiment
The following examples just to the explanation and the explanation of technical scheme of the present invention, do not form any restriction to protection scope of the present invention.Raw material among the following embodiment all can be bought from the market and obtain, and can obtain the purchase information of following arbitrary raw material by the internet.
Embodiment 1
The raw material that takes by weighing following weight mixes making beating, and being ground to particle diameter through ball mill under cooling conditions is 0.5um, regulates pigment concentration with softening water then, separate grinding medium and aqueous color paste obtain ink.
This ink composition is bright-colored, tinctorial yield is high, stable storing, non-foam.Implement printing and have excellent printability, good fastness, impregnation permeates.
Embodiment 2
The raw material that takes by weighing following weight mixes making beating, and being ground to particle diameter through ball mill under cooling conditions is 0.5um, regulates pigment concentration with softening water then, separate grinding medium and aqueous color paste obtain ink.
| A, CI. pigment Blue 15: 3 | ??25Kg |
| The 20 weight % ammonia solns of B, Korea S Han Hua water soluble acrylic acid solid resin S20 | ??30Kg |
| C, fatty alcohol-polyoxyethylene ether | ??0.5Kg |
| E, sterilant mould inhibitor DC-2011 | ??0.2Kg |
| F, water | ??44.3Kg |
This ink composition is implemented printing back impregnation and is permeated.The printing rate of drying is fast, and the impregnation seepage velocity is fast.
Embodiment 3
The raw material that takes by weighing following weight mixes making beating, and being ground to particle diameter through ball mill under cooling conditions is 0.5um, regulates pigment concentration with softening water then, separate grinding medium and aqueous color paste obtain ink.
| A, carbon black | ??20Kg |
| The 40 weight % ammonia solns of B, water soluble acrylic acid solid resin village minister J678 | ??35Kg |
| C, tetramethyl alkynediols | ??0.7Kg |
| D, butyl glycol ether | ??4.5Kg |
| F, water | ??39.8Kg |
This ink composition has tinctorial yield, the non-foam of embodiment 1, implements printing and has excellent printability, good fastness, and impregnation permeates.
But arbitrary proportion mixes the adjustment required color between the color of above-mentioned ink composition of the present invention, and dispersible pigment color paste can be with removing light dilution agent to any concentration, and it is convenient to use.
Ink composition of the present invention is described by specific embodiment.Those skilled in the art can use for reference links such as content appropriate change raw material of the present invention, processing condition and realize corresponding other purpose, its relevant change does not all break away from content of the present invention, all similar replacements and change will become apparent to those skilled in the art that and all be regarded as comprising within the scope of the present invention.
Claims (10)
1, a kind of decorative paper gravure printing ink composition, component and parts by weight thereof that said composition comprises are as follows:
At least a pigment dyestuff of A and/or mineral dye 10-50 part
At least a acrylic resin of B or acrylic resin soln 10-40 part
At least a wetting agent 0.5-1 of C part
D hydrotrophy material 0-10 part
E additive 0-5 part
F water is mended to 100 parts.
2, composition according to claim 1, wherein pigment dyestuff is a CI. Pigment Yellow 73 18, CI. Pigment Yellow 73 24, CI. Pigment Yellow 73 55, CI. Pigment Yellow 73 62, CI. Pigment Yellow 73 75, CI. pigment yellow 81, CI. pigment yellow 83, CI. Pigment Yellow 73 95, CI. Pigment Yellow 73 97, CI. Pigment Yellow 73 110, CI. pigment Yellow 12 0, CI. pigment yellow 13 8, CI. pigment yellow 13 9, CI. pigment yellow 147, CI. Pigment Yellow 73 150, CI. pigment yellow 154, CI. pigment yellow 17 5, CI. Pigment Yellow 73 180, CI. Pigment Yellow 73 181CI. Pigment Yellow 73 194, CI. pigment orange 34, CI. pigment orange 36, CI. pigment orange, CI. pigment Red 89, CI. pigment red 122, CI. Pigment red 144, CI. pigment red 149, CI. Pigment red 166, CI. Pigment red 168, CI. Pigment red CI. Pigment red 170, CI. Pigment red 171, CI. Pigment red 175, CI. Pigment red 176, CI. Pigment red 177, CI. Pigment red 178, CI. Pigment red 179, CI. Pigment red 185, CI. Pigment red 187, CI. Pigment red 194, CI. Pigment red 202, CI. Pigment red 206, CI. Pigment Red 207, CI. Pigment red 208, CI. Pigment red 254, CI. Pigment red 255, CI. Pigment red 272, CI. pigment violet 19, CI. the blue 15:0 of pigment, CI. the blue 15:1 of pigment, CI. the blue 15:2 of pigment, CI. the blue 15:4 of blue 15:3 of pigment or CI. pigment, mineral dye is a titanium dioxide, the oxide compound of iron or carbon black.
3, composition according to claim 1 and 2, wherein acrylic resin is thermoplastic acrylic resin or thermosetting acrylic resin.
4, according to each described composition of claim 1-3, wherein acrylic resin soln be acrylic resin ammonia soln.
5, according to each described composition of claim 1-4, wherein acrylic resin is water soluble acrylic acid solid resin village minister J678 or Korea S Han Hua water soluble acrylic acid solid resin S20.
6, according to each described composition of claim 1-5, wherein acrylic resin soln is the ammonia soln of the 20-40 weight % of acrylic resin.
7, according to each described composition of claim 1-6, wherein component C wetting agent is the sulfo-succinic acid half ester sodium salt or the tetramethyl alkynediols of fatty alcohol-polyoxyethylene ether, fatty acid alkoxylates.
8, according to each described composition of claim 1-7, wherein component D hydrotrophy material is selected from ethylene glycol, propylene glycol, glycerine, glycol ether, triglycol, polyoxyethylene glycol, ethanol, Virahol, ethylene glycol ethyl ether, one or more in butyl glycol ether, propylene glycol monomethyl ether, the propylene glycol butyl ether;
9, according to each described composition of claim 1-8, wherein component E additive is selected from antisettling agent, sanitas, antioxidant, air release agent and/or defoamer, one or more in the filler.
10, according to each described composition of claim 1-8, the preparation of said composition prepares by the following method:
By the parts by weight of said components each component is mixed making beating, being ground to particle diameter through ball mill under cooling conditions is 0.5-2um, regulates final pigment concentration with softening water then, separate grinding medium and aqueous color paste obtain ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910069857 CN101608078B (en) | 2009-07-23 | 2009-07-23 | Decorative paper water-based gravure printing ink composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910069857 CN101608078B (en) | 2009-07-23 | 2009-07-23 | Decorative paper water-based gravure printing ink composition |
Publications (2)
| Publication Number | Publication Date |
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| CN101608078A true CN101608078A (en) | 2009-12-23 |
| CN101608078B CN101608078B (en) | 2012-09-19 |
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| CN 200910069857 Expired - Fee Related CN101608078B (en) | 2009-07-23 | 2009-07-23 | Decorative paper water-based gravure printing ink composition |
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Cited By (9)
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| CN101955709A (en) * | 2010-09-17 | 2011-01-26 | 天津市海山化工科技开发有限公司 | Water-containing coating paste and composition |
| CN102268840A (en) * | 2011-07-15 | 2011-12-07 | 浙江帝龙新材料股份有限公司 | Decorative paper used for floor or furniture |
| CN102936450A (en) * | 2012-11-21 | 2013-02-20 | 广州酷漫居动漫科技有限公司 | UV (ultraviolet) ink bridging agent and application thereof |
| CN103146257A (en) * | 2013-03-20 | 2013-06-12 | 哈尔滨绿科科技有限公司 | Special water-based ink for printing polyvinyl chloride (PVC) foam wallpaper and preparation method thereof |
| CN104263074A (en) * | 2014-10-13 | 2015-01-07 | 北京印刷学院 | Pure water-based white gravure ink for tipping paper and preparation method of white gravure ink |
| CN104877434A (en) * | 2015-06-02 | 2015-09-02 | 青岛伟健金属饰品有限公司 | Fading-free ink |
| CN106905764A (en) * | 2017-04-20 | 2017-06-30 | 孔硕硕 | A kind of preparation method of Neutral writing ink and obtained ink |
| CN110294963A (en) * | 2019-08-12 | 2019-10-01 | 厦门欧化实业有限公司 | Aqueous UV exempts from processing table printing ink and its processing method, process equipment |
| CN115449258A (en) * | 2022-09-16 | 2022-12-09 | 昆山大世界油墨涂料有限公司 | Decorative paper ink with high color spreading effect and preparation method thereof |
Family Cites Families (2)
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| CN101275043B (en) * | 2007-03-28 | 2012-03-14 | 樊官保 | Environment-friendly water-soluble plate engraving ink |
| CN101381535A (en) * | 2008-10-27 | 2009-03-11 | 浙江盛龙装饰材料有限公司 | Aqueous ink special for decorating paper and production method thereof |
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2009
- 2009-07-23 CN CN 200910069857 patent/CN101608078B/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101955709B (en) * | 2010-09-17 | 2016-01-20 | 天津市海山化工科技开发有限公司 | A kind of water-containing coating paste and composition |
| CN101955709A (en) * | 2010-09-17 | 2011-01-26 | 天津市海山化工科技开发有限公司 | Water-containing coating paste and composition |
| CN102268840A (en) * | 2011-07-15 | 2011-12-07 | 浙江帝龙新材料股份有限公司 | Decorative paper used for floor or furniture |
| CN102936450A (en) * | 2012-11-21 | 2013-02-20 | 广州酷漫居动漫科技有限公司 | UV (ultraviolet) ink bridging agent and application thereof |
| CN102936450B (en) * | 2012-11-21 | 2014-10-29 | 广州酷漫居动漫科技有限公司 | UV (ultraviolet) ink bridging agent and application thereof |
| CN103146257A (en) * | 2013-03-20 | 2013-06-12 | 哈尔滨绿科科技有限公司 | Special water-based ink for printing polyvinyl chloride (PVC) foam wallpaper and preparation method thereof |
| CN103146257B (en) * | 2013-03-20 | 2014-08-27 | 哈尔滨绿科科技有限公司 | Special water-based ink for printing polyvinyl chloride (PVC) foam wallpaper and preparation method thereof |
| CN104263074A (en) * | 2014-10-13 | 2015-01-07 | 北京印刷学院 | Pure water-based white gravure ink for tipping paper and preparation method of white gravure ink |
| CN104263074B (en) * | 2014-10-13 | 2016-08-17 | 北京印刷学院 | Pure water type cork paper gravure white ink and preparation method thereof |
| CN104877434A (en) * | 2015-06-02 | 2015-09-02 | 青岛伟健金属饰品有限公司 | Fading-free ink |
| CN106905764A (en) * | 2017-04-20 | 2017-06-30 | 孔硕硕 | A kind of preparation method of Neutral writing ink and obtained ink |
| CN110294963A (en) * | 2019-08-12 | 2019-10-01 | 厦门欧化实业有限公司 | Aqueous UV exempts from processing table printing ink and its processing method, process equipment |
| CN115449258A (en) * | 2022-09-16 | 2022-12-09 | 昆山大世界油墨涂料有限公司 | Decorative paper ink with high color spreading effect and preparation method thereof |
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| CN101608078B (en) | 2012-09-19 |
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