CN103146257A - Special water-based ink for printing polyvinyl chloride (PVC) foam wallpaper and preparation method thereof - Google Patents
Special water-based ink for printing polyvinyl chloride (PVC) foam wallpaper and preparation method thereof Download PDFInfo
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Abstract
The invention discloses special water-based ink for printing polyvinyl chloride (PVC) foam wallpaper. The special water-based ink comprises thermosetting acrylic resin, thermoplastic acrylic resin, pigment, defoamer, surfactant, cosolvent, water-based wax emulsion, wetting dispersant, a water-based thickener, and water. A method for preparing the special water-based ink for printing the PVC foam wallpaper is also provided by the invention. According to the special water-based ink for printing the PVC foam wallpaper, the heavy metal content test indicator and volatile organic compounds (VOC) technical standard completely accord with the national standard; the special water-based ink is wonderful in printing effect; and the heat resistance, the weather fastness, the water tolerance and the oil resistivity are equivalent to those of solvent ink. The water-based ink disclosed by the invention is simple in formula, low in price, good in printed adhesive force, strong in water resistance, and fast to dry. Thus, the water-based ink is especially suitable for package printed matters such as foods, beverage and medicaments.
Description
Technical field
The present invention relates to print the starting material fields, be specially a kind of for PVC foaming wallpaper printing aqueous ink special and preparation method thereof.
Background technology
Along with the raising of people's living standard, also when the river rises the boat goes up for finishing material, and wallpaper decoration is more and more higher in the occupation rate in decoration market, and PVC foaming wallpaper is various with its color, pattern abundant, price is suitable, short construction period, bear dirty, scrubbing resistance.Intensity is high, impact resistance, easy cleaning, not alice, do not take off seam.During replacing, can integral body peel off, do not damage metope, save a large amount of decoration costs again and occupy nearly half the market share, conventional P VC foaming wallpaper printing adopts solvent-borne type wallpaper printing ink, exists printing security low, Transport Safety is low, do not meet environmental requirement, need to install recovery system additional on printing press, greatly increased printing cost etc. shortcoming.Therefore, just proposed wallpaper printing ink is improved to the nontoxic water color ink that does not fire again.
The maximum difference of water color ink and solvent type ink, the solvent that is its use is water rather than organic solvent, obviously reduce the VOC quantity discharged, the energy air conservation, do not affect HUMAN HEALTH, nonflammable, China ink is stable, bright in luster, do not corrode plate, simple to operate, low price, seal postadhesion power is good, water resisting property is strong, and is rapidly dry, therefore be specially adapted to the package printed matters such as food, beverage, medicine, being universally acknowledged environmental printing material, is also present unique printing ink through the approval of U.S. food medicine association in all printing-inks.Therefore water color ink has fabulous market outlook.
Existing water color ink thermotolerance does not often pass a test, and (150～200 ℃ of foaming needs) tend to produce variable color, resin skinning, the phenomenons such as flavescence in foaming process.
Summary of the invention
In order to address the above problem, the first purpose of the present invention is to provide a kind of for PVC foaming wallpaper printing aqueous ink special.
The second purpose of the present invention is to provide a kind of method for preparing described water color ink.
In order to realize purpose of the present invention, technical scheme of the present invention is as follows:
A kind of for PVC foaming wallpaper printing aqueous ink special, it comprises the component of following weight percent:
Preferably, the molecular weight of described thermoplastic acrylic resin is that 5000～6000, pH is 6.9～7.5, and solid content is 35%～45%; The molecular weight of described thermosetting acrylic resin is that 8000～8500, pH is 6.9～7.5, and solid content is 35%～45%.
Preferably, the thermotolerance of described pigment is more than 200 ℃, and weathering resistance is at the pigment more than 7, and it has the average particulate diameter of 10～100nm scope.Described pigment is generally red, Huang, indigo plant, white pigments.For the sun-proof of lily chemical industry red, organic yellow, phthalein is blue or green blue, white titanium dioxide for the Jiang Huagong that jumps.
Preferably, described pigment has the average particulate diameter of 10～40nm scope.
Preferably, described defoamer is polysiloxane-copolyether emulsion.
Preferably, described tensio-active agent is non-ionic type upgrading derivative of fatty acid.
Preferably, described wetting dispersing agent is not for containing the dispersion agent of solvent, amine and ethoxylized nonylphenol.
Preferably, described water-based thickener is the water soluble acrylic acid associative thickener.
Preferably, described solubility promoter is ethanol, ethylene glycol, ethylene glycol monobutyl ether.
Further, the invention provides the described water color ink method of preparation, it comprises the steps:
(1) get the raw materials ready and weighing: with thermosetting acrylic resin, thermoplastic acrylic resin, pigment, defoamer, tensio-active agent, solubility promoter, water-based wax emulsion, wetting dispersing agent, water-based thickener, proportionally weighing is standby one by one for water;
(2) mix and stir: raw material thermosetting acrylic resin, pigment, defoamer, wetting dispersing agent that weighing is got ready, mixing in order feeds intake, the water that first adds total water amount 2/3 feeds intake under 300～400 rev/mins of stirrings of low speed successively, stirs 10～15 minutes;
(3) sand milling disperses: the compound that step (2) is stirred changes sand milling dispersion in sand mill over to, 1/3 water of total water amount is cleaned stirred vessel, and related water adds sand mill, grinds in sand mill 3～4 times, when material particle diameter to be mixed was 150～260nm, grinding distribution was complete;
(4) subsequent disposal: will grind complete compound in container with 300～500 rev/mins of stirrings, in whipping process, add thermoplastic acrylic resin, water-based wax emulsion, tensio-active agent, water-based thickener, solubility promoter to be transferred to appropriate viscosity (being coated with the 4# cup 15～30 seconds), stirred 50～70 minutes;
(5) filter packing.
Preferably, step (5) also comprises the form and aspect of checking product, admittedly contains, fineness, viscosity, qualified rear filtration, packing.
Beneficial effect of the present invention is as follows:
The present invention preparation be used for PVC foaming wallpaper printing aqueous ink special, its heavy metal content test rating and VOC technological standard meet national standard fully; Its printing effect is fabulous, and thermotolerance, weathering resistance, water tolerance and oil-proofness and solvent type ink are suitable.Water-soluble printing ink formula of the present invention is simple, low price, and seal postadhesion power is good, and water resisting property is strong, and is rapidly dry, therefore be specially adapted to the package printed matters such as food, beverage, medicine.
Embodiment
Introduce in detail the present invention below in conjunction with accompanying drawing and embodiment thereof.But protection of the present invention orientation is not limited to following instance, should comprise the full content in claims.
Provided by the invention a kind of for PVC foaming wallpaper printing aqueous ink special, wherein, described thermoplastic acrylic resin (playing the effect of binder), it refers to that high molecular is 5000～6000, its pH is within 6.9～7.5 scopes, and solid content is 35%～45%.Described thermosetting acrylic resin (playing the effect of binder and waterproof), its molecular weight is 8000～8500, and its pH is within 6.9～7.5 scopes, and solid content is 35%～45%.
Preferably, the thermotolerance of described pigment is more than 200 ℃, and weathering resistance is at the pigment more than 7, and it has the average particulate diameter of 10～100nm scope; Preferred, the average particulate diameter of described pigment is 10～40nm.Described pigment is generally red, Huang, indigo plant, white pigments or carbon black.For the sun-proof of lily chemical industry red, organic yellow, phthalein is blue or green blue, white titanium dioxide for the Jiang Huagong that jumps.
Preferably, described defoamer is polysiloxane-copolyether emulsion, and the present invention selects the high foamex842 of enlightening.
Preferably, described tensio-active agent is non-ionic type upgrading derivative of fatty acid, and the present invention selects the high twin4000 of enlightening.
Preferably, described wetting dispersing agent is not for containing the dispersion agent of solvent, amine and ethoxylized nonylphenol, and the present invention selects the high wet505 of enlightening..
Preferably, described water-based thickener is the water soluble acrylic acid associative thickener, and the present invention selects the high Viscoplus3000 of enlightening.
Preferably, described solubility promoter is ethanol, ethylene glycol, ethylene glycol monobutyl ether.
Properties and the effect thereof of the water color ink of the present invention's preparation are as follows:
1, the environmental labelling product authentication techniques require wallpaper HBC23-2004 to require as shown in table 1 to the heavy metal of wallpaper printing ink:
The technological standard of table 1HBC23-2004 to the heavy metal requirement of wallpaper printing ink:
The heavy metal content of this standard-required wallpaper printing ink self must be less than this standard, for this reason, and the elite use wallpaper of the present invention sole pigment, and select auxiliary agent, the resin of heavy metal free content; The water color ink heavy metal content test rating method of inspection of the present invention is by GB GB/T8449-1987, the method for inspection of GB/T8450-1987.As shown in table 2, it meets national standard fully.
The technological standard of the heavy metal of table 2 water color ink of the present invention:
2, the VOC problem of water-based wallpaper printing ink.
The environmental labelling product authentication techniques require wallpaper HBC23-2004 to the VOC of wallpaper printing ink require as shown in table 3:
The technological standard of table 3HBC23-2004 to the VOC requirement of wallpaper printing ink:
| Project | Unit | Index | Index classification |
| Volatile organic compounds | g/L | ≤250 | A |
| Halohydrocarbon (in methylene dichloride) | mg/kg | ≤500 | A |
| The total amount of benzene,toluene,xylene, ethylbenzene | mg/kg | ≤500 | A |
| Methyl alcohol | mg/kg | ≤300 | A |
| Ammonia and compound thereof | g/kg | ≤30 | A |
The VOC content of this standard-required wallpaper printing ink self must be less than this standard, and the present invention does not select any organic solvent and the resin that is mingled with organic solvent, auxiliary agent.The VOC standard test method of water color ink of the present invention is pressed the YC/T207 method of inspection, and as shown in table 4, it is well below national standard.
The technological standard of the VOC content of table 4 water color ink of the present invention:
| Project | Unit | Index | Check numerical value |
| Volatile organic compounds | g/L | ≤250 | 1.1 |
| Halohydrocarbon (in methylene dichloride) | mg/kg | ≤500 | Do not detect |
| The total amount of benzene,toluene,xylene, ethylbenzene | mg/kg | ≤500 | 0.13 |
| Methyl alcohol | mg/kg | ≤300 | 5.6 |
| Ammonia and compound thereof | g/kg | ≤30 | 0.23 |
[0049]3, the problem of water color ink printing effect
All the time, water color ink exists printing effect not as the problem of solvent type ink, this problem is the principal element of restriction water color ink development, the present invention has selected the high ink system of matching, special-purpose wetting dispersing agent, printing effect is fabulous, and is suitable with the solvent type ink printing effect, levelling property, color developing is fabulous.Solve the poor problem of water color ink printing effect, accelerated the development of water color ink.
4, the surface tension problem of water color ink
The main solvent of water color ink is water, the surface tension of water is larger than organic solvent, so surface tension of water color ink large (usually in the 38dyn left and right), make water color ink at paper surface, good adhesive ability be arranged, need printable fabric that larger surface tension (more than 38dyn) is arranged, the surface tension of wallpaper is approximately 7～10; Therefore, must reduce the surface tension of water-based wallpaper printing ink to adapt to printing, the present invention adopts non-ionic type upgrading derivative of fatty acid tensio-active agent, when not reducing printing effect, greatly reduce the surface tension of printing ink, improve printing adaptability, thereby solved the capillary problem of water color ink.
4, the poor problem of water color ink pH value and solubility.
Since consistent, the pH value of common water color ink is between 8.5～9.5, the main aminated compounds that relies on of the pH value of water color ink is kept, the volatilization of amine substance in printing process descends pH value, thereby causes that ink viscosity rises, transitivity is poor, the dry quickening stopped up anilox roll, the scumming fault occurs.Therefore to keep water color ink pH value stabilization, will avoid amine substance to leak on the one hand as far as possible, for example build the upper cover of ink tank.Interpolation stablizer that on the other hand will be at regular time and quantity.Usually the pH value of water color ink should remain between 8.0～9.5, and the too high too low printing quality that all affects of pH value when the pH value is too low, affects the printing performance performance of acrylic resin; When the pH value was too high, ink setting was slow, was prone to the poor problem of printing set-off and water resisting property.Need constantly to adjust the pH value of printing-ink in printing process, greatly increased the difficulty of printing and increased the difficulty that water color ink is promoted.The acrylic resin that the present invention adopts thermoplastic acrylic resin and thermosetting acrylic resin to mix makes printing ink pH be stabilized in 7 ± 0.5 left and right, and the printing ink solubility is excellent, stable viscosity.Stopped in printing process transitivity poor, the dry quickening stopped up anilox roll, the scumming fault occurs, reduced the labour intensity in the printing process.Solved the poor problem of water color ink pH value and solubility.
5, the thermotolerance problem of wallpaper printing ink
Because PVC foaming wallpaper printing ink printing art is at the printing post-foaming, unchanged through form and aspect after the drying tunnel foaming of 180 ℃～220 ℃ after printing, thermotolerance to water-based wallpaper printing ink has high requirement, and the present invention's pigment used is high-temperature resisting pigment, and thermotolerance is all more than 200 ℃.Solved the thermotolerance problem of water-based wallpaper printing ink.
6, the weathering resistance of wallpaper printing ink, water tolerance, oil-proofness problem
After decoration, work-ing life is more than 10 years due to wallpaper, during need its scouring, so weathering resistance, water tolerance, oil-proofness to water-based wallpaper printing ink require high.The present invention's pigment used is high-temperature resisting pigment, and resin is high-molecular-weight propylene acid hybrid resin, has solved weathering resistance, water tolerance, the oil-proofness problem of wallpaper printing ink.
The preparation of embodiment 1 Yellow ink
Make water color ink with following each composition
(1) get the raw materials ready and weighing: weighing is standby one by one according to above-mentioned part by weight;
(2) mix and stir: the high foamex842 of raw material thermosetting acrylic resin, pigment, enlightening, the high wet505 of enlightening that weighing is got ready, mixing in order feeds intake, the water that first adds total water amount 2/3 feeds intake under 300～400 rev/mins of stirrings of low speed successively, stirs 10～15 minutes;
(3) sand milling disperses: the compound that step (2) is stirred changes sand milling dispersion in sand mill over to, 1/3 water of total water amount is cleaned stirred vessel, and related water adds sand mill, grinds 3 times in sand mill, when material particle diameter to be mixed was 150～260nm, grinding distribution was complete;
(4) subsequent disposal: will grind complete compound in container with 300～500 rev/mins of stirrings, in whipping process, add thermoplastic acrylic resin, 842N, the high twin4000 of enlightening, the high Viscoplus3000 of enlightening, solubility promoter to be transferred to appropriate viscosity (being coated with the 4# cup 15～30 seconds), stirred 50 minutes;
(5) form and aspect of check product, admittedly contain, fineness, viscosity, qualified rear filtration, packing.
Examination and test of products standard is as follows:
The mensuration of 1 fineness
Method by GBT13217.3-2008 " the liquid ink fineness method of inspection " is carried out.
2 viscosimetric analysis
Method by GBT13217.4-2008 " the liquid ink viscosity method of inspection " is carried out.
The mensuration of 3 solid contents
3.1 test summary
Solid content refers to the ratio of quality with the former printing ink quality of its solid composition after a certain amount of printing ink complete drying, in per-cent (%).
3.2 main testing tool
A) balance (claiming accurate to 0.001g).
B) electric heating constant-temperature blowing drying box.
C) clean aluminium foil.
3.3 testing method
A) the electric heating constant-temperature blowing drying box design temperature for requiring temperature, is opened air blast.
B) accurately take printing ink to be measured and approximately in aluminium foil, be placed in electric heating constant-temperature blowing drying box in the 1g left and right, freeze-day with constant temperature 6hr takes out weighing.
3.4 method of calculation:
Solid content (%)=(W2-W)/(W1-W) * 100%
Wherein: W-----aluminium foil weight
W1----printing ink to be measured and aluminium foil weight
Printing ink and aluminium foil weight after the W2----drying
3.3.5 parallelly do two parts and average.
3.6 test condition:
A) the water color ink test condition is 150 ± 2 ℃.
B) must acutely rock evenly before all printing ink tests, guarantee that sampling accurately.
The mensuration of 4 colors
4.1 test summary
To be examined black sample and standard China ink sample and be compared to scrape side by side quadrat method, be inspected whether conformance with standard China ink sample quality standard of ink colors.
3.4.2 main testing tool and material:
A) RK.12 * 22cm impresses bed.
B) RDS06 silk rod.
C) clean cork paper.
D) transfer ink knife.
4.3 testing method
The drawdown sheet that a) will cut out is fixed on the impression bed.
B) with after transferring ink knife that standard specimen and sample (being mixed into China ink with binder) are stirred, take a morsel respectively and drip in upper left side and the upper right side of drawdown sheet, both adjacent and be not connected.
C) evenly at full tilt China ink is scraped lamellar from top to bottom with the silk rod on paper.
D) inspect the complexion of sample and standard.
4.4 assay
Inspect sample whether consistent with the complexion of standard specimen.
4.5 condition for surveys
A) check should be carried out under 25 ± 1 ℃ of temperature, humidity 65 ± 5% conditions.
When b) inspecting complexion, should carry out under the D65 standard illuminants of 45 ° ± 5 ° of input angles.
5 capillary mensuration
Method by GB/T18396-2008 " the around-France mensuration surface tension of natural rubber latex " is carried out.
Examination and test of products result is asked for an interview table 5, table 6 and table 7.
The preparation of embodiment 2 red inks
Make water color ink with following each composition
Preparation method and the method for inspection are with embodiment 1, and examination and test of products result is asked for an interview table 5, table 6 and table 7.
The preparation of embodiment 3 black inks
Make water color ink with following each composition
Preparation method and the method for inspection are with embodiment 1, and examination and test of products result is asked for an interview table 5, table 6 and table 7.
The preparation of embodiment 4 white inks
Make water color ink with following each composition
Preparation method and the method for inspection are with embodiment 1, and examination and test of products result is asked for an interview table 5, table 6 and table 7.
The preparation of embodiment 5 gold inks
Make water color ink with following each composition
Preparation method and the method for inspection are with embodiment 1, and examination and test of products result is asked for an interview table 5, table 6 and table 7.
Provided by the invention for PVC foaming wallpaper printing aqueous ink special, its heavy metal content test rating and VOC technological standard meet national standard fully; Its printing effect is fabulous, and thermotolerance, weathering resistance, water tolerance and oil-proofness and solvent type ink are suitable.
The technical result 1 of the heavy metal of each printing ink of table 5 the present invention:
The technical result 2 of the heavy metal of each printing ink of table 6 the present invention:
Table 7 particle diameter laboratory report
The above is only the preferred embodiment of the present invention; should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (10)
1. one kind is used for PVC foaming wallpaper printing aqueous ink special, it is characterized in that, comprises the component of following weight percent:
2. water color ink according to claim 1, is characterized in that, the molecular weight of described thermoplastic acrylic resin is that 5000～6000, pH is 6.9～7.5, and solid content is 35%～45%; The molecular weight of described thermosetting acrylic resin is that 8000～8500, pH is 6.9～7.5, and solid content is 35%～45%.
3. according to claim 1 described water color ink, is characterized in that, the thermotolerance of described pigment is more than 200 ℃, and weathering resistance is at the pigment more than 7, and it has the average particulate diameter of 10～100nm scope.
4. water color ink according to claim 3, is characterized in that, described pigment has the average particulate diameter of 10～40nm scope.
5. according to claim 1 described water color ink, is characterized in that, described defoamer is polysiloxane-copolyether emulsion.
6. according to claim 1 described water color ink, is characterized in that, described tensio-active agent is non-ionic type upgrading derivative of fatty acid.
7. according to claim 1 described water color ink, is characterized in that, described wetting dispersing agent is not for containing the dispersion agent of solvent, amine and ethoxylized nonylphenol.
8. according to claim 1 described water color ink, is characterized in that, described water-based thickener is the water soluble acrylic acid associative thickener.
9. according to claim 1 described water color ink, is characterized in that, described solubility promoter is ethanol, ethylene glycol or ethylene glycol monobutyl ether.
10. one kind prepares the described water color ink method of claim 1～9 any one, it is characterized in that, comprises the steps:
(1) get the raw materials ready and weighing: with thermosetting acrylic resin, thermoplastic acrylic resin, pigment, defoamer, tensio-active agent, solubility promoter, water-based wax emulsion, wetting dispersing agent, water-based thickener, proportionally weighing is standby one by one for water;
(2) mix and stir: raw material thermosetting acrylic resin, pigment, defoamer, wetting dispersing agent that weighing is got ready, mixing in order feeds intake, the water that first adds total water amount 2/3 feeds intake under 300～400 rev/mins of stirrings of low speed successively, stirs 10～15 minutes;
(3) sand milling disperses: the compound that step (2) is stirred changes sand milling dispersion in sand mill over to, 1/3 water of total water amount is cleaned stirred vessel, and related water adds sand mill, grinds in sand mill 3～4 times, when material particle diameter to be mixed was 150～260nm, grinding distribution was complete;
(4) subsequent disposal: will grind complete compound in container with 300～500 rev/mins of stirrings, in whipping process, add thermoplastic acrylic resin, water-based wax emulsion, tensio-active agent, water-based thickener, solubility promoter to be transferred to appropriate viscosity, stirred 50～70 minutes;
(5) filter packing.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103481605A (en) * | 2013-08-27 | 2014-01-01 | 浙江博泰塑胶有限公司 | Environment-friendly single-spray mosaic swimming pool cloth and production process thereof |
| CN103696328A (en) * | 2013-12-20 | 2014-04-02 | 吴江华尔美特装饰材料有限公司 | Production process of water-based frosted wallpaper |
| CN104269102A (en) * | 2014-10-17 | 2015-01-07 | 张钰源 | Special flexographic color hot-pressed label for resin grinding wheel |
| CN104403415A (en) * | 2014-11-26 | 2015-03-11 | 成都锦汇科技有限公司 | Wear-proof printing ink |
| CN105713450A (en) * | 2014-12-17 | 2016-06-29 | 施乐公司 | Acrylate ink compositions for ink-based digital lithographic printing |
| CN109929324A (en) * | 2019-03-29 | 2019-06-25 | 杭州顶正包材有限公司 | The production method and foaming vessel of foaming vessel |
| CN113088128A (en) * | 2021-03-31 | 2021-07-09 | 佛山方嘉机电科技有限公司 | Method and equipment for manufacturing ultra-high temperature resistant ink visible under specific wavelength |
| CN114395286A (en) * | 2022-01-08 | 2022-04-26 | 黄山豪泰塑胶有限公司 | Water-based ink for printing PVC decorative paper and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63317571A (en) * | 1987-06-19 | 1988-12-26 | Asahi Glass Co Ltd | Marking ink composition |
| US20080090034A1 (en) * | 2006-09-18 | 2008-04-17 | Harrison Daniel J | Colored glass frit |
| CN101608078A (en) * | 2009-07-23 | 2009-12-23 | 天津市海山化工科技开发有限公司 | A kind of decorative paper water-based gravure printing ink composition |
| CN102031039A (en) * | 2009-09-25 | 2011-04-27 | 中国科学院化学研究所 | Thermofixation ink for direct platemaking by ink-jet printing and preparation method and application thereof |
| CN102827506A (en) * | 2011-06-17 | 2012-12-19 | 富士胶片株式会社 | Ink set and image forming method |
-
2013
- 2013-03-20 CN CN201310089792.XA patent/CN103146257B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63317571A (en) * | 1987-06-19 | 1988-12-26 | Asahi Glass Co Ltd | Marking ink composition |
| US20080090034A1 (en) * | 2006-09-18 | 2008-04-17 | Harrison Daniel J | Colored glass frit |
| CN101608078A (en) * | 2009-07-23 | 2009-12-23 | 天津市海山化工科技开发有限公司 | A kind of decorative paper water-based gravure printing ink composition |
| CN102031039A (en) * | 2009-09-25 | 2011-04-27 | 中国科学院化学研究所 | Thermofixation ink for direct platemaking by ink-jet printing and preparation method and application thereof |
| CN102827506A (en) * | 2011-06-17 | 2012-12-19 | 富士胶片株式会社 | Ink set and image forming method |
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|---|---|---|---|---|
| CN103481605A (en) * | 2013-08-27 | 2014-01-01 | 浙江博泰塑胶有限公司 | Environment-friendly single-spray mosaic swimming pool cloth and production process thereof |
| CN103481605B (en) * | 2013-08-27 | 2015-10-28 | 浙江博泰塑胶有限公司 | Environment-friendlysingle-spray single-spray mosaic swimming pool cloth and production technology thereof |
| CN103696328A (en) * | 2013-12-20 | 2014-04-02 | 吴江华尔美特装饰材料有限公司 | Production process of water-based frosted wallpaper |
| CN103696328B (en) * | 2013-12-20 | 2016-08-17 | 吴江华尔美特装饰材料有限公司 | A kind of production technology of aqueous frosted wallpaper |
| CN104269102A (en) * | 2014-10-17 | 2015-01-07 | 张钰源 | Special flexographic color hot-pressed label for resin grinding wheel |
| CN104269102B (en) * | 2014-10-17 | 2016-07-06 | 张钰源 | The special circular flexo colored hot-pressed label of resin wheel |
| CN104403415A (en) * | 2014-11-26 | 2015-03-11 | 成都锦汇科技有限公司 | Wear-proof printing ink |
| CN105713450A (en) * | 2014-12-17 | 2016-06-29 | 施乐公司 | Acrylate ink compositions for ink-based digital lithographic printing |
| CN109929324A (en) * | 2019-03-29 | 2019-06-25 | 杭州顶正包材有限公司 | The production method and foaming vessel of foaming vessel |
| CN113088128A (en) * | 2021-03-31 | 2021-07-09 | 佛山方嘉机电科技有限公司 | Method and equipment for manufacturing ultra-high temperature resistant ink visible under specific wavelength |
| CN114395286A (en) * | 2022-01-08 | 2022-04-26 | 黄山豪泰塑胶有限公司 | Water-based ink for printing PVC decorative paper and preparation method thereof |
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