CN108517149A - A kind of manufacturing method of noctilucence color ink and wood-based plate noctilucence finishing paper - Google Patents
A kind of manufacturing method of noctilucence color ink and wood-based plate noctilucence finishing paper Download PDFInfo
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- CN108517149A CN108517149A CN201810246382.4A CN201810246382A CN108517149A CN 108517149 A CN108517149 A CN 108517149A CN 201810246382 A CN201810246382 A CN 201810246382A CN 108517149 A CN108517149 A CN 108517149A
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- noctilucence
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 239000002023 wood Substances 0.000 title claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 48
- 238000000034 method Methods 0.000 claims abstract description 40
- 230000008569 process Effects 0.000 claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 20
- 238000007639 printing Methods 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 18
- 238000004078 waterproofing Methods 0.000 claims abstract description 18
- 239000011230 binding agent Substances 0.000 claims abstract description 17
- 239000002904 solvent Substances 0.000 claims abstract description 16
- 230000003750 conditioning effect Effects 0.000 claims abstract description 15
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 9
- 239000011248 coating agent Substances 0.000 claims abstract description 9
- 238000000576 coating method Methods 0.000 claims abstract description 9
- 239000004615 ingredient Substances 0.000 claims abstract description 9
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000758 substrate Substances 0.000 claims abstract description 9
- 238000005470 impregnation Methods 0.000 claims abstract description 3
- 238000012545 processing Methods 0.000 claims abstract description 3
- 239000000565 sealant Substances 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 241000206575 Chondrus crispus Species 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000005538 encapsulation Methods 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 238000003801 milling Methods 0.000 claims description 7
- 238000012216 screening Methods 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 239000003094 microcapsule Substances 0.000 claims description 6
- 238000004220 aggregation Methods 0.000 claims description 5
- 230000002776 aggregation Effects 0.000 claims description 5
- 239000003085 diluting agent Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000001694 spray drying Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000009736 wetting Methods 0.000 claims description 5
- 238000005119 centrifugation Methods 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
- 239000000920 calcium hydroxide Substances 0.000 claims description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 3
- 239000005018 casein Substances 0.000 claims description 3
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 3
- 235000021240 caseins Nutrition 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000009434 installation Methods 0.000 claims description 3
- 235000013336 milk Nutrition 0.000 claims description 3
- 239000008267 milk Substances 0.000 claims description 3
- 210000004080 milk Anatomy 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 238000000643 oven drying Methods 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 239000001509 sodium citrate Substances 0.000 claims description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 3
- 235000010215 titanium dioxide Nutrition 0.000 claims description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 2
- 239000001632 sodium acetate Substances 0.000 claims description 2
- 235000017281 sodium acetate Nutrition 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 238000010422 painting Methods 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 230000008033 biological extinction Effects 0.000 abstract description 6
- 239000011247 coating layer Substances 0.000 abstract description 6
- 238000003860 storage Methods 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 5
- 238000004020 luminiscence type Methods 0.000 abstract description 4
- 239000000976 ink Substances 0.000 description 46
- 230000008901 benefit Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000002966 varnish Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000004972 Polyurethane varnish Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- BDKZHNJTLHOSDW-UHFFFAOYSA-N [Na].CC(O)=O Chemical compound [Na].CC(O)=O BDKZHNJTLHOSDW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 238000007540 photo-reduction reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/20—Applying plastic materials and superficially modelling the surface of these materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/0446—Ornamental plaques, e.g. decorative panels, decorative veneers bearing graphical information
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/04—Printing inks based on proteins
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of noctilucence color ink and the manufacturing method of wood-based plate noctilucence finishing paper, noctilucence color ink, including following ingredients：Luminescent powder, resin solvent, binder, anti-settling agent, PH conditioning agents, water-proofing agent；The wood-based plate manufacturing method of noctilucence finishing paper, includes the following steps：Step 1 configures noctilucence color ink；Step 2 carries out multiple roll double exposure intaglio plate trans-printing to paper using the color ink that step 1 produces, obtains luminous ink coating；Paper is dried in step 3；Step 4 carries out impregnation sealant processing using melamine to paper；Step 5 after letterweight is attached on substrate by high temperature and pressure, obtains noctilucence finishing paper；The present invention not only solves the problem of noctilucence color ink water proofing property, and fluorescent powder is in stable condition, is evenly distributed；The present invention enables the degree that the coating layer thickness of luminous ink ensures that extinction, storage light, luminescence process may be repeated by printing technology.
Description
Technical field
The present invention relates to decoration material field, the manufacturer of especially a kind of noctilucence color ink and wood-based plate noctilucence finishing paper
Method.
Background technology
Common water borne ink is shifted by intaglio press in the market, and traditional decorative encasing (wood is formed after printing is dry
Line) paper；Noctilucence technology is not related on facing (wood grain) paper also, and market can not temporarily solve the water proofing property of luminescent powder；And night
The coating of light ink can not reach the thickness that can ensure that extinction, storage light, luminescence process may be repeated；The present invention solves in this way
The problem of.
Invention content
To solve the deficiencies in the prior art, the purpose of the present invention is to provide a kind of noctilucence color inks and wood-based plate to be adornd with noctilucence
The manufacturing method of facial tissue；The present invention not only solves the problem of noctilucence color ink water proofing property, and fluorescent powder is in stable condition, and distribution is equal
It is even；The present invention by printing technology enable the coating layer thickness of luminous ink ensure extinction, storage light, luminescence process repeat into
Capable degree.
In order to realize that above-mentioned target, the present invention adopt the following technical scheme that：
A kind of noctilucence color ink, including following ingredient：Luminescent powder, resin solvent, binder, anti-settling agent, PH conditioning agents are water-fast
Agent；The weight ratio of ingredient is：1：3：1.5：0.1：0.1：0.1-0.2.
A kind of noctilucence color ink above-mentioned, resin solvent are acrylate copolymer or acrylic acid.
A kind of noctilucence color ink above-mentioned, binder are the edible casein that a kind of milk industries refine.
A kind of noctilucence color ink above-mentioned, anti-settling agent are White Mineral Oil or polyamide wax.
A kind of noctilucence color ink above-mentioned, PH conditioning agents include：Sodium citrate, phosphate, sodium acetate, calcium hydroxide, hydrogen-oxygen
Change potassium, sodium hydroxide.
The wood-based plate manufacturing method of noctilucence finishing paper, includes the following steps：
Step 1 configures noctilucence color ink；
1) luminescent powder is mixed with resin solvent；
2) it is proportionally added into binder in mixture, temperature is promoted between 50-60 degree；
3) mixture configured is put into Milling and screening machine to grind repeatedly, is refiltered；
4) mixture after encapsulation grinding is used；
5) viscosity is adjusted；
6) water-proofing agent is used to carry out the resistance to water process in surface；
7) add anti-settling agent, high-speed stirred；
8) pH value for adjusting color ink by PH conditioning agents obtains noctilucence color ink between alkalescent 8-9；
Step 2 carries out multiple roll double exposure intaglio plate trans-printing to paper using the color ink that step 1 produces, obtains noctilucence oil
Black coating；
Paper is dried in step 3；
Step 4 carries out impregnation sealant processing using melamine to paper；
Step 5 after letterweight is attached on substrate by high temperature and pressure, obtains noctilucence finishing paper.
The wood-based plate above-mentioned manufacturing method of noctilucence finishing paper, includes the following steps：
Step 1 configures noctilucence color ink
1) luminescent powder is mixed with resin solvent；
2) it is proportionally added into binder in mixture, temperature is promoted between 50-60 degree；
3) mixture configured is put into Milling and screening machine and grinds fully wetting 2 hours repeatedly, refiltered to more than 80 mesh；
4) mixture after using encapsulation to grind, specific method are：
Step a, is dispersed in mixture as heartwood in the medium of microencapsulation, obtains dispersion；
Step b, then be put into carragheen as wall material in the dispersion；
Step c by carragheen aggregation, is wrapped in around the heartwood disperseed；
Step d, is granulated using spray drying process, obtains the microcapsules of pack mixture；
5) adjustment viscosity is 30s or more；Adjustment viscosity specific method be：In the state of stirring, if viscosity is high, plus
Water be diluted to 30-35 seconds 4mmDINcup/20 DEG C, if viscosity is low, plus diluent improve viscosity；
6) water-proofing agent is added in mixture, after mixing, using centrifugation, obtains by the resistance to water process in surface
Mixture；
7) add anti-settling agent, high-speed stirred 30min in the mixture by the resistance to water process in surface；
8) pH value of color ink is adjusted between alkalescent 8-9 by PH conditioning agents；
Step 2, the color ink produced using step 1 are carried out multiple roll to paper using electronic engraving roller intaglio press and folded
Intaglio plate trans-printing is printed, luminous ink coating is obtained；
Step 3, on printing machine online installation cover oven drying device more, paper is dried in printing；
Step 4 impregnates paper using melamine, then baking and curing melamine makes the face seal of paper；
Step 5 is 180-200 degree in temperature, and pressure is under conditions of the high temperature and pressure of 10-30 megapascal, closure time 30
After letterweight can be attached on substrate by the second, noctilucence finishing paper/plate is obtained.
The manufacturing method of wood-based plate above-mentioned noctilucence finishing paper, paper use the extraordinary titanium white paper in decorating base paper.
The manufacturing method of wood-based plate above-mentioned noctilucence finishing paper, substrate include：Ecological board, density board, it is particieboard, artificial
Plate.
The specific method of the manufacturing method of wood-based plate above-mentioned noctilucence finishing paper, multiple roll double exposure intaglio plate trans-printing is：
The color ink produced using step 1 carries out multiple double exposure using the gravure carving electronics roller deeply of 80 mesh of more sets to paper.
The invention has the beneficial effects that：
Present invention adds binders, can give full play to the interconnection advantage of each component, the attached of luminescent powder can be improved
Put forth effort；
The present invention using encapsulation grinding after mixture so that fluorescent powder it is in stable condition, be evenly distributed, shine
Effect is good, and service life is long；
The present invention carries out the resistance to water process in surface using water-proofing agent to color ink, and is carried out to the mixture after microcapsules is made
Resistance to water process improves noctilucence color ink water resistance；
The present invention carries out paper by color ink the printing of 80 mesh gravure of more sets carving electronics roller double exposure multipass deeply so that noctilucence
The thickness of ink coating is more than or equal to 100 microns, and the coating layer thickness of such luminous ink can ensure extinction, storage light, shine
The degree that journey may be repeated.
Description of the drawings
Fig. 1 is the step flow chart of manufacturing method of the present invention.
Specific implementation mode
Specific introduce is made to the present invention below in conjunction with the drawings and specific embodiments.
A kind of noctilucence color ink, including following ingredient：Luminescent powder, resin solvent, binder, anti-settling agent, PH conditioning agents are water-fast
Agent；The weight ratio of ingredient is：1：3：1.5：0.1：0.1：0.1-0.2.
As a kind of embodiment, resin solvent is acrylate copolymer or acrylic acid.Binder is that a kind of milk industries carry
The edible casein of refining.Anti-settling agent is White Mineral Oil or polyamide wax.PH conditioning agents include：Sodium citrate, phosphate, acetic acid
Sodium, calcium hydroxide, potassium hydroxide, sodium hydroxide.
The manufacturing method of wood-based plate noctilucence finishing paper, which is characterized in that include the following steps：
Step 1 configures noctilucence color ink
1) by luminescent powder and resin solvent according to 1:3 proportional arrangement is good；
2) it is proportionally added into binder in mixture, temperature is promoted between 50-60 degree；Connection is added
Material can give full play to the interconnection advantage of each component, and the adhesive force of luminescent powder can be improved；
3) mixture configured is put into Milling and screening machine and grinds fully wetting 2 hours repeatedly, refiltered to more than 80 mesh；
4) mixture after using encapsulation to grind, specific method are：
Step a, is dispersed in mixture as heartwood in the medium of microencapsulation；
Step b, then be put into carragheen as wall material in the dispersion；
Step c by carragheen aggregation, is wrapped in around the heartwood disperseed；
Step d, is granulated using spray drying process, obtains the microcapsules of pack mixture；
5) adjustment viscosity is 30s or more；Adjustment viscosity specific method be：In the state of stirring, if viscosity is high, plus
Water be diluted to 30-35 seconds 4mmDINcup/20 DEG C, if viscosity is low, plus diluent improve viscosity.
6) water-proofing agent is added in mixture, after mixing, using centrifugation, obtains by the resistance to water process in surface
Mixture；Water-proofing agent can select the kind of the resin that can be selected and varnish to include：Epoxy resin (E440), polyurethane resin
The shallow alcohol of (or varnish), alkyd resin, acrylic resin, Hydroxylated acrylic resin, acroleic acid polyurethane varnish (bi-component), color
Sour varnish, fluorocarbon resin.
7) add anti-settling agent, high-speed stirred 30min in the mixture by the resistance to water process in surface；
8) pH value for adjusting color ink by PH conditioning agents obtains noctilucence color ink between alkalescent 8-9；
The specific method of step 2, multiple roll double exposure intaglio plate trans-printing is：It is used using the color ink that step 1 produces more
The gravure carving electronics roller deeply for covering 80 mesh, carries out multiple double exposure to paper, obtains luminous ink coating；As a preferred embodiment, paper is adopted
With the extraordinary titanium white paper in decorating base paper.The thickness of luminous ink coating is more than or equal to 100 microns.
Step 3, on printing machine online installation cover oven drying device more, paper is dried in printing；
Step 4 impregnates paper using melamine, then baking and curing melamine makes the face seal of paper；
Step 5 is 180-200 degree in temperature, and pressure is under conditions of the high temperature and pressure of 10-30 megapascal, closure time 30
After letterweight can be attached on substrate by the second, noctilucence finishing paper/plate is obtained.As a kind of embodiment, substrate includes：It is ecological board, close
Spend plate, particieboard, wood-based plate.
The water resistance of the present invention is verified through the following experiment；
The ingredient of sample 1, selection includes：Luminescent powder, resin solvent, binder, anti-settling agent, PH conditioning agents, water-proofing agent；At
Point weight ratio be：1：3：1.5：0.1：0.1：0.1-0.2；
Configuration noctilucence color ink sample 1 in accordance with the following steps；
1) by luminescent powder and resin solvent according to 1:3 proportional arrangement is good；
2) it is proportionally added into binder in mixture, temperature is promoted between 50-60 degree；
3) mixture configured is put into Milling and screening machine and grinds fully wetting 2 hours repeatedly, refiltered to more than 80 mesh；
4) mixture after using encapsulation to grind, specific method are：
Step a, is dispersed in mixture as heartwood in the medium of microencapsulation；
Step b, then be put into carragheen as wall material in the dispersion；
Step c by carragheen aggregation, is wrapped in around the heartwood disperseed；
Step d, is granulated using spray drying process, obtains the microcapsules of pack mixture；
5) adjustment viscosity is 30s or more；Adjustment viscosity specific method be：In the state of stirring, if viscosity is high, plus
Water be diluted to 30-35 seconds 4mmDINcup/20 DEG C, if viscosity is low, plus diluent improve viscosity.
6) water-proofing agent is added in mixture, after mixing, using centrifugation, obtains by the resistance to water process in surface
Mixture；Water-proofing agent selects acroleic acid polyurethane varnish as water-proofing agent.
7) add anti-settling agent, high-speed stirred 30min in the mixture by the resistance to water process in surface；
8) pH value for adjusting color ink by PH conditioning agents obtains the resistance to water sample of noctilucence color ink between alkalescent 8-9；
The ingredient of contrast sample 2, selection includes：Luminescent powder, resin solvent, binder, anti-settling agent, PH conditioning agents；Ingredient
Weight ratio be：1：3：1.5：0.1：0.1；
Configuration noctilucence color ink contrast sample 2 in accordance with the following steps；
1) by luminescent powder and resin solvent according to 1:3 proportional arrangement is good；
2) it is proportionally added into binder in mixture, temperature is promoted between 50-60 degree；
3) mixture configured is put into Milling and screening machine and grinds fully wetting 2 hours repeatedly, refiltered to more than 80 mesh；
4) mixture after using encapsulation to grind, specific method are：
Step a, is dispersed in mixture as heartwood in the medium of microencapsulation；
Step b, then be put into carragheen as wall material in the dispersion；
Step c by carragheen aggregation, is wrapped in around the heartwood disperseed；
Step d, is granulated using spray drying process, obtains the microcapsules of pack mixture；
5) adjustment viscosity is 30s or more；Adjustment viscosity specific method be：In the state of stirring, if viscosity is high, plus
Water be diluted to 30-35 seconds 4mmDINcup/20 DEG C, if viscosity is low, plus diluent improve viscosity.
6) add anti-settling agent, high-speed stirred 30min in the mixture by the resistance to water process in surface；
7) pH value for adjusting color ink by PH conditioning agents obtains noctilucence color ink contrast sample between alkalescent 8-9；
Resistance to water sample and contrast sample are subjected to immersion test respectively, briliancy (10min/cd.m-2) is measured and obtains table one；
Table one
The above experiment shows to remove the process of addition water-proofing agent, just no longer shine after color ink inundation, and sample 1 is water-fast
Superior performance.
Method using the present invention is verified through the following experiment, and the coating layer thickness of luminous ink is enabled to be more than or equal to
100 microns.
Sample 1 is using identical proportioning and production method above but uses common gravure printing roller, produces sample；
Sample 2 is using identical proportioning and production method above but uses a set of 80 mesh gravure carving electronics roller deeply, system
Produce sample；
Sample 3 is using identical proportioning and production method above but uses 2 set of 80 mesh gravure carving electronics roller double exposure deeply
Twice, produce sample；
Sample 4 is using identical proportioning and production method above but uses 3 set of 80 mesh gravure carving electronics roller double exposure deeply
3 times, produce sample；
Sample 5 is using identical proportioning and production method above but uses 2 set of 80 mesh gravure carving electronics roller double exposure deeply
3 times, produce sample；
The thickness such as table two of three samples is measured,
| Sample | 1 | 2 | 3 | 4 | 5 |
| Thickness | 50 microns | 80 microns | 110 microns | 108 microns | 113 microns |
Table two
Enabled to as can be seen from the above table using the methods of 80 mesh gravures of more sets carving electronics roller double exposure multipass deeply so that
The thickness of luminous ink coating is more than or equal to 100 microns, and the coating layer thickness of such luminous ink can ensure extinction, storage light, hair
The degree that photoreduction process may be repeated.
The present invention provides a kind of noctilucence color ink and the manufacturing method of wood-based plate noctilucence finishing paper；The present invention not only solves
The problem of noctilucence color ink water proofing property, and fluorescent powder is in stable condition, is evenly distributed；The present invention makes luminous ink by printing technology
Coating layer thickness can ensure the degree that extinction, storage light, luminescence process may be repeated.
The basic principles, main features and advantages of the invention have been shown and described above.The technical staff of the industry should
Understand, the invention is not limited in any way above-described embodiment, all to be obtained by the way of equivalent substitution or equivalent transformation
Technical solution is all fallen in protection scope of the present invention.
Claims (10)
1. a kind of noctilucence color ink, which is characterized in that including following ingredient：Luminescent powder, resin solvent, binder, anti-settling agent, PH tune
Save agent, water-proofing agent；The weight ratio of mentioned component is：1：3：1.5：0.1：0.1：0.1-0.2.
2. a kind of noctilucence color ink according to claim 1, which is characterized in that above-mentioned resin solvent be acrylate copolymer or
Acrylic acid.
3. a kind of noctilucence color ink according to claim 1, which is characterized in that above-mentioned binder is refined for a kind of milk industries
Edible casein.
4. a kind of noctilucence color ink according to claim 1, which is characterized in that anti-settling agent is White Mineral Oil or polyamide wax.
5. a kind of noctilucence color ink according to claim 1, which is characterized in that above-mentioned PH conditioning agents include：Sodium citrate, phosphorus
Hydrochlorate, sodium acetate, calcium hydroxide, potassium hydroxide, sodium hydroxide.
6. the wood-based plate manufacturing method of noctilucence finishing paper, which is characterized in that include the following steps：
Step 1 configures noctilucence color ink；
1) luminescent powder is mixed with resin solvent；
2) it is proportionally added into binder in mixture, temperature is promoted between 50-60 degree；
3) mixture configured is put into Milling and screening machine to grind repeatedly, is refiltered；
4) mixture after encapsulation grinding is used；
5) viscosity is adjusted；
6) water-proofing agent is used to carry out the resistance to water process in surface；
7) add anti-settling agent, high-speed stirred；
8) pH value for adjusting color ink by PH conditioning agents obtains noctilucence color ink between alkalescent 8-9；
Step 2 carries out multiple roll double exposure intaglio plate trans-printing to paper using the color ink that step 1 produces, obtains luminous ink painting
Layer；
Paper is dried in step 3；
Step 4 carries out impregnation sealant processing using melamine to paper；
Step 5 after letterweight is attached on substrate by high temperature and pressure, obtains noctilucence finishing paper.
7. the wood-based plate according to claim 6 manufacturing method of noctilucence finishing paper, which is characterized in that including walking as follows
Suddenly：
Step 1 configures noctilucence color ink
1) luminescent powder is mixed with resin solvent；
2) it is proportionally added into binder in mixture, temperature is promoted between 50-60 degree；
3) mixture configured is put into Milling and screening machine and grinds fully wetting 2 hours repeatedly, refiltered to more than 80 mesh；
4) mixture after using encapsulation to grind, specific method are：
Step a, is dispersed in mixture as heartwood in the medium of microencapsulation, obtains dispersion；
Step b, then be put into carragheen as wall material in the dispersion；
Step c by carragheen aggregation, is wrapped in around the heartwood disperseed；
Step d, is granulated using spray drying process, obtains the microcapsules of pack mixture；
5) adjustment viscosity is 30s or more；Adjustment viscosity specific method be：In the state of stirring, if viscosity is high, plus water is dilute
Release to 30-35 seconds 4mmDINcup/20 DEG C, if viscosity is low, plus diluent improve viscosity；
6) water-proofing agent is added in mixture, after mixing, using centrifugation, obtains the mixing by the resistance to water process in surface
Object；
7) add anti-settling agent, high-speed stirred 30min in the mixture by the resistance to water process in surface；
8) pH value of color ink is adjusted between alkalescent 8-9 by PH conditioning agents；
Step 2, the color ink produced using step 1 are recessed to paper progress multiple roll double exposure using electronic engraving roller intaglio press
Version trans-printing, obtains luminous ink coating；
Step 3, on printing machine online installation cover oven drying device more, paper is dried in printing；
Step 4 impregnates paper using melamine, then baking and curing melamine makes the face seal of paper；
Step 5 is 180-200 degree in temperature, and for pressure under conditions of the high temperature and pressure of 10-30 megapascal, closure time 30 seconds is i.e.
After letterweight being attached on substrate, noctilucence finishing paper/plate is obtained.
8. the wood-based plate according to claim 6 manufacturing method of noctilucence finishing paper, which is characterized in that above-mentioned paper is using dress
Adorn the extraordinary titanium white paper in body paper.
9. the wood-based plate according to claim 6 manufacturing method of noctilucence finishing paper, which is characterized in that aforesaid substrate packet
It includes：Ecological board, density board, particieboard, wood-based plate.
10. the wood-based plate according to claim 6 manufacturing method of noctilucence finishing paper, which is characterized in that above-mentioned multiple roll is folded
Print intaglio plate trans-printing specific method be：The color ink produced using step 1 carves electronic edition deeply using the gravure of 80 mesh of more sets
Roller carries out multiple double exposure to paper.
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| CN111548675A (en) * | 2020-05-08 | 2020-08-18 | 宁波佐图文化用品有限公司 | Self-luminous neutral ink for writing in dark room and preparation method thereof |
| CN112210241A (en) * | 2020-09-14 | 2021-01-12 | 天津华彩顺成装饰材料有限公司 | Molandie color series ink, preparation method of melamine decorative paper and furniture decorative panel |
| CN112482093A (en) * | 2020-12-10 | 2021-03-12 | 淄博欧木特种纸业有限公司 | Preparation method of preimpregnated facing base paper and preparation method of preimpregnated facing paper |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110373950A (en) * | 2019-07-26 | 2019-10-25 | 临安福马装饰材料有限公司 | A kind of ultra-deep embosses the processing technology of synchronous finishing paper |
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| CN112210241A (en) * | 2020-09-14 | 2021-01-12 | 天津华彩顺成装饰材料有限公司 | Molandie color series ink, preparation method of melamine decorative paper and furniture decorative panel |
| CN112482093A (en) * | 2020-12-10 | 2021-03-12 | 淄博欧木特种纸业有限公司 | Preparation method of preimpregnated facing base paper and preparation method of preimpregnated facing paper |
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