CN101589178B - 用于氧气的电化学还原的催化剂 - Google Patents

用于氧气的电化学还原的催化剂 Download PDF

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CN101589178B
CN101589178B CN2008800014558A CN200880001455A CN101589178B CN 101589178 B CN101589178 B CN 101589178B CN 2008800014558 A CN2008800014558 A CN 2008800014558A CN 200880001455 A CN200880001455 A CN 200880001455A CN 101589178 B CN101589178 B CN 101589178B
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sulfide
noble metal
catalyst
conductive carbon
rhodium
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CN101589178A (zh
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A·F·古拉
R·J·艾伦
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Industrie de Nora SpA
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Industrie de Nora SpA
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/042—Electrodes formed of a single material
    • C25B11/043—Carbon, e.g. diamond or graphene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/043—Sulfides with iron group metals or platinum group metals
    • B01J27/045—Platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/24—Halogens or compounds thereof
    • C25B1/26—Chlorine; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C25B11/093—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one noble metal or noble metal oxide and at least one non-noble metal oxide
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H01M4/923—Compounds thereof with non-metallic elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
    • H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/20—Improvements relating to chlorine production

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
CN2008800014558A 2007-02-22 2008-02-20 用于氧气的电化学还原的催化剂 Active CN101589178B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US90280907P 2007-02-22 2007-02-22
US60/902,809 2007-02-22
PCT/EP2008/052061 WO2008101955A1 (en) 2007-02-22 2008-02-20 Catalyst for electrochemical reduction of oxygen

Publications (2)

Publication Number Publication Date
CN101589178A CN101589178A (zh) 2009-11-25
CN101589178B true CN101589178B (zh) 2011-06-01

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CN2008800014558A Active CN101589178B (zh) 2007-02-22 2008-02-20 用于氧气的电化学还原的催化剂

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US (2) US7956004B2 (enExample)
EP (1) EP2113039B1 (enExample)
JP (1) JP5220771B2 (enExample)
KR (1) KR101465461B1 (enExample)
CN (1) CN101589178B (enExample)
AR (1) AR065449A1 (enExample)
AU (1) AU2008219273B2 (enExample)
BR (1) BRPI0807555A2 (enExample)
CA (1) CA2673754C (enExample)
DK (1) DK2113039T3 (enExample)
EG (1) EG26702A (enExample)
ES (1) ES2660563T3 (enExample)
HU (1) HUE036063T2 (enExample)
MX (1) MX2009009019A (enExample)
MY (1) MY148278A (enExample)
NO (1) NO2113039T3 (enExample)
PL (1) PL2113039T3 (enExample)
PT (1) PT2113039T (enExample)
RU (1) RU2431699C2 (enExample)
TW (1) TWI429785B (enExample)
WO (1) WO2008101955A1 (enExample)
ZA (1) ZA200904279B (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9315912B2 (en) * 2006-11-29 2016-04-19 Industrie De Nora S.P.A. Carbon-supported metal sulphide catalyst for electrochemical oxygen reduction
TWI429785B (zh) * 2007-02-22 2014-03-11 Industrie De Nora Spa 氧之電化學還原用觸媒及製法和氣體擴散電極
JP5678499B2 (ja) * 2010-07-15 2015-03-04 トヨタ自動車株式会社 リチウム空気電池
CN103691456B (zh) * 2013-12-30 2016-03-30 北京化工大学 炭黑负载Rh-Rh17S15催化剂及其制备方法
WO2018179006A1 (en) * 2017-03-25 2018-10-04 Jawaharlal Nehru Centre For Advanced Scientific Research Palladium based selenides as highly stable and durable cathode materials in fuel cell for green energy production
CN108823602B (zh) * 2018-07-12 2021-01-15 北京化工大学 一种硫化钌颗粒复合材料、其制备方法及用途
US20220033978A1 (en) * 2018-11-29 2022-02-03 Atmonia Ehf. Process for electrolytic production of ammonia from nitrogen using metal sulfide catalytic surface
KR102311346B1 (ko) * 2018-12-31 2021-10-08 한화솔루션 주식회사 수소화반응용 촉매 및 이의 제조방법
KR102528310B1 (ko) * 2019-06-28 2023-05-02 한화솔루션 주식회사 수소화반응용 촉매 및 이의 제조방법
CN115679342B (zh) * 2022-10-27 2025-04-08 常州大学 RuS2/CoNi2S4@NF高效电催化剂及其制备方法和在电催化析氧中的应用
WO2025224127A1 (en) * 2024-04-23 2025-10-30 Industrie De Nora S.P.A. Ruthenium-rhodium sulphides based gas diffusion electrode and method for making the same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1353777A (zh) * 1999-05-27 2002-06-12 德·诺拉电极股份公司 铑电催化剂及其制法
US6967185B2 (en) * 2004-01-28 2005-11-22 De Nora Elettrodi S.P.A. Synthesis of noble metal, sulphide catalysts in a sulfide ion-free aqueous environment
CN1795293A (zh) * 2003-05-27 2006-06-28 德·诺拉电极股份公司 用于氧还原的催化剂

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US3793081A (en) * 1971-04-28 1974-02-19 Exxon Research Engineering Co Sulfided transition metal fuel cell cathode catalysts
US4288422A (en) * 1979-02-23 1981-09-08 Exxon Research & Engineering Co. Method of preparing chalcogenides of group VIII by low temperature precipitation from monaqueous solution, the products produced by said method and their use as catalysts
JPH01210036A (ja) * 1988-02-18 1989-08-23 Tanaka Kikinzoku Kogyo Kk 高表面積金属担持触媒の製造方法
DE19745904A1 (de) * 1997-10-17 1999-04-22 Hoechst Ag Polymerstabilisierte Metallkolloid-Lösungen, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren für Brennstoffzellen
US6402930B1 (en) * 1999-05-27 2002-06-11 De Nora Elettrodi S.P.A. Process for the electrolysis of technical-grade hydrochloric acid contaminated with organic substances using oxygen-consuming cathodes
ITMI20010402A1 (it) * 2001-02-28 2002-08-28 De Nora Elettrodi Spa Nuova composizione elettrocatalitica per catodo depolarizzato ad ossigeno
US6855660B2 (en) * 2001-11-07 2005-02-15 De Nora Elettrodi S.P.A. Rhodium electrocatalyst and method of preparation
US20070093006A1 (en) * 2005-10-24 2007-04-26 Basol Bulent M Technique For Preparing Precursor Films And Compound Layers For Thin Film Solar Cell Fabrication And Apparatus Corresponding Thereto
US9315912B2 (en) * 2006-11-29 2016-04-19 Industrie De Nora S.P.A. Carbon-supported metal sulphide catalyst for electrochemical oxygen reduction
TWI429785B (zh) * 2007-02-22 2014-03-11 Industrie De Nora Spa 氧之電化學還原用觸媒及製法和氣體擴散電極
JP5010409B2 (ja) * 2007-09-14 2012-08-29 トヨタ自動車株式会社 硫化物の単結晶微粉末、及びその製造方法

Patent Citations (3)

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CN1353777A (zh) * 1999-05-27 2002-06-12 德·诺拉电极股份公司 铑电催化剂及其制法
CN1795293A (zh) * 2003-05-27 2006-06-28 德·诺拉电极股份公司 用于氧还原的催化剂
US6967185B2 (en) * 2004-01-28 2005-11-22 De Nora Elettrodi S.P.A. Synthesis of noble metal, sulphide catalysts in a sulfide ion-free aqueous environment

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Also Published As

Publication number Publication date
HUE036063T2 (hu) 2018-06-28
WO2008101955A1 (en) 2008-08-28
NO2113039T3 (enExample) 2018-05-05
CA2673754C (en) 2014-12-09
ZA200904279B (en) 2010-08-25
EP2113039B1 (en) 2017-12-06
CA2673754A1 (en) 2008-08-28
TW200839034A (en) 2008-10-01
EG26702A (en) 2014-06-12
RU2431699C2 (ru) 2011-10-20
US20080202923A1 (en) 2008-08-28
TWI429785B (zh) 2014-03-11
US20110262344A1 (en) 2011-10-27
KR20090129439A (ko) 2009-12-16
HK1139189A1 (en) 2010-09-10
AU2008219273B2 (en) 2011-09-22
JP5220771B2 (ja) 2013-06-26
EP2113039A1 (en) 2009-11-04
MY148278A (en) 2013-03-29
DK2113039T3 (en) 2018-02-12
AR065449A1 (es) 2009-06-10
ES2660563T3 (es) 2018-03-23
PL2113039T3 (pl) 2018-05-30
PT2113039T (pt) 2018-02-28
KR101465461B1 (ko) 2014-11-26
RU2009135258A (ru) 2011-03-27
AU2008219273A1 (en) 2008-08-28
BRPI0807555A2 (pt) 2014-07-01
US7956004B2 (en) 2011-06-07
MX2009009019A (es) 2009-09-03
CN101589178A (zh) 2009-11-25
JP2010519029A (ja) 2010-06-03
US8258072B2 (en) 2012-09-04

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