CN101578985A - Sterilization composition containing kresoxim-methyl and triflumizole - Google Patents
Sterilization composition containing kresoxim-methyl and triflumizole Download PDFInfo
- Publication number
- CN101578985A CN101578985A CNA2009100226882A CN200910022688A CN101578985A CN 101578985 A CN101578985 A CN 101578985A CN A2009100226882 A CNA2009100226882 A CN A2009100226882A CN 200910022688 A CN200910022688 A CN 200910022688A CN 101578985 A CN101578985 A CN 101578985A
- Authority
- CN
- China
- Prior art keywords
- methyl
- kresoxim
- fluorine bacterium
- bacterium azoles
- triflumizole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a sterilization composition. Effective active components of the sterilization composition contain kresoxim-methyl and triflumizole, wherein the weight ratio of the kresoxim-methyl to the triflumizole is 1-60: 40-1. Effective active components can be made into wettable powder, water dispersible granules and suspending agents after an additive and an excipient are added. The sterilization composition is mainly used for preventing and controlling powdery mildew and scab of vegetables and fruit trees.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of application of bactericidal composition on the vegetables fruit diseases that contains kresoxim-methyl and fluorine bacterium azoles.
Technical background
Kresoxim-methyl (kresoxim-methyl) is the methoxy acrylic bactericide of BASF Aktiengesellschaft's exploitation.Molecular formula: C
18H
19NO
4, chemical name: methyl (E)-2-methoxyimino-2-[2-(0-toloxyl) phenyl] and acetate.
Kresoxim-methyl belongs to the mitochondrial respiratory inhibitor, be a kind of wide-spectrum bactericide, and the lasting period is long, and most of diseases that pathomycetes such as Ascomycetes, Basidiomycetes, Fungi Imperfecti and oomycetes subclass are caused have protection, treat and root out activity.
Fluorine bacterium azoles (triflumizole) is a kind of sterol demethylation inhibitor, and by Japanese Cao Da company development product, molecular formula is C
15H
15F
3Cl N
3O, chemical name are (E)-4-chloro-α, α, α-three fluoro-N-(1-imidazoles-1-base-α-third oxygen ethylidene) neighbour-toluidines fluorine bacterium azoles.
The protection of fluorine bacterium azoles tool, treatment and eradicant action are the systemic fungicides of wide spectrum, and the Erysiphaceae on vegetables and the fruit, Fusarium are had activity, are used to prevent and treat powdery mildew, rust, scab of wheat class, vegetables, fruit tree etc.
No matter be kresoxim-methyl, fluorine bacterium azoles or other efficient germicides, long-term use separately makes disease develop immunity to drugs easily, causes problems such as dosage increasing, preventive effect reduction, lasting period shortening, is unfavorable for the environment sustainable development.The active ingredient of different action principles is carried out composite, is to delay the disease method commonly used that develops immunity to drugs, and according to the effect in the production application, judge this composite be synergistic effect or antagonism.Complex role is more significantly filled a prescription, and can obviously improve preventive effect, reduces the dosage of agricultural chemicals greatly, also can enlarge fungicidal spectrum, improves germicidal efficiency.Kresoxim-methyl belong to two kinds of mechanisms of action with fluorine bacterium azoles and the mode of action different, mutually compositely can not produce conflict, good synergistic effect is arranged within the specific limits.And composite about kresoxim-methyl and fluorine bacterium azoles do not see relevant report at present at home and abroad as yet.
Summary of the invention
Purpose of the present invention proposes a kind of have synergistic effect, use cost is low, preventive effect the is good bactericidal composition that contains kresoxim-methyl and fluorine bacterium azoles.
The present invention is achieved through the following technical solutions:
A kind of bactericidal composition that contains kresoxim-methyl and fluorine bacterium azoles, wherein kresoxim-methyl and fluorine bacterium azoles percentage by weight are 1～60: 40～1.
The described bactericidal composition that contains kresoxim-methyl and fluorine bacterium azoles, wherein the percentage by weight of kresoxim-methyl and fluorine bacterium azoles is 5～55: 35～5.
The described bactericidal composition that contains kresoxim-methyl and fluorine bacterium azoles, wherein the percentage by weight of kresoxim-methyl and fluorine bacterium azoles is 10～50: 30～10.
The described bactericidal composition that contains kresoxim-methyl and fluorine bacterium azoles, kresoxim-methyl and the common auxiliary agent of fluorine bacterium azoles are mixed and made into wetting powder, water dispersible granules, suspending agent.
When making wetting powder, composition comprises following constituent content: kresoxim-methyl 1～60%, fluorine bacterium azoles 1～40%, dispersant 3～15%, wetting agent 2～12%, filler 8～84%.
Kresoxim-methyl, fluorine bacterium azoles, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into kresoxim-methyl triflumizole wettable powder product.
When making water dispersible granules, composition comprises following constituent content: kresoxim-methyl 1～60%, fluorine bacterium azoles 1～40%, dispersant 3～12%, wetting agent 2～8%, disintegrant 0～8%, binding agent 0～5%, filler 8～84%.
Kresoxim-methyl, fluorine bacterium azoles, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, add other auxiliary agents such as adhesive again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes kresoxim-methyl triflumizole water dispersant product.
When making suspending agent, composition comprises following constituent content: kresoxim-methyl 1～40%, fluorine bacterium azoles 1～30%, dispersant 3～12%, wetting agent 2～10%, defoamer 0.1～0.5%, thickener 0～2%, antifreeze 0～8%, deionized water surplus.
Dispersant, wetting agent, defoamer, thickener, antifreeze in the above-mentioned formulation material are mixed through high speed shear, add kresoxim-methyl, fluorine bacterium azoles, ball milling is 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, makes kresoxim-methyl fluorine bacterium azole suspending agent product.
Described dispersant is selected from polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, in phonetic one or more of polyoxyethylene carboxylate, fatty acid glyceride polyoxyethylene.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, the sodium bicarbonate.
Described binding agent is selected from: one or more in gum Arabic, white dextrin, carboxy-propyl cellulose, xanthan gum, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, polyvinyl alcohol, anhydrous succinic acid-styrene copolymerized, the polyvinyl acetate.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, the glycerine.
Described defoamer is selected from: one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound.
Described thickener is selected from: one or more in xanthan gum, CMC, hydroxyethylcellulose, methylcellulose, polyvinyl alcohol, the polyethylene glycol.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention is mainly used in powdery mildew, the scab of control vegetables and fruit tree.
Beneficial effect of the present invention: (1) present composition effective active composition kresoxim-methyl and fluorine bacterium azoles belong to the bactericide of two kinds of different mechanisms of action, and both are mixed mutually and can produce conflict; (2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single agent, and dosage is little; (3) the inapplicable organic solvent of the present invention is difficult for producing poisoning, is convenient to the transporter storage; (4) present composition has special efficacy to powdery mildew, scab.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect, on this basis, carry out field trial again.
Implementation of an application example one the implementation of Formulation Example
Embodiment 180% kresoxim-methyl triflumizole wettable powder
Kresoxim-methyl 40%, fluorine bacterium azoles 40%, polycarboxylate 5%, lauryl sodium sulfate 3%, spaonin powder 2%, kaolin 10%, mixture carries out comminution by gas stream, makes 80% kresoxim-methyl triflumizole wettable powder.
Embodiment 260% kresoxim-methyl triflumizole wettable powder
Kresoxim-methyl 40%, fluorine bacterium azoles 20%, lignosulfonates 4%, tea are withered 4%, white carbon 8%, kaolin 24%, and mixture carries out comminution by gas stream, makes 60% kresoxim-methyl triflumizole wettable powder.
Embodiment 345% kresoxim-methyl triflumizole wettable powder
Kresoxim-methyl 28%, fluorine bacterium azoles 17%, alkyl benzene sulfonate calcium salt 5%, wetting and penetrating agent F 3%, white carbon 8%, bentonite 39%, mixture carries out comminution by gas stream, makes 45% kresoxim-methyl triflumizole wettable powder.
Embodiment 410% kresoxim-methyl triflumizole wettable powder
Kresoxim-methyl 7%, fluorine bacterium azoles 3%, lignosulfonates 2%, silkworm excrement 3%, white carbon 5%, attapulgite 80%, mixture carries out comminution by gas stream, makes 10% kresoxim-methyl triflumizole wettable powder.
Embodiment 575% kresoxim-methyl triflumizole water dispersant
Kresoxim-methyl 60%, fluorine bacterium azoles 15%, polycarboxylate 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, ammonium sulfate 2%, starch 13%, the mixed 75% kresoxim-methyl triflumizole water dispersant that gets.
Embodiment 655% kresoxim-methyl triflumizole water dispersant
Kresoxim-methyl 31%, fluorine bacterium azoles 24%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 3%, polyoxyethylene carboxylate 3%, soapberry powder 4%, sodium bicarbonate 3%, starch 20%, kaolin 12%, the mixed 55% kresoxim-methyl triflumizole water dispersant that gets.
Embodiment 730% kresoxim-methyl triflumizole water dispersant
Kresoxim-methyl 19%, fluorine bacterium azoles 11%, alkyl benzene sulfonate calcium salt 5%, Nekal BX 6%, succinic acid 3%, citric acid 1%, starch 20%, precipitated calcium carbonate 35%, the mixed 30% kresoxim-methyl triflumizole water dispersant that gets.
Embodiment 820% kresoxim-methyl triflumizole water dispersant
Kresoxim-methyl 14%, fluorine bacterium azoles 6%, alkylphenol-polyethenoxy are phonetic 5%, DBSA 2%, starch 20%, diatomite 53%, mixed 20% kresoxim-methyl triflumizole water dispersant.
Embodiment 950% kresoxim-methyl fluorine bacterium azole suspending agent
Kresoxim-methyl 40%, fluorine bacterium azoles 10%, alkyl benzene sulfonate calcium salt 4%, sodium lignin sulfonate 3%, DBSA 4%, silicone oil 0.1%, xanthan gum 0.3%, deionized water adds to 100%, the mixed 50% kresoxim-methyl fluorine bacterium azole suspending agent that gets.
Embodiment 1035% kresoxim-methyl fluorine bacterium azole suspending agent
Kresoxim-methyl 20%, fluorine bacterium azoles 15%, polycarboxylate 4%, soapberry powder 5%, silicone compound 0.1%, hydroxyethylcellulose 0.1%, ethylene glycol 2%, deionized water add to 100%, the mixed 35% kresoxim-methyl fluorine bacterium azole suspending agent that gets.
Embodiment 1115% kresoxim-methyl fluorine bacterium azole suspending agent
Kresoxim-methyl 11%, fluorine bacterium azoles 4%, polyoxyethylene carboxylate 4%, spaonin powder 5%, silicone compound 0.1%, polyvinyl alcohol 0.4%, propane diols 2%, deionized water add to 100%, the mixed 15% kresoxim-methyl fluorine bacterium azole suspending agent that gets.
Embodiment 125% kresoxim-methyl fluorine bacterium azole suspending agent
Kresoxim-methyl 3%, fluorine bacterium azoles 2%, polycarboxylate 2%, neopelex 2%, silicone compound 0.1%, polyethylene glycol 0.5%, glycerine 4%, deionized water add to 100%, the mixed 5% kresoxim-methyl fluorine bacterium azole suspending agent that gets.
Implementation of an application example two: kresoxim-methyl and fluorine bacterium azoles are composite to the powdery mildew of cucumber Toxicity Determination
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
After the effective inhibition concentration scope of each medicament was determined in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament powdery mildew of cucumber.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.Result of the test is as shown in table 1:
Table 1 kresoxim-methyl, fluorine bacterium azoles and composite toxicity test analysis of results table thereof to powdery mildew of cucumber
As shown in Table 1, fluorine bacterium azoles, kresoxim-methyl are to the EC of powdery mildew of cucumber
50Be respectively 1.41mg/L and 0.63mg/L.The virulence of fluorine bacterium azoles is higher than the virulence of kresoxim-methyl.Kresoxim-methyl and 1: 2,1: 1,2: 1,4: 1,6: 1 synergy ratio of fluorine bacterium azoles proportioning are respectively 1.19,1.53,1.69,1.66,1.48, both proportionings are to show as certain synergistic effect at 1: 1,2: 1,4: 1 o'clock, and it is comparatively reasonable to illustrate that fluorine bacterium azoles and kresoxim-methyl were mixed in the scope at 1: 1～4: 1.
Embodiment uses three kresoxim-methyls and the fluorine bacterium azoles and the composite powdery mildew of cucumber test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is at Pucheng County, Shaanxi Province plant protection unit, and test medicine is researched and developed, provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 30% triflumizole wettable powder (commercial), 30% kresoxim-methyl suspending agent (commercial).
Dispenser for the first time on June 7 is investigated before the medicine and is calculated the powdery mildew of cucumber disease index, dispenser for the second time on June 14, and dispenser is 2 times altogether, investigates disease indexs in 7 days, 15 days after the dispenser for the second time and calculates preventive effect.Experimental result is as follows:
The table 2 kresoxim-methyl fluorine bacterium azoles and the composite powdery mildew of cucumber test of pesticide effectiveness of preventing and treating thereof
| Handle medicament | The preparation dosage | 7 days preventive effects (%) behind the medicine for the second time | 15 days preventive effects (%) behind the medicine for the second time |
| 80% kresoxim-methyl triflumizole wettable powder | 8 gram/mus | 87.41 | 91.38 |
| 55% kresoxim-methyl triflumizole water dispersant | 12 gram/mus | 89.23 | 93.07 |
| 15% kresoxim-methyl fluorine bacterium azole suspending agent | 40 gram/mus | 88.80 | 95.96 |
| 30% triflumizole wettable powder | 20 gram/mus | 85.45 | 87.27 |
| 30% kresoxim-methyl suspending agent | 30 gram/mus | 83.19 | 85.35 |
As can be seen from Table 2, effective powdery mildew of cucumber after kresoxim-methyl and fluorine bacterium azoles are composite, control efficiency all is better than contrasting medicament, and the lasting period is long.In the test scope of medication, the target crop is had no adverse effects, and cucumber downy mildew is had certain preventive effect.
Implementation of an application example four: kresoxim-methyl and fluorine bacterium azoles and the composite apple mildew test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in suburb, Liquan County, Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 30% triflumizole wettable powder (commercial), 30% kresoxim-methyl suspending agent (commercial).
The investigation apple mildew state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 3 times.Investigated the apple disease index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the third time.Experimental result is as follows:
The table 3 kresoxim-methyl fluorine bacterium azoles and the composite apple mildew test of pesticide effectiveness of preventing and treating thereof
| Handle medicament | Extension rate | 7 days preventive effects (%) behind the last medicine | 14 days preventive effects (%) behind the last medicine | 30 days preventive effects (%) behind the last medicine |
| 60% kresoxim-methyl triflumizole wettable powder | 7500 times | 81.06 | 90.65 | 97.94 |
| 30% kresoxim-methyl triflumizole water dispersant | 4000 times | 82.55 | 93.18 | 98.43 |
| 5% kresoxim-methyl fluorine bacterium azole suspending agent | 600 times | 85.72 | 92.30 | 95.97 |
| 30% triflumizole wettable powder | 5000 times | 80.67 | 86.49 | 89.46 |
| 30% kresoxim-methyl suspending agent | 3000 times | 76.00 | 85.14 | 83.29 |
As can be seen from Table 3, energy effectively preventing apple mildew after kresoxim-methyl and fluorine bacterium azoles are composite, control efficiency all is better than contrasting medicament, and dosage is little, and the lasting period is long.In the test scope of medication, the target crop there is not harm.
Implementation of an application example five: kresoxim-methyl and fluorine bacterium azoles and the composite control banana freckle test of pesticide effectiveness thereof
This experimental establishment is at Changtai County, Fujian Province one banana garden, and test medicine is researched and developed, provided by Wei Erqi crop protection Co., Ltd, contrast medicament 30% triflumizole wettable powder (commercial), 30% kresoxim-methyl suspending agent (commercial).
Investigation banana freckle state of an illness radix, total number of sheets, the sick number of sheets and sick leaf-size class number before the medicine, in the dispenser of banana freckle initial stage of origination, dispenser in per 7 days once is total to dispenser 3 times, 3.5 kilograms of every sub-district water consumptions were investigated disease index respectively and were calculated preventive effect after the dispenser for the third time in 7 days, 14 days.Experimental result is as follows:
Table 4 kresoxim-methyl, fluorine bacterium azoles and the composite control banana freckle test of pesticide effectiveness thereof
| Handle medicament | Extension rate | 7 days preventive effects (%) behind the medicine for the third time | 14 days preventive effects (%) behind the medicine for the third time |
| 45% kresoxim-methyl triflumizole wettable powder | 5000 times | 84.09 | 92.86 |
| 20% kresoxim-methyl triflumizole water dispersant | 2500 times | 82.46 | 91.37 |
| 35% kresoxim-methyl fluorine bacterium azole suspending agent | 4000 times | 85.18 | 90.74 |
| 30% triflumizole wettable powder | 4000 times | 80.60 | 85.38 |
| 30% kresoxim-methyl suspending agent | 2500 times | 77.37 | 82.02 |
As can be seen from Table 4, can effectively prevent and treat banana freckle after kresoxim-methyl and fluorine bacterium azoles are composite and take place, control efficiency all is better than contrasting medicament, in this test scope of medication the target crop is had no adverse effects.
Implementation of an application example six: kresoxim-methyl and fluorine bacterium azoles and the composite pear scab test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in area just outside a city gate town, Pucheng County, Shaanxi Province, and test medicine is researched and developed, provided by Wei Erqi crop protection Co., Ltd, contrast medicament 30% triflumizole wettable powder (commercial), 30% kresoxim-methyl suspending agent (commercial).
In the dispenser of pear tree their early stage, dispenser in per 7 days once, altogether dispenser is 3 times, investigation disease index before the dispenser was investigated disease index respectively in 7 days, 14 days after the dispenser for the third time, and the calculation correction preventive effect, result of the test is as follows:
Table 5 kresoxim-methyl and fluorine bacterium azoles and the composite control pear scab test of pesticide effectiveness thereof
| Handle medicament | Extension rate | 7 days preventive effects (%) behind the medicine for the third time | 15 days preventive effects (%) behind the medicine for the third time |
| 10% kresoxim-methyl triflumizole wettable powder | 1500 times | 85.33 | 90.11 |
| 75% kresoxim-methyl triflumizole water dispersant | 9000 times | 84.96 | 92.58 |
| 50% kresoxim-methyl fluorine bacterium azole suspending agent | 6000 times | 88.01 | 93.26 |
| 30% triflumizole wettable powder | 5000 times | 80.77 | 83.42 |
| 30% kresoxim-methyl suspending agent | 3500 times | 81.00 | 83.35 |
As can be seen from Table 5, kresoxim-methyl, fluorine bacterium azoles energy effectively preventing pear scab, control efficiency all is better than contrasting medicament, and dosage is little, in the test scope of medication target crop is not had harm.
Claims (4)
1, a kind of bactericidal composition, its effective active composition contain kresoxim-methyl and fluorine bacterium azoles, and wherein the percentage by weight of kresoxim-methyl and fluorine bacterium azoles is 1～60: 40～1.
2, the bactericidal composition that contains kresoxim-methyl and fluorine bacterium azoles according to claim 1, it is characterized in that: the percentage by weight of kresoxim-methyl and fluorine bacterium azoles is 5～55: 35～5.
3, the bactericidal composition that contains kresoxim-methyl and fluorine bacterium azoles according to claim 1, it is characterized in that: the percentage by weight of kresoxim-methyl and fluorine bacterium azoles is 10～50: 30～10.
4, the bactericidal composition that contains kresoxim-methyl and fluorine bacterium azoles according to claim 1, it is characterized in that: kresoxim-methyl, fluorine bacterium azoles and usual auxiliaries are mixed and made into wetting powder, water dispersible granules, suspending agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100226882A CN101578985A (en) | 2009-05-25 | 2009-05-25 | Sterilization composition containing kresoxim-methyl and triflumizole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100226882A CN101578985A (en) | 2009-05-25 | 2009-05-25 | Sterilization composition containing kresoxim-methyl and triflumizole |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101578985A true CN101578985A (en) | 2009-11-18 |
Family
ID=41361413
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2009100226882A Pending CN101578985A (en) | 2009-05-25 | 2009-05-25 | Sterilization composition containing kresoxim-methyl and triflumizole |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101578985A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102007914A (en) * | 2010-12-26 | 2011-04-13 | 陕西韦尔奇作物保护有限公司 | Triflumizole-containing synergistic sterilization composition |
| CN102047874A (en) * | 2010-12-17 | 2011-05-11 | 上海生农生化制品有限公司 | Triflumizole suspending agent and preparation method thereof |
| CN105766919A (en) * | 2016-04-22 | 2016-07-20 | 广东中迅农科股份有限公司 | Bactericidal composition containing triflumizole and (E)2-[2-(2, 5-dimethylphenoxytoluene)-phenyl]-3-methoxyacrylate |
-
2009
- 2009-05-25 CN CNA2009100226882A patent/CN101578985A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102047874A (en) * | 2010-12-17 | 2011-05-11 | 上海生农生化制品有限公司 | Triflumizole suspending agent and preparation method thereof |
| CN102007914A (en) * | 2010-12-26 | 2011-04-13 | 陕西韦尔奇作物保护有限公司 | Triflumizole-containing synergistic sterilization composition |
| CN105766919A (en) * | 2016-04-22 | 2016-07-20 | 广东中迅农科股份有限公司 | Bactericidal composition containing triflumizole and (E)2-[2-(2, 5-dimethylphenoxytoluene)-phenyl]-3-methoxyacrylate |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101578985A (en) | Sterilization composition containing kresoxim-methyl and triflumizole | |
| CN101601388A (en) | A kind of bactericidal composition that contains Flutriafol and fluorine bacterium azoles | |
| CN101601386B (en) | Sterilization composite containing triflumizole and chlorothalonil | |
| CN101785461B (en) | Sterilization composition containing ethirimol and ZJ0712 | |
| CN101999380B (en) | Difenoconazole- and propineb-containing pesticidal composition | |
| CN101999364A (en) | Hexaconazole-containing germicide composition | |
| CN101755792B (en) | Fungicidal composition containing kresoxim methyl and thiophanate methyl | |
| CN101836639B (en) | Sterilization composition containing kresoxim and thiabendazole | |
| CN101731226A (en) | Bactericidal composition containing ethirimol and penconazole | |
| CN101779646A (en) | Bactericidal composite containing kresoxim-methyl and carbendazim | |
| CN101715772B (en) | Bactericidal composition containing carbendazim and ethirimol | |
| CN101755781B (en) | Fungicidal composition containing penconazole and carbendazim | |
| CN101697720B (en) | Bactericide composition containing ethirimol and kresoxim | |
| CN101779649A (en) | Bactericidal composite containing phenol cycloheximide and thiophanate-methyl | |
| CN101720770B (en) | Bactericidal composition containing phenylate bacterium ester and probenazole | |
| CN101720774B (en) | Bactericide composition containing penconazole and propineb | |
| CN101755758A (en) | Fungicidal composition containing kresoxim methyl and cyprodinil | |
| CN101595878A (en) | A kind of bactericidal composition that contains Flutriafol and cyprodinil | |
| CN101601389A (en) | The bactericidal composition of a kind of fluorine-containing bacterium azoles and Difenoconazole | |
| CN101785467A (en) | Sterilization composite containing ZJ0712 and thiophanate-methyl | |
| CN101755778B (en) | Fungicidal composition containing kresoxim methyl and propineb | |
| CN101779657B (en) | Bactericidal composite containing flusilazole and ethirimol | |
| CN101971816B (en) | Sterilizing composition containing cyproconazole and dithianon | |
| CN101779658A (en) | Bactericidal composite containing flusilazole and propineb | |
| CN101715767A (en) | Bactericidal composition containing kresoxim-methyl and penconazole |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20091118 |