CN1015271B - 氯酸的生产 - Google Patents
氯酸的生产Info
- Publication number
- CN1015271B CN1015271B CN89107135A CN89107135A CN1015271B CN 1015271 B CN1015271 B CN 1015271B CN 89107135 A CN89107135 A CN 89107135A CN 89107135 A CN89107135 A CN 89107135A CN 1015271 B CN1015271 B CN 1015271B
- Authority
- CN
- China
- Prior art keywords
- electrolysis
- chloric acid
- exchange membrane
- locellus
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 229940005991 chloric acid Drugs 0.000 title claims abstract description 47
- 238000004519 manufacturing process Methods 0.000 title description 5
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 39
- 238000000034 method Methods 0.000 claims abstract description 31
- 239000012528 membrane Substances 0.000 claims abstract description 24
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000007864 aqueous solution Substances 0.000 claims abstract description 23
- 239000003011 anion exchange membrane Substances 0.000 claims abstract description 18
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims abstract description 15
- 238000000909 electrodialysis Methods 0.000 claims abstract description 13
- 239000001257 hydrogen Substances 0.000 claims abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 6
- 125000002091 cationic group Chemical group 0.000 claims description 25
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 12
- 150000002500 ions Chemical class 0.000 claims description 11
- 230000004888 barrier function Effects 0.000 claims description 10
- 125000000129 anionic group Chemical group 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 56
- 230000008569 process Effects 0.000 abstract description 7
- -1 chlorate ions Chemical class 0.000 abstract description 5
- 229910001415 sodium ion Inorganic materials 0.000 abstract description 5
- 238000005341 cation exchange Methods 0.000 abstract description 2
- 210000004379 membrane Anatomy 0.000 description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000000047 product Substances 0.000 description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 239000006227 byproduct Substances 0.000 description 7
- 238000007600 charging Methods 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 150000002978 peroxides Chemical class 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 4
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920000557 Nafion® Polymers 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000003014 ion exchange membrane Substances 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000004076 pulp bleaching Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 240000005373 Panax quinquefolius Species 0.000 description 1
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- ISFLYIRWQDJPDR-UHFFFAOYSA-L barium chlorate Chemical compound [Ba+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O ISFLYIRWQDJPDR-UHFFFAOYSA-L 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 150000001457 metallic cations Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 101150101567 pat-2 gene Proteins 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
- B01D61/445—Ion-selective electrodialysis with bipolar membranes; Water splitting
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Urology & Nephrology (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000580794A CA1322543C (en) | 1988-10-20 | 1988-10-20 | Production of chloric acid |
| CA580,794 | 1988-10-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1044830A CN1044830A (zh) | 1990-08-22 |
| CN1015271B true CN1015271B (zh) | 1992-01-01 |
Family
ID=4138951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN89107135A Expired CN1015271B (zh) | 1988-10-20 | 1989-09-09 | 氯酸的生产 |
Country Status (15)
| Country | Link |
|---|---|
| EP (1) | EP0365113A1 (enExample) |
| JP (1) | JPH02157104A (enExample) |
| CN (1) | CN1015271B (enExample) |
| AR (1) | AR247253A1 (enExample) |
| AU (1) | AU608167B2 (enExample) |
| BR (1) | BR8904628A (enExample) |
| CA (1) | CA1322543C (enExample) |
| FI (1) | FI88312C (enExample) |
| IN (1) | IN176701B (enExample) |
| MX (1) | MX173661B (enExample) |
| NO (1) | NO893165L (enExample) |
| NZ (1) | NZ229852A (enExample) |
| PL (1) | PL161532B1 (enExample) |
| PT (1) | PT92067A (enExample) |
| ZA (1) | ZA895238B (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2020278A1 (en) * | 1989-03-15 | 1990-09-16 | Richard M. Berry | Process for generaating chloric acid and chlorine dioxide |
| US5258105A (en) * | 1990-02-06 | 1993-11-02 | Olin Corporation | Chloric acid - alkali metal chlorate mixtures and chlorine dioxide generation |
| BE1004126A3 (fr) * | 1990-05-11 | 1992-09-29 | Solvay | Procede pour la fabrication d'une solution aqueuse d'hydroxyde de metal alcalin et cellule d'electrolyse. |
| US5407547A (en) * | 1993-10-06 | 1995-04-18 | Eka Nobel Ab | Process for production of acidified process streams |
| NL9400504A (nl) * | 1994-03-30 | 1995-11-01 | Elektrolyse Project B V | Werkwijze voor het reinigen van een vervuilde oxyderende oplossing in een dialysecel. |
| CN102839383B (zh) * | 2012-09-24 | 2015-03-18 | 山东东岳高分子材料有限公司 | 一种基于氯碱用全氟离子交换膜的有机酸盐电解制备有机酸的方法 |
| CN103112826B (zh) * | 2013-03-20 | 2015-01-21 | 广西轻工业科学技术研究院 | 一种高纯二氧化氯的生产方法 |
| CN113398728A (zh) * | 2021-05-28 | 2021-09-17 | 江苏奥利思特环保科技有限公司 | 一种烟气脱硫脱硝及资源化的方法和系统 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3904495A (en) * | 1974-01-02 | 1975-09-09 | Hooker Chemicals Plastics Corp | Electrolytic-electrodialytic and chemical manufacture of chlorine dioxide, chlorine and chloride-free alkali metal hydroxide |
| US3904496A (en) * | 1974-01-02 | 1975-09-09 | Hooker Chemicals Plastics Corp | Electrolytic production of chlorine dioxide, chlorine, alkali metal hydroxide and hydrogen |
| US3884777A (en) * | 1974-01-02 | 1975-05-20 | Hooker Chemicals Plastics Corp | Electrolytic process for manufacturing chlorine dioxide, hydrogen peroxide, chlorine, alkali metal hydroxide and hydrogen |
-
1988
- 1988-10-20 CA CA000580794A patent/CA1322543C/en not_active Expired - Lifetime
-
1989
- 1989-07-06 NZ NZ229852A patent/NZ229852A/en unknown
- 1989-07-10 ZA ZA895238A patent/ZA895238B/xx unknown
- 1989-07-11 EP EP89307032A patent/EP0365113A1/en not_active Ceased
- 1989-07-12 IN IN624DE1989 patent/IN176701B/en unknown
- 1989-07-25 AU AU38958/89A patent/AU608167B2/en not_active Ceased
- 1989-08-04 NO NO89893165A patent/NO893165L/no unknown
- 1989-08-07 AR AR89314604A patent/AR247253A1/es active
- 1989-09-09 CN CN89107135A patent/CN1015271B/zh not_active Expired
- 1989-09-14 BR BR898904628A patent/BR8904628A/pt not_active Application Discontinuation
- 1989-10-13 MX MX017950A patent/MX173661B/es unknown
- 1989-10-16 JP JP1266399A patent/JPH02157104A/ja active Granted
- 1989-10-16 PL PL89281861A patent/PL161532B1/pl unknown
- 1989-10-18 FI FI894947A patent/FI88312C/fi not_active IP Right Cessation
- 1989-10-20 PT PT92067A patent/PT92067A/pt not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| NZ229852A (en) | 1990-09-26 |
| FI88312C (fi) | 1993-04-26 |
| JPH0573683B2 (enExample) | 1993-10-14 |
| AU3895889A (en) | 1990-04-26 |
| MX173661B (es) | 1994-03-22 |
| FI88312B (fi) | 1993-01-15 |
| AR247253A1 (es) | 1994-11-30 |
| EP0365113A1 (en) | 1990-04-25 |
| BR8904628A (pt) | 1990-04-24 |
| PL161532B1 (pl) | 1993-07-30 |
| FI894947A0 (fi) | 1989-10-18 |
| AU608167B2 (en) | 1991-03-21 |
| NO893165D0 (no) | 1989-08-04 |
| PT92067A (pt) | 1990-04-30 |
| NO893165L (no) | 1990-04-23 |
| CN1044830A (zh) | 1990-08-22 |
| JPH02157104A (ja) | 1990-06-15 |
| IN176701B (enExample) | 1996-08-24 |
| CA1322543C (en) | 1993-09-28 |
| ZA895238B (en) | 1991-03-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C13 | Decision | ||
| GR02 | Examined patent application | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: texas Applicant after: Sterling Canada, Inc. Address before: Ontario, Canada Applicant before: Tenneco Canada Inc. |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: TENNECO CANADA LTD. TO: STERLING CANADA, INC. |
|
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |